Compiled Property Calculation (30C) PDF

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Project : Tema Ground Fuels Depot Date: 25.02.2016
Client : Waterway petroleum & Partners
Location : Tema, Ghana, South Africa
PROPERTY CALCULATION
A. Purpose:
The following Products properties at operating temperature (30°C) is not available. To derive such
properties this calculation is performed.
Operating Temperature: 30°c
A. Gasoline
B. Gasoil / Diesel
B. Basis & Assumptions:
Density, Viscosity and vapour pressure for Gasoline has been considered as per MSDS provided by
CPPE. (Refer Attachment-1)
Density, Viscosity and vapour pressure for Gasoil has been considered as per MSDS by CPPE.
(Refer Attachment-2)
C. Data Given:
Gasoline
Relative Density : 0.735 at 15°C (60°F)
Viscosity : 0.625 cSt at 40°C (104°F) (Refer Attachment-3)
Vapor Pressure : 62.5 kPa at 37.8°C (100°F)
Vapor Pressure (RVP) : 9.06 PSI at 37.8°C (100°F)
Gasoil / (Diesel) Reference from existing project
Density : 0.845 g/cm3 at 15°C (60°F)
Viscosity : 6.0 cSt at 40°C (104°F)
Vapor Pressure : 1.0 hPa ~ 0.1 kPa at 20°c (68°F)
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Safe Handling: Technical Bulletin:
Vapor Pressure (RVP) : 0.2 PSI at 37.8°C (100°F) (Refer Attachment-4)
D. Density:
Relative Density of Gasoline @ 15°c is 0.735 available, corresponding value @ 30°C from ASTM-IP
Table -53 is 744.0 kg/m3. (Attachment-5)
Density of Gasoil / Diesel @ 15°c is 0.845 (g/cm3) available, corresponding value @ 30°C from ASTM-IP
Table -55 is 854.9 kg/cm3. (Attachment-6)
E. API Gravity Calculation:
Gasoline
° API = [141.5 / sp. Gr. At 60/60] - 131.5
= 141.5 / (0.735) – 131.5
= 61
Gasoil / Diesel
° API = [141.5 / sp. Gr. At 60/60] - 131.5
= 141.5 / (0.848) – 131.5
= 35.36
F. Vapour Pressure:
Gasoline
Vapor Pressure: 52.4 kPa or 7.6 Psi at 30°C (86°F) (Refer Attachment-7, 8, 9)
Gasoil / (Diesel)
Vapor Pressure: 0.959 kPa or 0.139 Psi at 30°C (86°F) (Refer Attachment-10, 11)
G. VISCOSITY:
Gasoline
X & Y co-ordinate calculation: (Ref. Process Heat Transfer by D.Q.Kern, Page 821)
°API 61 X = 14.1 Y = 9.48 (Refer Attachment – 12, 13 & 14)
Viscosity at 30°C as per Graph: 0.47 cP
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Gasoil / Diesel
X & Y co-ordinate calculation: (Ref. Process Heat Transfer by D.Q.Kern, Page 821)
°API 35.3 X = 10 .08 Y = 19.79 (Refer Attachment – 12, 13 & 15)
Viscosity at 30°C as per Graph: 3.7 cP
H. Summary:
Gasoline
Density : 744.0 kg/m3 at 30°C (86°F)
Viscosity : 0.47 cP at 30°C (86°F)
Vapor Pressure : 52.4 kPa at 30°C (86°F)
Gasoil / Diesel
Density : 854.9 kg/m3 at 30°C (86°F)
Viscosity : 3.7 cP at 30°C (86°F)
Vapor Pressure : 0.959 kPa at 30°C (86°F)
I. Attachments
1. MSDS of Gasoline
2. MSDS of Gasoil
3. MSDS of Gasoline 95 Octane
4. Technical Bulletin
5. ASTM-IP Table 55 for Gasoline Density
6. ASTM-IP Table 55 for Gasoil Density
7. Vapor Pressure Graph for Gasoline
8. True Vapor pressure calculation for Gasoline
9. True Vapor pressure calculation for Gasoil – Alternate Method
10. True Vapor pressure calculation for Gasoil / Diesel
11. True Vapor pressure calculation for Gasoline – Alternate Method
12. Gasoline & Gasoil X axis chart for viscosity calculation
13. Gasoline & Gasoil Y axis chart for viscosity calculation
14. Gasoline viscosity graph
15. Gasoil / Diesel viscosity graph
J. References
§ Process Heat Transfer By D.Q.Kern
§ Environmental Protection Agency (EPA)
3
Attachment : 1 - MSDS of Gasoline
Page : 1/ 12
SAFETY DATA SHEET Revision nr : 2
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Commercial Product Name : GASOLINE
EC Index : 649-378-00-4
EC No : 289-220-8
CAS No. : 86290-81-5
REACH Registration Number : 01-2119471335-39-0114
1.2. Relevant identified uses of the substance or mixture and uses advised against
Specific use(s) : Fuel
1.3. Details of the supplier of the safety data sheet

Company : Gunvor SA
Rue de Rhone 80-84
1204-Geneva, Switzerland
Tel.+3726110415
E-mail address:msds@tarcona.com
1.4. Emergency telephone number

Emergency telephone : +32 3 575 11 30 (This telephone number is available 24 hours per day, 7
days per week.)
UNITED KINGDOM
National Poisons Information Service
(Birmingham Centre) 0870 600 6266 (UK only)
City Hospital
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
2.1.1. Classification according to Regulation (EU) 1272/2008
CLP-Classification : The product is classified as hazardous in accordance with Directive
1272/2008/EEC.
Flam. Liq. 2 H225
Skin Irrit. 2 H315
Muta. 1B H340
Carc. 1B H350
Repr. 2 H361
STOT SE 3 H336
Asp. Tox. 1 H304
Aquatic Chronic 2 H411
Full text of H-phrases: see section 16
2.1.2. Classification according to EU Directives 67/548/EC or 1999/45/EC

Classification : The product is classified as dangerous in accordance with Directive
67/548/EEC.
Carc.Cat.2; R45
Page : 2/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
Muta.Cat.2; R46
Repr.Cat.3; R62
Repr.Cat.3; R63
F+; R12
Xn; R65
Xi; R38
N; R51/53
R67
Full text of R-phrases: see section 16
2.2. Label elements

2.2.1. Labelling according to Regulation (EU) 1272/2008
CLP pictograms :
GHS02 GHS07 GHS08 GHS09

Signal word : Danger
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H336 - May cause drowsiness or dizziness.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P501 - Dispose of contents/ container to an approved waste disposal plant.
2.2.2. Labelling according to Directives (67/548 - 1999/45)

Not relevant
2.3. Other hazards

Other hazards which do not result in : Results of PBT and vPvB assessment
classification Non-classified PBT substance
Non-classified vPvB substance
SECTION 3: Composition/information on ingredients

3.1. Substances
Substance name Product identifier % Classification according to
Directive 67/548/EEC
Page : 3/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
Gasoline (CAS No.) 86290-81-5 0 - 100 Carc.Cat.2; R45

(EC No) 289-220-8 Muta.Cat.2; R46
(EC Index) 649-378-00-4 Repr.Cat.3; R62
(REACH-no) 01-2119471335-39-0114 Repr.Cat.3; R63
F+; R12
Xn; R65
Xi; R38
N; R51/53
R67
Substance name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Gasoline (CAS No.) 86290-81-5 0 - 100 Flam. Liq. 1, H224
(EC No) 289-220-8 Asp. Tox. 1, H304
(EC Index) 649-378-00-4 Skin Irrit. 2, H315
(REACH-no) 01-2119471335-39-0114 Muta. 1B, H340
Carc. 1B, H350
STOT SE 3, H336
Aquatic Chronic 2, H411
Repr. 2, H361fd
Full text of R-, H- and EUH-phrases: see section 16.

3.2. Mixtures
Not applicable
SECTION 4: First aid measures
4.1. Description of first aid measures

Inhalation : Keep at rest.
Move to fresh air.
Oxygen or artificial respiration if needed.
Call a physician immediately.
Skin contact : Wash off immediately with soap and plenty of water.
Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use.
If skin irritation persists, call a physician.
Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes.
If eye irritation persists, consult a specialist.
Ingestion : Do NOT induce vomiting.
Drink plenty of water.
Never give anything by mouth to an unconscious person.
Consult a physician.
Additional advice : First aider needs to protect himself.
See also section 8
Never give anything by mouth to an unconscious person.
Show this safety data sheet to the doctor in attendance.
Treat symptomatically.
When symptoms persist or in all cases of doubt seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation : Vapours may cause drowsiness and dizziness.
Skin contact : Irritating to skin.
Eye contact : Contact with eyes may cause irritation.
Ingestion : Harmful: may cause lung damage if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Page : 4/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media : Use dry chemical, CO2, water spray or alcohol resistant foam.
Extinguishing media which shall not be used : High volume water jet
for safety reasons
5.2. Special hazards arising from the substance or mixture
Fire Hazard : Extremely flammable.
Specific hazards : Evacuate personnel to safe areas.
Fire or intense heat may cause violent rupture of packages.
Vapours may form explosive mixture with air.
Vapours are heavier than air and may spread along floors.
Flash back possible over considerable distance.
Possible decomposition products are: COx
Fire residues and contaminated fire extinguishing water must be disposed of
in accordance with local regulations.
5.3. Advice for firefighters

