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CHEMISTRY

Daily Practice Sheets

Target : IIT JEE DPS No.3 Topic : Basic Physical Chemistry

Miscellaneous 7. The number of moles of water are present in one


1. The vapour density of a gas is 15.15 g of the gas litre of water-
will occupy a volume of…….cm3 at N.T.P. a) 5.55 moles b) 0.55 moles
a) 11200 b) 22400 c) 1120 d) 2240 c) 55.5 moles d) 11 moles

2. The number of moles of barium carbonate which 8. How many methane molecules are there in 25.0g
contains 1.5 moles of oxygen atom is- of methane?
a) 0.5 b) 1.0 c) 1.5 d) 0.25 a) 9.41 × 1023 b) 9.41 × 10–23
c) 3.764 × 1024 d) 3.764 × 1023
3. At N.T.P, the mass of 1 litre of a gas is 3g
Molecular mass of the gas is 9. Vapour density of volatile substance is 4 in
a) 67.2 b) 65.6 c) 36.6 d) 38.8 comparison to methane (CH4 = 1). Its molecular mass
will be

4. Which statement is/are correct : a) 8 b) 2 c) 64 d) 128

a) Equal volumes of different gases under similar


conditions of temperature and pressure contain equal 10. 1.0 mole of CO2 contains-
number of atoms a) 6.02 × 1023 atoms of C
b) 1 mole of C12H22O11 contain equal number of b) 6.02 × 1023 atoms of O
atoms c) 18.1 × 1023 molecules of CO2
c) Gram molecular volume is the volume occupied by d) 3g atoms of CO2
1 mole of a gas
d) Gram atomic mass of an element may be defined
11. The largest number of molecules is in
as the mass of Avogadro’s number of atoms
a) 28g of CO b) 46g of C2H5OH
c) 36g of H2O d) 54g of N2O5
5. Which statement is incorrect
a) Mass of 3.01 × 1023 molecules of methane is 8g
12. The molecular mass of CO2 is 44 amu and
b) Avogadro’s number varies with temperature and
pressure Avogadro’s number is 6.02 × 1023. Therefore the
mass of one molecule of CO2 is
c) The vapour density of Ozone is 24
a) 7.31 × 10–23 b) 3.65 × 10–23
d) 18g of water vapour and 18g of ice will not
c) 1.01 × 10–23 d) 2.01 × 10–23
contain the same number of molecules
13. The number of moles of H2 in 0.224 litre of
hydrogen gas at NTP is
6. One litre of a gas at NTP weighs 1.97 g. The a) 1 b) 0.1 c) 0.01 d) 0.001
molecular mass of gas are-
a) 441.28 b) 89.25 14. The volume of 1g helium at NTP in litre is
c) 44.128 d) 882.54 a) 5.6 b) 0.56 c) 2.8 d) 0.28

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15. At room temperature and pressure , two flasks of 22. Complete the following table :-
equal volumes are filled with H2 and O2 separately. Mole of Compound Mole of cations Mole of anions
Particles which are equal in number in the two flasks 1 mole NaCl (a) (b)
are 2 mole Na2SO4 (c) (d)
(e) mole of 1 mole of Ca2+ (f)
a) atoms b) electrons
calcium nitrate
c) molecules d) Neutrons
(g) 0.50 mole of NH 4 0.25 mole
2
16. The total number of electrons present in 18 ml of of SO 4
water is- 23. What volume of solution of ethylene glycol,
a) 6.02 × 1024 b) 6.02 × 1023 C2H6O2, that is 56.0% ethylene glycol by mass
23
c) 9 × 6.02 × 10 d) 0.9 × 1025 contains 0.352 mol C2H6O2? The density of the
17. See the data given in the following table and fill solution is 1.072 g/mL.
in the blanks-
24. One mole of water contains :
Place Height g (msec– Pressur i) how many grams
2
of Hg in ) e ii) how many molecules
baromet (k Pa) iii) how many atoms of hydrogen
er iv) how many atoms of oxygen
New v) how much volume
Delhi, 76 cm 9.80530 100.9
India, Answers:
Greenwic 1a 2a 3a 4d 5b, d
h, X 9.79148 100.9 6c 7c 8a 9c 10a
England 11c 12a 13c 14a 15c
Brisbane, 16a 17a
Y 9.81184 100.9
Australia 18. 0.05 mol 19. 1.22
a) X = 76.07cm, Y = 75.91 cm 20. 2.142 mol H-atoms 21. a) O2, b) O2
22. a) 1 b) 1 c) 4 d) 2 e) 1 f) 2
b) X = 75.91 cm, Y = 76.07 cn 23. 36.35mL
c) X = 760 cm, Y = 76.91 cm 24. a) 18g; b) 6.02 × 1023 molecules;
23
d) X = 1.01325 cm, Y = 1.01325 cm c) 2 × 6.02 × 10 hydrogen atoms;
d) 6.02 × 1023 oxygen atoms; (e) 18 mL.
18. What is the final result of the following 1.12L
CO2 gas at NTP + 0.44g CO2 – 6.02 × 1021 molecules
1. Which of the following weighs the least?
of CO2 = x mol CO2
a) 2 g atom of N (at. wt. of N= 14)
19. What is the specific gravity of a liquid of 325 ml b) 3 × 1023 atoms of C (at. wt of C =12)
of the liquid has the same mass as 396 ml of water. c) 1 mole of S (at. wt. of S = 32)
d) 7 g silver (at. wt. of Ag = 108)
20. Suppose a sample of vitamin C is known to
contain 1.29 × 1024 hydrogen atoms (as well as other
kinds of atoms) Express the number of moles of 2. Which property of an element is always a whole
hydrogen atom. number?
a) Atomic weight b) Equivalent weight
21. Equal masses of SO2 and O2 are placed in a flask
c) Atomic number d) Atomic volume
at STP.
a) Which has larger number of molecules?
b) Which occupies larger volume? 3. The molecular weight of hydrogen peroxide is 34.
What is the unit of molecular weight?
a) g b) mol c) g mol–1 d) mol g –1

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4. Which of the following has smallest number of 12. How many moles of electron weigh one
molecules? kilogram
a) 0.1 mol of CO2 gas 1
a) 6.023 × 1023 b) 1031
b) 11.2 L of CO2 gas at NTP 9.108
c) 22 g of CO2 gas 6.023 1
c) 1054 d) 108
9.108  6.023
3
d) 22.4 ×10 ml of CO2 gas 9.108

5. At STP the density of CCl4 vapour in g/L will be 13. Which of the following represents/represent
nearest to 32 g of the substance?
a) 6.84 b) 3.42 c) 10.26 d) 4.57 a) one mole of oxygen atoms
b) one gram atom of sulphur
6. 1 c.c. of N2O at NTP contains c) 22.4 L of O 2 gas at STP
1.8 6.02 d) one mole of sulphur molecules
a) 1022 atoms b) 1023 molecules
224 22400
1.32 14. When 2.00 g of magnesium is made to react with
c) 1023 electrons d) all of the above
224 2 g of sulphur in the reaction Mg  S  MgS
a) Mg is the limiting reagent
7. The molecular weight of O2 and SO2 are 32 and b) 0.0625 mole of MgS is formed
64 respectively. At 150C and 150 mm Hg pressure, c) S is the limiting reagent
one litre of O2 contains ‘N’ molecules. The number
d) 0.02 mole of Mg is left unreacted
of molecules in two litres of SO 2 under the same
conditions of temperature and pressure will be
a) N/2 b) N c) 2N d) 4N 15. 4 g mixture of NaCl; and NaBr contains 30% Na
in the total mixture. Calculate the percentage
composition of mixture.
8. One litre of a gas at STP weighs 1.16 g. It can
possibly be
16. Calculate number of each atom present in 122.5
a) C2H2 b) CO c) O2 d) CH4
g KClO3.
9. The mass of a molecule of water
a) 3 × 10–26 kg b) 3 × 10–25 kg
17. If the components of air are N2 78%; O2 21%; Ar
c) 1.5 × 10–26 kg d) 2.5 × 10–26 kg 0.9% and CO2 0.1% by volume, what would be the
molecular weight of air?
10. The number of moles of oxygen in one litre of air
containing 21% oxygen by volume, in standard 18. Equal masses of oxygen, hydrogen and methane
conditions, is are taken in a container in identical conditions. Find
a) 0.186 mole b) 0.21 mole the ratio of their moles.
d) 2.10 mole d) 0.0093 mole
19. A sample of potato starch was ground in a ball
11. The number of atoms in 4.25 g of NH3 is mill to give starch like molecule of low molecular
approximately weight. The product analysed 0.086% of phosphorus.
If each molecule is assumed to contain one atom of
a) 1 × 1023 b) 2 × 1023 c) 4 × 1023 d) 6 × 1023
phosphours, what is the molecular weight of
material?

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20. Insulin contains 3.4% sulphur. Calculate 7. In the reaction 4NH3 (g) + 5O2 (g)  4NO (g) +
minimum mol. wt. of insulin. 6H2O (l) when 1 mol of ammonia and 1 mol of O2 are
Answer : made to react to completion then:

1. b 2. c 3. c 4. a 5. a a) 1.0 mol of H2O is produced

6. d 7. c 8. a 9. a 10. d b) 1.0 mol of NO will be produced

11. d 12. d 13. c 14. bcd c) all the oxygen will be consumed

15. 28.5g 16. 45.15% NaCl; d) all the ammonia will be consumed
54.85%NaBr 17. K = N; Cl = N,O = 3 N
atoms 8. The maximum number of molecules is present in:
18. 1:16:2 19. 3.6 ×104 20. 941.176 a) 15 L of H2 gas at STP b) 5 L of N2 gas at STP
c) 0.5 g of H2 gas d) 10 g of O2 gas
Miscellaneous
1. A sample of copper sulphate pentahydrate, 9. The number of moles present in 720 g of water is:
CuSO4. 5H2O contains 3.782 g of Cu. How many a) 14 mol b) 24 mol c) 34 mol d) 40 mol
grams of oxygen are in this sample?
a) 0.952 g b) 3.809 g c) 4.761 g d) 8.576 g 10. Volume of a gas at NTP is 1.12 × 10–7 cc. The
number of molecules in it is:
2. Cortisone is a molecular substance containing 21 a) 3.01 × 1012 b) 3.01 × 1018
atoms of carbon per molecule. The mass percentage d) 3.01 × 1024 d) 3.01 × 1030
of carbon in cortisone is 69.98%. What is the molar
mass of cortisone?
11. 1021 molecules are removed from 200 mg of
a) 176.5 b) 252.2 c) 287.6 d) 360.1 CO2. The moles of CO2 left are:
a) 2.88 × 10–3 b) 28.8 × 10–3
3. 2 mol of H2 S and 11.2 L SO2 at N.T.P react to c) 288 × 10–3 d) 28.8 × 103
form x mol of sulphur; x is:
SO2 + 2H2S  3S + 2H2O 12. At NTP, volume of a gas is 1.12 × 10 –7 cc. The
a) 1.5 b) 3 c) 11.2 d) 6 number of molecules is:
a) 3.01 × 1012 b) 3.01 × 1020
c) 3.01 × 1024 d) 3.01 × 1022
4. Which of the following samples contains
2.0 × 1023 atoms?
13. The vapour density of a gas A is four times
a) 8.0 g O2 b) 3.0 g Be c) 8.0 g C d) 12.0 g He than that of B. If molecular mass of B is 1, then
molecular mass of A is:
5. An unknown amino acid has 0.032% sulphur. If 1
a) 1 b) 2 c) d) 4
each molecule has one S-atom only, 1 g of amino 4
acid has… molecules:
a) 6.02 ×1018 b) 6.02 × 1019 14. A mixture of 1.65 × 1021 molecules of x and 1.85
c) 6.02 × 1021 d) 6.02 × 1023 × 1021 molecules of y weigh 0.688 g. If the molecular
weight of y is 187, what is the molecular weight of x?

