U 20% EXCESS

O2 21%
N2 79%

F P
C2H6 80% C2H6
O2 20% O2
N2
CO2
H2O
CO2
Nt F 1 Species
U 1
P 6
8 C2H6
O2
Nr C 1 N2
H 1 CO2
O 1 H2O
N 1 CO
10% CO 1 jumlah
10% Tidak bereaksi 1
20% Excess 1
7

Karena Nt 8=7 tidk sama

maka dapat dimisalkan Basis F=100mol
Kalau yang diketahui excess berarti menggunakan reaksi sempurna
Reaksi teoritis C2H6 + 3,5 O2 = 2CO2 + 3H2O
80 280 160 240

Excess udara (Mol Oksigen in - Mol Oksigen teoritis)/Mol Oksigen teoritis

0,2 mol O2 in - (280-20)/(280-20)
Mol O2 in 312

Udara yang masuk 100/21 x 312

1485.714

Masuk keluar
f u reaksi 1 reaksi2 p
x n x n koef n koef n x
0.8 80 0 1 64 1 8 0.0049088368
0.2 20 0.21 311.9999 3.5 224 2.5 20 0.0539971676
0 0 0.79 1173.714 0 0 0 0 0.7201963412
0 0 0 0 2 128 0 0 0.0785413882
0 0 0 0 3 192 3 24 0.1325385927
0 0 0 0 0 0 2 16 0.0098176735
1 100 1 1485.714
n
8
87.99994
1173.714
128
216
16
1629.714
Example 3

90% HNO3
P H2O

F U

10% HNO3 98% H2SO4

60% H2SO4 H2O
30% H2O S
65% H2SO4
20% HNO3
15% H2O

Persamaan NM total F+P+U=S

HNO3 44.23077
Lb larutan ntuk mendapatkan 1000 lb
Nt Nr
F 1 H2SO4
P 1 HNO3
U 1 H2O
S 1

Basis S 1000 lb
masuk Keluar
F P U S
x n x n x n x n
HNO3 0.1 44.23077 0.9 155.7692 0 0 0.2 200
H2SO4 0.6 265.3846 0 0 0.98 384.6154 0.65 650
H2O 0.3 132.6923 0.1 17.30769 0.02 7.849294 0.15 150
total 1 442.3077 1 173.0769 1 384.6154 1 1000
trial 392.4647
Eror E 0

masuk keluar
1 2 3 4
komponenx n x n x n x n
HNO3 0.1 0.9 0 0.2 200
H2SO4 0.6 0 0 0 0.98 980 0.65 650
H2O 0.3 0.1 0.02 0.15 150
total 1 0 1 0 1000 1 1000
trial 200
error
 soal 2.3

<M> sugar 1000lb/hr

<F> Cane crystalizer

<L>
16% sugar water
25% water
59% pulp N
<H>
mile screen evaporato
15% Sugar
r
<E>
13% Sugar <J> water
<D> Bagasse 14% Pulp vapor
80% pulp <G> Solid
95% pulp

F D E G H
KOMPONEx n x n x n x n x
sugar 0.16 13260.91 0 0.13 1016.461 0 0 0.15
pulp 0.59 48899.59 0.8 47804.94 0.14 1094.65 0.95 1094.65 0
water 0.25 20720.16 0.2 15012.35 0.73 5707.819 0.05 41.15226 0.85
total 1 82880.66 1 75061.73 1 7818.93 1 1152.263 1
trial 75061.73
error 0 trial 1152.263
eror 0
 Nt F 1 Nr F 1
D 1 D 1
E 1
G 1
L H 1
1500 lb/hrWater J 1
M 1
L 1
Jumlah 8

masuk keluar
F D E G
Sugar
Water
Pulp

J N L M
n x n x n x n x n
1000 0 0.4 1000 0 1 1000
0 0 0 0 0 0 0
5666.667 1 4166.667 0.6 1500 1 1500 0 0
6666.667 4166.667 1 2500 1500 1 1000

2500
 <M> sugar 1000lb/hr
crystalizer
<F> Cane
16% sugar
25% water N
59% pulp
screen <H>
mile evaporator
15% Sugar
<E>
13% Sugar
<D> Bagasse 14% Pulp <J>
80% pulp <G> Solid vapor
95% pulp
Basis 1 hr

Crytalizer
Masuk Keluar
N L M
x n x n x n
Sugar 0.4 1000 0 0 1 1000
Water 0.6 1500 1 1500 0 0
Pulp 0 0 0 0 0 0
total 1 2500 1000

Screen
Masuk Keluar
E G H
x n x n x n
Sugar 0.13 1016.461 0 0 0.15 1000 Sugar
Water 0.73 5707.819 0.05 41.15226 0.85 5666.667 Water
Pulp 0.14 1094.65 0.95 1094.65 0 0 Pulp
Total 1 7818.93 1 1152.263 1 6666.667 Total
trial 1152.263
eror 0

Nb 15 %sugar = 13% sugar asalkan sama saama dibuang kalau gak dibuang berarti tdk smaa
crystalizer
L
1500 lb/hrWater

evaporator

water

Evaporator
Masuk Keluar
N H J
x n x n x n
Sugar 0.4 1000 0.15 1000 0 0
Water 0.6 1500 0.85 5666.667 1 4166.667
Pulp 0 0 0 0 0 0
Total 1 2500 6666.667 4166.667

Mile
Masuk Keluar
F D E
x n x n x n
0.16 8482.584 0 0 0.13 1016.461
0.25 13254.04 0.2 7546.22 0.73 5707.818
0.59 31279.53 0.8 30184.88 0.14 1094.65
53016.15 37731.1 7818.929
trial 37731.1
eror 0
 W

Evaporator

Crystalizer

sistem mixing point

R F D
komponen
x n x n x n
KNO3 0.375 2875 0.2 2000 0.275943 4875
H2O 0.625 4791.667 0.8 8000 0.724057 12791.67
total 1 7666.667 1 10000 1 17666.67

sistem evaporator
D W M
komponen
x n x n x n
KNO3 0.275943 4875 0 0 0.5 4875
H2O 0.724057 12791.67 1 7916.667 0.5 4875
total 1 17666.67 1 7916.667 1 9750

sistem crystalizer
M C R
komponen
x n x n x n
KNO3 0.5 4875 0.96 2000 0.375 2875
H2O 0.5 4875 0.04 83.33333 0.625 4791.667
total 1 9750 1 2083.333 1 7666.667
D F

trial R 7666.6666667
E1 -5.820766E-11

trial C 2083.3333333
E2 4.638423E-11 ~ 0
Soal no 3.70 Himmelblau edisi 6
B D

A
Reactor distilator

Reactor
basis kgmol
komponen

Si
H
Cl
total

fraksi mol D
H2SiCl2 21.42 0.2142
SiCl4 14.29 0.1429
H2 64.29 0.6429

arus A 100kg massa fraksi massa

Si 28 100 1
H 1 0
Cl 35.5 0
100 1

arus B 100 mol

Si 28 0
H 1 100 0.0273972603
Cl 35.5 3550 0.9726027397
3650

arus D 100 mol

Si 28 999.88 0.2117806536
H 1 171.42 0.0363077966
Cl 35.5 3550 0.7519115498
4721.3

arus E 100 mol

Si 28 2800 0.2066420664
H 1 100 0.0073800738
Cl 35.5 10650 0.7859778598
13550
 A+B=D+E
E=D-B-A

stilator
E
Mr HSiCl3 135.5

masuk keluar
A B D E
x n x n x n x n
1 100 0 0 0.211781 50 0.206642 50
0 0 0.027397 10.35774 0.036308 8.572028643 0.00738 1.785714
0 0 0.972603 367.6999 0.751912 177.5213026 0.785978 190.1786
1 100 1 378.0576 1 236.0933312 1 241.9643
trial 236.0933312
error 0
 H2O
D O2
18% C2H6 terkonversi E N2

