PHYSICS, CHEMISTRY AND MATHEMATICS

Class II IIT-JEE Achiever 2016-2017 (ITP) Max. Marks 240

Test  01 (Advanced) Duration 3 hours
Paper II Date 10-04-2016
Instructions
1. This paper consists of three parts. PART  I: Physics, PART  II: Chemistry, and
PART  III: Mathematics. Each part contains 20 questions.

2. Section A: Questions 1 to 8 in each part are mcq’s with one correct alternative and each
question carries (3, 1) marks. Questions 9 to 12 in each part are mcq’s with one or more than
one correct alternatives and each question carries (4, 1) marks.
Section B: Questions 1 to 6 are numerical problems (integer type  0 to 99) and carry (4, 0)
marks each.
Section C: Questions 1 and 2 in each part are on column matching. Each question carry
(8, 4) marks. Each correctly answered subsections [(i), (ii), (iii))] of column  I will carry
equal marks.

Instructions for filling the OMR Sheet:

3. Write your name and Student code with blue/black ball point pen and darken the appropriate
circle under each alphabet/digit.
4. While marking your answers in the OMR sheet, darken the circle/s (in full) as shown in the
example below using Black ball point pen.

WRONG WRONG WRONG CORRECT

xA B C D

A B C D A B C D B C D

5. Folding of OMR’s, stray markings on the OMR’s will lead to rejection during evaluation.
6. Space for rough work is provided in the question paper booklet.
 PART  I: PHYSICS
Section A
Multiple choice questions with one correct alternative
1. A charge Q is uniformly distributed over a non-conducting semi-circular rod of radius R having a charge
q0 placed at the center. The force on q0 is
1 Qq 0 1 Qq 0 3 Qq 0
(A) 0 (B)  (C)  (D) 
2 0 R 2 4 0 R 2 2 0 R 2

2. A proton and a positron are subjected to the same electric field. The ratio of the force acting on them is
(A) 1 : 2 (B) 1 : 1 (C) 1 : 4 (D) 4 : 1

3. A charged particle is projected in the region of uniform electric field. Neglecting any other forces which
of the following trajectories are not possible
(A) straight line (B) parabola
(C) circular (D) all trajectory are correct

4. Five point charges, each of value +q coulomb, are placed on five vertices of a regular hexagon of side
‘L’ meter. The magnitude of the force on the point charge of value ‘q’ coulomb placed at the centre of
the hexagon is (SC)
1 q2 1 q2
(A) directed from q3 to O (B) directed from O to q3
4 0 L2 4 0 L2
1 q2 1 q2
(C) directed from O to q3 (D) directed from q3 to O
40 4L2 40 4L2

5. An isolated proton experiences a force of 8  1014 N towards east in an electric field. Then, the electric
field acting on the electron is
(A) 5  105 NC1 towards east (B) 5  105 NC1 towards west
(C) 5  105 NC1 towards north (D) 5  105 NC1 towards south

6. Two point charges q and 4 q are held at a separation r. The resultant electric field is zero at a point P.
The point P lies on the line joining q and 4 q.
(A) inside, at a distance (r/3) from charge q
(B) outside, at a distance (r/3) from charge q
(C) inside, at a distance (r/3) from charge 4 q
(D) outside, at a distance (2r/3) from charge 4 q

7. Which of the following graphs best represents the variation of electric field E due to a point charge q?

(A) (B) (C) (D)

2IIT1617ITPAT1PCMPII 2
8. A non-conducting ring of mass m and radius R is charged as shown. The charge density, i.e., charge per
unit length is . It is then placed on a rough non-conducting horizontal plane. At time t = 0, a uniform

electric field E  E 0 ˆi is switched on and the ring starts rolling without sliding. The angular acceleration
of ring is
(A) equal in magnitude but opposite it direction if there E0
y
had been no friction acting on the ring +
+
+
(B) half in magnitude to the angular acceleration if there  x

had been no friction 
(C) RE0 along +ve z-axis
(D) 2RE 0 along –ve z-axis

Multiple choice questions with one or more than one correct alternatives

9. A thin wire ring of radius r having mass per unit length  has an electric charge q. A point charge q0 is
placed at the ring’s centre. A small wave pulse is developed in the string then mark the correct option/s
qq 0
(A) the tension in string is
82 0 r 2
qq 0
(B) the tension in string is
4 2  0 r 2
1
 qq 2
(C) the speed of pulse in the string is  2 0 2 
 8  0r 
1
 qq 2
(D) the tension in string is  2 0 2 
 4  0r 

