ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS

SET – A
APT - 4 080156.1 Ai2TS-1
Time Allotted : 3 Hours Maximum Marks: 312
INSTRUCTIONS
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions

 Attempt ALL the questions. Answers have to be marked on the OMR sheets.
 This question paper contains Three Sections.
 Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
 Each Section is further divided into two Parts: Part – A & Part – B.
 Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
 Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.

B. Filling of OMR Sheet

CLASS XI

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have Only One Correct answer. Each
question carries +4 marks for correct answer and –2 marks for wrong answer.
PART-A (09 – 16) contains 4 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer and
–1 mark for a wrong answer.

(ii) PART-B(01 – 04) contains 4 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +12 marks for all correct answer however
for each correct row +3 marks will be awarded and –1 mark for each row matched incorrectly.

Name of Candidate :

Batch ID : Date of Examination : / / 2 0 1

Enrolment Number :

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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |1

Section – I (CHEMISTRY)
PART– A
(Single Correct Choice Type)

1. A compound H2X with molar weight of 80 g is dissolved in a solvent having density of 0.4 g/mL. Assuming no
change in volume upon dissolution, the molality of a 3.2 molar solution is
(A) 2 (B) 4 (C) 6 (D) 8

2. The compressibility factor of a real gas in the critical state is

3 8 5 4
(A) (B) (C) (D)
8 3 8 5
16 –1
3. When a certain metal was irradiated with light of frequency 4.0 × 10 s , the photoelectrons emitted had
16 –1
three times the kinetic energy as the kinetic energy when irradiated with light of frequency 2.0 × 10 s .
Calculate the threshold frequency (0) of the metal.
16 –1 12 –1 16 –1 12 –1
(A) 10 s (B) 10 s (C) 2 × 10 s (D) 2 × 10 s

4. Choose the incorrect statement:

(A) The noble gases have the highest ionization energy in their respective periods.
(B) Ionization energy: B > Ga  Al > In
(C) Electron gain enthalpy:
 S  S   O  O 
2 2

(D) If ionization energy (IE) and electron gain enthalpy (EA) are taken in eV then electronegativity may be
 I E  EA 
equal to  .
 2 
5. Stability of following hydride is
CaH2, SrH2, BaH2
(A) CaH2>SrH2>BaH2 (B) BaH2>SrH2>CaH2 (C) BaH2>CaH2>SrH2 (D) SrH2>BaH2>CaH2

6. When a gas filled in a closed vessel is heated through 1°C its pressure is increased by 0.4%, the initial
temperature of the gas was
(A) 250 K (B) 2500 K (C) 250°C (D) 25°C

7. A 10 g sample of a mixture of CaCl2 and NaCl, is treated with Na2CO3 to precipitate the calcium as CaCO3.
This CaCO3 is heated to convert all the calcium to CaO and the final mass of CaO is 1.62 grams. The
percentage by mass of CaCl2 in the original mixture is:
(A) 15.2% (B) 32.1% (C) 21.8% (D) 11.07%

8. What is the strength of 22.4 ‘V’ H2O2 in g/L? [ V  volume strength]

(A) 34 (B) 3.4 (C) 68 (D) 7.2

space for rough work

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Comprehension Type
Paragraph for question Nos. 09 to 10
2+
The hydrogen-like species Li is in a spherically symmetric state S1 with one radial node. Upon absorbing
light the ion undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the
ground state energy of the hydrogen atom.

9. Energy of the state S1 in units of the hydrogen atom ground state energy is
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50

10. The orbital angular momentum quantum number of the state S2 is

(A) 0 (B) 1 (C) 2 (D) 3

Paragraph for question Nos. 11 to 12

The amount of energy released when an electron is added to an isolated gaseous atom to produce a
monovalent anion is called electron affinity. First electron affinity is assigned a negative sign as the addition of
–
an electron to a neutral atom in an exothermic process. The addition of electron to A required energy to
overcome the force of repulsion. Thus the second electron affinity is an endothermic process.

