agent (VX) https //wiw.cbdcom.apge..-k/safety/meds/vxi.html “ty MATERIAL SAFETY DATA SHEET LETHAL NERVE AGENT (VX) SECTION I - GENERAL INFORMATION DATE: 14 September 1988 REVISED: 28 February 1996 MANUFACTURER'S ADDRESS: U.S. ARMY CHEMICAL BIOLOGICAL DEFENSE COMMAND EDGEWOOD RESEARCH DEVELOPMENT, AND ENGINEERING CENTER (ERDEC) ATTN: SCBRD-ODR-S ABERDEEN PROVING GROUND, MD 20101-5423 Emergency telephone # s: 0700-1630 EST: 410-671-4411/4414 ‘After: 1630 EST: 410- 278-5201, Ask for Staff Duty Officer CAS REGISTRY NUMBERS: 50782-69-9, 51848-47-6, 53800-40-1, 70938-84-0 CHEMICAL NAME: O-ethyl-S-(2-iisopropylaminoethyl) methyl phosphonothiolate ‘TRADE NAME AND SYNONYMS: Phosphonothioic acid, methyl-, S-(2-bis(1-methylethylamino)ethyl) 0-ethyl ester O-ethyl S-(2-diisopropylaminoethyl) methylphosphonothiolate §-2-Diisopropylaminoethyl O-ethyl methylphosphonothioate $-2((2-Diisopropylamino)ethyl) O-ethyl methylphosphonothiolate O-ethyl S-(2-diisopropylaminoethyl) methylphosphonothioate O-ethyl S-(2-diisopropylaminoethy!) methyithiolphosphonoate $-(2-diisopropylaminoethyl) o-ethyl methyl phosphonothiolate Ethyl-S-dimethylaminoethy! methylphosphonothiolate Vx EA 1701 TX60 CHEMICAL FAMILY: Sulfonated organophosphorous compound FORMULA/CHEMICAL STRUCTURE.Nerve Agent (VX) https //www.cbdcom.apge. sk/eafety/msde/vx1. html FORMULA/CHEMICAL STRUCTURE: C11H26NO2PS cH, /CHCH,), [Po S-CHCH SN, CH,CH,O CH(CH,), NEPA 704 HAZARD SIGNAL: Health - 4 Flammability - 1 Reactivity - 1 Special - 0 SECTION Il - HAZARDOUS INGREDIENTS AIRBORNE INGREDIENTS PERCENTAGE BY EXPOSURE FORMULA WEIGHT EXPOSURE LIMIT (AEL) VX C1IH26NO2PS 100% 0.0001 mg/m3 SECTION Ill - PHYSICAL DATA BOILING POINT : 298 C (568 F) VAPOR PRESSURE (mm Hg): 0.0007 @ 20 C VAPOR DENSITY (AIR=1): 9.2 FREEZING/MELTING POINT : Below -51 C LIQUID DENSITY (g/cc): 1.0083 @ 20 C PERCENTAGE VOLATILE BY VOLUME: 10.5 mg/m3 @ 25 C SOLUBILITY: Slightly soluble in water at room temperature, Soluble in organic solvents. APPEARANCE AND ODOR: Colorless to straw colored liquid & odorless, similar in appearance to motor oil. SECTION IV - FIRE AND EXPLOSION DATA a FLASHPOINT: 159 C (McCutchan - [emp 4Nerve agent (VX) http: //www.cbdcom.apge.. -k/safety/meds/vx1.htm FLASHPOINT: 159 C (McCutchan - Young) ad FLAMMABILITY LIMITS (% by volume): Not Available LOWER EXPLOSIVE LIMIT: Not Applicable UPPER EXPLOSIVE LIMIT: Not Applicable EXTINGUISHING MEDIA: Water mist, fog, foam, CO2. Avoid using extinguishing methods that will cause splashing or spreading of the VX. SPECIAL FIRE FIGHTING PROCEDURES: All persons not engaged in extinguishing the fire should be immediately evacuated from the area. Fires involving VX should be contained to prevent contamination to uncontrolled areas. When responding to a fire alarm in buildings of areas containing VX , fire fighting personnel should wear full firefighter protective clothing (without TAP clothing) during chemical agent firefighting and fire rescue operations. Respiratory protection is required. Positive pressure, full face piece, NIOSH-approved self-contained breathing apparatus (SCBA) will be worn where there is danger of oxygen deficiency and when directed by the fire chief of chemical accident/incident (CAI) operations officer. In cases where firefighters are responding to a chemical accident/incident for rescue/reconnaissance purposes they will wear appropriate levels of protective clothing (See Section vin). Do not breathe fumes, Skin contact with nerve agents must be avoided at all times. Although the fire may destroy most of the agent, care must still be taken to assure the agent or contaminated liquids do not further contaminate other areas or sewers. Contact with liquid VX or vapors can be fatal UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. SECTION V - HEALTH HAZARD DATA _ ‘AIRBORNE EXPOSURE LIMITS (AEL): The permissible airborne exposure concentration for VX for an 8-hour workday of a 40-hour work week is an 8-hour time weighted average (TWA) of 0.00001 rmg/m3. This value can be found in "AR 40-8, Occupational Health Guidelines for the Evaluation and Control of Occupational Exposure to Nerve Agents GA, GB, GD, and VX." To date, however, the ‘Occupational Safety and Health Administration (OSHA) has not promulgated a permissible exposure concentration for VX. ‘VX is not listed by the International Agency for Research on Cancer (IARC), American Conference of Governmental Industrial Hygienists (ACGIH), Occupational Safety and Health Administration (OSHA), or National Toxicology Program (NTP) as a carcinogen. EFFECTS OF OVEREXPOSURE: VX is a lethal cholinesterase inhibitor. Doses which are potentially life-threatening may be only slightly larger than those producing least effects, Death usually occurs within 15 minutes after absorption of a fatal dosage. Vx