Advice for firefighters : Special protective equipment for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
In the event of fire, cool tanks with water spray.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel : Ensure adequate ventilation.
Wear personal protective equipment.
See also section 8
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Keep away from open flames, hot surfaces and sources of ignition.
Ensure all equipment is electrically grounded before beginning transfer
operations.
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixture with air.
Flash back possible over considerable distance.
Advice for emergency responders : Only qualified personnel equipped with suitable protective equipment may
intervene.
6.2. Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Page : 5/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation.
Remove all sources of ignition.
Use only explosion-proof equipment.
Prevent further leakage or spillage if safe to do so.
Dam up.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust).
Sweep up and shovel into suitable containers for disposal.
Dispose of in accordance with local regulations.
Local authorities should be advised if significant spillages cannot be
contained.
6.4. Reference to other sections

See also section 8
See also section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Handling : Ensure adequate ventilation.
Wear personal protective equipment.
See also section 8
Avoid contact with skin, eyes and clothing.
Do not breathe vapours or spray mist.
Ensure all equipment is electrically grounded before beginning transfer
operations.
Do not burn, or use a cutting torch on, the empty drum.
Do not puncture or incinerate.
Always replace cap after use.
Take care to avoid waste and spillage when weighing, loading and mixing
the product.
Take any precaution to avoid mixing with incompatible materials.
Do not let product enter drains.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.
Remove and wash contaminated clothing before re-use.
Wash hands before breaks and immediately after handling the product.
When using, do not eat, drink or smoke.
Keep working clothes separately.
Keep away from food, drink and animal feedingstuffs.
7.2. Conditions for safe storage, including any incompatibilities

Storage : Keep tightly closed in a dry, cool and well-ventilated place.
Keep away from open flames, hot surfaces and sources of ignition.
Do not store near or with any of the incompatible materials listed in section
10.
7.3 Specific end use(s)
No data available
Page : 6/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure limit(s) :
Component : Gasoline (86290-81-5)
TLV-TWA (ppm) : 300 (CH, VLA-ED Spain, 2008)
TLV-TWA (mg/m³) : 1100 (CH), 250 (UT4, Kraftstoff, DE); mist: 5 (BE, GB, FR, NL, ES, FI, DK, NO); mist:
1 (SE);
TLV-STEL (mg/m³) : mist: 10 (BE, GB); mist: 3 (SE)
Recommended monitoring procedures : Personal monitoring

Concentration measurement in air
DNEL/DMEL (workers)
Acute - systemic effects, inhalation : 1300 mg/m³
Acute - local effects, inhalation : 1100 mg/m³
Long-term - local effects, inhalation : 840 mg/m³
DNEL/DMEL (general population)
Acute - systemic effects, inhalation : 1200 mg/kg bodyweight/day
Acute - local effects, inhalation : 640 mg/m³
Long-term - local effects, inhalation : 180 mg/m³
8.2. Exposure controls

Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment.
Recommended Filter type: A (EN 141)
Respirator with a half face mask (EN 140)
Respirator with a full face mask (EN 136)
Hand protection : Nitrile rubber - Rubber gloves (EN 374) The selection of specific gloves for a
specific application and time of use in a working area, should also take into
account other factors on the working space, such as (but not limited to):
other chemicals that are possibly used, physical requirements (protection
against cutting/drilling, skill, thermal protection), and the
instructions/specification of the supplier of gloves.
Eye protection : Safety glasses (EN166)
Thermal hazard protection : not required under normal use.
Use dedicated equipment.
Engineering measures : Ensure adequate ventilation.
Use only in area provided with appropriate exhaust ventilation.
Organisational measures to prevent /limit releases, dispersion and exposure
See also section 7
Ensure that eyewash stations and safety showers are close to the
workstation location.
Environmental exposure controls : Do not flush into surface water or sanitary sewer system.
Comply with applicable Community environmental protection legislation.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance : liquid
Colour : yellow
Page : 7/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
Odour : petroleum hydrocarbon odour

pH : no data available
Melting point/range : < -60 °C
Boiling point/boiling range : ca. 25 - 200 °C
Flash point : < -40 °C
Evaporation rate : no data available
Explosion limits : no data available
Vapour pressure : ca. 350 - 900 hPa @ 37,8°C
Vapour density : no data available
Relative density : ca. 0,68 - 0,79 @ 15°C
Water solubility : slight (30 - 100 mg/l @ 20°C)
Partition coefficient: n-octanol/water : 2,1 - 6
Autoignition temperature : ca. 280 - 470 °C
Viscosity : no data available
Explosive properties : not applicable
Oxidizing properties : not applicable
9.2. Other information

No data available
SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity : Flammable liquid
See also section 10.5
10.2. Chemical stability
: Stable under normal conditions.
Stability
10.3. Possibility of hazardous reactions
Hazardous reactions : Vapours may form explosive mixtures with air.
See also section 7
Handling and storage
10.4. Conditions to avoid
Conditions to avoid : Heat, flames and sparks.
See also section 7
10.5. Incompatible materials
Incompatible materials : Oxidizing agents See also section 7 Handling and storage
10.6. Hazardous decomposition products
Hazardous decomposition products : Carbon oxides
Page : 8/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity : Not classified (Not classified due to data which are conclusive although
insufficient for classification.)
Gasoline (86290-81-5)
LD50/oral/rat > 5000 mg/kg
LD50/dermal/rat > 2000 mg/kg
LC50/inhalation/4h/rat 5,2 mg/l/4h
Skin corrosion/irritation : Causes skin irritation.

pH: no data available
Serious eye damage/irritation : Not classified (Not classified due to data which are conclusive although
pH: no data available
Respiratory/skin sensitisation : Not classified (Not classified due to data which are conclusive although
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Specific target organ toxicity (single : May cause drowsiness or dizziness.

exposure)
Specific target organ toxicity (repeated : Not classified (Not classified due to data which are conclusive although
exposure) insufficient for classification.)
Aspiration hazard : May be fatal if swallowed and enters airways.
Further information : Symptoms related to the physical, chemical and toxicological characteristics
See section 4.2.
SECTION 12: Ecological information

12.1. Toxicity
Ecotoxicity effects : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Component : Gasoline (86290-81-5)

LC50/96h/fish : 82 mg/l
EC50/48h/daphnia : 7,6 mg/l
12.2. Persistence and degradability

Persistence and degradability : Inherently biodegradable.
Page : 9/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
12.3. Bioaccumulative potential

Bioaccumulation : Does not bioaccumulate.
Partition coefficient: n-octanol/water : 2,1 - 6
12.4. Mobility in soil
Mobility : no data available
12.5. Results of PBT and vPvB assessment

PBT/vPvB : This substance is not considered to be persistent, bioaccumulating nor toxic
(PBT).
This substance is not considered to be very persistent nor very
bioaccumulating (vPvB).
12.6. Other adverse effects

Further information : No data available
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste from residues / unused products : Handle with care.
See also section 7
Dispose of in accordance with local regulations.
Where possible recycling is preferred to disposal or incineration.
Collect and dispose of waste product at an authorised disposal facility.
Contaminated packaging : Do not puncture or incinerate.
Do not burn, or use a cutting torch on, the empty drum.
Empty containers should be taken to an approved waste handling site for
recycling or disposal.
Additional ecological information : Do not flush into surface water or sanitary sewer system.
Codes of waste (2001/573/EC, : Waste codes should be assigned by the user, preferably in discussion with the
75/442/EEC, 91/689/EEC) waste disposal authorities.
The following Waste Codes are only suggestions:
130702 - petrol
150110 - packaging containing residues of or contaminated by dangerous
substances
SECTION 14: Transport information

14.1. UN number
UN-No. : 1203
14.2. UN proper shipping name
Proper shipping name : MOTOR SPIRIT / GASOLINE / PETROL
14.3. Transport hazard class(es)

14.3.1. Overland transport
Class : 3 - Flammable liquid
Page : 10/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
Hazard identification number (Kemler No.) : 33

Classification code : F1
ADR/RID-Labels : 3 - Flammable liquid
14.3.2. Inland waterway transport (ADN)

Class (ADNR) : 3
14.3.3. Transport by sea

14.3.4. Air transport

14.4. Packing group

Packing group : II
14.5. Environmental hazards

Environmental hazards : p
Other information : No supplementary information available.
14.6 Special precautions for user

No data available
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No data available
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Authorisations/Restrictions on use : not applicable
This product contains an ingredient
according to the candidate list of Annex
XIV of the REACH
Regulation1907/2006/EC. : not applicable
Special rules on packaging : Child resistant fastenings (EN 862),Tactile warning of danger (EN/ISO 11683)
Page : 11/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
15.1.2. National regulations

DE: WGK : 3
DE: German storage class (LGK) : LGK 3 - Flammable liquid materials (Flashpoint < 55 °C)
DE: TA-Luft : Organic Substances
DE: Technische Regeln für Gefahrstoffe (TRGS) : applicable
DE: Risk classification according to VbF : A I - Liquids with a flashpoint below 21°C
FR : Installations classées : 143X; 117X; 113X
NL : ABM : 4 - Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment. (A)
NL: NeR (Nederlandse emissie Richtlijn) : Organic substances in vapour or gaseous form
DA : At-vejledning C.2.1 (Kræftrisikable stoffer og : Gasoline
materialer)
NO: Produktforskriften (FOR 2004-06-01 nr 922) : Gasoline
15.2. Chemical safety assessment

