J Resonence Educating for better tomorrow TARGET : JEE (ADVANCED) 2015 CDAILY PRACTICE PROBLEMS Course : VETA& VIJAY (JPAD & JRAD) Date : 21-04-2015 NO. 05 TEST INFORMATION DATE : 22.04.2015, PART TEST (PT) - 02 Syllabus : Organic : Organic Nomenclature, Isomerism, Stereoisomerism, GOC, POC, Tautomerism, Acids & Bases. Physical : Gaseous State, Solid State, Surface Chemistry, Thermodynamics & Thermochemistry. DPP No. # 05 (JEE-ADVANCED) Total Marks : 170 Max. Time : 137 min. Single choice Objective (~1 negative marking) Q.1 to .14 (3 marks 2% min.) (42, 35] Multiple choice objective (~1 neg: (4 marks, 3 min.) , Assertion and Reason (‘-1" negative marking) Q.20 to Q.22 (3 marks'2% min.) [09, 7%] Comprehension (1 negative marking) Q.23 to @.31 @ marks 2% min) [27, 22%] Single Digit Subjective Questions (no negative marking) .32toQ.39 (4 marks 2% min.) Double Digits Subjective Questions (no negative marking) @.40 to @.41 (4 marks 2% min.) Match the column (4 vs 4) (no negative marking) Q.42 to Q.45 (8 marks, 8 min.) 1 dilNaQH ——> A+NaF +H, : F, + conc. NaOH ——> B+ NaF +H, ‘Aand B respectively are (A) OF and 0, (8) 0, and OF, (©) Both o, (0) Both oF, When F, is passed into a solution of mineral acid X, a greenish yellow gas Y is formed. Which on treating with slaked lime forms "Z". When Red litmus is kept in contact with Z, it changes into (A) Blue colour (®) Nochange in colour (C) White incolour” —_(D) None of these 3. Bywhich of the following methods, H,0, can't be synthesised ? (A) Addition of ice cold H.SO, on BaO., (8) Addition of ce cold H.SO, on PbO, (C) Aerial oxidation of 2-ethyl anthraquinol (0) Electrolysis of (NH,),SO, at a high current density 4. Onhydrolysis of compound A, two acids P and Q forms. P is used in etching of glass, Q on strongly heating gives oxide R. Ris used in estimation of carbon monoxide. A is. (PF, ®IF, (NF, Oar, 5, One gas bleaches the colour of flowers by reduction, while the other by oxidation, the two gases respectively may be (A) CO and ci, (8) HS and Br, (©) NH, and so, (0)SO, andl, 6. SbF, reacts with XeF, to form an adduct. The shapes of cation and anion in the adduct are respectively (A) square planar, trigonal bipyramidal (©) T-shaped, octahedral (C) square pyramidal, octahedral (O) square planar, octahedral 7. Consider the following transformations ® e ()XeF, + NaF —> Na [XeF,F (i) 2PCL(s) —> [PCL [Pclj (UIP [AI(H,O),>* + HO —> [AI(H,O), OH + HO" Possible transformations are (A) | UL Lu Olt olin 8 Which of the following statements are correct about the reaction between the copper metal and concentrated HNO.? (1) The principal reducing product is NO gas. () Cu metal is oxidised to Cu (aq,) ion which is blue in colour. {ll AIIHNO, used act as oxcising agent {) The principal reducing product is NO, gas. (A) LUI (B) I (OLIV (D)All the above arporaTe Oe TC Tost Aa 62K, War Gi Wa, ava RoR iy THOS Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETO10 1. 12. is 14, 15. 16_ wT 48, 19, 20. C1,(g) + Ba(OH), —> X(aq.) + BaCl, + H,0 X+H,SO, —> Y+BaSO, Y Soak Zlgreen) +H,0+0, Y and Z are respectively (A)HCIO,, ClO, ®)HCIO,, clo, ()HCIO,, C10, Q)HCIO,, C10, A substance (P), when heated in a dry test tube, liberated a colourless odourless gas that rekindled a glowing splinter. it may be : (A) KCIO, (@)NaN, (ks0, ()Caco,, Consider the following metallurgical processes ()) Heating impure metal with CO and distilling the resulting volatile carbonyl (b.p. 43°C) and finally decomposition at 150°-200°C to get the pure metal (1) Heating the sulphide ore in air until a partis converted to oxide and then further heating in the absence of airto let the oxide react with unchanged metal sulphide (lll Electrolysis of the motten electrolyte containing approximately equal amounts of the metal chloride and NaCl to obtained the metal The processes used for obtaining magnesium, nickel and copper are respectively. (A) (), i) and (tt) 8) (W), (Mand (}) (©) dil), (and (tl (©) i), () and (tt Give the correct order of initials T or F for following statements. Use Tif statement is true and F if tis false. () In Gold Schmidt's thermite process aluminium acts as a reducing agent. (ii) Mg is extracted by electrolysis of aq, solution of MgCl, (iil) Extraction of Pb is possible by smelting of its oxide. (iv) Red Bauxite is purified by Serpeck’s process. A)TTTE (@)TFFT (FTTT (O)TFTF Sodium carbonate cannot react with (A) MgCl, (aa) (©)CatHco,), ()HS0, @)dryyco, AG® vs T plot in the Ellingham’s diagram slopes downward for the reaction (A)Mg+0,>MgO (8) 2Ag+O.>AgO (C)C+0,>CO (0)CO+0,>Co, ‘Aqueous solution of boric acids treated with salicylic acid. Which ofthe following statements is/are incorrect for the product formed in the above reaction ? (A) no product will be formed because both are acids. (8) products 4-coordinated complex and optically resolvable. (C) product is 4-coordinated complex and optically non-resolvable (0) there are two newly formed five membered rings, NH.(excess) + Cl, —> NH,Cl+A(gas) NH, + Cl,(excess) —> B+HCI Correct statement regarding A and B. (A) Ais highly reactive gas at room temperature. (B) Bond order of gas 'A’is similar to C,? {C) Compound 8’ is explosive. (©) Bond angle of compound Bis higher than bond angle of NF. Select the correct statement(s) regarding reaction of SO, with PCI, (A) Itis a redox reaction. (B) One of the productis sulphuryl chloride (C) Both the products on addition of water produce strongly acidic solutions. (D) Both the products have same hybridisation of central atom. Froth floatation (A)is a physical method of separating mineral from the gangue. (6) isa method to concentrate the ore depending on the difference in wettability of gangue and the ore. (C) is used for the sulphide ores. (©) is.a method in which impurities sink tothe bottom, Na,S.0, is oxidised to Na,SO, by ac, Br, Ol, ()KMno, Statement-4 : Aluminium and zinc metal evolve H, gas from NaOH solution Statement-2 : Several non-metals such as P'S, Cl, etc. yield a hydride instead of H, gas from NaOH. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False. (D) Statement-1 is False, Statement-2 is True. Garporate ice TC Tost RAB 67, Wat Gy Wa Tava RoR oi yO Resonance} ducating for better tomorrow21. 22, Statement-t : Lead, tin and bismuth are purified by iquation method. Statement-2 : Lead, tin and bismuth have low m.p. as compared to impurities (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (8) Statement-1 is True, Statement-2is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2is False. (0) Statement-1 is False, Statement-2 is True. Statement-t : 2PbO, + H,SO, > 2PbSO, + 2H,0 + O, In this reaction H,SO, acts as reducing agent. Statement-2 : If PbO, is considered as lead peroxide then the above reaction is an example of disproportionation. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (8) Statement-1 is True, Statement-2is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2is False. (0) Statement-1 is False, Statement-2 is True. Comprehension # 1 23. 24. A white solid having garlic smell (A) 25> (B) jaan? Ga (C) having rotten fish smell + acid (0) Ais (A)P (White) ©)P (Red) ©P.0, (2) (COOH), With increase in temperature following heating, acid (D) produces the following products in which correct sequence ? (A) Pyro acid , meta acid , anhydride (8) Meta acid , Pyro acid , anhydride (C) Meta acid, anhydride, pyro acid (0) Pyro acid , anhydride , meta acid Comprehension # 2 25. 26. In SF, sulphur is octahedrally hybridized (sp'd’). Hence , it is still having some vacant 34-orbitals to accommodate the nucleophilic attack through the sp'd! (pentagonal bipyramid) hybridization. But the size of sulphuris too small to tolerate the seven co-ordination number. Which of the following product is formed when BeCl, is hydrolysed in alkaline medium ? (A) Be(OH), ©) [Be(oHy.F- (C) [Ber], () None of these The product of hydrolysis of SF, and TeF;, are. and respectively. (A) H.SO, and H.TeO, (@H.SO, andH.Te0, (C)H,SO, and Te(OH), (©)H'S0, and TE(OH), Comprehension # 3 27. 28. A pungent smeliing gas '"X’ is produced when a salt 'P*is treated with concentrated H,SO,. The gas "X' is, coloriess and also give dense white fumes with NH.. The solution of salt P gives white precipitate with AgNO, . The white precipitate dissolves in dilute NH, Gas X gets oxidised by oxygen in the presence of CuCl, to produce gas 'Y" and liquid'Z’ at room temperature. Which of the following is incorrect about gas X ? (A) X react readily with sodium carbonate. © Xis an oxidising agent. (C)X produces acidic solution in water. (0) Xis not oxidised by ferric chloride, Gas Y reacts with hypo solution to produce gas X and species W. Wis Nas @)Na,SO, (©)NaHSO, os Comprehension # 4 29. 30. 31. 32, The mineral colemanite is fused with sodium carbonate, compound (2) is obtained along with white ppt When (Z) reacts with dil. H,SO, gives a compound (A) which on strong heating gives an oxide (C). (C) on reduction with Mg produced (D) and non metal (X). Treatment of chlorine on a mixture of (C) and carbon at high temperature gives a halide (E) which is fuming liquid (D. pt. 13°C) along with a gas (F). (E) is a Lewis acid, @) may be ()H,80, (®)Baco, (©) borax (0)NaBo, (A) and (C) may be @BH,.B (®)BH,,8.0, (©)H.80,,8 (0)H,80,,8,0, (€) and ) willbe : (A)BCI,, CO C10, cc, (©)Boc!, co (scl, col, ‘Among the following, the number of compounds, that can act as dehydrating agent is, Conc. H,S0, , anhyd, CaCl, , Conc. HNO, , CaO , CuSO,,5H,O , P,O, arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow