W (mmHg)x

kg NH3/100 kgpNH3 y
Q 40 m3/h Recuperar 90% 60 945 0.38848921 1.24342105 Título del gráfico
T 20 °C 50 686 0.34615385 0.90263158 0.7000
P 1 atm 40 470 0.29752066 0.61842105
G 1664.01118 mol/h 30 298 0.24107143 0.39210526 0.6000
25 227 0.20930233 0.29868421
ARRIBA ABAJO 20 166 0.17475728 0.21842105 0.5000

L0 G1 1139.85 LN GN+1 1664.01 15 114 0.13705584 0.15

Ls Gs 1081.61 Ls Gs 1081.61 10 69.6 0.09574468 0.09157895 0.4000

Lg0 Gg1 58.24 LgN 524.16 GgN+1 582.40 7.5 50 0.07356948 0.06578947
0.3000
x0 0.02 y1 0.051094891 xN yN+1 0.35 5 31.7 0.05027933 0.04171053
X0 0.02040816 Y1 0.0538 XN YN+1 0.5385 4 24.9 0.04063205 0.03276316
0.2000
3 18.2 0.03078677 0.02394737
2 12 0.02073733 0.01578947
0.1000

YN+1 XNYN+1 0.278 0.5385 0.0000

X0Y1 0.02040816 0.0538 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35

(Ls/Gs)min 1.88133052

Ls min 2034.86077

Lsmin 2034.86
Ls/Lsmin 1.35 Título del gráfico
Ls 2747.06 0.7

0.6

ARRIBA ABAJO 0.5

L0 2803.12 G1 1139.85 LN 3327.29 GN+1 1664.01 X Y
Ls 2747.06 Gs 1081.61 Ls 2747.06 Gs 1081.61 Etapas 0.02040816 0.0538 0.4
Lg0 56.06 Gg1 58.24 LgN 580.23 GgN+1 582.40 0.063 0.0538
x0 0.02 y1 0.051094891 xN 0.17438406 yN+1 0.35 0.063 0.16202074 1 0.3
X0 0.02040816 Y1 0.0538 XN 0.21121693 YN+1 0.5385 0.143 0.16202074
0.143 0.36520444 1 0.2

0.234 0.36520444
0.1
0.234 0.59632589 1
XNYN+1 0.21121693 0.5385
0
X0Y1 0.02040816 0.0538 Nteorica 3 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35
pendiente intercepto eficiencia 0.3
2.5397962 0.00201358 Nreal 10
 2.5397962 0.00201358 Nreal 10

0.07

0.06

0.05

0.04

0.03

0.02

0.01

Psat 76 mmHg Q 500000 L/h 0

0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8
P 760 mmHg P 1 atm
K 0.1 T 293.15 K
G 20.80 kmol/h
Recupera 0.95

ARRIBA ABAJO Curva Equilibrio

L0 G1 19.61 LN GN+1 20.80 x y X Y
Ls Gs 19.55 Ls Gs 19.55 0 0 0 0
Lg0 0 Gg1 0.06 LgN 1.19 GgN+1 1.25 0.1 0.01 0.11111111 0.01010101
x0 0 y1 0.003181336 xN yN+1 0.06 0.2 0.02 0.25 0.02040816
X0 0 Y1 0.003191489 XN YN+1 0.06382979 0.3 0.03 0.42857143 0.03092784
0.4 0.04 0.66666667 0.04166667
YN+1 0 0.063829787 X0 Y1 0 0.00319149 0.5 0.05 1 0.05263158
1.6 0.063829787 XN YN+1 0.845 0.06382979 0.6 0.06 1.5 0.06382979
0.62 0.062 1.63157895 0.06609808
Lsmin/Gs 0.0717613

Ls min 1.40

41.0 OJABA ABIRRA

Y X 08.02 1+NG 34.3 NL 16.91 1G 42.2 0L
21.0
2300.0 0 sapatE 55.91 sG 42.2 sL 55.91 sG 42.2 sL
1.0 2300.0 530.0 52.1 1+NgG 91.1 NgL 60.0 1gG 0 0gL
1 21012700.0 530.0 60.0 1+Ny 72306543.0 Nx 633181300.0 1y 0 0x
80.0 2700.0 80.0 97928360.0 1+NY 521825.0 NX 984191300.0 1Y 0 0X
1 49673210.0 80.0
60.0 4210.0 241.0 94191300.0 0 1Y 0X
1 66594910.0 241.0 97928360.0 521825.0 1+NY NX
40.0
5910.0 242.0 otpecretni etneidnep
120.0 64779030.0 242.0 94191300.0 80818411.0
0130.0 534.0
10 53731350.0 534.0
8.1 6.1 4.1 2.1 1 8.0 6.0 4.0 2.0 0 1350.0 20.1
1 39503021.0 20.1

WANKAT 6
D4. We have a steam stripper operating isothermally at 100°C. The entering liquid stream contains
0.0002 mole frac nitrobenzene in water at 100°C. Flow rate of entering liquid is 1 kmol/min. The ETAPAS Curva de equilibrio
entering steam is pure water at 100°C. We desire an outlet liquid mole frac of 0.00001 0.00001 x y X Y Título del gráfico
nitrobenzene. L/V = 12.0. You can assume that total liquid and gas flow rates are constant. At 0.00020004 0.00228048 0 0 0 0 0.003
100°C equilibrium in terms of nitrobenzene mole frac is y = 28 x. Find the outlet mole fraction of 8.12889E-05 0.00228048 0.00001 0.00028 1E-05 0.00028008
the nitrobenzene in the vapor stream and the number of stages. 8.12889E-05 0.00087547 1 0.00002 0.00056 2E-05 0.00056031 0.0025 y = 28.054x
y = 12x - 0.0001
3.12065E-05 0.00087547 0.00003 0.00084 3.0001E-05 0.00084071
0.002
Ls/Gs 12 3.12065E-05 0.00027448 1 0.00004 0.00112 4.0002E-05 0.00112126
9.78391E-06 0.00027448 0.00005 0.0014 5.0003E-05 0.00140196 0.0015
ARRIBA ABAJO 9.78391E-06 1.7407E-05 1 0.00006 0.00168 6.0004E-05 0.00168283
0.001
L0 1 G1 0.083506669 LN 0.99981 GN+1 0.08331667 0.00007 0.00196 7.0005E-05 0.00196385
Ls 0.9998 Gs 0.083316667 Ls 0.9998 Gs 0.08331667 0.00008 0.00224 8.0006E-05 0.00224503 0.0005
Lg0 0.0002 Gg1 0.000190002 LgN 9.9981E-06 GgN+1 0 0.00009 0.00252 9.0008E-05 0.00252637
x0 0.0002 y1 0.00227529 xN 0.00001 yN+1 0 0
0 0.00005 0.0001 0.00015 0.0002 0.00025
X0 0.00020004 Y1 0.002280479 XN 1E-05 YN+1 0
-0.0005

X0Y1 0.00020004 0.00228048

XNYN+1 1.00001E-05 0
 CURVA DE EQUILIBRIO
P 760 0.045

pCl2 gCl2/kgH2O y x X Y 0.04

0 0
0.035
5 0.424 0.00658 0.00011 0.00011 0.00662
10 0.553 0.01316 0.00014 0.00014 0.01333
0.03
30 0.873 0.03947 0.00022 0.00022 0.0411
50 1.106 0.06579 0.00028 0.00028 0.07042 0.025
100 1.573 0.13158 0.0004 0.0004 0.15152
150 1.966 0.19737 0.0005 0.0005 0.2459 0.02
200 2.34 0.26316 0.00059 0.00059 0.35714
250 2.69 0.32895 0.00068 0.00068 0.4902 0.015
300 3.03 0.39474 0.00077 0.00077 0.65217
0.01

0.005

0
0 0.00005 0.0001 0.00015 0.0002 0.00025

OPERACIÓN
Q 50 m3/min
T 30 °C Recupera 75%
P 1 atm
G 2011.4 mol/min

ARRIBA ABAJO
L0 G1 1966.14 LN GN+1 2011.40
Ls Gs 1951.06 Ls Gs 1951.06
Lg0 0 Gg1 15.09 LgN 45.26 GgN+1 60.34
x0 0 y1 0.00767 xN yN+1 0.03
X0 0 Y1 0.00773 XN YN+1 0.03093

YN+1 0 0.03093 X0Y1 0 0.00773

0.0002 0.03093 XNYN+1 0.00019 0.03093

(Ls/Gs)min120.812

Gs 1951.06 mol/min

Lsmin 235711 mol/min

Lsmin 4242.8 kg/min

molNH3/molA
molNH3/molW molNH3/molW
molNH3/molA
0 0
0.015 0.02 0.02 0.015
0.032 0.04 0.04 0.032
0.05 0.06 0.06 0.05
0.072 0.08 0.08 0.072
0.093 0.1 0.1 0.093

BC 1 mol Aire
3 mol W/mol Aire

ARRIBA ABAJO 0.1

L0 3.03 G1 LN GN+1 1.08696 0.09
Ls 3 Gs 1 Ls 3 Gs 1
0.08
Lg0 0.03 Gg1 LgN GgN+1 0.08696
0.07
x0 0.0099 y1 0.0074 xN yN+1 0.08
X0 0.01 Y1 0.00746 XN YN+1 0.08696 0.06