11. Which of the following processes is endothermic in nature?

 
(A) O  e   O2  
(B) Cl  e  Cl 
 
S
(C) S  e 

(D) F  e 
F 

12. The electron affinities of halogens are (in kJ/mol)

F = –332, Cl = –349, Br = –324, I = –295
The highest value of Cl as compared to that of F is due to
(A) higher atomic radius of F (B) smaller electro negativity of F
(C) weaker electron repulsion in Cl (D) more vacant p-subshell in Cl

Paragraph for question Nos. 13 to 14

Methyl isocyanate (CH3NCO) is used to make certain pesticides. In December 1984, water leaked into a tank
containing this substance at a chemical plant, producing a toxic cloud that killed thousands of people in
Bhopal.

13. How many  and  bonds are present in the structure of methyl isocyanate?
(A) 6, 2 (B) 4, 2 (C) 2, 6 (D) 6, 3

14. Specify the hybridization of both carbon atoms in methyl isocyanate?

3 2 3 2 3
(A) sp , sp (B) sp , sp (C) sp, sp (D) sp, sp

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Paragraph for question Nos. 15 to 16

According to Dalton’s law of partial pressures, the total pressure of a mixture of non-reacting gases is equal to
the sum of the partial pressures of the constituent gases.

15. 500 mL of N2 gas at a pressure of 700 mm Hg and 600 mL of O 2 gas at 800 mm Hg are passed into 2 L flask
at the same temperature. Calculate the total pressure of the mixture of gases (in mm Hg)
(A) 215 (B) 350 (C) 415 (D) None of these

16. In a mixture of CO2 and H2 gases, the partial pressure of CO2 is 0.4 atm. If the total pressure is 2 atm, what is
percentage composition of the mixture by volume?
(A) CO2  20%, H 2  80% (B) CO2  70%, H 2  30%
(C) CO2  40%, H 2  60% (D) CO2  10%, H 2  90%

PART – B
(Matrix Match Type)

1. Match the gases under specified conditions listed in the Column-I with their properties or laws in Column-II
Column-I Column-II
(A) Hydrogen gas (P = 200 atm, T = 273 K) P. Compressibility factor 1
(B) Hydrogen gas (P~0, T = 273 K) Q. Attractive forces are dominant
(C) CO2 (P = 1 atm, T = 273 K) R. PV = nRT
(D) Real gas with very large molar volume S. P(V–nb) = nRT

2. According to Bohr’s theory,

En = Total energy, Kn = Kinetic energy
n
Vn = Potential energy, r = radius of nth orbit
Match the following
Column-I Column-II
(A) Vn P. 0
?
Kn
(B) r n  Enx , x  ? Q. –1
(C) Angular momentum in lowest orbital R. –2
(D) 1 S. 1
n
 Z y, y  ?
r
T. 2

3. Match the compounds (in Column-I) with the structures (in Colum-II).
Column-I Column-II
(A) (CH3)3B P. Square planar
(B) NH4Cl Q. Trigonal bipyramidal
–
(C) [ICl4] R. Tetrahedral
(D) PCl5 S. Trigonal
T. Ionic

4. Match the equivalent weight of compounds given in Column-II with the corresponds given in Column-I (where
M stands Molar mass)
Column-I Column-II
(A) MgCl2 P. M/2
(B) Al2Cl6 Q. M/6
(C)  NH  SO Fe  SO  .24H O R. M/8
4 2 4 2 4 3 2

(D) Fe2O3 S. M/3

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Section – II (MATHEMATICS)
PART– A
(Single Correct Choice Type)

1. Let 2 x  3 y  0 be a given line and P  sin  ,0  and Q  0,cos  be two points. Then P and Q lies on the
same side of the given line if  lies in the quadrant
(A) I , II (B) II , III (C) II , IV (D) III , IV

2. If the sum of the slopes of line 4 x 2  2 | k | xy  7 y 2  0 is equal to the product of the slopes then sum of all
possible values of k
(A) 4 (B) - 4 (C) 2 (D) 0

3. The maximum value of sin  cos x  is equal to

1 1
(A) 1 (B) (C) sin1 (D) sin
2 2

 1 
If  cos 2 x   1  tan 2 y   3  sin 3z   4 then y can take values equal to
2
4.
 cos x 
2

   
(A) (B) (C) (D)
4 3 2 6

5. Area of the triangle formed by the line x  y  3 and angle bisectors of the pair of straight lines
x2  y 2  2 y  1 is
(A) 2 sq. units (B) 4 sq. units (C) 6 sq. units (D) 8 sq. units

  3    6  
The value of expression 3 sin 4      sin   3   2 sin      sin   5  is
4 6
6.
  2     2 
(A) 0 (B) 1 (C) sin 2 (D) cos 2

 5 7
7. The value of expression sin  sin  sin is equal to
18 18 18
1 1 1
(A) (B) (C) (D) can’t determine
2 4 8

8.  
Let P   1,0  , Q   0,0  , R  3,3 3 be three points then the equation of the bisector of the angle PQR is

(A) 3x  2 y  0 (B) x  3 y  0 (C) 3x  y  0 (D) 2 x  3 y  0

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Comprehension Type
Paragraph for question Nos. 09 to 10

A triangle ABC is given where A  1,1 and the orthocentre = (2, 4). Also sides AB and BC are member of the family
of lines ax  by  c  0 where a, b, c are in A.P. then
9. The vertex B is
(A)  2,1 (B) 1, 2  (C)  1,2  (D)  2,1
10. Triangle ABC is/are
(A) right angled triangle (B) acute angled triangle
(C) obtuse angled triangle (D) equilateral triangle

Paragraph for question Nos. 11 to 12

x, y, z are respectively the sines and p, q, r are respectively cosines of the angles  ,  ,  which are in AP. with
2
common difference
3
11. yz  zx  xy is equal to
3 3
(A) p  q  r (B) x  y  z (C)  (D) 
4 8

12. Value of x
2
 qy  rz   y 2  rz  px   z 2  px  qy  is equal to
3 3
(A) 0 (B) x  y  z (C) p  q  r (D)
8

Paragraph for question Nos. 13 to 14

 
Consider f n     2cos  1 2cos 2  1 2cos 2   1 ...... 2cos 2
2
      1
n 1

13. The value of f n   is equal to
2cos  2n    1 2cos  2n    1 2cos  2n    1 2cos  2n    1
(A) (B) (C) (D)
2cos  1 2cos   1 2cos  1 2cos  1

 15 
14. The value of f 5   is equal to
 4 
   3
(A) 3cot (B) 3tan (C) cot (D) tan
8 8 8 8

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Paragraph for question Nos. 15 to 16

If the lines represented by 2 x 2  5xy  2 y 2  0 be the two sides of a parallelogram and the line 5x  2 y  1 be one of
its diagonal.
15. The equation of the other diagonal is
(A) 10 x  11y  0 (B) 11x  10 y  0 (C) 3x  2 y  0 (D) 2 x  3 y  0

16. The coordinate of mid point of diagonal is

 5 11   11 5   5 11   11 5 
(A)  ,  (B)  ,  (C)  ,  (D)  , 
 72 36   72 36   36 72   36 72 

PART – B
(Matrix Match Type)
1. .
Column I Column II
(A)  3   3  (P) 1
If cos  x    sin  x    sin  x  32  
 2   2  3
18cos  x  19   cos  x  56   9sin  x  17 
b
 a sin x  b cos x then the value of is
a
(B) 1   2 1   2 (Q) 2
If cos1  2cos2 then tan tan is
2 2
(C) If  sin x  cos x   k sin x cos x  1 holds  x  R (R)
2
1
then the value of k is 3
(D) 4  (S) 2
If cos  then the value of tan is
5 2

2. ABC is a right angled triangle at C and the angles A, B, C are in AP

Column I Column II
(A) sin A  sin B  sin C (P) 1
(B) cos A  cos B  cos C (Q) 3
(C) sin 2 A  sin 2B  sin 2C (R) 3 3
2
(D) cot B cot C  cot C cot A  cot Acot B (S) 3 1
2

