Documente Academic
Documente Profesional
Documente Cultură
ACRYLONITRILE-BUTADIENE- STANDARD
STYRENE PLASTICS FOR MOLDING 55234
(ABS)
normazione Page: 1/16
Date: 01/30/2002
PURPOSE
TMD
This Standard covers requirements for rigid plastics consisting of three different monomers:
acrylonitrile, butadiene and styrene (ABS) produced in both normal and reinforced types.
Code
Annex 1 lists the trade names of the three plastics: acrylonitrile - butadiene - styrene qualified
B
by FIAT Auto according to the various classes.
These materials, except where otherwise specified in drawing are not binding, though must be
Ch.
considered as Supplier's preferential choice.
9
Edition
Change Date Description
= Oct. '84 Edition 7 -Melt-index value changed for types SA 85.200 B, SA 90.150
B, SA 100.120 B (were 23 to 25, 7 to 9, 3 to 4) and deleted for
types : SA 90.40 B, SA 105.75. (PS)
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
Class ABS 90.170 LOG added. (FD)
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
A Feb. '94 Low" thermal resistance value for ABS 90.170 LOG changed to Medium" THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
and methods for reaction to chemical agents testing specified. (FD)
= Sept.'96 Edition 9 -Test method for measuring Volumic mass" and new materials
in Annex 1 added. (FD)
CONFIDENTIAL
ANY PRINTED COPY IS TO BE DEEMED AS UNCHECKED; THEREFORE THE UPDATED COPY MUST BE CHECKED IN THE APPROPRIATE WEB SITE
1
GENERAL
Thermoplastic resins covered herein consist of three monomers: acrylonitrile, butadiene and
styrene (ABS).
By varying the ratio of the three polymers it is possible to obtain materials with different thermal,
physical and mechanical properties:
- acrylonitrile provides good chemical resistance;
- butadiene provides toughness and impact strength;
- Styrene provides stiffness and heat resistance.
These are amorphous polymers that are easy to process and particularly suitable for the producĆ
tion of thin articles with large dimensions, dimensionally stable with good resistance and resilĆ
ience.
Results of surface finishing processes such as painting, vacuum metallization, chromium plating
and hot embossing are good.
2
INDICATIONS ON DRAWING
3
CLASSIFICATION/USE
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
The table below gives the FIAT Denominations", corresponding ISO" codes and certain apĆ
plications according to Class.
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
DENOMINATION
APPLICATION EXAMPLE
FIAT ISO
- Metallic finished trims
ABS 85.180
CONFIDENTIAL
4
MARKING OF MATERIALS FOR RECYCLING
Unless otherwise specified on drawing, marking must be undertaken directly during moulding
adopting the ISO denominations indicated in the schedule at § 3, in compliance with Std. 07416.
5
PROPERTIES
With the exception of fluidity and charge content (obtained from granules), the characteristics
given in the tables are obtained from injection moulded samples, under ideal transformation conĆ
ditions (defined with the Manufacturers) and conditioned for at least 24 hours at 23±2 °C with 50%
R.H. Readings of the mechanical properties on samples obtained from articles may NOT conform
to the values indicated, being influenced by the moulding conditions of the component and the
sample zone; values up to -2 °C with respect to nominal values are considered acceptable for
the Vicat scale.
Exclusively regarding fluidity, values up to +30% max. on the article with respect to those indiĆ
cated, are still acceptable. The listed values refer to natural or black coloured materials. DependĆ
ing on specific requirements, materials with different fluidity may be utilised provided that the
parties are agreed.
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
CONFIDENTIAL
5.1
Non reinforced materials
ABS 85.180
High impact
PROPERTIES UNITS TEST METHOD
resistance
-
Std. 50430/09
Density g/cm3 1.03 to 1.06
ISO 1183 Met. A
Coefficient of linear thermal expansion 10-6/°C 80 to 100 Std. 50560
values must
be within the
HYSICAL
at -30 °C 2,300
elasticĆ at 23 °C
Modulus of elastic 2,000
ity in flexure (min.) at 60 °C 1,600
at 80 °C N/mm2 1,400 Std. 50555
at -30 °C 85 (velocity = 2 mm/min)
CAL
ANICA
Resistance to flexĆ
flex at 23 °C 55
ECHA
ure (min.) at 60 °C 30
MEC
at 80 °C 25
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
at 23 °C 1.8
IZOD iimpactt at 0 °C J/cm2 1.2 Std. 50559
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
strength (min.)
at -30 °C 0.8
at 23 °C 10.0
Impact resistance
with dropping dart at 0 °C J/mm 5.0 Std. 50424
CONFIDENTIAL
(min ) B
(min.)