0.05

0.04

0.03
YN+1 0 0.08696 X0 0.01 0
0.1 0.08696 0.01 0.06 0.02

Suponer 0.01
XN YN+1 0.0365 0.08696 Y1 0.00746 0
X0 Y1 0.01 0.00746 y1 0.00751 0 0.02 0.04 0.06 0.08 0.1 0.12
 TRABAJO EJERCICIOS PROPUESTOS 12.1’12.22

p 3
t 20 293.15
R 0.082
Q Y=1.186X 1.186
G

se va en el liquido se va en el gas x y X Y
ARRIBA ABAJO 0 0 0 0
L0 251.0911825 G1 99.62 LN 268.64 GN+1 100.00 0.01 0.01186 0.01010101 0.01200235
Ls 251.0660733 Gs 99.60 Ls 251.0660733 Gs 99.60 0.02 0.02372 0.02040816 0.02429631
Lg0 0.025109118 Gg1 0.02 LgN 17.57 GgN+1 0.40 0.03 0.03558 0.03092784 0.03689264
x0 0.0001 y1 0.0002 xN 0.065420561 yN+1 0.004 0.04 0.04744 0.04166667 0.04980264
X0 0.00010001 Y1 0.0002 XN 0.07 YN+1 0.18 0.05 0.0593 0.05263158 0.06303816
entra sale sale entra CONDICION IDEAL 0.06 0.07116 0.06382979 0.07661169
0.07 0.08302 0.07526882 0.09053633
TOPE X0Y1 0.00010001 0.0002 LINEA DE INTERSECCION 0 0.18 0.08 0.09488 0.08695652 0.10482588
FONDO XNYN+1 0.07 0.18 0.145 0.18 0.09 0.10674 0.0989011 0.11949488
LS/GS 2.520743708 PEND 2.520743708 0.1 0.1186 0.11111111 0.13455866
INTER -5.20596E-05 0.11 0.13046 0.12359551 0.15003335
ETAPAS TOPE 0.12 0.14232 0.13636364 0.16593601
X Y 0.13 0.15418 0.14942529 0.18228465
0.00010001 0.00 PENDI 1.21944506
0.000168663 0.00 INTERSE -0.00075564
0.000168663 0.00
0.000314565 0.00 Título del gráfico
0.000314565 0.00 0.20
0.000668497 0.00
0.18
0.000668497 0.00
0.00142046 0.00 0.16
0.00142046 0.00 0.14
0.003017374 0.00
0.12
0.003017374 0.01
0.006405536 0.01 0.10
0.006405536 0.02 0.08
0.013580042 0.02
0.06
0.013580042 0.03
0.028709115 0.03 0.04
0.028709115 0.07 0.02
0.06033406 0.07
0.00
0.06033406 0.15
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16
0.125247623 0.15

x y X Y
0 0 0 0
0.000001 0.0001692 1E-06 0.00016923
0.000002 0.0003384 2E-06 0.00033851
0.000003 0.0005076 3E-06 0.00050786
0.000004 0.0006768 4E-06 0.00067726
0.000005 0.000846 5E-06 0.00084672
H2S 0.000006 0.0010152 6E-06 0.00101623
p 2.5 0.000007 0.0011844 7E-06 0.0011858
t 15 288.15
R LS/LSMIN
Q
G Y=423X
RECUPERA 0.97 ELIMINA 0.03 169.2
se va en el liquido se va en el gas
ARRIBA ABAJO
L0 2000 G1 9.99 LN 2000.01 GN+1 10.00
Ls 0 Gs 9.99 Ls 2000.00 Gs 9.99
Lg0 0 Gg1 0.00 LgN 0.01 GgN+1 0.01
x0 0 y1 0.000036 xN 0.00000582 yN+1 0.0012
X0 0 Y1 0.0000 XN 5.82003E-06 YN+1 0.00
entra sale sale entra CONDICION IDEAL

tope X0Y1 0 0.0000 LINEA DE INTERSECCION

fondo XNYN+1 5.82003E-06 0.00 YN+1 0 0.00
VALOR ASU 0.000007 0.00
PENDI 199.998836
ETAPAS X Y INTER 0.000036
TOPE 0 0.0000 Título del gráfico
2.12758E-07 0.0000
0.0014
2.12758E-07 7.85514E-05
4.64216E-07 0.0001 0.0012
4.64216E-07 0.000128843
0.0010
7.61384E-07 0.0001
7.61384E-07 0.000188276 0.0008
1.11253E-06 0.0002
0.0006
1.11253E-06 0.000258505
1.52742E-06 0.0003 0.0004
1.52742E-06 0.000341482
0.0002
2.01753E-06 0.0003
2.01753E-06 0.000439503 0.0000
2.5964E-06 0.0004 0 0.000001 0.000002 0.000003 0.000004 0.000005 0.000006 0.000007 0.000008
2.5964E-06 0.000555277
3.27997E-06 0.0006
3.27997E-06 0.00069199
4.08697E-06 0.0007
4.08697E-06 0.000853388
5.03939E-06 0.0009
5.03939E-06 0.001043872
6.16306E-06 0.0010
6.16306E-06 0.001268606
 p Y=MX 3.653333333
t 25
R
Q
G
x y X Y
0 0 0 0
ARRIBA ABAJO 0.0000001 3.6533E-07 1E-07 3.6533E-07
LN 100000.00 GN-1 10000.03 L2 99999.84 G3 10000.00 0.0000002 7.3067E-07 2E-07 7.3067E-07
Ls 99999.80 GS 10000.00 Ls 99999.80 Gs 10000.00 0.0000003 1.096E-06 3E-07 1.096E-06
LgN 0.20 GgN-1 0.03 Lg2 0.04 Gg3 0.00 0.0000004 1.4613E-06 4E-07 1.4613E-06
Xn 0.000002 Yn-1 2.99999E-06 x2 0.0000004 y3 0 0.0000005 1.8267E-06 5E-07 1.8267E-06
XN 2E-06 YN-1 0.0000 X2 4E-07 Y3 0.00 0.0000006 2.192E-06 6E-07 2.192E-06
entra sale sale entra CONDICION IDEAL 0.0000007 2.5573E-06 7E-07 2.5573E-06
X Y X Y 0.0000008 2.9227E-06 8E-07 2.9227E-06
XNYN-1 TOPE 2E-06 0.0000 Y3 0 0.00
X2Y3 FONDO 4E-07 0.00 0.000002 0.00
PENDIEN 1.8749955
ETAPAS INTERC -7.49999E-07
Título del gráfico
TOPE X Y
0.0000
2E-06 0.0000
8.21166E-07 0.0000 0.0000
8.21166E-07 7.89684E-07
0.0000
2.16154E-07 0.0000
0.0000

0.0000

0.0000

0.0000

0.0000
0 0.0000005 0.000001 0.0000015 0.000002 0.0000025

p 1.3 988
t 0 273.15
R 0.082 LS=1.5LSMIN
Q
G RECUPERA 0.98 PIERDE 0.02 KGNH3/100KGH20
LIQUIDO GAS PRESION PARCIAL
se va en el liquido se va en el gas x y X Y
ARRIBA ABAJO
L0 G1 22.29 LN GN+1 29.98 869.4 100 947 0.51428571 0.95850202
Ls Gs 22.14 Ls Gs 22.14 90 785 0.48795181 0.79453441
Lg0 Gg1 0.16 LgN GgN+1 7.84 80 636 0.45859873 0.6437247
x0 0 y1 0.007037365 xN yN+1 0.26164499 0.172 70 500 0.42567568 0.50607287
X0 0 Y1 0.0071 XN YN+1 0.35 0.20772947 60 380 0.38848921 0.38461538
entra sale sale entra CONDICION IDEAL 50 275 0.34615385 0.27834008
40 190 0.29752066 0.19230769
TOPE XOY1 0 0.0071 Y1 0 0.3544 30 119 0.24107143 0.12044534
FONDO XNYN+1 0.38 0.35 0.389 0.3544 25 89.5 0.20930233 0.09058704
PENDI 0.913881037 LS/GS MIN 0.91388104 20 64 0.17475728 0.06477733
INTERC 0.007087241 LSMIN 20.2290987 15 42.7 0.13705584 0.04321862
se va en el liquido se va en el gas LS 30.343648 10 25.1 0.09574468 0.02540486
ARRIBA ABAJO 7.5 17.1 0.07356948 0.01730769
L0 30.34364799 G1 22.29 LN 38.03 GN+1 29.98 869.4 5 11.2 0.05027933 0.01133603
Ls 30.34364799 Gs 22.14 Ls 30.34364799 Gs 22.14 PENDI 1.02536256
Lg0 0 Gg1 0.16 LgN 7.69 GgN+1 7.84 INTER -0.08366828
x0 0 y1 0.007037365 xN 0.20212766 yN+1 0.26164499 0.172
X0 0 Y1 0.0071 XN 0.253333333 YN+1 0.35 0.20772947
entra sale sale entra CONDICION IDEAL

TOPE XOY1 0 0.0071 PENDIEN 1.370821555

FONDO XNYN+1 0.253333333 0.35 INTER 0.007087241
Título del gráfico
0.45
ETAPAS X Y
FONDO 0.253333333 0.35 0.40
0.253333333 0.18
0.12328592 0.18 0.35
0.12328592 0.04
0.30
0.02601159 0.04
0.25

