CHEMICAL KINETICS (ORDER/FIRST ORDER/HALF -LIFE)
1. The t1/2 for a certain reaction equals
(2−√2) 1/2
Co . What is the order of
𝐾 manufacturer to deliver a 92Tc sample
reaction?
a) 1 b) 0.5 c) 1.5 d) 2.0
2. For a 1st order reaction, the initial
rate=0.84% per minute. Calculate the
t1/2.
a)85.2 b)52.8 c)82.5 d)58.2min
3. A reaction is 50% complete in 40
minutes and 75% complete in 60
minutes. Calculate the order of
reaction and rate constant.
a) 0, 0.0152 mol L-1min-1
b) 1, 0.0165 mol L-1min-1
c) 0, 0.0125 mol L-1min-1
d) 1, 0.0172 mol L-1min-1
4. A+B C. the rate of reaction
becomes fourfold when [A] is
doubled. The rate is independent of
[B]. what are the partial orders?
a)2,0 b)1,0 c)2,1 d)1,1
5. In a zero-order reaction for every 10°
rise of temperature, the rate is
doubled. If the temperature is
increased from 10°C to 100°C, the
rate of the reaction will become:
a) 64 times b) 128 times
c) 256 times d) 512 times
6. *Sucrose decomposes in acid soln into
glucose and fructose as per first order
kinetics, with t1/2=3hrs. What fraction
of sample of sucrose remains after 8
hrs?
a)1.023M b)0.8725M
c)0.023M d)0.1576M
7. Calculate the ratio of t7/8 to t1/2 for 1st
order reaction is:
a) 3 b) 2 c) 5 d) 7
8. In the thermal decomposition of a gas
the following data were observed.
T1/2 400 160 114.3
Initial pressure 200 500 700
Po mmHg
Determine the order of reaction.
a) 2 b) 1 c) 1.5 d) 0
CODE: 2019-20/3
9. The half-life of 92Tc is 6.00hrs. if it
takes exactly 12.00hrs for
to hospital, how much be shipped for
the hospital to receive 10mg?
a)40mg b)30mg c)20mg d)15mg
10. For which reaction order, the half-life
of the reactant is half of the full
lifetime (time for 100% conversion) of
the reactant?
(A) Zero order (B) Half order
(C) First order (D) Second order
11. Consider a reaction A B + C. if the
initial concentration of A was reduced
from 2M to 1M in 1hr and from 1M to
0.25 in 2hrs, the order of reaction is:
A) 0 b) 1 c) 2 d) 3
12. The half-life of a first order reaction is
60 min. how long will it take to
consume 90% of the reaction?
a) 50min b)100 min
c)150min d)200min
13. The half-life periods of a reaction at
initial concentrations 0.1 mol/L and
0.5mol/L are 200s and 40s
respectively. the order of the reaction
is:
a) 1 b) ½ c) 2 d) 0
14. The half-life of a substance is 50min at
a certain initial concentration. when
the concentration is reduced to one-
half of its initial concentration, the
half-life period is found to be 25min.
calculate the order of reaction.
a) 1 b) ½ c) 2 d) 0
15. During the study of kinetics of
chemical or nuclear reaction, t1/3 can
be defined as:
a) 1/3rd of reaction molecules are left
b) 2/3rd of reaction molecules are left
c) 1/3rd of half of reaction molecules
are left
d) 1/3rd of 2/3rd reaction molecules
are left