A B C Separator (CH2)2O
Reactor
C2H6
air

O2 R
N2
C2H6

Sistem mixing point

masuk keluar
komponen R A B
x n x n x n
C2H6 0.909091 udara pada A
O2 0 0.019091
N2 0 0.071818
H2O 0 0 0
(CH2)2O 0 0 0
Total 0 1

sistem reactor
masuk keluar
komponen B c
x n x n
C2H6 0 0
O2 0 0
N2 0 0
H2O 0 0
(CH2)2O 0 0
Total 0

sistem separator
masuk keluar
komponen c D E F
x n x n x n x n
C2H6 0 0
O2 0 0
N2 0 0
H2O 0 0
(CH2)2O 0 0
Total
 F

udara pada A 0.090909

O2 0.019091
N2 0.071818

R
x n
 F1 F2 F3 Absorber &
Catalytic Reactor
C3H8 Distillation Tower

F6
0,8 C3H8
0,2 C3H6

sistem mixing point

masuk keluar
komponen F6 F1 F2
x n x n x n
C3H8
C3H6
H2
Total 0 0

sistem catalytic reactor

masuk keluar
komponen F2 F3
x n x n
C3H8 0 0
C3H6 0 0
H2 0 0
Total 0 0

sistem absorber dan destilation tower

masuk keluar
komponen F3 F4 F5 F6
x n x n x n x
C3H8 0 0
C3H6 0 0
H2 0 0
Total
 F4 H2
orber &
tion Tower
F5 C3H6

F6
n
 F2 100% H2O

F1 F3 F4
reaktor konversi 60% separator
C2H2 52.50%
C2H4 47.50%
C2H2
C2H4
H2O F6 C2H4
C2H2

Basis 100 mol

mol C2H2 : mol C2H4 1/1,105

C2H4 0,4 Kg dari Air
Misal basis 100 kg

MOl H2O Di F2
H2O massa BM C2H4 massa BM mol H2O
0.4 18 28 171.8889
 F5
separator
C2H5OH 70%
air
C2H4O2

sistem mixing point

masuk
komponen F6 F1 F2
x n x n x n
C2H2 0.415646 27.5625 0.525 262.5 0 0
C2H4 0.584354 38.75 0.475 237.5 0 0
H2O 0 0 0 0 1 100
C2H5OH 0 0 0 0 0 0
C2H4O2 0 0 0 0 0 0
Total 1 66.3125 1 571.8889 1 100

sistem reaktor
masuk keluar
komponen F3 F4
x n x n
C2H2 0.392931 290.0625
C2H4 0.37422 276.25
H2O 0.232848 171.8889
C2H5OH 0 0
C2H4O2 0 0
Total 1 738.2014 0

sistem separator
masuk keluar
komponen F4 F5 F6
x n x n x n
C2H2
C2H4
H2O
C2H5OH
C2H4O2
Total 0 0 0
 Keluar
F3
x n
0.392931 290.0625
0.37422 276.25 Trial R 500
0.232848 171.8889 E1 71.88889
0 0
0 0
1 738.2014
 sistem mixing point

komponen

<1> <3> H2
H2 Ar
N2 N2
Ar NH3
Total

Sistem Reaktor

komponen

H2O
Ar
N2
NH3
Total

0.1999

sistem separator

komponen

H2O
Ar
N2
NH3
Total

Over all
1 6 7
x n n m n m
H 0.7516 150.32 0.8001
N 0.2457 49.14
Ar 0.0027 0.27 0 0 0.27
1
Basis 100 mol mol
H2 0.7516 150.32 150.32
N2 0.2457 49.14 687.96
Ar 0.0027 0.27 10.8
Total 1
sistem mixing point
Masuk Keluar
1 2 3
x n x n x n

#DIV/0! #DIV/0! 1 #DIV/0! #DIV/0! 0

0 0 0 0 #DIV/0! 0
0 0 0 0 0 0
0 0 0 0 0 0

Sistem Reaktor
masuk keluar
3 4
x n x n

sistem separator
masuk keluar
F4 F5 F6
x n x n x n