Chemical Safety Assessment : A Chemical Safety Assessment has been carried out for this substance.
SECTION 16: Other information
Full text of R-, H- and EUH-phrases

Aquatic Chronic 2 : Hazardous to the aquatic environment - chronic hazard category 2
Asp. Tox. 1 : Aspiration hazard Category 1
Carc. 1B : Carcinogenicity Category 1B
Flam. Liq. 1 : Flammable liquids Category 1
Flam. Liq. 2 : Flammable liquids Category 2
Muta. 1B : Germ cell mutagenicity, hazard categories 1B
Repr. 2 : Reproductive toxicity, Hazard Category 2
Repr. 2 : Reproductive toxicity, Hazard Category 2
Skin Irrit. 2 : skin corrosion/irritation Category 2
STOT SE 3 : Specific target organ toxicity (single exposure) Category 3
H224 : Extremely flammable liquid and vapour.
H225 : Highly flammable liquid and vapour.
H304 : May be fatal if swallowed and enters airways.
H315 : Causes skin irritation.
H336 : May cause drowsiness or dizziness.
H340 : May cause genetic defects.
H350 : May cause cancer.
H361 : Suspected of damaging fertility or the unborn child.
H361fd : Suspected of damaging fertility. Suspected of damaging the unborn child.
H411 : Toxic to aquatic life with long lasting effects.
R12 : Extremely flammable.
R38 : Irritating to skin.
R45 : May cause cancer.
R46 : May cause heritable genetic damage.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R62 : Possible risk of impaired fertility.
R63 : Possible risk of harm to the unborn child.
R65 : Harmful: may cause lung damage if swallowed.
R67 : Vapours may cause drowsiness and dizziness.
F+ : Extremely flammable
N : Dangerous for the environment
Page : 12/ 12
Issuing date :
06/03/2012
Supersedes :
GASOLINE 18/06/2009
Xi : irritating
Xn : Harmful
Sources of key data used to compile : European Chemicals Bureau
the datasheet CSR Low Boiling Point Naphthas Concawe
ECHA Website
Safety datasheet sections which have : 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16
been updated:
Abbreviations and acronyms : ADNR = Accord Européen relatif au Transport International des Marchandises
Dangereuses par voie de Navigation du Rhin
ADR = Accord européen relatif au transport international des marchandises Dangereuses
par Route
CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods Code
LEL = Lower Explosive Limit/Lower Explosion Limit
UEL = Upper Explosion Limit/Upper Explosive Limit
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals
N = Dangerous for the environment
TWA = time weighted average
vPvB = very persistent and very bioaccumulating
WGK = Wassergefärhdungsklasse (Water Hazard Class under German Federal Water
Management Act)
T = Toxic
TLV = Threshold limits
STEL = Short term exposure limit
DNEL = Derived No Effect Level
CSR = Chemical Safety Report
EC50 = Median Effective Concentration
The contents and format of this SDS are in accordance with EEC Commission Directive 1999/45/EC, 67/548/EC,
1272/2008/EC and EEC Commission Regulation 1907/2006/EC (REACH) Annex II.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this SDS information may not be applicable.
Attachment : 2 - MSDS of Diesel
Diesel (ULSD/Gasoil)
Version 1.1
Effective Date 10.03.2014
Safety Data Sheet
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Material Name : Diesel (ULSD/Gasoil)

Recommended Use / : Fuel for on-road diesel-powered engines. Fuel for use in off-
Restrictions of Use road diesel engines, boilers, gas turbines and other
combustion equipment.
Supplier : Shell Eastern Trading (PTE) Ltd
9 North Buona Vista Drive,

#07-01,
Tower 1, The Metropolis
Singapore 138588
Singapore
Telephone : +65-6384 8000

Emergency Telephone : +44 (0) 151 350 4595
Number
2. HAZARDS IDENTIFICATION
GHS Classification : Flammable liquids, Category 3

Aspiration hazard, Category 1
Acute toxicity, Category 4, Inhalation
Skin corrosion/irritation, Category 2
Carcinogenicity, Category 2
Specific target organ toxicity - repeated exposure, Category 2,
Blood., Thymus., Liver
Hazardous to the aquatic environment - Long-term Hazard,
Category 2
Acute hazards to the aquatic environment, Category 2
GHS Label Elements

Symbol(s) :
Signal Words : Danger
Hazard Statement : PHYSICAL HAZARDS:

H226: Flammable liquid and vapour.
HEALTH HAZARDS:
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H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.
H332: Harmful if inhaled.
H351: Suspected of causing cancer.
H373: May cause damage to organs or organ systems through
prolonged or repeated exposure.
ENVIRONMENTAL HAZARDS:
H411: Toxic to aquatic life with long lasting effects.
H401: Toxic to aquatic life.
GHS Precautionary Statements

Prevention : P210: Keep away from heat/sparks/open flames/hot surfaces. -
No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P280: Wear protective gloves/protective clothing/eye
protection/face protection.
Response : P301+P310: IF SWALLOWED: Immediately call a POISON

CENTER or doctor/physician.
P331: Do NOT induce vomiting.
Disposal: : P501: Dispose of contents and container to appropriate waste

site or reclaimer in accordance with local and national
regulations.
Other Hazards which do : Vapour in the headspace of tanks and containers may ignite
not result in classification and explode at temperatures exceeding auto-ignition
temperature, where vapour concentrations are within the
flammability range.
May ignite on surfaces at temperatures above auto-ignition
temperature.
This material is a static accumulator. Even with proper
grounding and bonding, this material can still accumulate an
electrostatic charge. If sufficient charge is allowed to
accumulate, electrostatic discharge and ignition of flammable
air-vapour mixtures can occur.
Additional Information : This product is intended for use in closed systems only.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture Description : Complex mixture of hydrocarbons consisting of paraffins,

cycloparaffins, aromatic and olefinic hydrocarbons with carbon
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numbers predominantly in the C9 to C25 range. May also

contain several additives at <0.1% v/v each. May contain
cetane improver (Ethyl Hexyl Nitrate) at <0.2% v/v.
May contain catalytically cracked oils in which polycyclic

aromatic compounds, mainly 3-ring but some 4- to 6-ring
species are present.
Classification of components according to GHS

Chemical Identity Synonyms CAS Hazard Class Hazard Conc.
(category) Statement
Fuels, diesel Fuels, diesel 68334-30-5 Flam. Liq., 3; H226; H304; 60.00 -
Asp. Tox., 1; H332; H315; 100.00 %
Acute Tox., 4; H351; H373;
Skin Corr., 2; H411; H401;
Carc., 2;
STOT RE, 2;
Aquatic
Chronic, 2;
Aquatic Acute,
2;
Distillates (Fischer- Distillates 848301-67- Asp. Tox., 1; H304; H227; 0.00 - 30.00
Tropsch) C8-26 - (Fischer- 7 Flam. Liq., 4; %
Branched and Tropsch) C8-
Linear 26 - Branched
and Linear
Kerosine (Fischer Kerosine 848301-66- Asp. Tox., 1; H304; H226; 0.00 - 10.00
Tropsch), Full (Fischer 6 Flam. Liq., 3; %
range, C8-C16 Tropsch), Full
branched and range, C8-
linear alkanes C16 branched
and linear
alkanes
Additional Information : Dyes and markers can be used to indicate tax status and
prevent fraud. Contains Cumene, CAS# 98-82-8 Contains
Naphthalene, CAS # 91-20-3.
Refer to Ch 16 for full text of H phrases.
4. FIRST-AID MEASURES
Inhalation : Remove to fresh air. If rapid recovery does not occur, transport
to nearest medical facility for additional treatment.
Skin Contact : Remove contaminated clothing. Immediately flush skin with
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large amounts of water for at least 15 minutes, and follow by

washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment. When using high pressure
equipment, injection of product under the skin can occur. If
high pressure injuries occur, the casualty should be sent
immediately to a hospital. Do not wait for symptoms to develop.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration. If
any of the following delayed signs and symptoms appear within
the next 6 hours, transport to the nearest medical facility: fever
greater than 101° F (38.3°C), shortness of breath, chest
congestion or continued coughing or wheezing. Give nothing
by mouth.
Most Important : If material enters lungs, signs and symptoms may include
Symptoms/Effects, Acute coughing, choking, wheezing, difficulty in breathing, chest
& Delayed congestion, shortness of breath, and/or fever. The onset of
respiratory symptoms may be delayed for several hours after
exposure. Skin irritation signs and symptoms may include a
burning sensation, redness, or swelling.
Immediate medical : Treat symptomatically.
attention, special
treatment
5. FIRE-FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
Specific hazards arising : Hazardous combustion products may include: A complex

from Chemicals mixture of airborne solid and liquid particulates and gases
(smoke). Oxides of sulphur. Unidentified organic and inorganic
compounds. Carbon monoxide may be evolved if incomplete
combustion occurs. Will float and can be reignited on surface
water. Flammable vapours may be present even at
temperatures below the flash point. The vapour is heavier than
air, spreads along the ground and distant ignition is possible.
Suitable Extinguishing : Foam, water spray or fog. Dry chemical powder, carbon
Media dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use direct water jets on the burning product as they
Media could cause a steam explosion and spread of the fire.
Simultaneous use of foam and water on the same surface is to
be avoided as water destroys the foam.
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Protective Equipment & : Proper protective equipment including chemical resistant

Precautions for Fire gloves are to be worn; chemical resistant suit is indicated if
Fighters large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).
Additional Advice : Keep adjacent containers cool by spraying with water. If
possible remove containers from the danger zone. If the fire
cannot be extinguished the only course of action is to evacuate
immediately. Contain residual material at affected sites to
prevent material from entering drains (sewers), ditches, and
waterways.
6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations. Evacuate the area of all non-
essential personnel. Ventilate contaminated area thoroughly. Take precautionary measures
against static discharges.
Personal Precautions, : Do not breathe fumes, vapour. Do not operate electrical

Protective Equipment and equipment. Shut off leaks, if possible without personal risks.
Emergency Procedures Remove all possible sources of ignition in the surrounding area
and evacuate all personnel. Attempt to disperse the gas or to
direct its flow to a safe location for example by using fog
sprays. Take precautionary measures against static discharge.
Ensure electrical continuity by bonding and grounding
(earthing) all equipment. Monitor area with combustible gas
meter.
Environmental : Take measures to minimise the effects on groundwater.
Precautions Contain residual material at affected sites to prevent material
from entering drains (sewers), ditches, and waterways. Prevent
from spreading or entering into drains, ditches or rivers by
using sand, earth, or other appropriate barriers.
Methods and Material for : Take precautionary measures against static discharges.
Containment and For small liquid spills (< 1 drum), transfer by mechanical means
Cleaning Up to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely. For large liquid spills
(> 1 drum), transfer by mechanical means such as vacuum
truck to a salvage tank for recovery or safe disposal. Do not
flush away residues with water. Retain as contaminated waste.
Allow residues to evaporate or soak up with an appropriate
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absorbent material and dispose of safely. Remove

contaminated soil and dispose of safely. Shovel into a suitable
clearly marked container for disposal or reclamation in
accordance with local regulations.
Additional Advice : Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities
should be advised if significant spillages cannot be contained.
Maritime spillages should be dealt with using a Shipboard Oil
Pollution Emergency Plan (SOPEP), as required by MARPOL
Annex 1 Regulation 26.
7. HANDLING AND STORAGE
General Precautions : Avoid breathing vapours or contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material. Air-dry
contaminated clothing in a well-ventilated area before
laundering. Prevent spillages. Use local exhaust ventilation if
there is risk of inhalation of vapours, mists or aerosols. Never
siphon by mouth. Contaminated leather articles including
shoes cannot be decontaminated and should be destroyed to
prevent reuse.
Maintenance and Fuelling Activities - Avoid inhalation of
vapours and contact with skin.
Precautions for Safe : Avoid inhaling vapour and/or mists. Avoid prolonged or
Handling repeated contact with skin. When using do not eat or drink.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks. Earth all equipment. Properly dispose
of any contaminated rags or cleaning materials in order to
prevent fires. Use local exhaust ventilation if there is risk of
inhalation of vapours, mists or aerosols. The vapour is heavier
than air, spreads along the ground and distant ignition is
possible.
Conditions for Safe : Drum and small container storage: Drums should be stacked to
Storage a maximum of 3 high. Use properly labelled and closeable
containers. Tank storage: Tanks must be specifically designed
for use with this product. Bulk storage tanks should be diked
(bunded). Locate tanks away from heat and other sources of
ignition. Must be stored in a diked (bunded) well-ventilated
area, away from sunlight, ignition sources and other sources of
heat. Vapours from tanks should not be released to
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atmosphere. Breathing losses during storage should be

controlled by a suitable vapour treatment system. The vapour
is heavier than air. Beware of accumulation in pits and confined
spaces. Keep container tightly closed and in a cool, well-
ventilated place. Keep in a cool place. Electrostatic charges will
be generated during pumping. Electrostatic discharge may
cause fire. Ensure electrical continuity by bonding and
grounding (earthing) all equipment to reduce the risk. The
vapours in the head space of the storage vessel may lie in the
flammable/explosive range and hence may be flammable.
Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product. Keep in a
bunded area with a sealed (low permeability) floor, to provide
containment against spillage. Prevent ingress of water.
Product Transfer : Avoid splash filling. Wait 2 minutes after tank filling (for tanks
such as those on road tanker vehicles) before opening hatches
or manholes. Wait 30 minutes after tank filling (for large
storage tanks) before opening hatches or manholes. Keep
containers closed when not in use. Contamination resulting
from product transfer may give rise to light hydrocarbon vapour
in the headspace of tanks that have previously contained
gasoline. This vapour may explode if there is a source of
ignition. Partly filled containers present a greater hazard than
those that are full, therefore handling, transfer and sampling
activities need special care. Even with proper grounding and
bonding, this material can still accumulate an electrostatic
charge. If sufficient charge is allowed to accumulate,
electrostatic discharge and ignition of flammable air-vapour
mixtures can occur. Be aware of handling operations that may
give rise to additional hazards that result from the accumulation
of static charges. These include but are not limited to pumping
(especially turbulent flow), mixing, filtering, splash filling,
cleaning and filling of tanks and containers, sampling, switch
loading, gauging, vacuum truck operations, and mechanical
movements. These activities may lead to static discharge e.g.
spark formation. Restrict line velocity during pumping in order
to avoid generation of electrostatic discharge (<= 1 m/s until fill
pipe submerged to twice its diameter, then <= 7 m/s). Avoid
splash filling. Do NOT use compressed air for filling,
discharging, or handling operations.
Recommended Materials : For containers, or container linings use mild steel, stainless
steel. Aluminium may also be used for applications where it
does not present an unnecessary fire hazard. Examples of
suitable materials are: high density polyethylene (HDPE) and
Viton (FKM), which have been specifically tested for
compatibility with this product. For container linings, use
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amine-adduct cured epoxy paint. For seals and gaskets use:

graphite, PTFE, Viton A, Viton B.
Unsuitable Materials : Some synthetic materials may be unsuitable for containers or
container linings depending on the material specification and
intended use. Examples of materials to avoid are: natural
rubber (NR), nitrile rubber (NBR), ethylene propylene rubber
(EPDM), polymethyl methacrylate (PMMA), polystyrene,
polyvinyl chloride (PVC), polyisobutylene. However, some may
be suitable for glove materials.
Container Advice : Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform
similar operations on or near containers.
Other Advice : Ensure that all local regulations regarding handling and storage
facilities are followed. See additional references that provide
safe handling practices for liquids that are determined to be
static accumulators: American Petroleum Institute 2003
(Protection Against Ignitions Arising out of Static, Lightning and
Stray Currents) or National Fire Protection Agency 77
(Recommended Practices on Static Electricity). CENELEC
CLC/TR 50404 (Electrostatics – Code of practice for the
avoidance of hazards due to static electricity).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on

this document, it is provided for information only.
Occupational Exposure Limits
Material Source Type ppm mg/m3 Notation

Naphthalene ACGIH TWA 10 ppm
ACGIH STEL 15 ppm
ACGIH SKIN_DES Can be absorbed

through the skin.
SG OEL TWA 10 ppm 52 mg/m3
SG OEL STEL 15 ppm 79 mg/m3
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Fuels, diesel ACGIH SKIN_DES(I Can be absorbed

nhalable through the skin.as
fraction and total hydrocarbons
vapor.)
ACGIH TWA(Inhala 100 mg/m3 as total

ble fraction hydrocarbons
and vapor.)
Cumene ACGIH TWA 50 ppm
SG OEL TWA 50 ppm 246 mg/m3
Additional Information : Skin notation means that significant exposure can also occur
by absorption of liquid through the skin and of vapour through
the eyes or mucous membranes.
Biological Exposure Index (BEI)
Material Determinant Sampling Time BEI Reference
Naphthalene 1-Naphthol, with Sampling time: ACGIH BEL (02

hydrolysis + 2- End of shift. 2013)
Naphthol, with
hydrolysis
Appropriate Engineering : The level of protection and types of controls necessary will vary
Controls depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Use sealed systems as far as
possible. Adequate explosion-proof ventilation to control
airborne concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended. Eye washes and
showers for emergency use. Always observe good personal
hygiene measures, such as washing hands after handling the
material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove
contaminants. Discard contaminated clothing and footwear that
cannot be cleaned. Practice good housekeeping. Define
procedures for safe handling and maintenance of controls.
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Educate and train workers in the hazards and control

measures relevant to normal activities associated with this
product. Ensure appropriate selection, testing and
maintenance of equipment used to control exposure, e.g.
personal protective equipment, local exhaust ventilation.
Firewater monitors and deluge systems are recommended.
Drain down system prior to equipment break-in or
maintenance. Retain drain downs in sealed storage pending
disposal or for subsequent recycle.
Individual Protection : Personal protective equipment (PPE) should meet
Measures recommended national standards. Check with PPE suppliers.
Respiratory Protection : If engineering controls do not maintain airborne concentrations

to a level which is adequate to protect worker health, select
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are suitable, select an appropriate combination of
mask and filter. Where air-filtering respirators are unsuitable
(e.g. airborne concentrations are high, risk of oxygen
deficiency, confined space) use appropriate positive pressure
breathing apparatus. All respiratory protection equipment and
use must be in accordance with local regulations. Select a filter
suitable for combined particulate/organic gases and vapours
[boiling point >65°C(149 °F)].
Hand Protection : Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended. Suitability and
durability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material,
dexterity. Always seek advice from glove suppliers.
Contaminated gloves should be replaced. For continuous
contact we recommend gloves with breakthrough time of more
than 240 minutes with preference for > 480 minutes where
suitable gloves can be identified. For short-term/splash
protection we recommend the same, but recognise that
suitable gloves offering this level of protection may not be
available and in this case a lower breakthrough time may be
acceptable so long as appropriate maintenance and
replacement regimes are followed. Glove thickness is not a
good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Select gloves tested to a relevant standard (e.g. Europe
EN374, US F739). When prolonged or frequent repeated
contact occurs, Nitrile gloves may be suitable. (Breakthrough
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time of > 240 minutes.) For incidental contact/splash protection

Neoprene, PVC gloves may be suitable.
Eye Protection : Chemical splash goggles (chemical monogoggles). If a local
risk assessment deems it so, then chemical splash goggles
may not be required and safety glasses may provide adequate
eye protection.
Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron (where
risk of splashing).
Thermal Hazards : Not applicable.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate. Validated exposure measurement methods
should be applied by a competent person and samples
analysed by an accredited laboratory. Examples of sources of
recommended exposure measurement methods are given
below or contact the supplier. Further national methods may be
available.
National Institute of Occupational Safety and Health (NIOSH),
USA: Manual of Analytical Methods http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA:
Sampling and Analytical Methods http://www.osha.gov/
Environmental Exposure : Local guidelines on emission limits for volatile substances must
Controls be observed for the discharge of exhaust air containing vapour.
Information on accidental release measures are to be found in
section 6. Take appropriate measures to fulfil the requirements
of relevant environmental protection legislation. Avoid
contamination of the environment by following advice given in
Chapter 6. If necessary, prevent undissolved material from
being discharged to waste water. Waste water should be
treated in a municipal or industrial waste water treatment plant
before discharge to surface water.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Colourless to yellowish. Liquid.

Odour : May contain a reodorant
Odour threshold : Data not available
pH : Not applicable
Initial Boiling Point and : 170 - 390 °C / 338 - 734 °F
Boiling Range
Pour point : <= 6 °C / 43 °F
Flash point : > 55 °C / 131 °F
Upper / lower : 1 - 6 %(V)
Flammability or
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Explosion limits
Auto-ignition temperature : > 220 °C / 428 °F
Vapour pressure : 1 hPa at 20 °C / 68 °F
Relative Density : Data not available
Density : 0.8 - 0.89 g/cm3 at 15 °C / 59 °F
Water solubility : Data not available
Solubility in other : Data not available
solvents
n-octanol/water partition : 3-6

coefficient (log Pow)
Dynamic viscosity : Data not available
Kinematic viscosity : 1.5 - 6 mm2/s at 40 °C / 104 °F
Vapour density (air=1) : Data not available
Electrical conductivity : Low conductivity: < 100 pS/m, The conductivity of this material
makes it a static accumulator., A liquid is typically considered
nonconductive if its conductivity is below 100 pS/m and is
considered semi-conductive if its conductivity is below 10 000
pS/m., Whether a liquid is nonconductive or semi-conductive,
the precautions are the same., A number of factors, for example
liquid temperature, presence of contaminants, and anti-static
additives can greatly influence the conductivity of a liquid.
Evaporation rate : Data not available
(nBuAc=1)
Decomposition : Data not available
Temperature
Flammability : Not applicable.
10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal use conditions.

Possibility of Hazardous : No hazardous reaction is expected when handled and stored
Reactions according to provisions.
Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Incompatible Materials : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage. Thermal decomposition is highly
dependent on conditions. A complex mixture of airborne solids,
liquids and gases, including carbon monoxide, carbon dioxide
and other organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative
degradation.
Sensitivity to Static : Yes, in certain circumstances product can ignite due to static
Discharge electricity.
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11. TOXICOLOGICAL INFORMATION
Information on Toxicological effects
Basis for Assessment : Information given is based on product data, a knowledge of the
components and the toxicology of similar products. Unless
indicated otherwise, the data presented is representative of the
product as a whole, rather than for individual component(s).
Likely Routes of : Exposure may occur via inhalation, ingestion, skin absorption,
Exposure skin or eye contact, and accidental ingestion.
Acute Oral Toxicity : Low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Harmful if inhaled. LC50 > 1.0 - <= 5.0 mg/l , 4 h, Rat
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
Skin corrosion/irritation : Irritating to skin.
Serious eye : Expected to be slightly irritating.

damage/irritation
Respiratory Irritation : Inhalation of vapours or mists may cause irritation to the
respiratory system.
Respiratory or skin : Not expected to be a sensitiser.

sensitisation
Aspiration Hazard : Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
Germ cell mutagenicity : Positive in in-vitro, but negative in in-vivo mutagenicity assays.
Carcinogenicity : Limited evidence of carcinogenic effect.

Repeated skin contact has resulted in irritation and skin cancer
in animals.
Material : Carcinogenicity Classification

Naphthalene : ACGIH Group A4: Not classifiable as a human carcinogen.
Naphthalene : NTP: Reasonably Anticipated to be a Human Carcinogen.
Naphthalene : IARC 2B: Possibly carcinogenic to humans.
Naphthalene : GHS / CLP: Carcinogenicity Category 2
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Fuels, diesel : ACGIH Group A3: Confirmed animal carcinogen with unknown
relevance to humans.
Fuels, diesel : GHS / CLP: Carcinogenicity Category 2
Distillates (Fischer- : GHS / CLP: No carcinogenicity classification
Tropsch) C8-26 - Branched
and Linear
Kerosine (Fischer : GHS / CLP: No carcinogenicity classification
Tropsch), Full range, C8-
C16 branched and linear
alkanes
Cumene : IARC 2B: Possibly carcinogenic to humans.
Cumene : GHS / CLP: No carcinogenicity classification
Reproductive and : Not expected to impair fertility. Not expected to be a

Developmental Toxicity developmental toxicant.
Specific target organ : Not classified.

toxicity - single exposure
Specific target organ : May cause damage to organs or organ systems through
toxicity - repeated prolonged or repeated exposure. Blood. Thymus. Liver.
exposure
Additional Information : Classifications by other authorities under varying regulatory
frameworks may exist.
12. ECOLOGICAL INFORMATION
Basis for Assessment : Information given is based on a knowledge of the components

and the ecotoxicology of similar products. Fuels are typically
made from blending several refinery streams. Ecotoxicological
studies have been carried out on a variety of hydrocarbon
blends and streams but not those containing additives. Unless
indicated otherwise, the data presented is representative of the
product as a whole, rather than for individual component(s).
Acute Toxicity : Expected to be toxic: LL/EL/IL50 > 1 <= 10 mg/l (to aquatic
organisms) LL/EL50 expressed as the nominal amount of
product required to prepare aqueous test extract.
Fish : Expected to be toxic: LL/EL/IL50 > 1 <= 10 mg/l
Aquatic crustacea : Expected to be toxic: LL/EL/IL50 > 1 <= 10 mg/l
Algae/aquatic plants : Expected to be toxic: LL/EL/IL50 > 1 <= 10 mg/l
Microorganisms : Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l
Chronic Toxicity
Fish : NOEC/NOEL expected to be > 0.01 - <= 0.1 mg/l (based on
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modeled data)
Aquatic crustacea : NOEC/NOEL expected to be > 0.1 - <= 1.0 mg/l (based on
modeled data)
Mobility : Partly evaporates from water or soil surfaces, but a significant
proportion will remain after one day. If product enters soil, one
or more constituents will be mobile and may contaminate
groundwater. Large volumes may penetrate soil and could
contaminate groundwater. Floats on water.
Persistence/degradability : Major constituents are inherently biodegradable. The volatile
constituents will oxidize rapidly by photochemical reactions in
air.
Bioaccumulative : Contains constituents with the potential to bioaccumulate. Log
Potential Kow > =4
Other Adverse Effects : Films formed on water may affect oxygen transfer and damage
organisms.
13. DISPOSAL CONSIDERATIONS
Material Disposal : Recover or recycle if possible. It is the responsibility of the

waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses. Do not dispose of tank water
bottoms by allowing them to drain into the ground. This will
result in soil and groundwater contamination. Waste arising
from a spillage or tank cleaning should be disposed of in
accordance with prevailing regulations, preferably to a
recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Container Disposal : Send to drum recoverer or metal reclaimer. Drain container
thoroughly. After draining, vent in a safe place away from
sparks and fire. Residues may cause an explosion hazard if
heated above the flash point. Do not puncture, cut or weld
uncleaned drums. Do not pollute the soil, water or environment
with the waste container. Comply with any local recovery or
waste disposal regulations.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations. Local regulations may
be more stringent than regional or national requirements and
must be in compliance.
14. TRANSPORT INFORMATION
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Land (as per ADR classification): Regulated

Class : 3
Packing group : III
Hazard indentification no. : 30
UN number : 1202
Danger label (primary risk) : 3
Proper shipping name : DIESEL FUEL
Environmentally Hazardous : Yes
IMDG
Identification number UN 1202
Proper shipping name DIESEL FUEL
Class / Division 3
Packing group III
Environmental hazards: Yes
IATA (Country variations may apply)

UN number : 1202
Proper shipping name : Diesel fuel
Class / Division : 3
Packing group : III
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution Category : Not applicable.
Ship Type : Not applicable.
Product Name : Not applicable.
Special Precaution : Not applicable.
Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
Local Regulations
Workplace Safety and : This product is subject to the requirement in the Act/
Health Act & Workplace Regulations.
Safety and Health (General
Provision) Regulations
Environmental Protection : This product is subject to the requirement in the Act/
and Management Act and Regulations.
Environmental Protection
and Management
16/18
Print Date 16.04.2014 000000038684
MSDS_SG
Version 1.1
Safety Data Sheet
(Hazardous Substances)
Regulations
Maritime and Port Authority : This product is subject to the requirement in the Act/
of Singapore (Dangerous Regulations.
Goods, Petroleum and
Explosives) Regulations
Fire Safety Act and Fire : This product is subject to the requirement in the Act/
Safety (Petroleum & Regulations.
Flammable Materials)
Regulations
Classification triggering : Contains fuels, diesel.

components
Other Information : IARC has classified diesel exhaust emissions as a Class 1

carcinogen - carcinogenic to humans. Steps should be taken
to prevent personal exposure to diesel exhaust emissions.
16. OTHER INFORMATION

Hazard Statement
H226 Flammable liquid and vapour.
H227 Combustible liquid.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs or organ systems through prolonged or repeated
exposure.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Additional Information : This document contains important information to ensure the

safe storage, handling and use of this product. The information
in this document should be brought to the attention of the
person in your organisation responsible for advising on safety
matters.
SDS Version Number : 1.1
SDS Effective Date : 10.03.2014
SDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
Uses and Restrictions : This product must not be used in applications other than those
recommended in Section 1, without first seeking the advice of
the supplier.
This product is not to be used as a solvent or cleaning agent;
17/18
Print Date 16.04.2014 000000038684
MSDS_SG
Version 1.1
Safety Data Sheet
for lighting or brightening fires; as a skin cleanser.
SDS Distribution : The information in this document should be made available to

all who may handle the product.
Key/Legend to : The standard abbreviations and acronyms
Abbrevations used in this used in this document can be looked up in
SDS reference literature (e.g. scientific dictionaries)
and/or websites.
Flam. Liq. Flammable liquids

Asp. Tox. Aspiration hazard
Acute Tox. Acute toxicity
Skin Corr. Skin corrosion/irritation
Carc. Carcinogenicity
STOT RE Specific target organ toxicity - repeated
exposure
Key Literature References : The quoted data are from, but not limited to, one or more
sources of information (e.g. toxicological data from Shell Health
Services, material suppliers’ data, CONCAWE, EU IUCLID
date base, EC 1272 regulation, etc).
Disclaimer : This information is based on our current knowledge and is

intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
18/18
Print Date 16.04.2014 000000038684
MSDS_SG
Attachment : 3 - MSDS of Unleaded Gasoline 95 Octane
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BB E BB
Attachment : 4 - Technical Bulletin
Using Physical and Chemical Properties to Manage Flammable Liquid Hazards

Part 1-B: Physical & Chemical Properties of Selected Fuels
SECTION 1: GENERAL INFORMATION
Hydrogen CNG Propane Methanol Ethanol Gas

Property/Information H2 CH4 83-99%; C2H6 C3 CH3OH C2H5OH C4
(gas) 1-13% (liquid) (liquid) (liquid) (liq
(gas)
DOT Number UN 1049 UN UN 1971 UN 1075 UN 1230 UN 1170 UN
1966 UN 1978
DOT Hazard Class or Division 2.1 2.1 2.1 3.6.1 3
flammable flammable flammable gas flammable flammable flam
gas gas liquid liquid liq
DOT Guide Number 22 17 22 28 26
CAS Number 1333-74-0 74-82-8 74-98-6 65-56-1 64-17-5 8006
STCC Number 4905746 4905755 4905781 4909230 - 490

ICC, OSHA, NFPA IB IB
Liquid Flammability Class - - - flammable flammable flam
liquid liquid liq
DOT Packing Group - - - PG II PG II P
DOT Packaging (non-bulk/bulk) 302/302 302/302 304/314 202/242 202/242 202
Types of Shipping Containers Pressurized Pressurized pressurized NON-BULK: NON-BULK: BU
cylinders cylinders cylinders, tank 1-119 gal DOT 1-119 gal DOT pipelin
& trucks, tank cars, PG-II PG-II cars
tank cars performance- performance- tru
oriented oriented
containers containers
BULK: BULK:
tank cars, tank cars,
tank trucks tank trucks
SINGAPORE! Suntec Tower Three 8 Temasek Blvd Singapore 038988 +65.6.866.3238

!WASHINGTON DC! 4100 North Fairfax Drive, Suite 740, Arlington, VA 22203 703.248.3636
SECTION 1: GENERAL INFORMATION (CONT.)

(gas)
Shipping Container Hazards rupture, rupture, rupture, BLEVE: rupture, BLEVE: rupture, BLEVE: rup
BLEVE: BLEVE: containers may containers may containers may BL
containers fragment fragment fragment & contain
containers may
may fragment fragment & & & rocket in fire frag
& rocket in fire rocket in fire rocket in fire
rocket in fire rocke
Special Fire Hazards blue flame yellow luminous yellow luminous blue flame blue flame ye
invisible in flame visible in flame visible in invisible in invisible in lum
daylight; daylight; flame daylight; flame daylight; flame flame
flame flashes daylight; flame flashes back flashes back flashes back daylig
back from flashes back from from ignition from ignition from ignition flash
ignition ignition source to source to leak source to leak source to leak from
source to leak leak point; point; point; point; sourc
point; accumulated vapor accumulated accumulated accumulated po
accumulated may vapor may vapor may vapor may accum
vapor may explode if ignited explode if ignited explode if explode if vapo
explode if in confined area ignited in ignited in exp
in confined area or
ignited in deflagrate as a or deflagrate as a confined area or confined area, igni
confined or in non-buoyant deflagrate as a or deflagrate as confin
buoyant radiant
unconfined radiant fire ball near- neutral- a near-neutral- or de
fireball in
area unconfined area in unconfined buoyancy buoyancy fire as a
area radiant fire ball ball in bu
in unconfined unconfined radian
poorly poorly in unc
ventilated area ventilated area a
!

SECTION 1: GENERAL INFORMATION (CONT.)

(gas)
Other Information H2 gas release CNG gas release is liquid floats & liquid floats & liquid floats & liquid
is very buoyant and boils on water; mixes with mixes with wate
buoyant and invisible, natural heavier-than-air water; near water; near va
invisible gas has visible vapor neutral vapor neutral vapor pre
characteristic odor cloud buoyancy buoyancy expe
form n
buo
vapo
Molecular Weight 2.02 (2) 16.04 (2) 44.1 (2) 32.04 (1,2) 46.07 (1,2) 100-
Chemical Composition
Carbon (w/w%) 0 (2) 75 (2) 82 (2) 37.5 (2) 52.2 (2) 85-
Hydrogen (w/w%) 100 (2) 25 (2) 18 (2) 12.6 (2) 13.1 (2) 12-
Oxygen (w/w%) 0 (2) - - 49.9 (2) 34.7 (2)
!

!
SECTION 2: LIQUID PROPERTIES

(gas)
Freezing Point Temp. (oF) -435 (2) -296 (2) -305.8 (2) -143.5 (1,2) -173.2 (1,2) -4
Specific Gravity (@ 60 oF/60 oF) 0.07 (2) 0.424 (2) 0.508 (2) 0.796 (1) 0.794 (1) 0.72-
Density (lb/gal @ 60 oF) - 1.07 (2) 4.22 (2) 6.63 (1,2) 6.61 (1,2) 6.0 –
Viscosity
@ -4 oF - - - 1.15 (1) 2.84 (1) 0.6-

(centipoises / mm2/s) 1.345 (2) 3.435 (2) 0.8 -
@ 68 oF - - - 0.59 (1) 1.19 (1) 0.37–
(centipoises / mm2/s) 0.74 (2) 1.50 (2) 0.5 –
@ 104 oF - - - - -
(centipoises / mm2/s) - - - - -
Specific Heat (Cp, Btu/lb-oF) - - - 0.60 (1,2) 0.57 (1,2) 0.4

Thermal Conductivity 0.097 (4) 0.17 (4) 0.075 (6) 0.12 (3) 0.099 (3) 0.0
(Btu/hr-ft-oF)
Coefficient of Thermal Volume
Expansion (@ 60 oF & 1 atm) - - - 0.00067 (1) 0.00062 (1) 0.00
Electrical Conductivity
Neat or without additives - - - 4.4 x 107 pS/m 1.35 x 105 25 p
(1,26, 32)
pS/m (1,26, 32)

!
SECTION 2: LIQUID PROPERTIES (CONT.)