0.20

0.15

0.10

0.05

0.00
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45
 p 1 x y X Y
t 80 Y=1.414X 1.414 0 0 0 0
R 0.001 0.001414 0.001001 0.001416
Q 0.002 0.002828 0.00200401 0.00283602
Título del gráfico
G 0.003 0.004242 0.00300903 0.00426007
0.014
L/V 0.65 LS/GS 0.65 0.004 0.005656 0.00401606 0.00568817
0.005 0.00707 0.00502513 0.00712034
0.012
ARRIBA ABAJO 0.006 0.008484 0.00603622 0.00855659
LN 66.33 GN-1 101.20 L2 65.13 G3 100.00 0.007 0.009898 0.00704935 0.00999695
0.01
Ls 65.00 GS 100.00 Ls 65.00 Gs 100.00 0.008 0.011312 0.00806452 0.01144143
LgN 1.33 GgN-1 1.20 Lg2 0.13 Gg3 0.00 0.009 0.012726 0.00908174 0.01289004 0.008
Xn 0.02 Yn-1 0.011857708 x2 0.001942843 y3 0 0.01 0.01414 0.01010101 0.01434281
XN 0.020408163 YN-1 0.0120 X2 0.001946625 Y3 0.00 0.011 0.015554 0.01112235 0.01579975 0.006
entra sale sale entra CONDICION IDEAL
REAL 0.012 0.016968 0.01214575 0.01726088
0.013 0.018382 0.01317123 0.01872623 0.004
TOPE XNYN-1 0.020408163 0.012 YN-1 0 0.012 0.014 0.019796 0.01419878 0.0201958
FONDO X2Y3 0 0.00 0.025 0.012 0.015 0.02121 0.01522843 0.02166961 0.002
PENDIEN 0.588
INTERC 0 0
ETAPAS X Y 0 0.005 0.01 0.015 0.02 0.025 0.03
TOPE 0.020408163 0.012
0.00845685 0.012
0.00845685 0.004972628
0.003511597 0.004972628
0.003511597 0.002064819
0.001459386 0.002064819
0.001459386 0.000858119
0.000606721 0.000858119
0.000606721 0.000356752
0.000252273 0.000356752

D11.* An absorption column for laboratory use has been carefully constructed so thatmit has exactly 1.40262
4
equilibrium stages and is being used to measure equilibrium data. Water is used as the solvent to ETAPAS
absorb ammonia from air. The system operates isothermally at 80°F and 1 atm. The inlet Delta
water is 0.0006
pure distilled water. The ratio of L/V = 1.2, inlet gas concentration is 0.01 mole frac ammonia,
x y X Y X Y
Título del gráfico
and the measured outlet gas concentration is 0.0027 mole frac ammonia. Assuming that 0 0 0 0 0.00000 0.00271
0.01200
equilibrium is of the form y = mx, calculate the value of m for ammonia. Check your result. 0.0006 0.00084 0.0006 0.00084 0.00192 0.00271
Ls/Gs 1.2 0.0012 0.00168 0.0012 0.00169 0.00192 0.00502 0.01000
BC Gs 10 mol/h 0.0018 0.00252 0.0018 0.00253 0.00357 0.00502
Ls 12 mol/h 0.0024 0.00337 0.00241 0.00338 0.00357 0.00699 0.00800
0.003 0.00421 0.00301 0.00423 0.00497 0.00699
ARRIBA ABAJO 0.0036 0.00505 0.00361 0.00508 0.00497 0.00867 0.00600
L0 12 G1 10.0271 LN 12.0739 GN+1 10.101 0.0042 0.00589 0.00422 0.00593 0.00616 0.00867
0.00400
Ls 12 Gs 10 Ls 12 Gs 10 0.0048 0.00673 0.00482 0.00678 0.00616 0.0101
Lg0 0 Gg1 0.02707 LgN 0.07394 GgN+1 0.10101 0.0054 0.00757 0.00543 0.00763 0.00200
x0 0 y1 0.0027 xN 0.00612 yN+1 0.01 0.006 0.00842 0.00604 0.00849
X0 0 Y1 0.00271 XN 0.00616 YN+1 0.0101 0.0066 0.00926 0.00664 0.00934 0.00000
0.0072 0.0101 0.00725 0.0102 7.7E-07 0.00000 0.00200 0.00400 0.00600 0.00800

X0Y1 0.00000 0.00271

XNYN+1 0.00616 0.01010

1.2 0.00271 1.40672

D4. We have a steam stripper operating isothermally at 100°C. The entering liquid stream contains
0.0002 mole frac nitrobenzene in water at 100°C. Flow rate of entering liquid is 1 kmol/min. The ETAPAS Curva de equilibrio Título del gráfico
entering steam is pure water at 100°C. We desire an outlet liquid mole frac of 0.00001 0.00001 x y X Y 0.003
nitrobenzene. L/V = 12.0. You can assume that total liquid and gas flow rates are constant. At 0.00020004 0.00228048 0 0 0 0
0.0025 y = 28.054x
100°C equilibrium in terms of nitrobenzene mole frac is y = 28 x. Find the outlet mole fraction of 8.12889E-05 0.00228048 0.00001 0.00028 1E-05 0.00028008 y = 12x - 0.0001
the nitrobenzene in the vapor stream and the number of stages. 8.12889E-05 0.00087547 1 0.00002 0.00056 2E-05 0.00056031 0.002
3.12065E-05 0.00087547 0.00003 0.00084 3.0001E-05 0.00084071
0.0015
Ls/Gs 12 3.12065E-05 0.00027448 1 0.00004 0.00112 4.0002E-05 0.00112126
9.78391E-06 0.00027448 0.00005 0.0014 5.0003E-05 0.00140196 0.001
ARRIBA ABAJO 9.78391E-06 1.7407E-05 1 0.00006 0.00168 6.0004E-05 0.00168283
L0 1 G1 0.083506669 LN 0.99981 GN+1 0.08331667 0.00007 0.00196 7.0005E-05 0.00196385 0.0005
Ls 0.9998 Gs 0.083316667 Ls 0.9998 Gs 0.08331667 0.00008 0.00224 8.0006E-05 0.00224503
0
Lg0 0.0002 Gg1 0.000190002 LgN 9.9981E-06 GgN+1 0 0.00009 0.00252 9.0008E-05 0.00252637 0 0.00005 0.0001 0.00015 0.0002 0.00025
x0 0.0002 y1 0.00227529 xN 0.00001 yN+1 0 -0.0005
X0 0.00020004 Y1 0.002280479 XN 1E-05 YN+1 0

X0Y1 0.00020004 0.00228048

XNYN+1 1.00001E-05 0

D12.* Read Section 13.4 on cross flow in Chapter 13 before proceeding. We wish to strip CO2 from a
liquid solvent using air as the carrier gas. Since the air and CO2 mixtures will be vented and since
cross flow has a lower pressure drop, we will use a cross-flow system. The inlet liquid is 20.4
wt % CO2, and the total inlet liquid flow rate is 1000 kg/h. We desire an outlet liquid composition
that is 2.5 wt % (0.025 wt frac) CO2. The gas flow to each stage is 25,190 kg air/h. In the last
stage a special purified air is used that has no CO2. Find the number of equilibrium stages
required. In weight fraction units, equilibrium is y = 0.04x. Use unequal axes for your McCabe-
Thiele diagram. Note: With current environmental concerns, venting the CO2 is not a good idea
even if it is legal.

ARRIBA ABAJO N
G1 25373.590 L1 1000.000 G2 25190.000 L2 816.410 0.256 0.007 Título del gráfico
Gs 25190.000 Ls 796.000 Gs 25190.000 Ls 796.000 0.222 0.007 0.009
Gg1 183.590 Lg1 204.000 Gg2 0.000 Lg2 20.410 0.222 0.00620491 0.008
y1 0.007 x1 0.204 y2 0.000 x2 0.025 0.182 0.006 0.007
Y1 0.007 X1 0.256 Y2 0 X2 0.02564103 0.182 0.00494092 0.006
OPERACIÓN 0.14 0.005 0.005
X2Y2 0.02564103 0.000 m EQUILIBRIO 0.14 0.00361373 0.004
X1Y1 0.256 0.0073 0 0 0 0 0.1 0.004 0.003
0.05 0.002 0.05263158 0.00200401 0.1 0.00234973 0.002
0.03159984 -0.00081025 0.1 0.004 0.11111111 0.00401606 0.063 0.002 0.001
0.15 0.006 0.17647059 0.00603622 0.063 0.00118054 0.000
0.2 0.008 0.25 0.00806452 0.03 0.001 -0.0010.000 0.050 0.100 0.150 0.200 0.250 0.300
0.2 0.008 0.25 0.00806452 0.03 0.00013774 -0.002
0.005 0.000
0.005 -0.00065225

0.2 ABSORBEDOR
D23.* A complete gas treatment plant often consists of both an absorber to remove the solute and a
stripper to regenerate the solvent. Some of the treated gas is heated and is used in the stripper. 0.18

This is called stream B. In a particular application we wish to remove obnoxious impurity A from 0.16
the inlet gas. The absorber operates at 1.5 atm and 24°C where equilibrium is given as y = 0.5x
0.14
(units are mole fracs). The stripper operates at 1 atm and 92°C where equilibrium is y = 3.0x
(units are mole fracs). The total gas flow rate is 1400 mol/day, and the gas is 15 mol% A. The 0.12
nonsoluble carrier is air. We desire a treated gas concentration of 0.5 mol% A. The liquid flow
0.1
rate into the absorber is 800 mol/day and the liquid is 0.5 mol% A.
a. Calculate the number of stages in the absorber and the liquid concentration leaving. 0.08

b. If the stripper is an already existing column with four equilibrium stages, calculate the gas flow 0.06
rate of stream B (concentration is 0.5 mol% A) and the outlet gas concentration from the stripper.
0.04

