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35m³/t)
TYPES
Coal duff – coal with an upper size of 7mm.
Coal slurry – coal with particles generally under 1mm in size.
Coke – solid residues from the distillation of coal.
Small coal – sufficient particle material below 7mm to exhibit a
flow state when saturated with water.
HAZARDS
1. Spontaneous heating
Coal is liable to spontaneous heating. Freshly mined coal
absorbs O2 forming peroxides which break up into CO &
CO2. This is an exothermic reaction (chemical reaction
giving out heat and light). The heat released causes
further oxidation and more heat. CO has a large
flammable range (12% to 75% by volume) and is also
highly toxic.
3. Corrosion
Many coals contain sulphur. Coals left over from earlier
mining, dumped into fresh water ponds for later retrieval
and shipment, is called “pond coal”. It has a high moisture
and sulphur content. Due to self-heating, pond coal in the
presence of sulphur and moisture can release sulphuric
acid which is highly corrosive to the ship’s holds.
4. Liquification
This is a process whereby moisture in the cargo migrates
to the surface due to compaction and vibration during the
voyage, resulting in the development of a flow state. This
happens particularly when carrying coal slurry, small coal,
even coal duff. The surface of the cargo behaves like a
liquid and a transverse shift of cargo will result in reduced
ship’s stability.