10. A block having mass m = 4 kg and charge q = 50 C is connected to a spring (with force constant
k = 100 Nm1). The block lies on a frictionless horizontal track and a uniform electric field
E = 5  105 Vm1 exists as shown. The block is released from rest when the spring is unstretched
(at x = 0). Then,

(A) The motion of the block is oscillatiory but not simple harmonic E
(B) The motion of the block is SHM
q, m
(C) The amplitude of oscillation is 0.35 m
(D) The amplitude of oscillation is 0.25 m

11. Mark the wrong statement/s regarding charge:

(A) The charge observed on a body varies with the speed of the observer according to expression
q0
q (where c is the speed of light)
v2
1 2
c
1
(B) A charge of  e is not possible at all.
3
(C) Using gold leaf electroscope to check whether a body is charged or not, the body must be brought in
contact with the electroscope.
(D) Two charged metallic spheres can never attract each other.

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12. In a region, the electric field varies along x-axis according to the equation E = P – Qx. A particle having
charge q and mass m is released from point (0, 0). Neglecting gravity mark the correct option/s:
(A) The particle will execute SHM
2P
(B) The maximum displacement along x-axis that particle can attain is
Q
2P
(C) The amplitude of oscillation is
Q
(D) The time period is independent of P

Section B
Numerical problems
1. A point charge q is kept at a point P which is at a distance R (point lying on the perpendicular drawn to
the wire at one of its end) from a semi-infinite uniformly charged wire. (Linear charge density = .).
Find the angle with the horizontal of the direction of its initial acceleration.
2. A negatively charged oil drop is falling with a constant speed in a vertical electric field 2.5  104 NC1.
If the mass of the oil drop is 1.6  1015 kg, the number of excess electrons it carries is
[Assume g = 10 ms2]
3/2
 11 
3. A charge q1  11   109 C is located at the origin in free space and another charge q is at
3
(2, 0, 0). If the x component of electric field at (3, 1, 1) is zero, the magnitude of q is 11  nC. Find .
4. Two mutually perpendicular wires carry charge densities 1 and 2. The electric line of force makes

angle 30 with second wire then 1  x . Find x
2

5. Two identical charged spheres are suspended by strings of equal length. The strings make an angle of
30 with each other. When suspended in a liquid of density 0.8 g cm3, the angle remains the same. If the
density of the material of the sphere is 1.6 g cm3, what is the relative permitivity of the liquid?
6. In the following figure, A and B are two identically charged, non-conducting spheres with charges
q = 3 C and mass m = 10 g each. The sphere A is fixed to a non-conducting rigid support. Sphere B is
connected to A through a silk thread that can oscillate in the vertical plane. Initially the thread (of length
l = 0.1 m) is pulled aside until it makes an angle  = 60 with respect to the vertical. The sphere B is then
16.6
released from this position. The tension in the string is N when the thread is vertical. Find x.
x
1
(Take  9  10 9 N m 2 C  2 and g  10 m s 2 ) .
4πε 0

A +


l

+
  B

2IIT1617ITPAT1PCMPII 4
Section C
Choose the appropriate entry/entries from column II to match each of the entries of the
column I. It is possible that an option(s) in column II may be valid more than once, for a
given entry in column I.
1. Match the entry/entries from column II giving the magnitude and direction of the force on charge Q
represented in various situations shown in column I
Y

Column - I Column - II

q q

(i) q q (P) zero

+Q
q q

q q

(ii) q q (Q) along +X axis

Q
q q

+Q

(iii) (R) along X axis

q q

(iv) q Q q (S) non-zero

(T) Along +Y axis

2. Column – I Column – II
(Physical quantity) (Dimension)
(i) E, electric field (P) MLT3A1
(ii) E, electric flux (Q) ML3T3A1
(iii) 0, permittivity of air (R) M1L3T4A2
(iv) r, relative permittivity (S) dimensionless
(T) None of these

2IIT1617ITPAT1PCMPII 5
 PART  II: CHEMISTRY
Section A
Multiple choice questions with one correct alternative
1. Diazo-isopropane dissociates to hexane and nitrogen. If Pi is the initial pressure of diazo-isopropane and
the system pressure after time t sec is Pt, the partial pressure of reactant at time t
(A) is Pt  Pi . (B) is Pi  Pt .
(C) is 2Pi  Pt . (D) cannot be found since order is not known.