(gas)
Electrical Conductivity Cont.
Industrial use - - - 30 µS/m (28) -
Fuel specification - - - < 1000 µS/m (32) < 500 µS/m(27)
Latent Heat of Vaporization
(Btu/gal @ 60 oF) - - 775 (2) 3,340 (1,2) 2,378 (1,2) ≈90
(Btu/lb @ 60 oF) 192.1 (2) 219 (2) 193.1 (2) 506 (1,2) 396 (1,2) ≈15
Heating Value (a)
Lower [liquid fuel -
56800 (1) 76000 (1) 109
combusted to water as vapor] - - 119
(Btu/gal @ 60 oF)(1) 84250 (2) 57250 (2) 76330 (2) 116
Lower [liquid fuel combusted - - - 8570 (1) 11500 (1) 18000

to water as vapor] (Btu/lb) 52217 (2) 20263 (2) 19900 (2) 8637 (2) 11585 (2) 186
Higher [liquid fuel combusted - - 91420 (2) 65200 (2) 84530 (2) 124
to liquid water] (Btu/gal)
Higher [liquid fuel combusted - - 9750 (1) 12800 (1) 18800
to liquid water] (Btu/lb) 59806 (2) 22449 (2) 21594 (2)
9837 (2) 12830 (2)
20
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
a
The higher heating value (HHV) and heat of combustion are cited for completeness only. No vehicles currently in use or under development for future us
condensation from water of combustion. Use the lower heating value (LHV) for practical comparison between fuels which combust accidentally as a resu


(gas)
Heat of Combustion [∆Hc0] 60000 (30,31) 23000 (30,31) 21500 (30,31) 9900 (30,31) 12900 (30,31) 2000
[liquid fuel combusted to 61000 (34) 21000 (34) 9378 (35) 12000 (34)
liquid water] (Btu/lb) 12764 (36)
Equilibrium Vapor Pressure

Reid [RVP] - 4.6 (1,2) 2.3 (1,2) 8–
(psi @ 100 oF) 2400 (2)
208 (2)
True Vapor Pressure [TVP] - - 6257.7 (13) 92 (10) 43 (9) 258-

(mm Hg @ 68 oF) 104 (11) (@ 1
Boiling Pt. Temperature (oF) -423 (2) -263.2 – 126.4 (2) -44 (2) 149 (1,2) 172 (1,2) 80 –
o
Water Solubility @ 70 F
Fuel in Water (v/v %) - Negligible (2) Negligible (2) 100 (1,2) 100 (1,2) Negli
Water in Fuel (v/v %) - - - 100 (1,2) 100 (1,2) Negli
Vapor Specific Heat (Btu/lb/oF) 3.42 (16) 0.59 (16) 0.39 (16) 0.38 (18) 0.45 (19) 0.3
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
b
This value of Cp for an ideal gas at STP (60 oF and 1 atm of pressure) uses the heat capacity of heptane (C7H16) as a surrogate for gasoline vapor.

WASHINGTON DC! 4100 North Fairfax Drive, Suite 740, Arlington, VA 22203 703.248.3636
!

(gas)
Equilibrium Vapor Pressure (c)
Reid (psi @ 100 oF) - 2400 (2) 208 (2) 4.6 (1,2) 2.3 (1,2) 8–
True Vapor Pressure - - 6257.7 (13) 92 (10) 43 (9) 258-
(mm Hg @ 68 oF) 104 (11) (@ 1
Vapor Density (air=1) 0.07 (24, calc’d) 0.55-0.69 (25, calc’d) 1.5 (12) 1.1 (23) 1.6 (11) 3–
Vapor Heat of Combustion
Lower [gaseous fuel combusted to - - - 9080 (1) 11900 (1) 19000
water as vapor] (Btu/lb @ 60 oF)
!
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
c
True Vapor Pressure is the partial pressure of fuel vapor in air, compared to Reid Vapor Pressure which is the total pressure of fuel vapor, and air contain
apparatus. Reid Vapor Pressure (RVP) is determined experimentally, and is typically used in reference to hydrocarbon mixtures such as natural gas, Liqu
gasoline, kerosene, diesel, and fuel oil. RVP is expressed as differential pressure in pounds per square inch (psi); true vapor pressure is expressed as a
(mmHg) or pounds per square inch absolute (psia). One atmosphere of pressure is equivalent to 0.0 psi of differential pressure, and 14.7 psia or 760 m

!
SECTION 4: FLAMMABILITY PROPERTIES

(gas)
Flash Point Temperature
Closed Cup (oF) - -300 (2) -156 (1) 52 (1) 55 (1) -4
o
Open Cup ( F) - - - - -
o
Autoignition Temperature ( F) 867 (1,2)
793 (1,2) 49
932 (2) 900 – 1170 (2) 842 (2)
Flammability Limits
Lower (v/v %) 4.1 (2) 5.3 (2) 2.2 (2) 7.3 (1,2) 4.3 (1,2) 1.
Upper (v/v%) 74 (2)
15.0 (2)
9.5 (2)
36.0 (1,2)
19.0 (1,2)
7.
Flammability Range 69.9 (calc by diff) 9.7 (calc by diff) 7.3 (calc by diff) 28.7 14.7 (calc by diff) 6.2 (c
(v/v %) (calc by diff)
Stoichiometric air/fuel ratio 34.3 (2) 17.2 (2) 15.7 (2) 6.45 (1,2) 9.00 (1,2) 14
(w/w)
Fuel in Vaporized - - - 12.3 (2) 6.5 (2) 2
Stoichiometric Mixture (v/v%)
Stoichiometric Flame Speed 10.63 –14.44 1.48 (20) 1.48 (20) 1.41 (20) - 1.1
(20)
(ft/s)
Minimum Ignition Energy (mJ) 0.017 (20) 0.30 (20) 0.26 (20) 0.14 (20) - 0.2
o
Adiabatic Flame Temperature ( F) 3807 (21) 3542 (21) 3610 (21) 3470 (21) 3281 (21) 35
Flame Temperature (oF) 3722 (20) 3542 (20) 3497 (20) 3,398 (20) 3,488 (20) 3,6
Mass Burning Rate (lb/ft2) - - - 0.083(29) - 0.2

!
SECTION 5: SOURCES OF INFORMATION

!
(1) Rene M. Tshiteya, Ph.D., Ezio N. Vermiglio, and Steven Tice: “Properties of Alcohol Transportation Fuels, Alcohol Fuels Reference Work #1, P
Meridian Corporation, 4300 King Street, Alexandria, VA 22302; Prepared for Biofuels Systems Division, Office of Alternative Fuels, U.S. Depar
(2) Internet web page as of March 2011:: http://eerc.ra.utk.edu/etcfc/docs/altfueltable.pdf
(3) Internet web page as of March 2011: http://www.engineeringtoolbox.com/thermal-conductivity-liquids-d_1260.html
(4) Internet web page as of March 2011: http://www.engineeringtoolbox.com/thermal-conductivity-d_429.html
(5) Internet web page as of March 2011: http://eng-tips.com/viewthread.cfm?qid=245443&page=5
(6) Internet web page as of March 2011: http://webserver.dmt.upm.es/~isidoro/dat1/eLIQ.htm
(7) Johnathan P. McCrady, Valerie L. Stringer, Alan C. Hansen, Chia-fon F. Lee: “Computer Analysis of Biodiesel Combustion in a Low Temperatu
Fuel Properties,” © 2007 SAE International, 07PFL-655, University of Illinois at Urbana-Champaign
(8) Internet web page as of March 2011: http://www3.ntsb.gov/recs/letters/1987/M87_23_25.pdf
(9) Internet web page as of March 2011: http://www.distill.com/materialsafety/msds-usa.html
(10) Methanex: “Technical Information & Safe Handling Guide for Methanol,” version 3.0, September 2006
(11) Internet web page as of March 2011: http://en.wikipedia.org/wiki/Methanol_(data_page)#Material_Safety_Data_Sheet
(12) Internet web page as of March 2011: http://www.campora.com/msds.htm
(13) Internet web page as of March 2011: http://www.engineeringtoolbox.com/propane-d_1423.html
(14) Internet web page as of March 2011: http://www.petrocard.com/products/MSDS-ULS.pdf
(15) Internet web page as of March 2011: http://www.albina.com/fuel/chevronrugasmsds.htm
(16) Internet web page as of March 2011: http://www.engineeringtoolbox.com/hydrogen-d_976.html
(17) Internet web page as of March 2011: http://www.engineeringtoolbox.com/specific-gravities-gases-d_334.html

(18) Internet web page as of March 2011: http://www.engineeringtoolbox.com/methanol-properties-d_1209.html
(19) Internet web page as of March 2011: http://answers.yahoo.com/question/index?qid=20080403121038AAnMf9y
(20) Internet web page as of March 2011: http://www.faqs.org/faqs/autos/gasoline-faq/part4/preamble.html
(21) Charles E. Baukal, and Robert E. Schwartz: The John Zink Combustion Handbook, © John Zink Company, LLC, 2001, CRC Press LLC, p. 64.
(22) Internet web page as of March 2011: http://www.nrc.gov/reading-rm/doc-collections/nuregs/staff/sr1805/ch3-6.pdf
(23) Internet web page as of March 2011: http://oehha.ca.gov/oublic_info/pdf/TSD&20Methanol%20Meth%20Labs%2010’8’03.pdf
(24) Internet web page as of March 2011: http://wiki.answers.com/Q/What_is_the_density_of_hydrogen_gas_using_the_ideal_gas_law
(25) Internet web page as of March 2011: http://www.engineeringtoolbox.com/gas-density-d_158.html
(26) Internet web page as of March 2011: http://www.scribd.com/doc/22568364/Liq-Handbook-51-6009-Conductance-Data-for-Commonly-Use
(27) Internet web page as of March 2011: http://www.itecref.com/pdf/fuel_alcohol_specifications_Comparison.pdf
(28) Internet web page as of March 2011: http://baltchemtrade.com/site/files/metanol-en.pdf; and http://n-azot.ru/download/product/product_337
(29) Internet web page as of March 2011: http://www.nrc.gov/reading-rm/doc-collections/nuregs/staff/sr1805/ch3-6.pdf
(30) Internet web page as of March 2011: http://en.wikipedia.org/wiki/Heat_of_combustion - Heat_of_combustion_tables
(31) Internet web page as of March 2011: http://www.gexcon.com//handbook/GEXHBchap4.htm
(32) Internet web page as of March 2011: http://www.pccmorava-chem.cz/ttw/mch.nsf/id/EN_Methanol
(33) William D. McCain, Jr.: The Properties of Petroleum Fluids, 2nd edition, © 1990 by PennWell Publishing Company, p. 492-493, ISBN 0 87814
(34) Internet web page as of March 2011: http://www.enotes.com/topic/Heat_of_combustion#Heat_of_combustion_tables
(35) Internet web page as of March 2011: http://webbook.nist.gov/cgi/cbook.cgi?Name=methanol&Units=SI&cTC=on
(36) Internet web page as of March 2011: http://webbook.nist.gov/cgi/cbook.cgi?Name=ethanol&Units=SI&cTC=on

Attachment : 5 - ASTM IP 53 Table for Gasoline Density
Attachment : 6 - ASTM IP 53 Table for Gas-oil Density
Attachment : 7 - Vapor Pressure graph for Gasoline
Temp: 30°C (86°F)
Gasoline:
TVP : 7.6 psi
FOR Gasoline:
RVP : 9.50 PSI at 37.8 °C.
PROJECT NAME : TEMA Ground Fuel Depot Date: 03.12.2015
Attachment : 8 - True vapor pressure calculation for gasoline
Client : VIHAMA- GHANA
TVP Calculation Sheet [ Petroleum Refined Products ]
GASOLINE
REF : Environmental Protection Agency, (Figure : 7.1-14b)
Sr.No
1 Temperature 30 °C INPUT
2
3 86 °F RESULT
4
5 RVP 9.11 Psi a 62.8 kPa
6
7 T + 459.6 545.6
8
9 A 0.00 A = 0.7553 - {413.0 / ( T+ 459.6 ) }
10
11 S 3 Motor Gasoline
12
13 S0.5 1.73
14
15 Log10 RVP 0.959
16
17 B -0.0558 B = 1.854 - { 1042 / ( T + 459.6 ) }
18
19 C 2.4152 C= { 2416 / ( T + 459.6 ) } - 2.013
20
21 D 16.023 D= { 8742 / ( T + 459.6 ) }
22
23 E 2.028 E = ( A x S0.5 x log RVP ) - ( B x S0.5 )
24 + ( C x log RVP ) - D+15.64
25
26 P 7.602 PSIA P=exp ( E )
27
28 0.524 bar
29
30 52.413 kpa
Attachment : 9 - True vapor pressure calculation for Gasoline (Alternate Method)
Project: Tema Ground Fuel Depot (Ghana) Date: 03.12.2015
Client : Vihama Terminals
REF : Environmental Protection Agency, (Eq. 1-24, page 17)
S 3
0.5
S 1.732050808
0
T 30 C
0
86 F
0
545.65 R
RVP 9.06 Psi
REF : Environmental Protection Agency, (Fig 7.1-15, page 56)
A 11.75420138
B 5310.152416
PVA 7.556507962 Psi A

Attachment : 10 - True vapor pressure calculation for Gas-Oil
Project: Tema Ground Fuel Depot (Ghana) Date: 03.12.2015
Client : Vihama Terminals
REF : Environmental Protection Agency, (Eq. 1-24, page 17)
S 3
0.5
S 1.732050808
0
T 30 C
0
86 F
0
545.65 R
RVP 0.2 Psi
REF : Environmental Protection Agency, (Fig 7.1-15, page 56)
A 12.92140636
B 8125.402923
PVA 0.139480617 Psi A

Attachment : 11 - True vapor pressure calculation for Gas-Oil (Alternate Method)
PROJECT NAME : TEMA Ground Fuel Depot Date: 03.12.2015
Client : VIHAMA- GHANA
Gasoil
REF : Environmental Protection Agency, (Figure : 7.1-14b)
Sr.No
1 Temperature 30 °C INPUT
2
3 86 °F RESULT
4
5 RVP 0.20 Psi a 1.37895 kPa
6
7 T + 459.6 545.6
8
9 A 0.00 A = 0.7553 - {413.0 / ( T+ 459.6 ) }
10
11 S 3 Motor Gasoline
12
13 S0.5 1.73
14
15 Log10 RVP -0.699
16
17 B -0.0558 B = 1.854 - { 1042 / ( T + 459.6 ) }
18
19 C 2.4152 C= { 2416 / ( T + 459.6 ) } - 2.013
20
21 D 16.023 D= { 8742 / ( T + 459.6 ) }
22
23 E -1.972 E = ( A x S0.5 x log RVP ) - ( B x S0.5 )
24 + ( C x log RVP ) - D+15.64
25
26 P 0.139 PSIA P=exp ( E )
27
28 0.010 bar
29
30 0.959 kpa
Attachment : 12 - X Axis Co-ordinates for Gasoline / Gas-Oil
VISCOSITY CHART FOR X-AXIS
80
75
X ° API 70
14.4 76
65
14 56
11.6 42 60
10 35
10.3 34 55
°API GRAVITY
10 28 50
45
Gasoline X = 14.1
40
35
30
Gas-Oil / Diesel = 10.08 25
20
15
10
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
X- AXIS
[REF.D.Q. KernPage
[REF.D.Q. Kern Page821]821]
Attachment : 13 - Y Axis Co-ordinates for Gasoline / Gas-Oil
VISCOSITY CHART FOR Y-AXIS

80
75
X ° API
6.4 76 70
10.5 56
65
16 42
20 35 60
21.3 34 55
23.6 28
50
°API Gravity
45
40
Gasoline Y = 9.48
35
30
25
20
Gas-Oil / Diesel Y = 19.79 15
10
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Y- Axis
[REF.D.Q. Kern Page 821]

Attachment : 14 - Viscosity graph for Gasoline
Viscosity @ 30°C = 0.47 cP
Y= 9.48
X=14.1
Gasoline
Attachment : 15 - Viscosity graph for Gasoil
Viscosity @ 30°C = 3.7 cP

Y=19.79
X=10.03
Gas-Oil / Diesel

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Project : Tema Ground Fuels Depot Date: 25.02.2016

Client : Waterway petroleum & Partners

Location : Tema, Ghana, South Africa

Operating Temperature: 30°c

B. Basis & Assumptions:

Relative Density : 0.735 at 15°C (60°F)

Viscosity : 0.625 cSt at 40°C (104°F) (Refer Attachment-3)

Vapor Pressure : 62.5 kPa at 37.8°C (100°F)

Vapor Pressure (RVP) : 9.06 PSI at 37.8°C (100°F)

Gasoil / (Diesel) Reference from existing project

Density : 0.845 g/cm3 at 15°C (60°F)

Viscosity : 6.0 cSt at 40°C (104°F)

Vapor Pressure : 1.0 hPa ~ 0.1 kPa at 20°c (68°F)

Safe Handling: Technical Bulletin:

Vapor Pressure (RVP) : 0.2 PSI at 37.8°C (100°F) (Refer Attachment-4)

E. API Gravity Calculation:

° API = [141.5 / sp. Gr. At 60/60] - 131.5

= 141.5 / (0.735) – 131.5

° API = [141.5 / sp. Gr. At 60/60] - 131.5

= 141.5 / (0.848) – 131.5

°API 61 X = 14.1 Y = 9.48 (Refer Attachment – 12, 13 & 14)

Viscosity at 30°C as per Graph: 0.47 cP

°API 35.3 X = 10 .08 Y = 19.79 (Refer Attachment – 12, 13 & 15)

Viscosity at 30°C as per Graph: 3.7 cP

Density : 744.0 kg/m3 at 30°C (86°F)

Viscosity : 0.47 cP at 30°C (86°F)

Vapor Pressure : 52.4 kPa at 30°C (86°F)

Density : 854.9 kg/m3 at 30°C (86°F)

Viscosity : 3.7 cP at 30°C (86°F)

Vapor Pressure : 0.959 kPa at 30°C (86°F)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

Full text of H-phrases: see section 16

2.1.2. Classification according to EU Directives 67/548/EC or 1999/45/EC

Full text of R-phrases: see section 16

2.2. Label elements

GHS02 GHS07 GHS08 GHS09

2.2.2. Labelling according to Directives (67/548 - 1999/45)

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Gasoline (CAS No.) 86290-81-5 0 - 100 Carc.Cat.2; R45

Full text of R-, H- and EUH-phrases: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

SECTION 8: Exposure controls/personal protection

Recommended monitoring procedures : Personal monitoring

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties