A) Naphthalene + Diphenylamine

Cooling curve graph

100

90

80

70

60
Temperature, °C

50

40

30

20

Time, s
10

0
0 30 60 90 120 150 180 210 240 270 300

Pure Naphthalene N + 0.5g DPA N + 1.0g DPA N + 1.5g DPA N + 2.0g DPA

Graph 1
N-Naphthalene
DPA-Diphenylamine
B) Diphenylamine + Naphthalene

Cooling curve graph

60

50

40
Temperature , °C

30

20

Time, s
10

0
0 30 60 90 120 150 180 210 240 270 300

Pure DPA DPA + 0.5g N DPA + 1.0g N DPA + 1.5g N DPA + 2.0g N

Graph 2
DPA- Diphenylamine
N- Naphthalene
 Phase diagram of naphthalene-diphenylamine system
Diphenylamine Naphthalene
90

80 D

Liquid
70

60

Solid
Naphthalene
Freezing point, °C

50 + Liquid

C Solid Diphenylamine + Liquid

40 E

30

Solid
20 Diphenylami
ne + Solid
Naphthalene
10

0
0 0.25 0.4 0.5 0.57 0.64 0.73 0.84 1
Composition

Phase Diagram Naphthalene-Diphenylamine

 Graph log X vs 1/T for naphthalene
0
0.0125 0.0147 0.0156 0.0182 0.0233
0

-0.05 -0.0757

-0.1
-0.137
Log X

-0.15
-0.194
-0.2
-0.244
-0.25

-0.3
1/T (°C-1)

Graph 3
−0.22−(−0.05)
m=
0.00255−0.00242

= -1307.69

−∆𝐻° 1
log 𝑋 = ( )
2.303 𝑅 𝑇

−∆𝐻°
= 𝑔𝑟𝑎𝑑𝑖𝑒𝑛𝑡
2.303 𝑅

−∆𝐻°
= −1307.69
2.303 𝑥 8.314

∆H° = 25.04 kJ/mol

Thus, heat of fusion for naphthalene is 25.04 kJ/mol