2. The rate constant, activation energy and Arrhenius parameter of a chemical reaction at 25 C are
3  104 s1, 104.4 kJ mol1 and 6  1014 s1 respectively. The value of rate constant as T   is
(A) 2  1018 s1 (B) 6  1014 s1
(C) infinity (D) 3.6  1030 s1
3. For the reaction
1
N2O5  2NO2 + O2 ,
2
  d  N 2 O5  
log    log k  log  N 2 O5 
 dt 
The slope of the line that fits this equation, will be unity if
(A) the order of the reaction is zero (B) the order of the reaction is one
(C) the order of the reaction is two (D) the order of the reaction is three
4. Activation energy of a chemical reaction can be determined by
(A) evaluating k at standard temperature
(B) evaluating velocities of a reaction at two different temperatures using two different [A]0
(C) evaluating rate constant at two different temperatures
(D) changing concentration of reactants
5. The most stable reaction intermediate (X) of following reaction is

NH2 HNO2
OH (X)

+ +
+
OH
(A) OH (B) (C) (D) +
OH OH

6. The reaction intermediate (X) exhibits the characteristics given below

 Under the influence of strong electrical field, moves towards anode
 It is stabilized by delocalizing charge in a conjugate system
 It is aromatic
 Hybridised state of electron rich carbon is sp2 with filled p-orbital.
The reaction intermediate (X) is

(A)
.. (B) (C) (D)
..
.. ..

2IIT1617ITPAT1PCMPII 6
7. The major product (X) of following reaction is
O
H+
X
heat
OH OH
OH O
(A) (B) (C) (D)

8. Consider the following reactions

Br Br
Cl Mg/ether
Cl X
heat

The major product (X) of the reaction is

(A) (B) (C) (D)

Multiple choice questions with one or more than one correct alternatives

9. A dilute hydrogen peroxide solution is allowed to dissociate to water and oxygen in a thermostat at
constant temperature. The volume of oxygen released is measured at constant pressure and temperature.
At time t, the oxygen volume was Vt and at the end of decomposition the volume was V. If the reaction
follows first order kinetics, which of the following statements is true?
(A) The hydrogen peroxide concentration falls off exponentially with time.
V
(B) If k is the rate constant then kt  ln
V  Vt
V
(C) kt  ln t
V
V
(D) kt  ln 
Vt

10. At constant temperature in a closed rigid vessel, the compound (CH3)2CHN = NCH(CH3)2 dissociates to
nitrogen and n-hexane all in gaseous state following first order kinetics. The initial pressure of reactant
only is p0 and at time t, the system pressure is pt. Which of the following statements is true?
(A) pt is always greater than p0. (B) pt is always less than p0.
p0 p
(C) kt  ln (D) kt  ln 0
2 p0  pt pt

11. Which of the following reactions are accompanied by the rearrangement of reaction intermediate?
+
OH H
H+
(A) (B)
OH O
O
OH
OH HNO2
H+ H
(C) (D) Ph NH2 Ph
OH

2IIT1617ITPAT1PCMPII 7
12. In which of the following pairs, both the carbanions are stabilised by resonance?
..
(A) .. and .. (B) .. and

.. ..
(C) .. and (D) and
..

Section B
Numerical problems
1. 75% of a first order reaction was computed in 32 minutes. How long did it take to complete 50% of the
reaction?
2. For the reaction
Cl2 (g)  2NO(g) 
 2NOCl(g)
It is found that doubling the concentration of both the reactants increases the rate by a factor of 8. If only
the concentration of Cl2 is doubled, the rate increases by a factor of 2. The order of the reaction with
respect to NO is
3. To which order of the reaction, the following plot corresponds?

1
(a  x) 2

t
4. The hydrocarbon X is mainly formed when bromoethane is heated with sodium metal in ether. Number
of monobromo derivatives formed (including stereoisomers) when compound (X) and bromine vapours
are exposed to sunlight is ___.
5. A mixture of pentane and chlorine is heated in presence of sunlight. The percentage of secondary
monochloro derivative obtained is 75 %. The selectivity of chlorine towards 2 hydrogen is ____ times
that of 1 hydrogen under the given conditions,
6. Indicate the number of monochloro derivatives formed when butane is heated with chlorine in presence
of sunlight.

Section C
Choose the appropriate entry/entries from column II to match each of the entries of the
column I. It is possible that an option(s) in column II may be valid more than once, for a
given entry in column I.
1. Column  I (Unit of) Column  II (Order of the reaction)
(i) rate is mol dm3 min1 (P) 0
1
(ii) rate constant is s (Q) 1
(iii) rate constant is L mol1 min1 (R) 2
(iv) rate constant is mol L1 min1 (S) 3
(T) 4

2IIT1617ITPAT1PCMPII 8
 2. Column  I Column  II
(Reaction intermediate) (hybridised state of e deficient carbon)
(i) O (P) sp
.
(ii) . (Q) sp2

(iii) (R) sp2/sp3

.

(iv) Ph  C  O (S) sp3
(T) electrically neutral

PART  III: MATHEMATICS

Section A
Multiple choice questions with one correct alternative

 n[n 2 / 3] 
1. The sequence {an} defined by a n   3  where [] is the greatest integer function, converges to
 [n / 6] 
1
(A) 2 (B) 1 (C) 0 (D)
2
x[ x ]
2. lim where [] denotes the greatest integer function
x  1 sin | x |

2 1
(A) (B) (C) sin 2 (D) none of these
sin 1 sin 1
sin x
 1
1 
3. For x  0 ; Lt  (sin x) x     is
x 0 
 x 
(A) 0 (B)  1 (C) 1 (D) none of A, B, C
1
  f (x)   x 3
4. If lim 1   x     e , then f(x) =
x 0
  x 
1
(A) x3 (B) 2x2 (C) (D) none of these
x
1  cos3 x
5. lim 
x 0 x sin x cos x

2 3 3 3
(A) (B) (C) (D)
5 5 2 4
 x, if x  Q
6. The function f (x)   is
1  x, if x  Q
(A) continuous everywhere (B) continuous no where
1
(C) continuous only at x  (D) none of these
2

2IIT1617ITPAT1PCMPII 9
 9 2  1  cos 3x 
7. If f(x) is continuous and f    , then lim f   is equal to
2 9 x 0  x2 
9 2
(A) (B) (C) 0 (D) none of these
2 9
1
8. The number of points at which the function f (x)  is discontinuous is
log | x |
(A) 1 (B) 2 (C) 3 (D) 4

Multiple choice questions with one or more than one correct alternatives

9. lim x ( x  1  x ) equals
x 

ln(1  x)  x 1  cos x
(A) lim (B) lim
x 0 x2 x 0 x2
(1  x)  1 x
(C) lim (D) lim
x 0 x x 0
x  (x 2  2x)

(e x  1)4
10. The value of a for which lim  8 , is
x 0  x2   x2 
sin  2  log e 1  
a   2
(A) 2 (B) 1 (C) 1 (D) 2
11. If the function f(x) defined as
 3 , x0
 1/ x
f (x)   ax  bx 3 
 1   , x0
 x2 
is continuous at x = 0, then
(A) a = 0 (B) b = e3 (C) a = 1 (D) b = ln 3

12. Let f(x) = [x] + [x]. Then for any integer n and k  R  I, . . .
(A) lim f (x) exists (B) lim f (x) exists
xn x k

(C) f is continuous at x = n (D) f is continuous at x = k

Section B
Numerical problems
1
 4 1  3x  x 2  x4 1 
1. lim  2  
  3.   ____
x 1  x  x 1 1 x3 x 3  x 1 
  

cot 1 ( x  a log a x )
2. The value of lim (a  1) is equal to
x  sec 1 (a x log x a )

3. Lt (cos ecx) x is equal to ________

x 0

8  2(cos x  sin x)5

4. Find the value of lim .
x 1  sin 2x
4

2IIT1617ITPAT1PCMPII 10
5. If  and  are the roots of the quadratic equation 4x2 – 44x + 105 = 0, then
1  cos  4x 2  44x  105 
lim 2
 ______
x 
2 x   

 1
 1
6. If f (x)  lim x n  1 , n  0 and f satisfies 18. f    k  f (x)  0, then k =
n 
x

Section C
Choose the appropriate entry/entries from column II to match each of the entries of the
column I. It is possible that an option(s) in column II may be valid more than once, for a
given entry in column I.
1. Column  I Column  II
(i) 1 (P) 6
If f(x) is continuous in [0, 1] and f    2 , then
2
 n 
lim f   
 2 n 1
n 

(ii) If a function f, defined and continuous on [2, 5], (Q) 2

takes rational values for all x and f(4) = 8, then
f(3.7) =
(iii) The number of points in the interval (1, 2), where (R) 3
the function f(x) = [x3 – 3] ([.] denotes the greatest
integer function) is discontinuous, is
(iv) The number of points of discontinuity of the (S) 8
  
function f (x)  [3  2cos x], x    ,  , where
 2 2
[.] denotes the greatest integer function, is

(T) 1

2. Column I Column II
(i)  |x| 
x
(P) lim f (x)  e 2
x 
If f (x)    , then
 | x | 2 
(ii) (1  x)1/x  e (Q) lim f (x)  e 2
If f (x)  , then x 0
x
(iii)  1  5x 2 
1/x 2
(R) lim f (x)  e 2
x 
If f (x)   2 
, then
 1  3x 
(iv) If lim (cos x  a sin bx)1/x  e 2 , then (S) e
x 0 lim f (x)  
x 0 2
(T) ab = 2

***
2IIT1617ITPAT1PCMPII 11
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