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+ H+
Conjugate Acid-Base Pairs: Base Acid
- H+
e.g.,
conjugate pair
conjugate pair
more examples:
conjugate acids
conjugate bases
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(b) Amphoteric Substances -- molecules or ions that can
function as both acids and bases (e.g., H2O itself !)
Periodic Table
2
Oxo acids e.g., HNO3, H2SO4, H3PO4, etc.
Periodic Table
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3. Lewis Acid-Base Concept (most general)
H + H
..
H N H H O : + H N H
..
H H
.. -
.. :
H O Lewis acids
.. ..
- -
Lewis H O: H O:
.. ..
base :O C O : :O C O : : O C O:
.. .. .. .. .. ..
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4. Auto-ionization of Water and the pH Scale
equilibrium constant:
Kc = [H+] [OH-] / [H2O]
but, [H2O] ∼ constant ∼ 55.6 mole/L at 25°C
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(c) relative acidity of solutions:
neutral solution
[H+] = [OH-] = 1.0 x 10-7 M
pH = pOH = 7.00
acidic solution
[H+] > 10-7 (i.e., greater than in pure water)
so, pH < 7.00
[OH-] < 10-7 and pOH > 7.00
basic solution
[H+] < 10-7 (i.e., less than in pure water)
so, pH > 7.00
[OH-] > 10-7 and pOH < 7.00
Problem
The water in a soil sample was found to have [OH-] equal to 1.47
x 10-9 mole/L. Determine [H+], pH, and pOH
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5. Strong acids and Bases
Problem
What mass of Ba(OH)2 (171.34 g/mole) is required to prepare
250 mL of a solution with a pH of 12.50?
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6. Weak Acids and Bases
Problem
Hypochlorous acid, HOCl, has a pKa of 7.52. What is the pH of
0.25 M solution of HOCl? What is the percent ionization?
pKa = - logKa
HOCl(aq) H+ + OCl-(aq)
Initial 0.25 0 0
Change -x +x +x
Equil 0.25 - x x x
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now, substitute the appropriate equilibrium concentrations:
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7. Salts of Weak Acids and Bases
K a: HA H+ + A-
K b: A- + H2O HA + OH-
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(c) Salt of a Weak Base (e.g., NH4Cl) -- Acidic Solution
K a: NH4+ H+ + NH3
pH = 4.78 (acidic !)
Problem
The pKa value for HCN is 9.21. What molar concentration of
NaCN is required to make a solution with a pH of 11.75?
[answer: 2.0 M NaCN]
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8. Polyprotic Acids
Problem
Ascorbic acid (vitamin C), H2C6H2O6, is an example of a diprotic
acid with Ka1 = 7.9 x 10-5 and Ka2 = 1.6 x 10-12. For a 0.10 M
solution of ascorbic acid, determine the pH and the concentrations
of the mono anion, HC6H2O6-, and the dianion, C6H2O62-.
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