at -30 °C 1.5
Distortion temperature underload
85 Std. 50566 - ISO 75
(σf = 18.5 daN/cm2) (min.) F
°C
Std. 50565
RMAL
ABS 85.180
High impact
PROPERTIES UNITS TEST METHOD
resistance
-
Maximum continuous operating temĆ
°C 85 -
perature Y
Good with black
Resistance to light - pigmentation; Std. 50451/01
CTORS
for other
colours compoĆ
compo
NMENTAL FACT
nent stabilisaĆ
tion with prelimĆ
Accelerated ageing by atmospheric inary qualificaĆ
- Std. 50451
agents tion is required
(suffix L).
REACTION TO ENVIRON
Resistance to
petrol, diesel
oil, acid and alĆ
kaline soluĆ
tions, soluble in
Chemical agents - aromatic hydroĆ Std. 50432/01
carbons, chloriĆ
nates, ketones,
acetates atĆ
tacked by oxyaĆ
cids.
Chromatic
co-ordinates
must be within
Colour - Std. 50430/05
the limits of the
qualified mateĆ
rial
Method under
Gloss - -
development
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Data processing code No. (Std. 50022) - 52040 -
B Test velocity 4.43 m/s, impact mass 7.17 Kg and specimen thickness ∼3 mm.
F To be undertaken on sample conditioned for 2 hours at 90°C and after re-conditioning
at 23±2 °C for at least 24 hours.
J To be carried out with a load of 1 daN.
L To be carried out with a load of 5 daN.
Y The maximum continuous service temperature is given in a purely indicative manner, as
it is considerably influenced by form, assembly limitations etc.
Any specific specifications are included in the Procurement Specifications of individual
components.
ABS 95.150
Medium imĆ
PROPERTIES UNITS pact and heat TEST METHOD
resistance
:
Std. 50430/09
Density g/cm3 1.03 to 1.06
ISO 1183 Met. A
Coefficient of linear thermal expansion 10-6/°C 80 to 90 Std. 50560
values must
be within the
HYSICAL
at -30 °C 2,450
elasticĆ at 23 °C
Modulus of elastic 2,200
ity in flexure (min.) at 60 °C 1,750
at 80 °C N/mm2 1,600 Std. 50555
at -30 °C 100 (velocity = 2 mm/min)
CAL
ANICA
Resistance to flexĆ
flex at 23 °C 60
ECHA
ure (min.) at 60 °C 35
MEC
at 80 °C 30
at 23 °C 1.5
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
strength (min.)
at -30 °C 0.5
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
at 23 °C 7.0
Impact resistance
with dropping dart at 0 °C J/mm 3.0 Std. 50424
(min ) B
(min.)
at -30 °C 1.0
Distortion temperature underload
CONFIDENTIAL
ABS 95.150
Medium imĆ
PROPERTIES UNITS pact and heat TEST METHOD
resistance
:
Maximum continuous operating temĆ
°C 90 -
perature Y
Good with black
Resistance to light - pigmentation; Std. 50451/01
CTORS
for other
colours compoĆ
compo
ONMENTAL FAC
nent stabilisaĆ
tion with prelimĆ
Accelerated ageing by atmospheric inary qualificaĆ
- Std. 50451
agents tion is required
(suffix L).
REACTION TO ENVIRON
Resistance to
petrol, diesel
oil, acid and alĆ
kaline soluĆ
tions, soluble in
Chemical agents - aromatic hydroĆ Std. 50432/01
carbons, chloriĆ
nates, ketones,
acetates atĆ
tacked by oxyaĆ
cids.
Chromatic
co-ordinates
must be within
Colour - Std. 50430/05
the limits of the
qualified mateĆ
rial
Method under
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
Gloss - -
development
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Data processing code No. (Std. 50022) - 52047 -
A To be carried out at temperature 220 °C with a load of 10 daN with material dried for 2 h at 100 °C.
B Test velocity 4.43 m/s, impact mass 7.17 Kg and specimen thickness ∼3 mm.
F To be undertaken on sample conditioned for 2 hours at 90°C and after re-conditioning
at 23±2 °C for at least 24 hours.
J To be carried out with a load of 1 daN.
L To be carried out with a load of 5 daN.
Y The maximum continuous service temperature is given in a purely indicative manner, as
it is considerably influenced by form, assembly limitations etc.
Any specific specifications are included in the Procurement Specifications of individual
components.
at -30 °C 2,000
Modulus of elasĆ at 23 °C 1,600
ticity in flexure
((min.)) at 60 °C 1,400
at 80 °C N/mm2 1,300 Std. 50555
at -30 °C 70 (velocity = 2 mm/min)
CAL
ANICA
Resistance to at 23 °C 40
ECHA
flexure (min.) at 60 °C 30
MEC
at 80 °C 20
at 23 °C 1.7
IZOD iimpact at 0 °C J/cm2 1.0 Std. 50559
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
strength (min.)
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
at -30 °C 0.5
Impact
p resistĆ at 23 °C 12.0
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
ance with
ith dropĆ
d
at 0 °C J/mm 4.5 Std. 50424
ping dart (min.)
B at -30 °C 1.0
Distortion temperature underload
90 Std. 50566 - ISO 75
(σf = 18.5 daN/cm2) (min.) F
CONFIDENTIAL
°C
Std. 50565
RMAL
external compoĆ
As specified on Std. 50433/01
Resistance to nents
- drawings or rele
releĆ
combustion internal compoĆ vant standards Std. 50433
nents
Resistance to petĆ
rol, diesel oil, acid
and alkaline soluĆ
tions, soluble in
Chemical agents - aromatic hydroĆ Std. 50432/01
carbons, chloriĆ
nates, ketones,
acetates attacked
by oxyacids.
Chromatic co-orĆ
dinates must be
Colour - within the limits of Std. 50430/05
the qualified mateĆ
rial
Method under
Gloss - -
development
Data processing code No. (Std. 50022) - 52192 -
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
; Values also influenced by component geometry.
= To be carried out at temperature 230 °C with a load of 5 daN with material dried for 2 h at 100 °C.
ABS 100.120
PROPERTIES UNITS High heat TEST METHOD
resistance
Std. 50430/09
Density g/cm3 1.03 to 1.08
ISO 1183 Met. A
Coefficient of linear thermal expansion 10-6/°C 80 to 90 Std. 50560
values must be
within the limits
HYSICAL
at -30 °C 2,750
Modulus of elasĆ at 23 °C 2,300
ticity in flexure
((min.)) at 60 °C 1,900
at 80 °C N/mm2 1,700 Std. 50555
at -30 °C 100 (velocity = 2 mm/min)
CAL
ANICA
Resistance to at 23 °C 65
ECHA
flexure (min.) at 60 °C 40
MEC
at 80 °C 30
at 23 °C 1.2
IZOD iimpact at 0 °C J/cm2 0.7 Std. 50559
strength (min.)
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
at -30 °C 0.4
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Impact
p resistĆ at 23 °C 8.0
ance with
ith dropĆ
d
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
Std. 50565
RMAL
ABS 100.120
PROPERTIES UNITS High heat TEST METHOD
resistance
Maximum continuous operating temĆ
°C 100 -
perature Y
Good with black
Resistance to light - pigmentation; Std. 50451/01
CTORS
for other
colours compoĆ
compo
ONMENTAL FAC
nent stabilisaĆ
tion with prelimĆ
Accelerated ageing by atmospheric inary qualificaĆ
- Std. 50451
agents tion is required
(suffix L).
REACTION TO ENVIRO
Resistance to
petrol, diesel
oil, acid and alĆ
kaline soluĆ
tions, soluble in
Chemical agents - aromatic hydroĆ Std. 50432/01
carbons, chloriĆ
nates, ketones,
acetates atĆ
tacked by oxyaĆ
cids.
Chromatic co-
ordinates must
be within the
Colour - Std. 50430/05
limits of the
qualified materiĆ
al
Method under
Gloss - -
development
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
Data processing code No. (Std. 50022) - 52043 -
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
; Values also influenced by component geometry.
5.2
Reinforced materials
ABS 90.40
PROPERTIES UNITS TEST METHOD
Glass reinforced
Std. 50430/09
Density g/cm3 1.15 to 1.20
ISO 1183 Met. A
Values must be
within the limits of
HYSICAL
Elongation % 2
Tensile strength ISO 527
(min.) Rupture 60 (Sample type I,velocity C)
at -30 °C 5,000
at 80 °C N/mm2 3,000
Std. 50555
at -30 °C 100 (velocity = 2 mm/min)
AL
ANICA
Resistance to at 23 °C 80
flexure
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
ECHA
(min.) at 60 °C 60
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
ME
at 80 °C 40
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
at 23 °C 0.4
IZOD impact
strength at 0 °C J/cm2 0.3 Std. 50559
(min )
(min.)
at -30 °C 0.2
CONFIDENTIAL
at 23 °C 1.5
Impact resistĆ
resist
ance with dropĆ at 0 °C 1.0
J/mm Std. 50424
ping dart
(min.) B at -30 °C 0.5
ABS 90.40
PROPERTIES UNITS TEST METHOD
Glass reinforced
Distortion temperature under load
90 Std. 50566 - ISO 75
(σf = 18.5 daN/cm2) (min.) F
°C
ERMAL
L
°C 100 -
NVI-
temperature Y
RONMENTAL FACTO
REACTION TO ENV
Resistant to petrol,
diesel oil, acid and
alkali solutions solĆ
uble in aromatic hyĆ
Chemical agents - Std. 50432/01
drocarbons, chloriĆ
nates, ketones,
acetates attacked
by oxyacids.
