CM011 Reviewer

1. What is the smallest whole number coefficient for carbon dioxide for the following combustion of
isopropyl alcohol.
C3H8O + O2 → CO2 + H2O
A. 6 B. 3 C. 13 D. 4
2. How many grams of oxygen are required to burn 0.10 mole of C3H8
C3H8 + 5O2 → 3CO2 + 4H2O
A. 32 g B. 8.0 g C. 16 g D. 12
3. A combustion reaction produces 49.4 g of CO2. Determine the number of moles of carbon dioxide
present.
A. 0.882 moles B. 0.891 moles C. 1.12 moles D. 1.78 moles
4. How many moles of CaCO3 would have to be decomposed to produce 129 grams of CaO?
CaCO3 → CaO + CO2
A. 2.3 B. 1.86 C. 2.00 D. 1.75
5. A compound contains sulfur, oxygen, and chlorine. Analysis shows that it contains by mass 26.95% Sulfur
and 59.61% chlorine. What is the simplest formula for this compound?
A. SOCl2 B. SOCl C. SO2Cl2 D. SO2Cl
6. A 25.00 mL sample of NaOH solution is neutralized by exactly 18.92 mL of 0.3193 M HCl. What is the
molarity of the NaOH solution?
A. 0.4219 M B. 1.481 x 10-3 M C. 0.2416 M D. 6.041 x 10-3 M
7. What is the mass of 0.432 moles of C8H9O4?
A. 169 g B. 73.0 g C. 391 g D. 86.9 g
8. Determine the formula weight of Ca3(PO4)2.
A. 279 amu B. 215 amu C. 310 amu D. 230 amu
9. A compound contains carbon, oxygen, and hydrogen. Analysis of a sample showed that it contained by
mass 68.9% carbon and 4.92% hydrogen. What is the simplest formula for this compound?
A. C8H6O2 B. C6H4O3 C. C7H6O2 D. C6H6O2
10. What is the molarity of a solution that results when 3.64 g KCl is dissolved in water and diluted to exactly
200.0 mL?
A. 1.82 M B. 0.0182 M C. 0.102 M D. 0.244 M
11. What is the molarity of 1600 mL of a solution that contains 3.25 g H 3PO4
A. 2.03 x 10-3 M B. 6.90 x 10-3 M C. 2.07 x 10-2 M D. 6.09 x 10-3 M
12. What is the maximum possible quantity of product obtained from a chemical reaction called?
A. Actual yield B. Theoretical yield C. Molecular weight of D. Percent yield
the product
13. Determine the percent by mass potassium present in K2SO4
 A. 28.9% B. 57.9% C. 22.4% D. 44.9%
14. For the reaction given below, how many moles of aluminum will react if 12 moles of Br 2 reacts and 8
moles of AlBr3 are produced?
2 Al + 3 Br2 → 2 AlBr3
A. 4 B. 16 C. 8 D. 12
15. A compound contains only carbon, hydrogen, and oxygen. Analysis of a sample showed that it contained
54.53% C and 9.15% H. Its molecular weight was determined to be approximately 88 g/mol. What is its
molecular formula?
A. C2H4O B. C4H8 C. C4H8O D. C4H8O2
16. Use the data below to calculate the ∆H°f for benzene, C6H6(l), at 25°C and 1 atm.
2C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(l) ∆H° = -6535 kJ
∆H° f(H2O(l)) = -285.8 kJ/mol, ∆H°f (CO2(g)) = -393.5 kJ/mol
A. 49.1 kJ/mol B. 1.76 x 103 kJ/mol C. 103 kJ/mol D. 3.51 x 104 kJ/mol
17. How much heat is released when 75 g of octane is burned completely if the enthalpy of combustion is -
5,500 kJ/mol C8H18.
C8H18+ 25/2O2 → 8CO2 + 9H2O
A. 7,200 kJ B. 3,600 kJ C. 5,500 kJ D. 8,360 kJ
18. Which of the following is not a formation reaction?
A. 4Al+ 3/2O2 → Al2O3 C. H2O+ SO3 → H2 SO4
B. 1/2H2+ 1/2Br2 → HBr D. H2+ 1/2O2 → H2O
19. Which statement concerning sign conventions for ∆E = q + w is false?
A. For heat absorbed by B. For work done by the C. When energy is D. If ∆E is positive,
the system, q is system, w is negative. released by the energy can be written
positive. reacting system, ∆E is as a product in the
negative. equation for the
reaction.

20. Which of the following statements about internal energy, E, is false?

A. It represents all the B. E is positive in C. In some D. In some
energy within a exothermic reactions. processes E = q processes E = q + w
certain amount of
matter.
21. Based on the following thermochemical equation, which statement is false?
NH3(l) → NH3(g) ∆H° = +23.4 kJ
A. The enthalpy change B. The internal energy of C. The thermochemical D. The pressure for the
is endothermic. the surroundings equation represents a process is known.
increases. physical change.

22. The enthalpy change, ∆H, of a process is defined as:

A. The quantity of heat B. The increase or C. The maximum D. The change in
 transferred in or out decrease in amount of useful molecular disorder in
of a system as it temperature in a work that can be a system.
undergoes a change at system. done in a system.
constant pressure.

