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Structural Isomers - are molecules with the same molecular formula but with diff
erent structural arrangements of atoms.
Sterioisomers - are compounds with the same strucutal formula, but with a differ
ent arrangement of atoms in space.
E/Z isomerism - is a type of sterioisomerism in which different groups attatched
to each carbon of a C=C double bond may be arranged differently in space becaus
e of the restricted rotation of the C=C double bond.
cis-trans isomerism - a special type of E/Z isomerism in which there is a non-hy
drogen group and hydrogen group on each C or a C=C double bond; the CIS isomer (
Z isomer) has the H atoms on each carbon atom on the same side; the TRANS isomer
(E isomer) has the H atoms on each carbon on different sides.
Homolytic Fission - the breaking of a covalent bond, with one of the bonded elec
trons going to each atom, forming two Radicals.
Heterolyric Fission - the breaking of a covalent bond with both of the bonded el
ectrons going to one of the atoms, forming a cation (+ ion) and an anion (- ion)
.
Radical - a species with an unpaired electron.
Nucleophile - is an atom (or group of atoms) that is attracted to an electron-de
ficient centre or atom, where it donates a pair of electrons to form a new coval
ent bond.
Electrophile - is an atom (or group of atoms) that is attracted to an electron-r
ich centre or atom, where it accepts a pair of electrons to form a new covalent
bond.