Data processing code No. (Std. 50022) - 52048 -
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
it is considerably influenced by form, assembly limitations etc.
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Any specific specifications are included in the Procurement Specifications of individual
components.
ABS 105.65
High heat resistĆ
PROPERTIES UNITS TEST METHOD
ance glass reinĆ
forced `
Std. 50430/09
Density g/cm3 1.15 to 1.18
ISO 1183 Met. A
Values must be
within the limits of
HYSICAL
Elongation % 2
Tensile strength ISO 527
(min.) Rupture 65 (Sample type I,velocity C)
at -30 °C 5,300
at 80 °C N/mm2 3,600
Std. 50555
at -30 °C 120 (velocity = 2 mm/min)
AL
ANICA
Resistance to at 23 °C 100
flexure
ECHA
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
(min.) at 60 °C 70
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
ME
at 80 °C 50
THE ONLY VALID REFERENCE IS THE ORIGINAL IT ALIAN EDITION
at 23 °C 0.65
IZOD impact
strength at 0 °C J/cm2 0.50 Std. 50559
(min )
(min.)
at -30 °C 0.40
CONFIDENTIAL
at 23 °C 2.0
Impact resistĆ
resist
ance with dropĆ at 0 °C 1.0
J/mm Std. 50424
ping dart
(min.) B at -30 °C 0.5
ABS 105.65
High heat resistĆ
PROPERTIES UNITS TEST METHOD
ance glass reinĆ
forced `
Distortion temperature under load
105 Std. 50566 - ISO 75
(σf = 18.5 daN/cm2) (min.) F
°C
ERMAL
L
°C 105 -
NVI-
temperature Y
RONMENTAL FACTO
REACTION TO ENV
Resistant to petrol,
diesel oil, acid and
alkali solutions solĆ
uble in aromatic hyĆ
Chemical agents - Std. 50432/01
drocarbons, chloriĆ
nates, ketones,
acetates. Attacked
by oxyacids.
Data processing code No. (Std. 50022) - 52121 -
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Y The maximum continuous service temperature is given in a purely indicative manner, as
it is considerably influenced by form, assembly limitations etc.
| § ”A” : REFERENCES
|07416 | Recycling markings for plastic, composite and elastomer components. TFO
|50433/01 | Burn resistance of nonmetallic materials for bodywork exterior components. TMD
|50451 | Accelerated weathering test (Weather-Ometer). TMD
|50451/01 | Accelerated ageing in sunlight. TMD
|50555 | Flexural properties of rigid plastics. TMD
|50567 | Plastics - Melt flow rate determination for thermoplastics by extrusion plastomeĆ
ter. TMD
|55210/01 | Thermoplastics and Thermosetting plastics. Comparative properties and correĆ
sponding ISO standard symbols. TMD
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
-
FIAT CLASSIFICATION MANUFACTURER TRADE NAME
TMD
BASF TERLURAN 978 T
BAYER NOVODUR P2M
Code
ABS 85.180 SINKRAL G323
ENICHEM
SINKRAL B620
GENERAL ELECTRIC CYCOLAC G100
B
BASF TERLURAN 958 I
Ch.
BAYER NOVODUR H 604
DOW MAGNUM 3404
ABS 95.150
9
SINKRAL C433
ENICHEM
SINKRAL F233
Edition
GENERAL ELECTRIC CYCOLAC G360
BAYER LUSTRAN 1500
SINKRAL C423/M3
ABS 90.170 LOG ENICHEM
SINKRAL C333/M2
DOW MAGNUM 3325 MT
BASF TERLURAN 969 T
BAYER NOVODUR H 802
ABS 100.120 DOW ABS 3416
ENICHEM SINKRAL C350
GENERAL ELECTRIC CYCOLAC G366
ENICHEM SINKRAL C142/V4
ABS 90
90.40
40
MAZZUCCHELLI SICOFLEX S302
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
BASF TERLURAN KR2810