ABSORCIÓN 0.02 DESORCIÓN 0.01 0.02

x y X Y x y X Y
0
0 0 0 0 0 0 0 0 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4
0.02 0.01 0.02040816 0.01010101 0.01 0.03 0.01010101 0.03092784
0.04 0.02 0.04166667 0.02040816 0.02 0.06 0.02040816 0.06382979
0.06 0.03 0.06382979 0.03092784 0.03 0.09 0.03092784 0.0989011
0.08 0.04 0.08695652 0.04166667 0.04 0.12 0.04166667 0.13636364
0.1 0.05 0.11111111 0.05263158 0.05 0.15 0.05263158 0.17647059
0.12 0.06 0.13636364 0.06382979 0.06 0.18 0.06382979 0.2195122
0.14 0.07 0.1627907 0.07526882 0.07 0.21 0.07526882 0.26582278
0.16 0.08 0.19047619 0.08695652 0.08 0.24 0.08695652 0.31578947
0.18 0.09 0.2195122 0.0989011 0.09 0.27
0.2 0.1 0.25 0.11111111 0.1 0.3
0.22 0.11 0.28205128 0.12359551 0.11
0.24 0.12 0.31578947 0.13636364 0.12
0.26 0.13 0.35135135 0.14942529 0.13

ABSORBEDOR
ARRIBA ABAJO
G1 1195.980 L0 800.000 GN+1 1400.000 LN 1004.020 0.26133178 0.17647059
Título del gráfico
Gs 1190.000 Ls 796.000 Gs 1190.000 Ls 796.000 0.26133178 0.116 1
0.350
Gg1 5.980 Lg0 4.000 GgN+1 210.000 LgN 208.020 0.17092977 0.116
y1 0.005 x0 0.005 yN+1 0.150 xN 0.20718719 0.17092977 0.079 1
0.300
Y1 0.0050 X0 0.005 YN+1 0.17647059 XN 0.26133178 0.1156157 0.079
0.1156157 0.055 1
0.250
XNYN+1 0.26133178 0.176 m 1.41 X 0.07973631 0.055
X0Y1 0.005 0.0050 0 0 0 0 0.07973631 0.0385 1
0.002 0.00282 0.00200401 0.00282797 0.05506922 0.0385 0.200

0.66890756 0.00166378 0.004 0.00564 0.00401606 0.00567199 0.05506922 0.0265 1

0.03712952 0.0265 0.150

0.03712952 0.018 1
0.02442224 0.018 0.100

0.02442224 0.012 1
0.01545239 0.012 0.050

0.01545239 0.0075 1
0.008725 0.0075 0.000
0.000 0.050 0.100 0.150 0.200 0.250 0.300
0.008725 0.005 1
0.00498756 0.005
DESORBEDOR N 4 9
ARRIBA ABAJO
GN 857.286 LN+1 1004.020 G0 653.266 L1 800.000 0.261 0.319
Gs 650.000 Ls 796.000 Gs 650.000 Ls 796.000 0.087 0.3189022
GgN 207.286 LgN+1 208.020 Gg0 3.266 Lg1 4.000 0.087 0.10541282 1
YyN 0.242 xn+1 0.207 y0 0.005 x1 0.005 0.0325 0.10541282
YN 0.3189 XN+1 0.261 Y0 0.00502513 X1 0.00502513 0.0325 0.03867128 1
0.012 0.03867128
X1Y0 0.00502513 0.005 m 1.41 X 0.012 0.01356666 1
XN+1YN 0.261 0.3189 0 0 0 0 0.004 0.01356666
0.002 0.00282 0.00200401 0.00282797 0.004 0.00376974 1
1.22461538 -0.00112872 0.004 0.00564 0.00401606 0.00567199

Lg entrada 208.020
Lg salida 4.000

fS 0.01922891
EXAMEN PARCIAL OPÉRACIONES UNITARIAS 3

p 1.5
t 24 297.15
R 0.082
Q Y=0.5X 0.5
G

se va en el liquido se va en el gas
ARRIBA ABAJO
L0 800 G1 1195.98 LN 1263.49 GN+1 1400.00
Ls 796 Gs 1190.00 Ls 796 Gs 1190.00
Lg0 4 Gg1 5.98 LgN 467.49 GgN+1 210.00
x0 0.005 y1 0.005 xN 0.37 yN+1 0.15
X0 0.00502513 Y1 0.0050 XN 0.58730159 YN+1 0.18
entra sale sale entra CONDICION IDEAL x y X Y
0 0 0 0
TOPE X0Y1 0.00502513 0.0050 LINEA DE INTERSECCION 0 0.18 0.01 0.005 0.01010101 0.00502513
FONDO XNYN+1 0.37 0.18 0.44 0.18 0.02 0.01 0.02040816 0.01010101
0.03 0.015 0.03092784 0.01522843 Título del gráfico
0.04 0.02 0.04166667 0.02040816 0.20
ARRIBA ABAJO 0.05 0.025 0.05263158 0.02564103
L0 800 G1 1195.98 LN 1004.02 GN+1 1400.00 0.06 0.03 0.06382979 0.03092784
0.18
Ls 796 Gs 1190.00 Ls 796 Gs 1190.00 0.07 0.035 0.07526882 0.03626943
Lg0 4 Gg1 5.98 LgN 208.02 GgN+1 210.00 0.08 0.04 0.08695652 0.04166667
x0 0.005 y1 0.005 xN 0.20718719 yN+1 0.15 0.09 0.045 0.0989011 0.04712042 0.16
X0 0.00502513 Y1 0.0050 XN 0.26133178 YN+1 0.18 0.1 0.05 0.11111111 0.05263158
entra sale sale entra CONDICION IDEAL
REAL 0.11 0.055 0.12359551 0.05820106 0.14
0.12 0.06 0.13636364 0.06382979
TOPE X0Y1 0.00502513 0.0050 0.13 0.065 0.14942529 0.06951872
FONDO XNYN+1 0.26133178 0.18 PENDIEN 0.66890756 0.14 0.07 0.1627907 0.07526882 0.12

INTERSEC 0.00166378 0.15 0.075 0.17647059 0.08108108

ETAPAS FONDO 0.16 0.08 0.19047619 0.08695652 0.10
X Y 0.17 0.085 0.20481928 0.09289617
0.26133178 0.18 0.18 0.09 0.2195122 0.0989011
0.08
0.26133178 0.18 0.19 0.095 0.2345679 0.10497238
0.26133178 0.11276537 0.2 0.1 0.25 0.11111111
0.16609408 0.11 0.21 0.105 0.26582278 0.11731844 0.06
0.16609408 0.07370412 0.22 0.11 0.28205128 0.12359551
0.1076985 0.07 0.23 0.115 0.2987013 0.1299435
0.04
0.1076985 0.04975348 0.24 0.12 0.31578947 0.13636364
0.07189289 0.05 0.25 0.125 0.33333333 0.14285714
0.07189289 0.035068 0.26 0.13 0.35135135 0.14942529 0.02
0.04993847 0.04 0.27 0.135 0.36986301 0.15606936
0.04993847 0.0260635 0.28 0.14 0.38888889 0.1627907
0.00
0.03647697 0.03 0.29 0.145 0.4084507 0.16959064 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5
0.03647697 0.02054234 0.3 0.15 0.42857143 0.17647059
0.02822298 0.02 0.31 0.155 0.44927536 0.18343195
0.02822298 0.01715701
0.02316199 0.02 PENDIEN 0.41014478
0.02316199 0.01508127 INTERSE 0.0055815
0.02005881 0.02
0.02005881 0.01380852
0.01815608 0.01
0.01815608 0.01302812
0.01698941 0.01
0.01698941 0.01254962
0.01627405 0.01
0.01627405 0.01225622

0 DESORBEDOR

DESORCION

p 1 760
t 122 395.15
R 0.082 3
Q
G

x y X Y
ARRIBA ABAJO 0 0 0 0
LN 1004.02 GN-1 L2 800.00 G3 0.01 0.03 0.01010101 0.03092784
Ls 796 GS Ls 796 Gs 0.02 0.06 0.02040816 0.06382979
LgN 208.02 GgN-1 Lg2 4.00 Gg3 0.03 0.09 0.03092784 0.0989011
Xn 0.20718719 Yn-1 x2 0.005 y3 0.005 0.04 0.12 0.04166667 0.13636364
XN 0.26133178 YN-1 X2 0.00502513 Y3 0.01 0.05 0.15 0.05263158 0.17647059
entra sale sale entra CONDICION IDEAL 0.06 0.18 0.06382979 0.2195122
X Y X Y 0.07 0.21 0.07526882 0.26582278
XNYN-1 TOPE 0.26133178 0.3400 Y3 0 0.34 0.08 0.24 0.08695652 0.31578947
X2Y3 FONDO 0.00502513 0.01 0.26 0.34 0.09 0.27 0.0989011 0.36986301

