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Minerals Engineering xxx (2012) xxx–xxx

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Minerals Engineering
journal homepage: www.elsevier.com/locate/mineng

The effect of frother type and dosage on flotation performance in the presence
of high depressant concentrations
Jenny Wiese ⇑, Peter Harris
Centre for Minerals Research, University of Cape Town, South Africa

a r t i c l e i n f o a b s t r a c t

Article history: The use of high dosages of polysaccharide depressants in order to depress the undesired naturally float-
Available online xxxx able gangue (NFG) present in ores beneficiated from the Bushveld Complex, South Africa, results in a sig-
nificant decrease in the stability of flotation froths. These unstable froths can result in restricted mass pull
Keywords: and decreased valuable mineral recovery. Previous work using a single polyglycol ether type frother,
Precious metal ores DOW 200, has shown that an increase in frother dosage could be used to overcome the destabilisation
Froth flotation of the froth to a certain extent and improve valuable mineral recovery. This resulted in an increase in
Flotation depressants
water recovery and dilution of the concentrate by entrained material. This work extends this study to
Flotation frothers
examine the effect of using a stronger frother, DOW 250, on the recovery of sulphide minerals and float-
able gangue from a Merensky ore at different dosages of guar gum and CMC, which are typically used as
depressants in the processing of Merensky ore. Results indicate that an increase in the strength of the
frother resulted in a more robust froth. Depressant type also had an influence on results obtained.
Ó 2012 Elsevier Ltd. All rights reserved.

1. Introduction CMC for any equilibrium concentration. Parolis et al. (2008)


showed that the adsorption of CMC on talc was enhanced by the
The presence of naturally floating gangue (NFG) in ores mined presence of Ca++, Mg++ and K+, commonly found in the recycle
from the Bushveld Complex, South Africa, can result in negative process water of Merensky flotation circuits.
effects during the flotation process. The presence of NFG, which The use of high depressant dosages invariably results in a
consists mainly of pyroxene associated with talcaceous minerals, marked decrease in froth stability due to the depression of froth
results in the stabilisation of the froth and although present in stabilising NFG (Bradshaw et al., 2005; Martinovic et al., 2005;
small amounts (0.5–5% by mass in the ore) can cause these un- Wiese, 2009). This could restrict solids recovery and result in de-
wanted effects. That these minerals are naturally floatable is due creased valuable mineral recovery. Low mass pulls may be over-
to the presence of talc along pyroxene grain boundaries (Becker come by an increase in frother dosage (Wiese et al., 2010), but
et al., 2006; Jasieniak and Smart, 2009). Increasingly, concentrators could result in problems further downstream. Valuable mineral
processing ores containing significant quantities of NFG are mak- grade and recovery are strongly dependent on the stability of the
ing use of high depressant dosages to minimise the recovery of froth since the recovery of entrained gangue is directly
these undesirable minerals and to increase the grade of the con- proportional to the amount of water recovered (Engelbrecht and
centrate. The two polysaccharide depressants most widely used Woodburn, 1975; Zheng et al., 2006a,b; Neethling and Cilliers,
in PGM flotation are guar gum and carboxymethyl cellulose 2002). A froth stability which is too low can, however, result in a
(CMC). The CMC molecule has a high negative charge density, loss in the recovery of valuable minerals and the inability to trans-
and when used at high concentration results in a strong negative port material for further processing. The polyglycol ether range of
charge as it adsorbs on particles resulting in significant dispersion. frothers has strong surface activity, and their molecular weight
The guar gum molecule has a very low charge density and does not (MW) and carbon chain-length determine their strength and per-
result in dispersed pulps particularly in the presence of the high io- formance (Bulatovic, 2007), with an increase in MW resulting in in-
nic strength waters found in concentrators. Steenberg and Harris creased frothability, but lower selectivity.
(1984), by conducting comparative adsorption studies of CMC, Wiese et al. (2010) using a single polyglycol frother, showed
guar gum and starch depressants on talc showed that starch and that an increase in frother dosage resulted in enhanced valuable
guar gum produced a higher level of adsorption on talc than did mineral recovery. This work extends that study to include the
use of a stronger frother, DOW 250, to determine whether its use
would result in better management of the froth under high depres-
⇑ Corresponding author. Tel.: +27 21 650 2517; fax: +27 21 650 5501.
sant dosages.
E-mail address: Jenny.Wiese@uct.ac.za (J. Wiese).

