FORM TP 2018169 2 een "| resr cope 02112010 MAY/JUNE 2018 CARIBBEAN EXAMINATIONS COUNCIL CARIBBEAN ADVANCED PROFICIENCY EXAMINATION® CHEMISTRY UNIT 1- Paper 01 1 hour 30 minutes 22 MAY 2018 (a.m.) READ THE FOLLOWING INSTRUCTIONS CAREFULLY. ‘This test consists of 45 items. You will have 1 hour and 30 minutes to answer them. In addition to this test booklet, you should have an answer sheet and a data booklet. Each item in this test has four suggested answers lettered (A), (B), (C), (D). Read each item you are about to answer and decide which choice is best. ‘On your answer sheet, find the number which corresponds to your item and shade the space having the same letter as the answer you have chosen. Look at the sample item below, ‘Sample Item ‘Which of the following eriergy transitions is the HIGHEST in an organic compound? ‘Sample Answer (noe 600 ®) stoa+ © atom ©) xtonm ‘The correct answer to this item is “o to 6*”, so (B) has been shaded. If you want to change your answer, erase it completely before you fill in your new choice. When you ate told to begin, tum the page and work as quickly and as carefully as you can. If you cannot answer an item, go onto the next one, ‘You may return to that item later. ‘You may do any rough work in this booklet. Figures are not necessarily drawn to scale. ‘You may use a silent, non-programmable calculator to answer items, DO _NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright © 2016 Caribbean Examinations Couneil Alll rights reserved,1. Which isotopic half-life is BEST suited for use as a tracer in medicine? Z(A)— Shours {B) 0.16 years (©) 5.7% 10" years (D) _ 14% 10" years Item_2 refers to the following graph which shows the log of successive ionization energies for ten electrons of an element, P. i 6 5 4 ' ' ' ' ' ‘ 1 1 9 eu eat Number of electrons lost io 2. Element P is MOST likely (A) neon AB) — sodium (©) chlorine (D) magnesium 3. Which of the following pairs of elements 4. Which of the following solids has a giant combine to produce naturally occurring molecular lattice? compounds with formulae type XY? (A) Copper oxide (A) Sodium and sulfur {B) _ Silicon dioxide (B) Sodium and nitrogen (©) Carbon dioxide (C) Magnesium and sulfur (@) — Magnesium oxide (©) — Magnesium and chlorine GO ON TO THE NEXT PAGE“Yellow metal’ is a type of alloy (brass) used to make omaments. It contains 60% copper and 40% zine by mass. How many moles of zine atoms are there in 260 grams of this alloy’? @ 16 @) 24 © 32 @) 40 ‘Item & refers to the following diagram of ‘a water molecule showing the angle X in degrees. i ‘The value of X is (A) 104.5° ®) —109.5° © 120.08 @) 180.0 Which of the following statements is true about 5 dm? of hydrogen gas and 5 dm? of oxygen gas at 0 °C and 101 kPa? (A) They react to produce $ dm? of ‘water. (B) They possess the same amount of kinetic energy. _(©) They contain the same number of molecules. (D) They react completely with each other. 9. 10. Itom 8 refers to the following reaction. 2PL(NO,), —#%> 2PbO +4NO, +0, ‘The molar volume of gas at rtp. is 24 dm’, ‘The maximum mass of lead(I) oxide which can be obtained from 13.23 g of lead(tl) nitrate is / (2238 B) 4468 ©) 891g ©) 13.328 John Dalton developed the first useful atomic theory of matter. Which of the following would be considered when ‘theories are accepted? I. Experiments should be replicable. TI. Data collected should be accurate and reliable. III. Theories should show congruence between evidence and theoretical constructs. (A) Tonly B) Land only AC) Wand I only ©) 1, Mandi Deviations from ideal gas behaviour generally occur under conditions of (A) low pressure and low temperature (B) _lowpressure and high temperature (C)__ high pressure and low temperature _() high pressure and high temperature GO ON TO THE NEXT PAGE