ARRIBA ABAJO
LN 1004.02 GN-1 855.01 L2 800.00 G3 949.01
Título del gráfico
Ls 796 GS 647.73 Ls 796 Gs 647.73 0.4
LgN 208.02 GgN-1 207.28 Lg2 4.00 Gg3 301.28
Xn 0.20718719 Yn-1 0.24242424 x2 0.005 y3 0.005
XN 0.26133178 YN-1 0.3200 X2 0.00502513 Y3 0.01 0.35
entra sale sale entra CONDICION IDEAL
REAL
X Y
0.3
XNYN+1 TOPE 0.26133178 0.32 PENDI 1.22889852
LS/GS 1.22889852 X2Y3 FONDO 0.00502513 0.01 INTERS -0.00115024
0.25
K 3
ETAPAS TOPE
X Y 0.2
0.26133178 0.32
0.08791209 0.32
0.15
0.08791209 0.10688479
0.03325839 0.10688479
0.03325839 0.03972094
0.1
0.01289875 0.03972094
0.01289875 0.01470101
0.00485277 0.01470101 0.05
0.00485277 0.00481332
0.00159931 0.00481332
0.00159931 0.00081515 0
0 0.05 0.1 0.15 0.2 0.25 0.3
0.00027157 0.00081515
LABORATORIO DE OPERACIONES UNITARIAS 3

p 107000 1.0560044 802.563344

t 26 299.15
R 0.082 LS/LSMIN 1.5
Q 0.25 250
G 10.7622451 0.01076225
RECUPERA 0.96 ELIMINA 0.04
se va en el liquido se va en el gas
ARRIBA ABAJO A B C PSAT K
L0 G1 LN GN+1 10.76 15.9008 2788.51 -52.36 99.651519 0.12416655
Ls Gs 10.55 Ls Gs 10.55
Lg0 Gg1 LgN GgN+1 0.22
x0 0.005 y1 0.00081566 xN yN+1 0.02 x y X Y
X0 0.005025126 Y1 0.0008 XN YN+1 0.02 0 0 0 0
entra sale sale entra CONDICION IDEAL 0.01 0.00124167 0.01010101 0.00124321
0.02 0.00248333 0.02040816 0.00248951
tope X0Y1 0.00502513 0.0008 LINEA DE INTERSECCION 0.03 0.003725 0.03092784 0.00373892
fondo XNYN+1 0.17 0.02 YN+1 0 0.02 0.04 0.00496666 0.04166667 0.00499145
VALOR ASU 0.19 0.02 0.05 0.00620833 0.05263158 0.00624711
PENDIENTE 0.11875649 LS/GSMIN 0.11875649 0.06 0.00744999 0.06382979 0.00750591
INTERCEPTO 0.00021956 LSMIN 1.2525247 0.07 0.00869166 0.07526882 0.00876787
LS 1.87878705 0.08 0.00993332 0.08695652 0.01003298
0.09 0.01117499 0.0989011 0.01130128
0.1 0.01241665 0.11111111 0.01257277
0.11 0.01365832 0.12359551 0.01384745
ARRIBA ABAJO 0.12 0.01489999 0.13636364 0.01512535
L0 1.888228192 G1 10.56 LN 2.09 GN+1 10.76 0.13 0.01614165 0.14942529 0.01640648
Ls 1.878787051 Gs 10.55 Ls 1.87878705 Gs 10.55 0.14 0.01738332 0.1627907 0.01769084
Lg0 0.009441141 Gg1 0.01 LgN 0.22 GgN+1 0.22 0.15 0.01862498 0.17647059 0.01897846
x0 0.005 y1 0.00081566 xN 0.10314575 yN+1 0.02 0.16 0.01986665 0.19047619 0.02026933
X0 0.005025126 Y1 0.0008 XN 0.11500838 YN+1 0.02
entra sale sale entra CONDICION REAL PENDIE 0.10646316
INTER 0.00048364
TOPE X0Y1 0.00502513 0.0008 PEND 0.178134732
FONDO XNYN+1 0.11500838 0.02 INTER -7.88229E-05
FONDO
ETAPAS X Y
0.00502513 0.0008
0.00661252 0.0008
0.00661252 0.0010991 Título del gráfico
0.00892096 0.0011
0.0250
0.00892096 0.00158913
0.01294349 0.0016
0.01294349 0.00230568 0.0200
0.01887628 0.0023
0.01887628 0.00336252
0.02773865 0.0034 0.0150
0.02773865 0.00494122
0.04123217 0.0049
0.04123217 0.00734488 0.0100

0.06238558 0.0073
0.06238558 0.01111304
0.0050
0.09711361 0.0111
0.09711361 0.01729931
0.15868706 0.0173 0.0000
0.15868706 0.02826768 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2
0.28435799 0.0283
0.28435799 0.05065403

DESORCION

p 1 760 GS/GSMIN 1.5

t 122 395.15
R 0.082
Q
G

A B C PSA K
ARRIBA ABAJO 15.9008 2788.51 -52.36 2359.14083 3.10413268
LN 2.09 GN-1 L2 1.89 G3 0.72
Ls 1.87878705 GS 0.72 Ls 1.87878705 Gs 0.72 x y X Y
LgN 0.22 GgN-1 Lg2 0.01 Gg3 0.00 0 0 0 0
Xn 0.10314575 Yn-1 x2 0.005 y3 0 0.01 0.03104133 0.01010101 0.03203576
XN 0.11500838 YN-1 X2 0.00502513 Y3 0.00 0.02 0.06208265 0.02040816 0.06619203
entra sale sale entra CONDICION IDEAL 0.03 0.09312398 0.03092784 0.10268656
X Y X Y 0.04 0.12416531 0.04166667 0.14176797
XNYN-1 TOPE 0.11500838 0.43 Y3 0 0.43 0.05 0.15520663 0.05263158 0.18372142
X2Y3 FONDO 0.00502513 0.00 0.116 0.43 0.06 0.18624796 0.06382979 0.22887557
0.07 0.21728929 0.07526882 0.27761123
PENDIENTE 3.90968626 LS/GSMIN 3.90968626 0.08 0.24833061 0.08695652 0.33037213
INTERCEPTO -0.01964666 GSMIN 0.48054676 0.09 0.27937194 0.0989011 0.38767841
GS 0.72082013 0.1 0.31041327 0.11111111 0.45014391
0.11 0.34145459 0.12359551 0.51849818
0.12 0.37249592 0.13636364 0.59361514
0.13 0.40353725 0.14942529 0.67655063 Título del gráfico
0.14 0.43457857 0.1627907 0.76859234 0.5
ARRIBA ABAJO 0.15 0.4656199 0.17647059 0.87132718
0.45
LN 2.09 GN-1 0.93 L2 1.89 G3 0.72 0.16 0.49666123 0.19047619 0.9867335
Ls 1.87878705 GS 0.72 Ls 1.87878705 Gs 0.72 0.4
LgN 0.22 GgN-1 0.21 Lg2 0.01 Gg3 0.00 0.35
Xn 0.10314575 Yn-1 0.22279793 x2 0.005 y3 0
XN 0.11500838 YN-1 0.2867 X2 0.00502513 Y3 0.00 0.3

entra sale sale entra CONDICION IDEAL

REAL 0.25

0.2
X Y
XNYN-1 TOPE 0.11500838 0.2867 PENDIENTE 2.60645751 0.15
X2Y3 FONDO 0.00502513 0.00 INTER -0.01309778
0.1

0.05

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14
EXAMEN RESUELTO DE LABORATORIO OPERACIONES UNITARIAS 3
P 1 760
T 20 293.15
R 0.082
Q 5 5000
G 208.001398
LS/LSMIN 1.5 A B C PSAT K
15.9008 2788.51 -52.36 75.1982565 0.1
RECUPERA 0.95 ELIMINA 0.05
se va en el liquido se va en el gas x y X Y
ARRIBA ABAJO 0 0 0 0
L0 G1 198.12 LN GN+1 208.00 0.01 0.001 0.01010101 0.001001
Ls Gs 197.60 Ls Gs 197.60 0.02 0.002 0.02040816 0.00200401
Lg0 Gg1 0.52 LgN GgN+1 10.40 0.03 0.003 0.03092784 0.00300903
x0 0.001 y1 0.00262467 xN yN+1 0.05 0.04 0.004 0.04166667 0.00401606
X0 0.001001 Y1 0.0026 XN YN+1 0.05 0.05 0.005 0.05263158 0.00502513
entra sale sale entra CONDICION IDEAL 0.06 0.006 0.06382979 0.00603622
0.07 0.007 0.07526882 0.00704935
tope X0Y1 0.001001 0.0026 LINEA DE INTERSECCION 0.08 0.008 0.08695652 0.00806452
fondo XNYN+1 0.68 0.05 YN+1 0 0.05 0.09 0.009 0.0989011 0.00908174
VALOR ASU 0.75 0.05 0.1 0.01 0.11111111 0.01010101
PENDIENTE 0.07363781 LS/GSMIN 0.07363781 0.11 0.011 0.12359551 0.01112235
INTERCEPTO 0.00255787 LSMIN 14.5509292 0.12 0.012 0.13636364 0.01214575
LS 21.8263939 0.13 0.013 0.14942529 0.01317123
0.14 0.014 0.1627907 0.01419878
se va en el liquido se va en el gas 0.15 0.015 0.17647059 0.01522843
ARRIBA ABAJO 0.16 0.016 0.19047619 0.01626016
L0 21.8482421 G1 198.12 LN 31.73 GN+1 208.00 0.17 0.017 0.20481928 0.017294
Ls 21.8263939 Gs 197.60 Ls 21.8263939 Gs 197.60 0.18 0.018 0.2195122 0.01832994
Lg0 0.02184824 Gg1 0.52 LgN 9.90 GgN+1 10.40 0.19 0.019 0.2345679 0.01936799
x0 0.001 y1 0.00262467 xN 0.31208454 yN+1 0.05 0.2 0.02 0.25 0.02040816
X0 0.001001 Y1 0.0026 XN 0.453667 YN+1 0.05 0.21 0.021 0.26582278 0.02145046
entra sale sale entra CONDICION IDEAL
REAL 0.22 0.022 0.28205128 0.02249489
0.23 0.023 0.2987013 0.02354145
TOPE X0Y1 0.001001 0.0026 PENDIENTE 0.11045672 0.24 0.024 0.31578947 0.02459016
FONDO XNYN+1 0.453667 0.05 INTERSECCION0.00252101 0.25 0.025 0.33333333 0.02564103
0.26 0.026 0.35135135 0.02669405
etapas 0.27 0.027 0.36986301 0.02774923
0.28 0.028 0.38888889 0.02880658
x y 0.29 0.029 0.4084507 0.02986612
0.001001 0.0026 0.3 0.03 0.42857143 0.03092784
0.02695418 0.00 0.31 0.031 0.44927536 0.03199174
0.02695418 0.005498282 0.32 0.032 0.47058824 0.03305785
0.05784526 0.01 0.33 0.033 0.49253731 0.03412616
0.05784526 0.008910409
Título del gráfico 0.34 0.034 0.51515152 0.03519669
0.09687267 0.01 0.0600 0.35 0.035 0.53846154 0.03626943
0.09687267 0.013221249 0.36 0.036 0.5625 0.0373444
0.0500
0.15006944 0.01 0.37 0.037 0.58730159 0.0384216
0.15006944 0.019097189 0.0400
0.38 0.038 0.61290323 0.03950104
0.23060748 0.02 0.39 0.039 0.63934426 0.04058273
0.23060748 0.027993157 0.0300 0.4 0.04 0.66666667 0.04166667
0.37420925 0.03 0.41 0.041 0.69491525 0.04275287
0.37420925 0.043854937 0.0200 0.42 0.042 0.72413793 0.04384134
0.72450906 0.04 0.43 0.043 0.75438596 0.04493208
0.0100
0.72450906 0.082547903
3.21112017 0.08 0.0000
3.21112017 0.357210803 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
-1.61276469 0.36
-1.61276469 -0.17561968

p 1 760 GS/GSMIN 1.5 k 0.1

t 20 293.15
R 0.082
Q
G

x y X Y
ARRIBA ABAJO 0 0 0 0
LN 31.73 GN-1 L2 G3 0.01 0.001 0.01010101 0.001001
Ls 21.8263939 GS Ls 21.8263939 Gs 0.02 0.002 0.02040816 0.00200401
LgN 9.90 GgN-1 Lg2 Gg3 0.03 0.003 0.03092784 0.00300903
Xn 0.31208454 Yn-1 x2 0.001 y3 0 0.04 0.004 0.04166667 0.00401606
XN 0.45 YN-1 X2 0.001001 Y3 0.00 0.05 0.005 0.05263158 0.00502513
entra sale sale entra CONDICION IDEAL 0.06 0.006 0.06382979 0.00603622
0.07 0.007 0.07526882 0.00704935
X Y X Y 0.08 0.008 0.08695652 0.00806452
XNYN-1 TOPE 0.45 0.032 Y3 0 0.03 0.09 0.009 0.0989011 0.00908174
X2Y3 FONDO 0.001001001 0.00 0.45 0.03 0.1 0.01 0.11111111 0.01010101
0.11 0.011 0.12359551 0.01112235
pendi 0.070692299 LS/GSMIN 0.0706923 0.12 0.012 0.13636364 0.01214575
Título del gráfico
interce -7.07631E-05 GS MIN 308.752075 0.13 0.013 0.14942529 0.01317123
0.05
GS 463.128112 0.14 0.014 0.1627907 0.01419878
ARRIBA ABAJO 0.15 0.015 0.17647059 0.01522843 0.045

LN 31.73 GN-1 473.01 L2 21.85 G3 463.13 0.16 0.016 0.19047619 0.01626016 0.04
Ls 21.8263939 GS 463.13 Ls 21.8263939 Gs 463.13 0.17 0.017 0.20481928 0.017294 0.035
LgN 9.90 GgN-1 9.88 Lg2 0.02 Gg3 0.00 0.18 0.018 0.2195122 0.01832994 0.03
Xn 0.31208454 Yn-1 0.02088773 x2 0.001 y3 0 0.19 0.019 0.2345679 0.01936799 0.025
XN 0.45 YN-1 0.0213 X2 0.001001 Y3 0.00 0.2 0.02 0.25 0.02040816
0.02
entra sale sale entra CONDICION IDEAL
REAL 0.21 0.021 0.26582278 0.02145046
0.015
0.22 0.022 0.28205128 0.02249489
0.01
x y 0.23 0.023 0.2987013 0.02354145
tope 0.45 0.0213 PENDI 0.047128199 0.24 0.024 0.31578947 0.02459016 0.005

fondo 0.001001 0.00 INTER -4.71754E-05 0.25 0.025 0.33333333 0.02564103 0

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
0.26 0.026 0.35135135 0.02669405
0.27 0.027 0.36986301 0.02774923
0.28 0.028 0.38888889 0.02880658
0.29 0.029 0.4084507 0.02986612
0.3 0.03 0.42857143 0.03092784
0.31 0.031 0.44927536 0.03199174
0.32 0.032 0.47058824 0.03305785
0.33 0.033 0.49253731 0.03412616
0.34 0.034 0.51515152 0.03519669
0.35 0.035 0.53846154 0.03626943
0.36 0.036 0.5625 0.0373444
0.37 0.037 0.58730159 0.0384216
0.38 0.038 0.61290323 0.03950104
0.39 0.039 0.63934426 0.04058273
0.4 0.04 0.66666667 0.04166667
0.41 0.041 0.69491525 0.04275287
0.42 0.042 0.72413793 0.04384134
0.43 0.043 0.75438596 0.04493208
 DESTILACION FLASH

F  L V 1
Mezcla Benceno Tolueno zi F  xi L  yiV 0.9
y1  K 1 x1 120

V 0.8 y 2  K 2 x2
Comp A B C Tb  110
F K1
BENZENE 15.9008 2788.51 -52.36 353.3 80.15 0.7 a 12 
TOLUENE 16.0137 3096.52 -53.67 383.8 110.65 0.6 K2 100
0.5 y1 y1
P 760 K x x y 1  x  Y 90
0.4 a 1 1  1  1 1  1
0.3
K 2 y 2 1  y1 x1 1  y1  X 1
x1 x2 T Psat1 Psat2 K1 K2 y1 y2 Sy a x y x2 1  x1 80
0 1 110.6259747 1784.46236 760 2.34797679 1 0 1 1 2.34797679 0 0 0.2
ax
0.1 0.9 106.136844 1589.75991 667.804454 2.09178936 0.87869007 0.20917894 0.79082106 1 2.38057698 0.1 0.21636574 0.1 y 70
0.2 0.8 102.1037277 1429.10081 592.724798 1.8803958 0.77990105 0.37607916 0.62392084 1 2.41106971 0.2 0.38318719 0 1  x a  1
0.3 0.7 98.45794887 1294.88672 530.762835 1.70379831 0.69837215 0.51113949 0.48886051 1 2.43967104 0.3 0.51573343 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.4 0.6 95.1432433 1181.49595 479.002699 1.55459994 0.63026671 0.62183997 0.37816003 1 2.46657473 0.4 0.62358369
0.5 0.5 92.11336983 1084.71343 435.286569 1.42725451 0.57274549 0.71362726 0.28637274 1 2.49195245 0.5 0.7130518 1 1
0.6 0.4 89.3301428 1001.33687 397.994697 1.31754851 0.52367723 0.79052911 0.20947089 1 2.51595531 0.6 0.78846832 0.9 0.9
0.7 0.3 86.76184944 928.902335 365.894552 1.22223991 0.4814402 0.85556794 0.14443206 1 2.53871595 0.7 0.85290258 0.8 0.8
0.8 0.2 84.38199112 865.490976 338.036094 1.13880392 0.44478433 0.91104313 0.08895687 1 2.56035078 0.8 0.90859064
0.7 0.7
0.9 0.1 82.168287 809.591321 313.678125 1.06525174 0.41273438 0.95872656 0.04127344 1 2.580962 0.9 0.95720011
0.6 0.6
1 0 80.10188524 760 292.235804 1 0.3845208 1 0 1 2.60063958 1 1
11 0.5 0.5
2.48494957 0.4 0.4
0.3 0.3
0.2 0.2
0.1 0.1
0
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
SISTEMA NO IDEAL 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Agua (1) 1,4-Dioxano ´(2) A B C

W 8.07131 1730.63 233.426
1,4D 7.43155 1554.679 240.337
P A12 A21
760 1.902973993 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1 K2 y1 y2 Sy
0 1 101.2953998 796.068444 760 6.70580784 1 7.02405528 1 0 1 1
0.05 0.95 94.61685477 624.724171 616.705491 5.47728489 1.00518915 4.50235824 0.81566536 0.22511791 0.77488209 1 1
yi  K i xi
0.1 0.9 91.32869851 552.423821 554.704827 4.53320645 1.02071271 3.2950674 0.74499246 0.32950674 0.67049321 0.99999995
P
Sat
0.15 0.85 89.55137321 516.353375 523.368245 3.80029602 1.04673942 2.581968 0.72082918 0.3872952 0.6127048 1 0.9
Ki  i i
0.2 0.8 88.56445099 497.191024 506.600972 3.22590286 1.08374745 2.11038151 0.72240462 0.4220763 0.5779237 1 P
0.25 0.75 88.0202953 486.883044 497.545266 2.77179716 1.13253278 1.77571189 0.74142937 0.44392797 0.55607203 1 0.8 Título del gráfico
0.3 0.7 87.72920808 481.442947 492.755601 2.4099407 1.19423246 1.52664336 0.7742957 0.45799301 0.54200699 1 105
0.35 0.65 87.58089225 478.690755 490.329674 2.11957319 1.2703634 1.33502643 0.81960115 0.46725925 0.53274075 1 0.7
0.4 0.6 87.51036636 477.386694 489.179545 1.88518445 1.36287795 1.18416049 0.87722634 0.4736642 0.5263358 1
0.45 0.55 87.48148613 476.853544 488.709206 1.69508929 1.47423902 1.06356492 0.94799234 0.47860421 0.52139579 1 0.6 100

0.5 0.5 87.47851926 476.798801 488.660909 1.54041639 1.60751821 0.96640617 1.03359383 0.48320308 0.51679692 1
0.55 0.45 87.50192757 477.230856 489.042074 1.41438454 1.76652209 0.88814203 1.1367153 0.48847812 0.51152188 1 0.5
95
0.6 0.4 87.56673761 478.428789 490.098665 1.31178016 1.9559529 0.82578078 1.26132882 0.49546847 0.50453153 1
0.65 0.35 87.7029253 480.95427 492.324993 1.22857721 2.18161266 0.77748613 1.41324005 0.50536598 0.49463402 1 0.4

0.7 0.3 87.95790352 485.712691 496.515459 1.16165857 2.45066141 0.74241093 1.60104115 0.51968765 0.48031235 1 90
0.75 0.25 88.40187883 494.092422 503.881507 1.10861075 2.77194433 0.7207318 1.83780459 0.54054885 0.45945115 1 0.3

0.8 0.2 89.13791727 508.251628 516.289602 1.06757177 3.15640607 0.71394091 2.14423636 0.57115273 0.42884727 1
0.85 0.15 90.32075355 531.717686 536.751247 1.03711819 3.61761654 0.72559748 2.55494762 0.61675786 0.38324214 1 0.2 85
0.9 0.1 92.19355831 570.72455 570.497001 1.01618121 4.17243897 0.76310469 3.13205779 0.68679422 0.31320578 1
0.95 0.05 95.16569447 637.529181 627.582281 1.00398471 4.84188066 0.84219678 3.99826119 0.80008694 0.19991306 1 0.1
80
1 0 99.99682974 760 730.213579 1 5.65217847 1 5.43065457 1 0 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
21 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 xT yT Series3

0.48 0.52 87.47690069 476.768939 488.634562 1.59850884 1.5513509 1.00278863 0.99742588 0.48133854 0.51866146 1 5.77316E-05
0.4813 0.5187 87.47689074 476.768756 488.6344 1.59458653 1.55488218 1.00032768 0.99969595 0.48145771 0.51854229 1 -1.33227E-05
0.48145 0.51855 87.47689061 476.768753 488.634398 1.5941353 1.55529068 1.0000446 0.99995859 0.48147147 0.51852853 1 1.33227E-05
0.481471474 0.51852853 87.4768906 476.768753 488.634398 1.59407072 1.55534918 1.00000409 0.9999962 0.48147344 0.51852656 1 0
0.481473444 0.51852656 87.4768906 476.768753 488.634398 1.5940648 1.55535455 1.00000038 0.99999965 0.48147363 0.51852637 1 -0.000102141
0.481473625 0.51852637 87.4768906 476.768753 488.634398 1.59406425 1.55535504 1.00000003 0.99999997 0.48147364 0.51852636 1 2.22045E-06

0.48147367 87.47689119
0.48147367 0.51852633 87.47689119 476.768764 488.634407 1.59406412 1.55535517 0.99999997 1.00000007 0.48147366 0.51852636 1.00000002
P A12 A21
152 1.902973993 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1 K2 y1 y2 Sy
0 1 55.80889426 122.414867 152 6.70580784 1 5.40059591 1 0 1 1
0.05 0.95 52.01629419 101.937323 129.939421 5.47728489 1.00518915 3.6732879 0.85930064 0.1836644 0.8163356 1
0.1 0.9 50.07738862 92.6548109 119.739494 4.53320645 1.02071271 2.76331175 0.80407647 0.27633117 0.72366883 1
0.15 0.85 49.02682303 87.935226 114.498991 3.80029602 1.04673942 2.19855191 0.78849084 0.32978279 0.67021721 1
0.2 0.8 48.4547651 85.4531849 111.727212 3.22590286 1.08374745 1.8135768 0.7966058 0.36271536 0.63728464 1
0.25 0.75 48.15259014 84.1665616 110.285951 2.77179716 1.13253278 1.53481997 0.82172668 0.38370499 0.61629501 1
0.3 0.7 48.00325218 83.5368653 109.579444 2.4099407 1.19423246 1.32446639 0.86094296 0.39733992 0.60266007 0.99999999
0.35 0.65 47.93821455 83.2638958 109.272945 2.11957319 1.2703634 1.16107843 0.91326546 0.40637745 0.59362255 1
0.4 0.6 47.91787244 83.1786753 109.177227 1.88518445 1.36287795 1.03162596 0.97891603 0.41265038 0.58734962 1
0.45 0.55 47.92183792 83.1952822 109.195881 1.69508929 1.47423902 0.92778574 1.0590844 0.41750358 0.58249642 1
0.5 0.5 47.9439674 83.2880102 109.300027 1.54041639 1.60751821 0.84406721 1.15593279 0.42203361 0.57796639 1
0.55 0.45 47.99002741 83.4812974 109.517062 1.41438454 1.76652209 0.77680695 1.27279151 0.42724382 0.57275618 1
0.6 0.4 48.07713648 83.8478973 109.928509 1.31178016 1.9559529 0.72361848 1.41457228 0.43417109 0.56582891 1
0.65 0.35 48.23477418 84.5148332 110.676385 1.22857721 2.18161266 0.68311183 1.5885066 0.44402269 0.55597731 1
0.7 0.3 48.50764807 85.6800813 111.981061 1.16165857 2.45066141 0.65480922 1.80544516 0.45836645 0.54163355 1
0.75 0.25 48.96134378 87.6480255 114.178833 1.10861075 2.77194433 0.63926015 2.08221954 0.47944512 0.52055488 1
0.8 0.2 49.69283697 90.9026402 117.798414 1.06757177 3.15640607 0.63845456 2.44618177 0.51076365 0.48923635 1
0.85 0.15 50.85049377 96.265203 123.723019 1.03711819 3.61761654 0.65683153 2.94462131 0.5583068 0.4416932 1
0.9 0.1 52.67458688 105.264907 133.563611 1.01618121 4.17243897 0.70373829 3.66635536 0.63336446 0.36663554 1
0.95 0.05 55.58767838 121.130724 150.632685 1.00398471 4.84188066 0.80008813 4.79832554 0.76008372 0.23991628 1 1
1 0 60.42574801 152 182.990744 1 5.65217847 1 6.8045812 1 0 1
21
0.9

P A12 A21
0.8
760 1.902973993 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1 K2 y1 y2 Sy
0 1 101.2953998 796.068444 760 6.70580784 1 7.02405528 1 0 1 1 0.7
0.05 0.95 94.61685477 624.724171 616.705491 5.47728489 1.00518915 4.50235824 0.81566536 0.22511791 0.77488209 1
0.1 0.9 91.32869851 552.423821 554.704827 4.53320645 1.02071271 3.2950674 0.74499246 0.32950674 0.67049321 0.99999995 0.6
0.15 0.85 89.55137321 516.353375 523.368245 3.80029602 1.04673942 2.581968 0.72082918 0.3872952 0.6127048 1
0.2 0.8 88.56445099 497.191024 506.600972 3.22590286 1.08374745 2.11038151 0.72240462 0.4220763 0.5779237 1 0.5
0.25 0.75 88.0202953 486.883044 497.545266 2.77179716 1.13253278 1.77571189 0.74142937 0.44392797 0.55607203 1
0.3 0.7 87.72920808 481.442947 492.755601 2.4099407 1.19423246 1.52664336 0.7742957 0.45799301 0.54200699 1
0.4
0.35 0.65 87.58089225 478.690755 490.329674 2.11957319 1.2703634 1.33502643 0.81960115 0.46725925 0.53274075 1
0.4 0.6 87.51036636 477.386694 489.179545 1.88518445 1.36287795 1.18416049 0.87722634 0.4736642 0.5263358 1
0.3
0.45 0.55 87.48148613 476.853544 488.709206 1.69508929 1.47423902 1.06356492 0.94799234 0.47860421 0.52139579 1
0.5 0.5 87.47851926 476.798801 488.660909 1.54041639 1.60751821 0.96640617 1.03359383 0.48320308 0.51679692 1
0.55 0.45 87.50192757 477.230856 489.042074 1.41438454 1.76652209 0.88814203 1.1367153 0.48847812 0.51152188 1 0.2
0.6 0.4 87.56673761 478.428789 490.098665 1.31178016 1.9559529 0.82578078 1.26132882 0.49546847 0.50453153 1
0.65 0.35 87.7029253 480.95427 492.324993 1.22857721 2.18161266 0.77748613 1.41324005 0.50536598 0.49463402 1 0.1
0.7 0.3 87.95790352 485.712691 496.515459 1.16165857 2.45066141 0.74241093 1.60104115 0.51968765 0.48031235 1
0.75 0.25 88.40187883 494.092422 503.881507 1.10861075 2.77194433 0.7207318 1.83780459 0.54054885 0.45945115 1 0
0.8 0.2 89.13791727 508.251628 516.289602 1.06757177 3.15640607 0.71394091 2.14423636 0.57115273 0.42884727 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.85 0.15 90.32075355 531.717686 536.751247 1.03711819 3.61761654 0.72559748 2.55494762 0.61675786 0.38324214 1
0.9 0.1 92.19355831 570.72455 570.497001 1.01618121 4.17243897 0.76310469 3.13205779 0.68679422 0.31320578 1
0.95 0.05 95.16569447 637.529181 627.582281 1.00398471 4.84188066 0.84219678 3.99826119 0.80008694 0.19991306 1
1 0 99.99682974 760 730.213579 1 5.65217847 1 5.43065457 1 0 1
21 180

P A12 A21
160
3800 1.902973993 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1 K2 y1 y2 Sy
0 1 163.2905399 5115.94318 3799.99995 6.70580784 1 9.02803472 0.99999999 0 0.99999999 0.99999999 140
0.05 0.95 151.4049871 3751.39619 2903.4878 5.47728489 1.00518915 5.4072278 0.76804064 0.27036139 0.72963861 1
0.1 0.9 145.8499112 3223.48589 2545.85434 4.53320645 1.02071271 3.84545448 0.68383839 0.38454545 0.61545455 1 120
0.15 0.85 142.8859657 2967.47007 2369.72321 3.80029602 1.04673942 2.96770124 0.65275861 0.44515519 0.55484481 1
0.2 0.8 141.2307194 2831.83629 2275.61578 3.22590286 1.08374745 2.40400757 0.64899811 0.48080151 0.51919849 1
0.25 0.75 140.2990701 2757.73772 2223.95637 2.77179716 1.13253278 2.01154988 0.66281671 0.50288747 0.49711253 1 100

0.3 0.7 139.7813165 2717.2442 2195.64907 2.4099407 1.19423246 1.72326247 0.69003037 0.51697874 0.48302126 1
0.35 0.65 139.4995732 2695.41291 2180.36492 2.11957319 1.2703634 1.50345393 0.72890942 0.52620888 0.47379112 1 80
0.4 0.6 139.3482387 2683.74553 2172.18993 1.88518445 1.36287795 1.3314093 0.77906046 0.53256372 0.46743628 1
0.45 0.55 139.2660236 2677.42425 2167.75885 1.69508929 1.47423902 1.19433505 0.8409986 0.53745077 0.46254923 1
60
0.5 0.5 139.2217842 2674.02782 2165.37746 1.54041639 1.60751821 1.08397797 0.91602203 0.54198899 0.45801101 1
0.55 0.45 139.2072287 2672.91111 2164.5944 1.41438454 1.76652209 0.99487478 1.00626416 0.54718113 0.45281887 1
0.6 0.4 139.2335638 2674.93185 2166.01135 1.31178016 1.9559529 0.92340067 1.114899 0.5540404 0.4459596 1 40
0.65 0.35 139.3308985 2682.41129 2171.25476 1.22857721 2.18161266 0.86724984 1.24653602 0.56371239 0.43628761 1
0.7 0.3 139.5501854 2699.32414 2183.10436 1.16165857 2.45066141 0.82518237 1.4079078 0.57762766 0.42237234 1
20
0.75 0.25 139.9682709 2731.80978 2205.83756 1.10861075 2.77194433 0.79697729 1.60906813 0.59773297 0.40226703 1
0.8 0.2 140.6976909 2789.24672 2245.94541 1.06757177 3.15640607 0.78361081 1.86555678 0.62688864 0.37311136 1
0.85 0.15 141.9048218 2886.45242 2313.57953 1.03711819 3.61761654 0.78778745 2.20253779 0.66961933 0.33038067 1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9 0.1 143.844357 3048.3802 2425.59326 1.01618121 4.17243897 0.81518597 2.66332628 0.73366737 0.26633263 1
0.95 0.05 146.9289853 3321.01659 2612.46674 1.00398471 4.84188066 0.87743418 3.32875057 0.83356247 0.16643753 1
1 0 151.8839914 3800 2936.07226 1 5.65217847 1 4.36715906 1 0 1
21

Una mezcla Benceno Tolueno que tiene 56% de benceno , se somete a flash a 1 atm de presión y se desea que se vaporice el 40% de la alimentación
a.- Determinar las composiciones y cantidades de las corrientes de salida
b.- Determinar la temperatura de operación

Mezcla Benceno Tolueno

1 115
Comp A B C Tb 120
BENZENE 15.9008 2788.51 -52.36 353.3 80.15 0.9
110
TOLUENE 16.0137 3096.52 -53.67 383.8 110.65
0.8
110
105
F 200 kmol/h V 80 kmol/h 0.7
zi 0.56 L 120 kmol/h
 0.4 100
0.6 100

0.5
0.56 110 95
T 92.95 0.56 0 90
0.4
90
0.3
T 0 92.95
1 92.95 0.2 85
80
L/V 1.5
x 0.473 L/V 1.50574713 0.1
80
y 0.691 0
70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 75
0.473 0
0.473 92.95 70
0.691 92.95 60 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.691 0
D1.* We are separating a mixture of methanol and water in a flash drum at 1 atm pressure. Equilibrium T x y
105
data are listed in Table 2-7. 100 0 0 1
a. Feed is 60 mol% methanol, and 40% of the feed is vaporized. What are the vapor and liquid 96.4 0.02 0.134 100
0.9
mole fractions and flow rates? Feed rate is 100 kmol/h. 93.5 0.04 0.23 95 0.8
b. Repeat part a for a feed rate of 1500 kmol/h. 91.2 0.06 0.304
90 0.7
c. If the feed is 30 mol% methanol and we desire a liquid product that is 20 mol% methanol, what 89.3 0.08 0.365
V/F must be used? For a feed rate of 1000 lbmol/h, find product flow rates and compositions. 87.7 0.1 0.418 85 0.6
d. We are operating the flash drum so that the liquid mole fraction is 45 mol% methanol. L = 1500 84.4 0.15 0.517 80 0.5
kmol/h, and V/F = 0.2. What must the flow rate and composition of the feed be? 81.7 0.2 0.579 0.4
75
e. Find the dimensions of a vertical flash drum for Problem 2.D1c. 78 0.3 0.665
0.3
Data: ρw = 1.00 g/cm3, ρm,L = 0.7914 g/cm3, MWw = 18.01, MWm = 32.04. Assume vapors are 75.3 0.4 0.729 70
ideal gas. 73.1 0.5 0.779 0.2
65
f. If z = 0.4, p = 1 atm, and Tdrum = 77°C, find V/F, xm, and ym. 71.2 0.6 0.825 0.1
60
g. If F = 50 mol/h, z = 0.8, p = 1 atm, and ym = 0.892 mole fraction methanol, find V, L, and xm. 69.3 0.7 0.87 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
67.6 0.8 0.915 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Txy 66 0.9 0.958
a. Feed is 60 mol% methanol, and 40% of the feed is vaporized. What are the vapor and liquid 65 0.95 0.979
mole fractions and flow rates? Feed rate is 100 kmol/h. 64.5 1 1

F 100 105
z 0.6 z 0.6 0
Y 0.4 100 0.6 100

V 40 95 T 0 73.37
L 60 1 73.37
90
L/V 1.5 x 0.486 0
85 0.486 73.37
y 0.774 73.37
80
0.774 0

0.174
75
0.114
70
1.52631579
65

60
V 40 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
L 60
1

-L/V -1.5 z 0.6 0

0.9 0.6 0.6
x0 0.6
y0 0.6 0.8 -L/V 0.6 0.6
0 1.5
x 0 0.7
y 1.5
0.6
x 0.486 0
y 0.486 0.773
0 0.773
0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

c. If the feed is 30 mol% methanol and we desire a liquid product that is 20 mol% methanol, what
V/F must be used? For a feed rate of 1000 lbmol/h, find product flow rates and compositions.

F 1000 1
z 0.3
x 0.2 0.9

z 0.3 0 0.8
0.3 0.3
0.7
x 0.2 0
0.2 1
0.6

-L/V 0.3 0.3

0.5
0.2 0.58 y

-2.8 0.4

L/V 2.8
0.3
Y 0.26315789
0.2
F 1000
V 263.157895 0.1
L 736.842105
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

D2.* Two flash distillation chambers are hooked together as shown in the diagram. Both are at 1 atm
pressure. The feed to the first drum is a binary mixture of methanol and water that is 55 mol%
methanol. Feed flow rate is 10,000 kmol/h. The second flash drum operates with (V/F)2 = 0.7 and
the liquid product composition is 25 mol% methanol. Equilibrium data are given in Table 2-7.
1
a. What is the fraction vaporized in the first flash drum?
b. What are y1, y2, x1, T1, and T2?
0.9

F1 10000 kmol/h
z1 0.55 0.8

0.7

z1 0.55 0.55 1 0.6

0.55 0
0.9
0.5
Y 0.162 0.8

F 10000 0.7 0.4

V 1620 0.6
L 8380 0.3
0.5
-L / V -5.17283951
0.4
0.2
x y 0.3
0.55 0.55
0.2 0.1
0 3.39506173
0.1

x y 0
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.506 0.77760494

Comp z x y F L V
MetOH 0.55 0.506 0.77760494 5500 4240.28 1259.72
W 0.45 0.494 0.22239506 4500 4139.72 360.28
10000 8380 1620 1
z1 0.506 0.506 0.9
0.506 0
0.8

Y 0.7 0.7
F 8380 0.6
V 5866
0.5
L 2514
-L / V -0.42857143 0.4

0.3
x y
0.2
0.506 0.506
0 0.72285714 0.1

0
x y 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.25 0.61571429