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3
Column I Column II
(A) If 2a  b  2c  0  a, b, c  R  then the (P)  2, 1
family of lines ax  by  c  0 is concurrent
at
(B) If the lines x  3 y  2  0, 3x  2 y  5  0 (Q) 1 3
and ax  by  3  0 are concurrent then  , 
2 2
ordered pair  a, b  can be
(C) The coordinates of a point which is at a (R)  2,1
1
distance of units from (1, 1) in the
2
direction of x  y  3  0 is
(D) The family of lines  3    x  1  5  y (S)  1
1, 
7 1     0    R  is concurrent at  2

4. If A  2a,4a  and B  2a,6a  are two vertices of a triangle ABC and the vertex C is given by
Column I Column II
(A)  4a,5a  (P) equilateral
(B)
 2  3  a,5a  (Q) right angled

(C)  6a,4a  (R) obtuse angled

(D)  a,3a  (S) isosceles

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Section – III (PHYSICS)

PART– A
(Single Correct Choice Type)

1. If average speed of lion for a day is 1296 km/day. Then its speed can also be expressed as
(A) 108 km/hr (B) 15 m/s (C) 30 m/s (D) 72 km/hr

A x
2. In the expression of potential energy of a particle U  , where x is distance from origin and A and B
x2  B
are constants
 5

(B) Dimensional formula of B   L 
2
(A) Dimensional formula of A   ML2 T 
3

 

2
3
 2  3

(C) Dimensional formula of A / B   ML T  2
(D) Dimension formula of AB   ML2 T 
   

3. If A  2iˆ  ˆj  kˆ and B  iˆ  ˆj  kˆ are two vectors, then a vector having magnitude 4 2 and
  ˆj  kˆ 
(A) perpendicular to A & B both is 4  ˆj  kˆ   (B) perpendicular to B is 
 2 


iˆ  ˆj  kˆ
(C) collinear with A is
2

1 ˆ ˆ ˆ
2i  j  k  (D) collinear with B is
3

4. In the following figure, the incorrect relation is C

(A) A  B  E  0
(B) C  D   A B
D A
(C) B  E  C   D
(D) B  E  C  D  0
E

5. The displacement of a body from a reference point is given by, x  2t  3, then

(A) Particle will at rest at t  2
(B) Motion is uniformly accelerated
(C) Motion is non-uniformly accelerated
(D) Particle will cover a distance of 8 m in 2 sec

6. The velocity time graph of a particle moving in a straight line is v(m/s)

given in the following figure. Which of the following is incorrect?
2 15
(A) acceleration of particle at t = 9sec is -2.5 m/s
2
(B) acceleration of particle at t = 16 sec is 5/8 m/s 10
(C) displacement during first 10 sec is 135 m
(D) displacement during first 10 sec is 105 m 5

t(s)
4 8 12 16 20

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7. The maximum height attained by a projectile is 4 m and horizontal range is 12m. Then
0
(A) Angle of projection is 37
(B) Velocity of projection is 5 5 m / s
(C) Time of flight is 4sec
(D) Minimum velocity during its flight is 4 5 m / s

2
8. A body has initial velocity of 3 m/s along +x-axis and has an acceleration of 1 m/s along +y-axis. Then
(A) Path followed by body will be parabola
(B) Path of the body can not be predicted with the given information
(C) Velocity of the body will be 5 m/s after 2 seconds
(D) Velocity of the body will be 7 m/s after 4 seconds
Comprehension Type
Paragraph for question Nos. 09 to 10

If a particle is moving along a curved path. Then component of acceleration along velocity is known as tangential
acceleration and perpendicular to velocity is known as normal acceleration. Now consider a particle with velocity
4iˆ  3 ˆj and acceleration 10 ˆj . Then
9. Tangential acceleration vector is

(A)
5

6 ˆ
4i  3 ˆj  (B) 
5

6 ˆ
4i  3 ˆj  (C)
5

8 ˆ
4i  3 ˆj  (D) 
8 ˆ
5

4i  3 ˆj 
10. Magnitude of normal acceleration is
(A) 10 (B) 6 (C) 8 (D) 5 2

Paragraph for question Nos. 11 to 12

A body is dropped from a balloon moving up with a velocity of 4 m/s, when balloon is at a height of 120.5 m from the
2
ground. (g = 9.8 m/s )

11. The height of the body from the ground after 5 sec
(A) 12 m (B) 8 m (C) 102.5 m (D) 18 m

12. The separation between body and balloon after 8 sec will be
(A) 122.5 m (B) 100.5 m (C) 152.5 m (D) 132.5 m

Paragraph for question Nos. 13 to 14

0
To a stationary man rain appears to be falling at his back at an angle 30 with the vertical. As he starts moving forward
with a speed of 0.5 m/s, he finds that rain falls vertically
13. The speed of rain with respect to stationary man is
3 1
(A) 0.5 m/s (B) 1 m/s (C) m/s (D) m/s
2 3

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Ai TS – 1 ( XI ) | SET – A | APT – 4 | P a g e | 10

14. The speed of rain with respect to man when he is in motion

3 1
(A) m/s (B) 0.5 m / s (C) 1m / s (D) m/s
2 3

Paragraph for question Nos. 15 to 16

0
A particle is projected from ground at an angle 60 with horizontal with a
2
speed of 10 3 m/s from point A as shown. At the same time sufficiently g=10m/s
long wedge is made to move with constant velocity 10 3 m / s towards u=10 3 m/s
right from point A as shown. 10 3 m/s 0 0
30 60
A
15. The time after which particle hits the wedge is
(A) 1 sec (B) 2 sec (C) 3 sec (D) 4 sec

16. Maximum separation between particle and inclined surface of the wedge is
5
(A) 5 m (B) 10 m (C) 15 m (D) 3m
2
PART – B
(Matrix Match Type)
1. The projectile collides perpendicularly with the inclined plane.
(Refer the figure)

u


Ground
.
Column I Column II
(A) Maximum height attained by the projectile (P) Zero
from the ground.
(B) Maximum separation attained by the (Q) g
projectile from inclined plane.
(C) Acceleration of the projectile before striking (R) u 2 sin 2 
the inclined plane.
2 g cos 
(D) Horizontal component of acceleration of the (S) u 2 sin 2    
projectile.
2g

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2. Column - I gives some graphs for a particle moving along x-axis in positive x-direction. The variables v, x and
t represent speed of particle. x  coordinate of particle and time respectively. Column-II gives certain
resulting interpretation. Match the graphs in column -I with the statements in column-II

Column I Column II
(A) v (P) Acceleration of particle in uniform

x
v-x graph
(B) v2 (Q) Acceleration of particle is non-uniform

x
v2-x graph
(C) v (R) Acceleration of particle is directly proportional to
't '

t
v-t graph
(D) v (S) Acceleration of particle is directly proportional to
'x' .

t2
v-t2 graph

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3. Both A and B are thrown simultaneously as shown from a very high tower.
Column I Column II
(A) 10m/s (P) Distance between the two balls after two
B seconds is 8 5 m.

A
10m/s

(B) 10m/s (Q) Distance between two balls after 2 seconds is

40 m.
5m/s

(C) 10m/s (R) Magnitude of relative velocity of B with respect

B to A is 5 5 m / s .
0
37
A
10m/s

(D) 10m/s (S) Magnitude of relative velocity of B w.r.t. A is

370
B 5 2 m / s.
370
A
10m/s

4. Match column - I with column - II

Column I Column II
(A) 3 (P)  ML2T 1 
Boltzmann constant  k  , E  kT
2
(B) v (Q)  ML1T 1 
Coefficient of viscosity   , F   A
x
(C) Planck’s constant  h  , E  hf (R)  MLT 3 K 1 
(D) KA  T  t (S)  ML2T 2 K 1 
Thermal conductivity  K  , Q 
l

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