23. Given the standard heats of formation for the following compounds, calculate the ∆H°rxn for the
following reaction.
CH4(g) +H2O(g) → CH3OH(l) + H2(g)
∆H°f -75 -242 -238 0

A. -594 kcal B. + 79 kJ C. -79 kJ D. + 594 kcal

24. Heating a 25.0 g sample of each substance below with 375 J of energy will cause which substance to have
the greatest increase in temperature?
A. water B. copper C. gold D. iron
(specific heat = 4.184 J (specific heat = 0.385 J (specific heat = 0.128 J (specific heat = 0.451 J
g−1 °C−1 ) g−1 °C−1 ) g−1 °C−1 ) g−1 °C−1 )

25. Which of the following techniques cannot be used to calculate ∆Hrxn?

A. Calorimetry B. Using melting points C. Using of Heats of D. Hess's Law
of reactants and Formation of
products reactants and
products
26. Which of the following statements about voltaic cells is false?
A. A salt bridge B. The cathode is C. Voltaic cells are D. Electrons flow from
maintains electrical positive. spontaneous the cathode to the
contact and charge reactions. anode.
neutrality in the half-
cells
27. Which of the following statements about the operation of a standard galvanic cell made of a Cu/ Cu2+
half-cell and a Zn/ Zn2+ half-cell is false?
A. The mass of the B. The copper electrode C. The [Cu2+] increases. D. The electrons flow
copper electrode is positive. from the copper
decreases. electrode to the zinc
electrode.
28. In voltaic cells, the salt bridge ____?
A. is not necessary in B. is tightly plugged with C. acts as a mechanism D. allows charge balance
order for the cell to firm agar gel through to allow mechanical to be maintained in
work which ions cannot mixing of the the cell
pass solutions.
29. Which one or two substances are reduced in the reaction below?
2 Al + 3 Cl2 → 2 AlCl3
A. Cl2 B. Al and Cl2 C. Al and AlCl3 D. Al
30. Which one of the following statements about the half-cell processes is true for the cell, Cd(s) | Cd2+(aq),
1.0 M || Cu2+(aq), 1.0 M | Cu(s)?
A. Cd2+ is reduced at the B. Cu2+ is reduced at the C. Cd2+ is reduced at the D. Cu2+ is reduced at the
anode. cathode. cathode. anode.
31. In any electrochemical cell, the anode is always _____ .
A. the positive electrode B. the electrode at which C. the electrode at which D. the negative electrode
some species gains some species loses
electrons electrons
32. In an electrolytic cell, the electrode that acts as a source of electrons to the solution is called the ____; the
chemical change that occurs at this electrode is called ______.
A. cathode: reduction B. cathode: oxidation C. anode: reduction D. anode: oxidation
33. Which of the following is the strongest reducing agent?
A. F2 B. Ag C. K D. Cu
34. Which one of the following describes the net reaction that occurs in the cell, Cd(s) | Cd2+(aq), 1.0 M ||
Cu2+(aq), 1.0 M | Cu(s)?
A. Cu + Cd2+→ Cu2+ + Cd C. Cu2++ Cd → Cu + Cd2+
B. Cu + Cd → Cu2+ + Cd2+ D. Cu2++ Cd2+→ Cu + Cd
35. Which of the following is the strongest oxidizing agent?
A. F- B. Mg2+ C. Mg D. F2
36. Which of the following is a nuclear reaction?
A. The production of x- B. Precipitating silver C. The decay of carbon- D. The neutralization of
rays in the dental chloride when silver 14 in dead plant hydrochloric acid by a
office. nitrate is added to a tissue. sodium hydroxide
sodium chloride solution
solution.
37. An element containing 26 protons, 26 electrons, and 30 neutrons will have the symbol:
A. 56Zn B. 82Te C. 52Zn D. 56Fe
38. The nuclear binding energy represents:
A. the amount of energy B. the amount of energy C. the amount of energy D. the amount of energy
that is absorbed from that is released in a that is released if the released in a fusion
protons and neutrons fission reaction. nucleus is formed reaction.
in forming the from initially separate
nucleus. protons and
neutrons.
39. Which isotope below will have the smallest nuclear binding energy per gram? (No calculations are
necessary)
A. 42He B. 168O C. 3216S D. 5525Mn
40. A positron has a mass number of ___, a charge of ____, and a mass equal to that of a(n) ___.
A. 0; 1+; proton B. 1; 2+; proton C. 0; 1+; electron D. 1; 2+; electron
41. Which of the following particles or rays has the greatest penetrating ability?
A. beta particles B. alpha particles C. gamma rays D. protons
42. Complete and balance the following equation: 8536Kr → ____ + 0-1β
A. 8535Kr B. 8537Rb C. 8436Kr D. 8535Br
43. Complete and balance the following equation: 147N +11H → 158O + ____
A. 0-1β B. 0+1β C. 42He D. 00γ
44. Complete and balance the following equation: 4421Sc +21H → ____ + 10n
A. 4521Sc B. 4522Ti C. 4220Sc D. 4621Sc
45. Which of the following statements about two isotope is true?
A. They will have the B. They will have C. They will have very D. They will have the
same atomic mass. different number of different chemical same atomic numbers.
protons. reactivity.
46. The half-life of Kr-79 is 35 hours. What is the value of the specific rate constant, k?
A. 0.639 h-1 B. 0.0571 h-1 C. 24.3 h-1 D. 0.0198 h-1
47. The specific rate constant for the decay of Bi-210 is 0.138 d-1. What is its half-life?
A. 0.20 d B. 2.18 d C. 5.02 d D. 0.096 d
48. What classification of polymer is made from polymerization reaction that produces small molecules (such
as water) as well as the polymer?
A. Condensation B. Elimination C. Natural D. Addition
49. Which of the following is a synthetic polymer?
A. Cellulose B. Polyisoprene C. DNA D. Poly(Vinyl Chloride)
50. Nylon and peptides have which functional group in common?
A. Alcohol B. Ketone C. Amine D. Amide