as Resonence Educating for better tomorrow TARGET : JEE (ADVANCED) 2015 DAILY PRACTICE PROBLEMS Course : VIJETA & VIJAY (ADP & ADR) —_Date : 14-04-2015, TEST INFORMATION DATE : 15.04.2015, PART TEST-01 (PT-01) Syllabus : Mole concept, Equivalent Concept, lonic equilibrium, Electrochemistry, Inorganic Nomenclature, Periodic table, Chemical bonding and Coordination compounds. DPP No. # 03 (JEE-ADVANCED) Total Marks : 170 Max. Time : 139 min. Single choice Objective (~1 negative marking) Q.1 to Q.15 (3 marks 2% min.) [45, 37%] Multiple choice objective (~1 negative marking) Q.16 to @.21 (4 marks, 3 min.) [24, 18] Assertion and Reason ('-1' negative marking) Q.22 to 0.24 (3 marks'2% min.) _[09, 09] Comprehension (~1 negative marking) Q.25 to Q.32 (3 marks 2% min.) [24,20] Single Digit Subjective Questions (no negative marking) Q.33 to Q.40 (4 marks 2% min.) _[32, 20] Double Digits Subjective Questions (no negative marking) Q.41 (4 marks 2% min.) [04, 2%] Match the column (4 vs 4) (no negative marking) Q.42 to Q.45 (8 marks, 8 min.) [32,32] 4. Which of the following compounds might be useful to the chemist trying to increase the optical purity of the (@ sample ? OK a) Ho” 2. Sumoftotal number of chiral centres (x) and total number of pairs of enantiomers (y) for following structure is : ol 2 B)3 o-4 Os 3. Determine the absolute configurations of the chiral centres in the following compound. (Aa=Rib=S (B)a=Rib=R (a=S;b=8 4. The binaphthol (Bnp) is: Z (A) an optically active compound having chiral centre a (B) an optically inactive compound 28 (©) ameso compound (D) an optically active compound without having chiral centre arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay RESONSNCE brennan Em ucating for better tomorrow areas TEGO TON EEG WHOS BSE SESS] CON, USSICART5. The element(s) of symmetry present in the following molecule is/are on, 4 on, 4 on, 4 () Alternating axis of symmetry Wy Plane of symmetry (Ill) Axis of symmetry (IV) Centre of symmetry (A) Land It (8) land ill (C)I, Wand tl (D)1, 11 Mhandiv 6. Which ofthe following structure has incorrect IUPAC name Me. Me “ ° 2-Brome-5,5dimethylyclopent-2-en-1-one Br No, cHo. ® 6-Methoxy-t-ntrocyctohex-t-ene Z ofl 6-(Cyclobut-2-eny))hex-2-ene CONH, Br oO TS 2-Bromo-6-nitrosobenzenecarboxamide 2 7. Howmany possible isomeric alkenes give 2,2-Dimethylpentane on catalytic hydrogenation as (BS cs (os 8. Onder of enolic content ©: oO ; en 0 90 P Q Ay R s UY 1 Ss JUL ()P>Q>R>S @P>S>R>Q_ C)R>S>P>Q_—D)S>R>P>Q 9% Write the total number of benzenoid structural isomers of molecular formula C,H,O, which can give Fehling test 2 (6)3 C4 1 Me Me Mey te Me Me 10. Me Me No, No, o a Dipole moment of above compound will be (1-441: 1-6.87D @1-6870; 11-41 (C)1-4.11D 5 1-4.11D0 (D)1-6.87D;1-0D eoipeate OWICe © GS Tovar KAGE EPR Wot ly Wal, Talat Road, Kola Ry SEE Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETO11. Which of the following compound is most stable ? ® oh? me » ££ Pe 42. Which statement about the following equilibrium is true ? pow + no = (A) The equilibrium favours the products (C) Waters the weaker acid (0) t-Butoxide is stabilized by resonance 7 43. Which of the following has lowest pk, value? “Ore ®) Oy-er-O) © oS >} O20 44, The heat of hydrogenation for 3-methylbutene and 2-pentene are ~30 kcal/mol and ~28 keal/mol respectively. The heats of combustion of 2-methyibutane and pentane are ~784 kcal/mole and ~782 kcal/mol respectively. All the values are given under standard conditions. Taking into account that combustion of both alkanes give the same products, what is AH (in kcal/mol) for the following reaction under same condtions ? ~~ ees (ayo @-4 ©-2 2 MeN: :NMe, 4,84lrathyamino) hapihalene Its basic strength is 10” more than 1, 1-dimethyl amino napthalene. Reason for high basic strength is (A) Resonance (©) Steric inhibition of Resonance (©) Ortho effect (©) Hyperconjugation 46. (C,H,0,) is molecular formula of many acids containing an aromatic ring also, (A) The total numberof carboxylic acids (with one benzene ring) is 4 (B) Out the three Toluic acids, the ortho isomer is the strongest acid. (C) All these Toluic acids are weaker acids than benzoic acid. (©)Allthese are weaker acids than H,CO. Garprate ice TC Tost ASH BT PIR War Gy Wa Tay Ron Roe oly Resonance} ducating for better tomorrow