J Resonence Educating for better tomorrow TARGET : JEE (ADVANCED) 2015 Course : VIJETA& VIJAY (ADP & ADR) Date : 08-05-2015 TEST INFORMATION DATE : 10.05.2015 JPT- 01 (ADVANCED) Syllabus : Full Syllabus DPP No. # 10 (JEE-ADVANCED) Total Marks : 169 Max. Time : 137 min. Single choice Objective (1 negative marking) Q.1 to Q.15 (3 marks 2% min.) (45, 37%] Multiple choice objective (-1 negative marking) Q.16 to Q.20 (4 marks, 3 min.) [20, 15] Assertion and Reason (‘-1" negative marking) Q.21 to Q.23 (3 marks 2% min.) [08, 7%] Comprehension (1 negative marking) Q.24 to Q.32 ( marks 2% min.) [27, 22%] Single Digit Subjective Questions (no negative marking) Q.33toQ.37 (4 marks 2% min.) —_—_[20, 12%] Double Digit Subjective Questions (no negative marking) @.38 10.41 (4 marks 2% min.) —_—[16, 10] Match the column (4 vs 4) (no negative marking) Q.42 to Q.44 (6 marks, 8 min.) [24,24] Match the column (4 vs §) (no negative marking) Q.45 (6 marks, 8 min.) —_[08, 08] 4. Equal volumes of 0.1 M solution of NaCl and 5 M solution of NaCl are kept in a closed vessel (see figure) and temperature is maintained constant. After equilibrium has been established, assuming that volumes are additive, which of the following is (are) true ? (A) Volume of 0.1 M solution is lesser than its original volume (B) Volume of 0.1 Msolution is greater than its original volume ‘O1MNaCl SOM NaCl (C) Volume of 5 M solution is lesser than its original volume (O) No change occurs at all 2 ml of an aqueous urea solution having osmotic pressure as 2.4 alm is mixed with 'V,' ml of another vs aqueous urea solution having osmotic pressure as 4,6 atm at same temperature, What will be value of h if resulting solution after mixing has osmotic pressure as 2.95 atm. wt @15 2 Ory 3, The vapour pressure of two pure liquids X and ¥ which form an ideal solution are 200 and 300 mm of Ha respectively at 300 K. A liquid solution of x’ and "Y" in which the mole fraction of 'X'is 0.5 is contained in a cylinder closed by a piston on which pressure can be varied- (A) Only if pressure above solution is less than 200 torr, vapour phase can exist. (B) Only if pressure above solution is less than 300 torr, vapour phase can exist. (C) Only if pressure above solution is more than 200 torr, liquid phase exist. (O) Only if pressure above solution is less than or equal to 250 torr, vapour phase can exist [Corporate Otfice + OG Tower, AAG & 62, PIA, Neat Giy Wall, Jhalawar Road, Kota (Raj) W24005 Resonance} ducating for better tomorrow10. n. 12. A student prepares 2 M, 50 mL HCI solution in water. He drops some of the solution which he compensates with pure water, the resultant soluton was found to be isotonic with 3.2 M urea solution, How much of the original solution (in mL) was dropped ? as 10 15 ()20 A solution containing large amount of A and water is steam distilled. The condensate hence obtained contained 0.25 mole fraction of A. The external pressure at which distillation is performed is (P,” =740 tor and temperature is same.) (A) 760 tor (8)791.3torr (©) 986.67 torr (0) 886.9 torr What is the % decrease in vapor pressure with respect to solution when saturated solution of Ag,PO, is prepared » Given Ky ofAGPO,= |g) “10”? (Assume no hydrolysis) (A) 6 x 10-4 (8) 1.5% 104 (9x 104 (0) 18 10+ How many grams of sucrose (molecular mass= 342) should be dissolved in 100 gm water in order to produce a solution with 105°C difference between the freezing point and boiling point at 1 atm? (K,= 2K kgimol and K, = 0.5 K kg/mol) (A) 34.29 (8)68.4g ©1719 (0) 342g Which one of the following statement is false ? (A) Raout’s law states that the vapor pressure of a component over a solution is proportional to its mole fraction in solution (8) The osmotic pressure (x) of a solution is given by the equation x = CRT (C = molarity of solution) (©) The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl, > KCI> HF (©) Two glucose solutions of same motality prepared in diferent solvents will have the same boiling point elevation. ‘The Henry's law constant for dissolution of a gas in aqueous medium is 3 x 10° atm. At what partial pressure 5 Of the gas (in atm) the molality of gas in aqueous solution will be 55 ? (A) 10+ atm, (8)3. atm (©)0.3.atm (0) 10.atm Addition of water to which ofthe following equilibria causes it to shift in the backward direction? (A) CH.NH, (aq) + H:0 (0) = CH:NH;" (aq) + OH- (aa) (B) AGC! (5) = Ag" (aq) + Cl (aa) (C) HEN (aq) + H,0 (0) == H,0" (aq) + CN (aq) (D) [Cr(dien),}* (aq) + 3H,0 (¢) + 3CI (aq) ==> [Cr (H,0),Cl.] (aq) + 2dien (aq) AL57°C, gaseous dinitrogen tetraoxide is 50% dissociated. Calculate the standard free energy change per mole of N;O, (g) at this temperature and at 1 atm intial pressure of NO, (R= 8.3,JK"' mot" , In 10=23, log 2=0.3, log 3= 0.48) (a)-756 J mor (®)- 856 J mor (C)-656 J mor" (O) None of these For the equilibrium CaCO, (s) => Ca0s) + CO, (g), the pressure of CO, depends on (A) the mass of CaCO, (s) © the mass of Ca0(s) (C) The masses of both CaCO,(s) and CaO(s) _(D) ternperature of the system arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow13. 14, 16. 16. 47. 18. Forthe reaction, NH,HS(s) ——> NH,(g)+H,S()__—_K, = 1228 (torr)? Ina vessel, NH,(@) at a partial pressure of 50 torr and H,S(Q) ata partial pressure 20 torris taken. After a long time, the total pressure of gas in the vessel becomes (A) 80 torr (®)less than 70 torr (C)7Otorr (©) =76 tor ‘Two moles of gas, are mixed with two moles of gas B, in a flask of volume 1 lt. Ifat equilibrium 0.5 moles of A, are obtained. Then find out K, for reaction Az (9) + By (@) == 2AB @) (ayiz (Bo os (0) 36 For which of the following reactions, K, > K, at 298 K (A) XeF (a) == Xe@) + 3F, @) (8) N, (@) + 0,0) == 2NO @) (©) $N@+ Hy (@) —= NH) (©) CO@) + H,0 (@) + CO, (@) +H.(@) A substance ‘A’has the following variation of vapor pressure with temperature for its solid state and liquid state. Identify the options which are correct Given for solid A: logyP = 47002 For iqud A: ogg = 9.5 ~ 1900 where P is in mm of Hg and T in (A) Triple point temperature of substance’A’ is 1000 K (8) AH, willbe approximately 9.212 Kcal/mol (C) AH.sen Will be approximately 9.212 Kcal/mol (0) dH,s, wil be approximately 6.909 Kcal/mol An ideal binary liquid solution of A and B has a vapour pressure of 900 mm of Hg. Itis distilled at constant 2 temperature til of the original amount is distiled, Ifthe mole fraction of ‘A’ inthe residue and mole fraction of Bin the condensate is 0.3 and 0.4 respectively and vapour pressure of residue is 860 mm of Ha, then which ofthe following is/are correct options (A) The initial mixture taken should be an equimolar mixture of A and B. (B) The first vapors formed will have more moles of A as compared to moles of B. (©) Px" = 1000 torr () The vapor pressure above the condensate is 920 torr at same temperature. 10 mlof FeC,0, solution requires 30 ml of 0.4 MKMnO, solution in acidic medium for titration. 25 ml of the same FeC;O, solution is mixed in some water to make a solution containg 900 g of water. Which of the following is/are true for this solution ? (K; for water = 1.8/K kg/mol) (A) Freezing point of the solution is 0.2 K (B) The RLVP of the solution is 2x10 (©) Osmotic pressure of the initial FeC,O, solution is 49.2 atm at 300 K. (D) Osmotic pressure of the initial KMnO,, solution (without acid) is 19.68 atm at 300 K. arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow