TUGAS 1 KINETIKA DAN KATALISIS KELOMPOK 2 (1 Oktober 2018)

Novelia Ananda Fitrila (1610814120011)

Syarifah Nur Aisyah (1610814120017)
Akrima Nur Amilia (1610814220001)
Hilda Nur Fadhillah (1610814220011)
Malini Soraya (1610814220013)
Dhea Sinta (1610814320003)

1.A reaction has the stoichiometric equation A+B = 2R. What is the order of reaction?
Penyelesaian:
tidak ada data hasil eksperimen dari soal ini, maka dapat diasumsikan reaksi tersebut
ialah reaksi elementer. Orde reaksinya adalah 2 dan laju reaksinya ialah:
-rA= K CA CB

1
2. Given the reaction 2𝑁𝑂 + 2 𝑂2 = 𝑁2 𝑂5 , What is the relation between the rates of
formation and dissapereance of the three reaction components?
Penyelesaian
Hubungan antara laju pembentukan dan laju habisnya dari ketiga komponen tersebut
ialah sebagai berikut:
−𝒓𝑵𝑶𝟐 −𝒓𝑶𝟐 −𝒓𝑵𝟐 𝑶𝟐
= =
𝟐 𝟏⁄ 𝟏
𝟐

3. A reaction with stoichiometric equition ½ A + B = R + ½ S has the following rate

expression
-rA = 2𝐶𝐴0.5 𝐶𝐵
What is the rate expression for this reaction if the stoichiometric equition is written as A + 2B
= 2R + S?
Penyelesaian:
Hal tersebut tidak berpengaruh jika persamaan tersebut ‘disetarakan’ dengan bentuk
yang lain karena laju reaksinya tidak akan berubah.

-rA = 𝟐𝑪𝟎.𝟓
𝑨 𝑪𝑩
4. For the complex reaction with stoichiometry A + 3B → 2R + S and with second order rate
expression:
-rA = k1[A][B]
Are the reaction rates related as follows: rA = rB = rR? If the rates are not so related then how
are they related? Please account for the signs, + or -.
Penyelesaian:
𝟐 𝟏 𝟏
rR = -2rA - 𝟑 rB atau –rA = -𝟑 rB = 𝟐 rR

5. A certain reaction has a rate given by

-rA = 0,005𝐶𝐴2 , mol/cm3·min
If the concentration is to be expressed in mol/liter time in hours, what would be the value and
units of the rate constant?

Penyelesaian:
𝒎𝒐𝒍
-rA = 0,005𝑪𝟐𝑨 𝟏
(𝟏𝟎)𝒍𝒊𝒕∗ 𝒉𝒓
𝟔𝟎

𝒎𝒐𝒍
-rA = 300𝑪𝟐𝑨 𝒍𝒊𝒕.𝒉𝒓

nilai laju konstan = 300

𝒎𝒐𝒍
satuan laju konstan = 𝒍𝒊𝒕.𝒉𝒓

6. For a gas reaction at 400 K the rate is reported as

𝑑𝑃𝐴 𝑎𝑡𝑚
− = 3.66𝑃 A2 ,
𝑑𝑡 ℎ𝑟

a. What are the unit of the rate constant?

b. What is the value of the constant for this reaction if the rate equation is exspressed as

−𝑟 −1 𝑑𝑁𝐴 𝑚𝑜𝑙
𝐴= =𝑘𝐶𝐴2 ,
𝑉 𝑑𝑡 𝑚3.𝑠

Penyelesaian:

a. persamaan dapat ditulis homogen dan orde reaksinya merupakan orde kedua,

maka satuan K adalah:

 K = (time)-1(cons)1-2

K = 3.66(time)-1(cons)-1

b. –rA = k𝑪𝟐𝑨

Pakai Hk. Gas ideal,

PV = nRT

𝒏𝑨 −𝒅𝑷𝑨
PA = 𝑹𝑻 = 𝑪𝑨 𝑹𝑻 → = 𝟑. 𝟔𝟔𝑷𝟐𝑨
𝑽 𝒅𝒕

𝒅𝑪𝑨 𝑹𝑻 𝒅𝑪𝑨
= 𝟑. 𝟔𝟔(𝑪𝑨 𝑹𝑻)𝟐 → = 𝟑. 𝟔𝟔𝑪𝟐𝑨 𝑹𝑻
𝒅𝒕 𝒅𝒕

𝒎𝒐𝒍
-rA = 3.66(0.0820) × 400 × 𝑪𝟐𝑨 (𝒍𝒊𝒕.𝒉𝒓)

𝒎𝒐𝒍
K = 120.13 (hr-1) ( 𝒍𝒊𝒕 )-1