0892-6875/$ - see front matter Ó 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.mineng.2012.03.028

Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028
2 J. Wiese, P. Harris / Minerals Engineering xxx (2012) xxx–xxx

For this work a Merensky ore containing a significant amount of Table 1


NFG (Becker et al., 2006; Wiese, 2009) was selected and since the Properties of the frothers used in this study.

PGE in this type of ore are strongly associated with the sulphide Frother Description Molecular Supplier
minerals the effect of the increased frother dosages on the recovery weight
of copper and nickel representing the sulphide minerals, chalcopy- Dowfroth Polypropylene glycol methyl 205 Betachem
rite and pentlandite may be assessed. The investigation into the ef- 200 ether
fects on PGE recovery is beyond the scope of the current paper. Dowfroth Tri-polypropylene glycol methyl 260 Betachem
250 ether
2. Experimental details

An ore from the southern section of the Merensky Reef in the were conducted in the absence of depressant where NFG was pres-
Bushveld Igneous Complex, South Africa was prepared at UCT (Wi- ent. All NFG was depressed at a depressant dosage of 500 g/t (Wi-
ese et al., 2007) for use in batch flotation tests. The mean copper ese, 2009) and this allows for the determination of gangue
(Cu), nickel (Ni) and sulphur (S) values for the ore were calculated recovered by entrainment. At a depressant dosage of 250 g/t it
using the concentrate and tailings values obtained from all the has been determined (Wiese et al., 2010) that the amount of NFG
batch flotation tests and are as follows: Cu 0.087 wt.%, Ni recovered in the concentrate is of the same order as that of en-
0.247 wt.%, S 0.367 wt.%. The NFG content of the ore sample was trained gangue reporting to the concentrate.
approximately 8%. All batch flotation tests were conducted using Two phase batch flotation tests i.e. water and air only, were
synthetic plant water, whereby distilled water is modified by the conducted using DOW 200 and DOW 250 at the same dosages as
addition of various chemical salts to contain total dissolved solids were used in the three phase tests (water, air and solids). The re-
of 1023 ppm (Wiese, 2009). sults of these tests are shown in Fig. 1. Greater amounts of water
Batch flotation tests were conducted using a method developed were recovered from tests using DOW 250 than from tests using
at UCT (Wiese, 2009). 1 kg portions of the ore sample were milled DOW 200 as the frother indicating that DOW 250 is the stronger
at 66% solids in synthetic plant water to achieve a grind of 60% frother of the two. The volume of froth obtained in these tests, as
passing 75 lm using a laboratory scale stainless steel rod mill. indicated by the water recovery, was substantially greater than
The milled slurry was transferred to a modified 3 L Leeds flotation that obtained from tests conducted in the presence of solids. This
cell. The volume in the cell was made up to produce 35% solids is as a result of the destabilising effects of the solids even in the ab-
using synthetic plant water. The flotation cell was fitted with a var- sence of a depressant where the maximum amount of froth stabil-
iable speed drive and the pulp level was controlled manually by ising NFG was present or possibly the adsorption of frother onto
the addition of synthetic plant water. The impeller speed was set the solids (Lotter et al., 2003).
at 1200 rpm. Results for total mass and water recovered for the various con-
The frothers, Dowfroth 200 (DOW 200) and Dowfroth 250 ditions using DOW 200 and DOW 250 at increasing dosages in the
(DOW 250), supplied by Betachem were added at dosages of 40, presence of guar gum at dosages of 0, 250 and 500 g/t are pre-
50 and 60 g/t. The collector, sodium isobutyl xanthate (SIBX), sup- sented in Fig. 2. Care should be taken in assessing the recovery of
plied by Senmin was added to the mill prior to grinding at a dosage solids as their recovery is dependent on the amount of water
of 150 g/t. The polymeric depressants used in the batch flotation recovered. In the absence of a depressant the amount of water
tests were Depramin 267, a carboxymethylcellulose (CMC) sup- recovered by both frothers was similar and the amounts of solids
plied by AKZO Nobel Functional Chemicals and Stypres 504, a mod- recovered may thus be compared. Greater amounts of solids were
ified guar gum supplied by Chemquest. The MW of Depramin 267 recovered from tests using DOW 200 than from equivalent tests
used in this study was 325,000 g/mol, and that of Stypres 504 was using DOW 250. This may be associated with the influence of the
230,000 g/mol. The depressants were added at dosages of 250 and frother on NFG. The system was dominated by the presence of
500 g/t. Depressants were made up every second day at dosages large amounts of NFG and the destabilising effects of the sulphide
corrected for active content. Tests were also conducted in the ab- minerals were overridden. Guar gum addition at a dosage of 250 g/
sence of a depressant. The chemical salts used in making up the t resulted in differences in the amount of water recovered, in that
synthetic plant water were obtained from Merck. (see Table 1). for equivalent dosages, DOW 250 always achieved higher water
The general formula for DOW 200 is CH3(C3H6O)3OH, and that recoveries than DOW 200. At a guar gum dosage of 500 g/t, gangue
of DOW 250 is CH3(C3H6O)4OH. Both frothers are totally soluble reporting to the concentrate was via entrainment alone as all NFG
in water. was depressed at this dosage. For all conditions an increase in
The air supply to the flotation cell was maintained at a flow rate frother dosage resulted in an increase in the stability of the froth
of 7 L/min in all tests and the froth height was kept constant at as indicated by increased water recovery. DOW 200 at a dosage
2 cm throughout. Four concentrates were collected at 2, 6, 12 of 60 g/t achieved similar water recoveries to DOW 250 at a dosage
and 20 min of flotation time by scraping the froth into a collecting of 50 g/t. For the Merensky ore used in this study the changes in
pan every 15 s. A feed sample was taken before and a tailings sam- water recovery on increased guar gum dosage were not large when
ple was taken after each test. Water recoveries were measured for compared to tests conducted in the absence of a depressant. How-
each test. Feeds, concentrates and tails were filtered, dried and ever, the mass of solids reporting to the concentrate was reduced
weighed before analysis. All batch flotation tests were conducted when guar gum dosage was increased from 250 to 500 g/t.
in duplicate. Error bars showing standard error between duplicate Statistical analysis using t tests of the data presented in Fig. 2 at
tests are included in figures. Copper and total nickel analysis of all the 10% significance level determined that the increases in the
samples was done using a Bruker S4 Explorer XRF spectrophotom- amounts of mass and water recovered when the frother dosage
eter. Sulphur analysis was carried out using a LECO S 632 sulphur was increased from 40 to 60 g/t at all depressant dosages for both
analyser. frothers were significant. Differences in the recovery of solids be-
tween the two frothers were significant only in the absence of a
3. Results and discussion depressant, whereas differences in water recoveries were signifi-
cant at depressant dosages of 250 and 500 g/t.
In order to determine the effect of the presence/absence of NFG Fig. 3 presents the results obtained for total mass and water
on the frothing behaviour upon increases in frother dosage, tests recovered for the various conditions using DOW 200 and DOW

Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028
J. Wiese, P. Harris / Minerals Engineering xxx (2012) xxx–xxx 3

1600
DOW 200
DOW 250
1400

1200

Cumulative water, g
1000

800

600

400

200

0
40 50 60
Frother dosage, g/t

Fig. 1. Cumulative water recovered for DOW 200 and DOW 250 from batch flotation tests conducted in the absence of solids.

Fig. 2. Final mass and water recovered for guar gum at dosages of 0, 250 and 500 g/t in the presence of DOW 200 and DOW 250 at dosages of 40, 50 and 60 g/t.

Fig. 3. Final mass and water recovered for CMC at dosages of 0, 250 and 500 g/t in the presence of DOW 200 and DOW 250 at dosages of 40, 50 and 60 g/t.

250 at increasing dosages in the presence of CMC at dosages of 0, the stability of the froth in comparison to the results obtained for
250 and 500 g/t. The addition of CMC resulted in a decrease in guar gum. High dosages of CMC result in dispersed pulps and at

Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028
4 J. Wiese, P. Harris / Minerals Engineering xxx (2012) xxx–xxx

a dosage of 250 g/t it is be expected that some degree of dispersion may have been some interaction of DOW 250 with NFG in that the
would be present. At this dosage slightly more froth was obtained increase in frother chain-length has led to an adsorption of the
from tests using DOW 250 than from DOW 200, which is evidence frother onto NFG which may have resulted in some NFG depres-
of it being a stronger frother. The destabilising effects of CMC are sion. In testwork conducted by Lotter et al. (2003) it was shown
more evident at the fully dispersive conditions at a dosage of using ToF-SIMS (time of flight secondary ion mass spectrometry)
500 g/t where tests conducted in the presence of DOW 200 re- that DOW 250 had an affinity for Mg silicates in that these particles
sulted in very low froth stability. A procedure developed at UCT were covered by a surface layer of DOW 250. Surrounding sulphide
to evaluate the coagulative/dispersive nature of a mineral pulp mineral particles were unaffected. NFG recovery for DOW 200 from
was used to determine the extent to which particle aggregates a feed mass of 1 kg ranged from 50 to 80 g depending on the froth-
were formed in a suspension of pulp at the depressant types and er dosage and that for DOW 250 from 45 to 70 g. The figure illus-
dosages evaluated. The procedure utilised an image analysis tech- trates that at a depressant dosage of 500 g/t there was, by
nique to measure the transmission of light through a mineral slur- definition, total depression of NFG. An attempt was made to mea-
ry with the same characteristics as the pulp phase used in the sure the residual concentration of frother in solution, but the re-
batch flotation tests i.e. 35% solids and a particle size distribution sults obtained were inconsistent.
of 60% passing 75 lm. In the absence of depressant there was an The analysis of the response of the sulphide minerals to frother
almost immediate settling of suspended particles as indicated by type and dosage in this study was determined by following the
the transmission of light through the suspension. In the presence recovery of copper and nickel. Some of the nickel present in Meren-
of Stypres 504 at both dosages evaluated there was a steady in- sky ore is associated with gangue minerals and total nickel recov-
crease in the transmission of light through the suspension during eries obtained are lower than the sulphide nickel recoveries would
the course of the experiment. This was indicative of aggregation be expected to be. In this work total nickel recoveries were suffi-
of particles. In the presence of Depramin 267 full dispersion of cient to monitor pentlandite behaviour (Brough, 2008; Wiese,
the pulp over the course if the experiment was indicated by zero 2009).
transmission of light through the suspension for both dosages eval- Fig. 6 presents final copper recoveries and grades for all dosages
uated in this study. of DOW 200 and DOW 250 in the presence of all dosages of guar
The increase in dosage of DOW 200 was not sufficient to devel- gum.
op a robust froth whereas DOW 250 was strong enough to over- Upon observation of the figure it is evident that copper recover-
come the destabilising conditions created by the high dosage of ies were at their maximum in the absence of a depressant with
CMC. The use of DOW 200 at a dosage of 60 g/t yielded lower water similar copper recoveries being obtained for both frothers under
recoveries than DOW 250 at a dosage of 40 g/t. At higher dosages of all conditions. Depressant addition resulted in a decrease in copper
CMC the destabilising conditions are probably as a result of the recovery probably due to the loss of partially liberated copper min-
slime-cleaning properties of CMC which would result in sulphide erals. There was, however, little difference in the recovery of cop-
particles with enhanced hydrophobicity. per when guar gum dosage was increased from 250 to 500 g/t.
