DTPMP Acid, DETPMP

CAS No.: 15827-60-8

Molecular Formula: C9H28O15N3P5

Molecular weight: 573.2

Structural Formula:

Properties:
DTPMP (DETPMP) acid is innocuous, easy to be dissolved in an acid solution. It has an excellent
scale and corrosion inhibition and good thermal tolerance ability. DTPMP (DETPMP) can inhibit the
scale formation of carbonate, sulfate, and phosphate. On the situation of alkali environment and high
temperature (above 210℃), DTPMP (DETPMP)has better scale and corrosion inhibition effect than
other organophosphines.

Specification:

Items Index

Appearance Brown transparent liquid

Active acid % 48.0-52.0

Chloride (as Cl–)% 12-17

pH (1% solution) 2.0 max

Density (20℃) g/cm3 1.35-1.45

Fe，mg/L 35 max

Usage:
DTPMP (DETPMP) can be used as scale and corrosion inhibitor in circulating cool water system
and boiler water. And especially in alkali circulating cool water system without additional pH
regulation, DTPMP (DETPMP) can also be used in oilfield refill water, cool water and boiler water
with high concentration of barium carbonate. When used alone, little scale sediment is found even
none of the dispersant is used.
DTPMP (DETPMP) can also be used as peroxide stabilizer, the chelating agent in woven & dyeing
industry, the pigment dispersant, microelement’s carrying agent in fertilizer and concrete modifier.
In addition, DTPMP (DETPMP) is used in papermaking, electroplating, acid cleaning and cosmetics.

Package and Storage:

200L plastic drum, IBC(1000L), customers’ requirement. Storage for ten months in a shady room
and dry place.

Safety Protection:
Acidity, avoid contact with eye and skin. Once contacted, flush with water.
 PBTC 50 (Phosphonobutane Tricarboxylic Acid
50%)
Keywords:
PBTC; Dequest 7000; Mayoquest 2100; Bayhibit AM; Belclene 650; Codex 551; Briquest
PBTC, PBTC tricarboxylic acid, 2-phosphonobutane-1 2 4-tricarboxylic acid

CAS No.:
37971-36-1, from ChemIDplus, EPA Chemicals under the TSCA, EPA DSStox, European
Chemicals Agency (ECHA).

40372-66-5, from ChemIDplus, European Chemicals Agency (ECHA).

EC No.:
253-733-5, from European Chemicals Agency (ECHA).

254-894-4, from European Chemicals Agency (ECHA).

Molecular Formula:
C7H11O9P

Molecular Weight:
270.13

Structural Formula:

Properties:
Phosphonobutane tricarboxylic acid is excellent as both antiscalants and corrosion inhibitors,
because of its structural feature of carboxylic acid and phosphoric acid. The PBTCA chemical is
stable and high efficiency in the condition of high hardness, temperature, pH value, and indexed
matter concentration.

While usually building with other organophosphates, PBTCA acid also widely works together with
zinc salts whose solubility it will increase. Phosphonobutane tricarboxylic acid can improve zinc
salt solubility. PBTC also have a higher tolerance to oxidation agents like chlorine or bromine in the
system.
The first reaction for PBTC 50 production is between dialkyl phosphite (usually dimethyl phosphate
in China) and maleic acid dimethyl ester under basic catalyst. Tetraalkyl ester of phosphonosuccinic
acid forms and immediately reacted with methyl acrylate. The following thereupon saponification
yields PBTCA.

Specification:

Items Index

Appearance Colorless or light yellow transparent liquid

Active acid % 49.0 – 51.0

Phosphorous acid (as PO33-)% 0.8 max

Phosphoric acid (as PO43-)% 0.5 max

pH (1% water solution) 1.5 – 2.0

Fe ppm 20.0 max

Chloride ppm 10.0 max

Density (20℃) g/cm3 1.27 min

Usage:
As an excellent inhibitor to both scale and corrosion, PBTC 50 is the excellent stabilizer for zinc salt.
It is widely applied in the refilling system and circulated cooling system for oil fields, steel mills,
and mines. PBTC 50 can be used in situations of high temperature, high hardness, high alkali, and
high concentration index. Besides, PBTC is used to chelate metal ions in lavation and detergent
industries as metal detergent. In pH 7-10, 5-15 mg/L is recommended if only PBTC.

PBTC 50 is usually used together with the zinc salt, copolymer, organophosphine, imidazole, and
other water treatment agents. When used alone, the dosage of 5-15 mg/l is preferred.

Package and Storage:

200L plastic drum, IBC (1000L), customers’ requirement.

Storage for one year in a shady room and dry place.

Safety Protection:
Acidity, Avoid contact with eye and skin, once contacted, flush with water.

Transport Info:
Corrosive. IMO class 8, UN 3265.
 HEDP 60%, HEDP Acid
Synonyms: HEDP(A);HEDPA; Etidronic Acid; 1-Hydroxy-1,1-Ethanediyl Ester; Dequest 2010;
Mayoquest 1500; Beleclene 660; Briquest ADPA-60A; Unihib 106; Excel Codex 661; Sequacel HD

HEDP is mainly produced by a reaction of Phosphorus Trichloride (PCl3) and Glacious Acetic Acid
(CH3COOH) in the tertiary amine. Besides, some plants also use another continuous process to
synthesize HEDP by Phosphorous Trichloride (PCl3) and Acetyl chloride (CH3COCl).

CAS No.: 2809-21-4

Molecular Formula: C2H8O7P2
Molecular weight: 206.02

Structural Formula:

Properties:
HEDP 60 is an excellent corrosion inhibitor and antiscalant. HEDP 60% can dissolve the oxidized
materials on these metals’ surfaces. It shows excellent scale and corrosion inhibition effects under
temperature 250℃.

Under high pH value and/or 250℃, HEDP 60% shows good chemical stability. It is difficult to be
decomposed by normal light and heat conditions. Actually, its tolerance to acid, alkali and chlorine
oxidation is better than most of the other organophosphates.

HEDP can react with metal ions in the water system to form a hexa-element chelating complex. It
can chelate with Ba, Pb, Fe, Zn, Cu ion and especially Ca ions. Therefore, HEDP 60 has good
antiscale and visible threshold effects. The oxidate on these metal surfaces will be dissolved by
HEDP. Synergy will be achieved when HEDP is built with other WT chemicals, usually
polycarboxylic acid.

Besides liquid, HEDP solid is offered in crystal powder for freezing regions, especially in winter.
Because of HEDP solid is high purity, it can be used as a cleaning agent in electronic fields and as
additives in daily chemicals.

Specification:

Items Index

Clear, Colorless to pale yellow White crystal

Appearance
aqueous solution powder

Active content
58.0-62.0 90.0 min
(HEDP)%
 Items Index

Phosphorous acid (as

2.0 max 0.8 max
PO33-)%

Phosphoric acid
0.8 max 0.5 max
(asPO43- )%

Chloride (as Cl-) % 0.01 max 0.01 max

pH (1% solution) 2.0 max 2.0 max

Density (20℃)g/cm3 1.40 min –

Fe，mg/l 10.0 max 5.0 max

Colour APHA (Hazen) 40.0 max –

Usage:
HEDP 60 is used as scale and corrosion inhibition in circulating cool water system, oil field and
low-pressure boilers in fields. HEDP is widely used power station, oil fields, chemical plants,
metallurgic plant for cooling water system and boilers as scale inhibitor with preferred dosage 1-
10mg/L (antiscalant) and 10-50mg/L (corrosion inhibitor).

In the daily chemical industry, HEDP is used as metal and nonmetal detergent. Dosage is usually
1,000-2,000mg/L. It is also a peroxide stabilizer and dye-fixing agent in the dyeing industry.

Usually, HEDP acid chemicals are used together with the polycarboxylic acid.

HEDP is widely used power station, oil fields, chemical plants, metallurgic plant for cooling water
system and boilers as scale inhibitor with preferred dosage 1-10mg/L (antiscalant) and 10-50mg/L
(corrosion inhibitor)

Package and Storage:

Liquid: 200L plastic drum, IBC (1000L), customers’ requirement.

Solid: 25 kg/bag, customers’ requirement.

Storage for ten months in a shady room and dry place.

Safety Protection:
Acidity, avoid contact with eye and skin. Once contacted, flush with water.

IMO class 8, UN 3265.

 Acrylic Acid Maleic Acid Copolymer, MA/AA
CAS No.: 26677-99-6

Structural Formula:

Properties:

The acrylic acid-maleic acid copolymer is a low molecular weight polyelectrolyte. A copolymer of
maleic anhydride and acrylic acid. It has good dispersant performance against carbonate and scale
inhibition for phosphate. The acrylic acid-maleic acid copolymer has good thermal stability. MA/AA
chemicals can be used under high temperature (300℃).

MA/AA has good compatibility when used together with other agents. The acrylic acid-maleic acid
copolymer is widely used in low-pressure boiler, centralized heating, centralized air-conditioner and
circulating cool system. It can also be used as chelating dispersants in woven and dyeing fields.

Specification:

Items Index

Appearance Brown transparent liquid

Solid content % 48 min

Free monomer (as MA) % 9.0 max

Density (20℃)g/cm3 1.18 min

pH(1% solution) 2.0~3.0

Usage:

The copolymer of maleic and acrylic acid(MA/AA) is used in circulating cool water system, medium
or lower pressure boiler and distillation system in which high temperature is usually encountered.
The copolymer of maleic and acrylic acid (MA/AA) can be used alone or together with other organic
phosphates.

When used together, the dosage of 2-10 mg/L is preferred. The dosage for use as woven & dyeing
and accessory detergent should be determined by experiments.

Package and Storage:

200L plastic drum, IBC (1000L), customers’ requirement. Storage for one year in a shady room and
dry place.

Safety Protection:

Acidity. Avoid contact with eye and skin. Once contacted, flush with water.
 Polyacrylic acid, PAA polymer
CAS No.: 9003-01-4

Structural Formula:

Properties:

Polyacrylic acid is innoxious and soluble in water, it can be used in situations of alkaline and high
concentration without scale sediment. The polyacrylic acid solution can disperse the microcrystals or
micro sand of calcium carbonate, calcium phosphate, and calcium sulfate.

Polyacrylic acid is used as a scale inhibitor and dispersant for circulating cool water system,
papermaking, weave, dyeing, ceramic, painting, etc.

Specification:

Items Index

Appearance Amber transparent liquid

Solid content % 50 min

Free monomer (CH2=CH-COOH) % 1.0 max

Density (20℃)g/cm3 1.2 min

pH(1% solution) 3.0-4.5

30%, 40% ,60% Polyacrylic Acid are supplied too.

Usage:

Polyacrylic acid can be used as a scale inhibitor and dispersant in circulating cool water systems in
power plants, iron & steel factories, chemical fertilizer plants, refineries, and air conditioning
systems. Dosage should be in accordance with water quality and equipment materials. When PAA
chemicals used alone, 1-15mg/L is preferred.

Package and Storage:

200L plastic drum, IBC (1000L), customers’ requirement. Storage for one year in shady room and
dry place.
Safety Protection:

Acidity, avoid contact with eye and skin. Once contacted, flush with water.

Related Products:

Polyacrylic Acid Sodium (PAAS)

Polyaspartic Acid Sodium(PASP)
Hydrolyzed Polymaleic Anhydride (HPMA)