Statistical analysis using t tests of the data presented in Fig. 3 at The copper grades obtained in the absence of a depressant were
the 10% significance level determined that the increase in the low as a result of dilution by NFG. For all dosages of guar gum
amounts of mass and water recovered from tests in which frother for both frothers, copper recoveries increased with an increase in
dosage was increased from 40 to 60 g/t for tests conducted in the frother dosage. This was accompanied by a decrease in copper
absence of depressant and at 250 g/t using both frothers was sig- grade due to the dilution of the concentrate by gangue. The highest
nificant. At a depressant dosage of 500 g/t this was only true when copper grades were obtained at depressant dosages of 500 g/t
DOW 250 was used as the frother, and for water only. Differences where there is no expectation of NFG recovery to dilute the grade.
in the recovery of solids between the two frothers were significant For all conditions, in the presence of guar gum, higher copper
only in the absence of a depressant. Differences in the recovery of grades were obtained for DOW 200 than for DOW 250. This has
water between the two frothers were significant only at a depres- been attributed to greater dilution of the concentrate grade by en-
sant dosage of 500 g/t. trained gangue as a result of the increased recovery of water in
The amounts of total gangue recovered as a function of water these tests. The slight differences in recovery obtained between
recovered are compared in Fig. 4 for DOW 200 and DOW 250. DOW 200 and DOW may be within experimental error as it is
The values shown on the figure are for all tests conducted at not expected that frother type would influence copper recovery.
500 g/t depressant dosage irrespective of frother dosage. The gradi- Final copper recoveries and grades for all dosages of DOW 200
ent of the line is equivalent to the entrainment factor and is equal and DOW 250 in the presence of all dosages of CMC are presented
to the amount of entrained material reporting to the concentrate in Fig. 7. The results obtained are similar to those obtained for
per unit water recovered. The values obtained for both frothers equivalent tests conducted using guar gum in that an increase in
are shown in Table 2. More gangue was recovered by entrainment frother dosage resulted in increased copper recovery with a reduc-
when using DOW 250 (3.19 g per 100 ml water) than when using tion in copper grade. The recovery of copper on CMC addition did
DOW 200 (2.92 g per 100 ml water). Values obtained for DOW not decrease as much as in the presence of gaur gum when com-
250 are slightly higher than for DOW 200 for guar gum and CMC. pared to tests conducted in the absence of a depressant. This is
The values obtained for CMC are slightly higher than for guar due to CMC not being as strong a depressant as guar gum with im-
gum, most probably due to full dispersion at the high CMC dosages. proved flotation of the partially liberated copper minerals (Wiese
These differences in the entrainment values would, however, result et al., 2007). Copper recovery was not impaired even at the lowest
in very small differences in the recovery of solids. froth stability conditions i.e. DOW 200 in the presence of CMC at a
Fig. 5 compares the amount of NFG reporting to the concentrate dosage of 500 g/t. The highest copper grades were obtained for
as a function of water recovered for DOW 200 and DOW 250 at all DOW 200 at a CMC dosage of 500 g/t. This is due to the strong
dosages evaluated. The amount of NFG reporting to the concen- destabilisation of the froth when using DOW 200 (see Fig. 2) and
trate in each case was determined using the entrainment factors the full depression of NFG.
as shown in Table 2. Greater amounts of NFG were recovered in Final recoveries and grades obtained for nickel for both frothers
tests using DOW 200 than from tests using DOW 250. This is par- at all dosages in the presence of guar gum at dosages of 0, 250 and
ticularly evident in the absence of a depressant, but the same trend 500 g/t are presented in Fig. 8. As observed with copper the highest
was seen at a depressant dosage of 250 g/t. This suggests that there nickel recoveries accompanied by the lowest nickel grades were

Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028
J. Wiese, P. Harris / Minerals Engineering xxx (2012) xxx–xxx 5

25

y = 0.0319x

20

Total gangue, g
15

y = 0.0292x

10

0
0 100 200 300 400 500 600 700 800
Water, g
Dow 200 Dow 250

Fig. 4. Total gangue versus water recovered for all tests conducted at increasing dosages of DOW 200 and DOW 250.

Table 2
Entrainment values determined for DOW 200 and DOW
grades for the two frothers. At a CMC dosage of 500 g/t in the pres-
250 in the presence of guar gum and CMC at dosages of ence of DOW 200 the recovery of nickel was impaired by froth
500 g/t. crowding under highly destabilised conditions. In these tests there
Frother type Guar gum CMC
was a reversal of the grade, in that the grade increased with an in-
crease in frother dosage which is the complete opposite trend to
DOW 200 0.0292 0.0334
that obtained for both copper and nickel under all conditions eval-
DOW 250 0.0319 0.0356
uated. This condition yielded the lowest froths as indicated by the
lowest water recovery (see Fig. 2). This has resulted in competitive
adsorption between copper and nickel in the highly unstable froth,
with copper floating at the expense of nickel. Under the same con-
obtained in the absence of a depressant. An increase in depressant ditions DOW 250 yielded higher grades and recoveries by over-
dosage resulted in a decrease in nickel recovery. Nickel recoveries coming the destabilising effects of the sulphide minerals as a
were more susceptible to depressant addition than the recoveries result of slime-cleaning. The phenomenon of slime coating re-
of copper. This decrease in nickel recovery was accompanied by moval from sulphide surfaces by CMC is known (Nagaraj and Rav-
an increase in nickel grade. Once again an increase in frother dos- isahnkar, 2007). In the absence of a depressant where there is NFG
age always led to an increase in recovery. As with copper under the present, similar results were obtained for the two frothers.
same conditions the highest grades were obtained using DOW 200 This testwork was carried out using an ore containing NFG in
as the frother. the form of partial talc rims along pyroxene grain boundaries. Fur-
The results obtained for nickel recoveries and grades in the ther work should include the evaluation of an ore with different
presence of CMC are presented in Fig. 9. At a CMC dosage of NFG mineralogy i.e. liberated talc to determine whether this re-
250 g/t there was very little difference in nickel recoveries and sults in differences in the mechanism of froth stabilisation.

90

80

70
Floating gangue, g

60

50

40

30

20

10

0
0 200 400 600 800 1000 1200
Water, g
DOW 200 - No depressant DOW 200 - 250 g/t Depressant DOW 200 - 500g/t Depressant
DOW 250 - No depressant DOW 250 - 250 g/t Depressant DOW 250 - 500 g/t Depressant

Fig. 5. Floating gangue versus water recovered for all tests conducted using DOW 200 and DOW 250 at dosages of 40, 50 and 60 g/t.

Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028
6 J. Wiese, P. Harris / Minerals Engineering xxx (2012) xxx–xxx

Fig. 6. Final copper grades and recoveries for all dosages of DOW 200 and DOW 250 in the presence of guar gum.

Fig. 7. Final copper grades and recoveries for all dosages of DOW 200 and DOW 250 in the presence of CMC.

Fig. 8. Final nickel grades and recoveries for all dosages of DOW 200 and DOW 250 in the presence of guar gum.

Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028
J. Wiese, P. Harris / Minerals Engineering xxx (2012) xxx–xxx 7

Fig. 9. Final nickel grades and recoveries for all dosages of DOW 200 and DOW 250 in the presence of CMC. The reversal of grade obtained using DOW 200 at a CMC dosage of
500 g/t is highlighted.

4. Conclusions Brough, C. 2008 An investigation into the process mineralogy of the Merensky Reef
at Northam Platinum Limited. MSc Thesis. Faculty of Engineering and the Built
Environment, University of Cape Town.
Increased frother dosage, from 40 to 60 g/t, resulted in in- Bulatovic, S.M., 2007. Handbook of flotation reagents. Chemistry, Theory and
creased froth stability (as indicated by water recovery) for all con- Practice, Flotation of Sulfide ores, vol. 1. Elsevier.
Engelbrecht, J.A., Woodburn, E.T., 1975. The effects of froth height, aeration rate and
ditions evaluated. gas precipitation of flotation. Journal of South African Institute of Mining and
The highly destabilised froths obtained using DOW 200 in the Metallurgy, 125–132.
presence of high dosages of CMC depressant resulted in froth Jasieniak, M., Smart, R.St.C., 2009. Collectorless flotation of pyroxene in Merensky
ore: residual layer identification using statistical ToF-SIMS analysis.
crowding with nickel competing with copper for adsorption. The
International Journal of Mineral Processing 92, 169–176.
increased strength of DOW 250 overcame this effect. Lotter, N.O., Kowal, D.L., Tuzun, M.A., Whittaker, P.J., Kormos, L., 2003. Sampling and
Under destabilising conditions DOW 250 showed improved per- flotation testing of sudbury basin drill core for process mineralogy modelling.
formance over that of DOW 200, but under conditions with maxi- Minerals Engineering 16, 857–864.
Martinovic, J., Bradshaw, D.J., Harris, P.J., 2005. Investigation of surface properties of
mum NFG presence there was little difference in their performance. gangue minerals in platinum bearing ores. Journal of the South African Institute
An increase in frother dosage resulted in slightly improved cop- of Mining and Metallurgy 105, 1–7.
per recoveries, with a more marked improvement in the recovery Nagaraj, D.R., Ravisahnkar, S.A., 2007. Flotation reagents – a critical overview from
an industry perspective. In: Fuerstenau, M.C., Jameson, G., Yoon, R.H. (Eds.),
of nickel, but at the expense of grade. Froth Flotation – A Century of Innovation. SME Littleton, Colorado, USA.
Higher amounts of NFG were recovered from tests using DOW Neethling, S.J., Cilliers, J.J., 2002. The entrainment of gangue into a flotation froth.
200 than equivalent tests using DOW 250 in the absence of a International Journal of Mineral Processing 64, 123–134.
Parolis, L.A.S., van der Merwe, R., Groenmeyer, G., Harris, P.J., 2008. The influence of
depressant. This may be due to the adsorption of DOW 250 on metal cations on carboxymethylcelluloses as talc depressants. Journal of
NFG particles. Colloids and Surfaces, A: Physiochemical and Engineering Aspects 317 (1–3),
It should be noted that an increase in frother dosage in a rough- 109–115.
Steenberg, E., Harris, P.J., 1984. Adsorption of carboxymethyl cellulose, guar gum
er circuit could affect downstream circuits.
and starch onto talc, sulphides, oxides and salt type minerals. South African
Journal of Chemistry 37 (3).
Acknowledgement Wiese, J. 2009. Investigating depressant behaviour in the flotation of selected
Merensky ores. MSc Thesis. Faculty of Engineering and the Built Environment,
University of Cape Town.
The members of the UCT Reagent Research Group are thanked Wiese, J., Harris, P., Bradshaw, D., 2007. The response of sulphide and gangue
for providing the financial support for this study. minerals in selected Merensky ores to increased depressant dosages. Minerals
Engineering 20, 986–995.
Wiese, J., Harris, P., Bradshaw, D., 2010. The effect of increased frother dosage on
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Please cite this article in press as: Wiese, J., Harris, P. The effect of frother type and dosage on flotation performance in the presence of high depressant
concentrations. Miner. Eng. (2012), http://dx.doi.org/10.1016/j.mineng.2012.03.028

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