6. The number of moles of oxygen in one litre of air 15. An alloy of Fe (71.0%), Co (12.0%), and Mo
containing 21% oxygen by volume, in standard (17.0%) has a density of 8.20 g cm–3. How many
conditions, is: cobalt atoms are there in a cylinder of radius of 2.50
a) 0.186 mol b) 0.21 mol cm and a length of 10.0 cm? (mass of the cylinder =
volume × density) = r2l × d) (Co = 57)
c) 0.0093 mol d) 2.10 mol

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16. What volume of solution of ethanol, C2H6O, that a) 0.25 b) 4 c) 2 d) 7
is 94% ethanol by mass contains 0.200 mol C2H6O?
The density of the solution is 0.807 g/mL. 7. The weight of one atom of uranium is 238 amu. Its
actual weight is
17. What is the mass in grams of 10.0 billion SO2 a) 1.43 × 1026g b) 3.94 × 10–22g
molecules? –27
c) 6.99 × 10 g d) None of these

18. Myoglobin stores oxygen for metabolic process


in muscle. Chemical analysis shows that it contains 8. 12 g of an alkaline earth metal gave 14.8 g of its
0.34% Fe by mass. What is the molar mass of nitride. Atomic weight of that metal is
myoglobin? a) 20 b) 12 c) 40 d) 14.8
(There is one Fe atom per molecule; Fe = 56)
9. The molecular weight of hydrogen peroxide is 34.
19. Atoms of the element X (atomic mass = 23) are What is the unit of molecular weight?
spherical. It each atom is at the corner of a cube in
contact; calculate length of the cube, (d = 6.2 g cm–3) a) g b) mol c) g mol–1 d) mol g–1

10. If 20% nitrogen is present in a compound, its


molecular weight will be
a) 144 b) 28 c) 100 d) 140
Answer :
1. d 2. d 3. a 4. b 5. a 11. How may moles of helium gas occupy 22.4 litres
6. c 7. c 8. a 9. d 10. a at 300C and 1 atmosphere?
11. a 12. a 13. d a) 0.11 b) 0.90 c) 1.0 d) 1.11
14. 230 15. 19.71 × 1023
16. 12.13 17. 1.063 × 10–12g
12. Number of molecules in 100 ml of each of O 2,
18. 16471 g mol– 19. AB = 2.27 A0 NH3 and CO2 at STP are
a) in the order CO2 < O2 < NH3
1. SI unit of time is
b) in the order NH3 < O2 < CO2
a) second b) minute c) hour d) day
c) the same
2. SI unit of mass is d) NH3 = CO2 < O2
a) gram b) kilogram c) pound d) none
13. The number of atoms present in 0.5 g atoms of
3. SI unit of length is nitrogen is same as the atoms in
a) Angstrom b) millimetre a) 12 g of C b) 32 g of S
c) metre d) kilometre c) 8 g of oxygen d) 24 g of Mg

4. SI unit of temperature is
14. The pair of gases containing the same number of
a) centrigrade b) Fahrenheit
molecules is
c) absolute d) Kelvin
a) 22 g of CO2 and 72 g of N2
5. Difference in density is the basis of
a) ultrafiltration b) molecular attraction b) 11 g of CO2 and 28 g of N2
c) gravity separation d) molecular seiving c) 44 g of CO2 and 7 g of N2
d) 11 g of CO2 and 7 g of N2
6. The ratio of the rates of diffusion of a given
element to that of helium is 4. What will be the
molecular weight of the element?

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15. Which has the highest mass?
a) 50 g of iron b) 5 moles of N2
c) 0.1 g atom of Ag d) 1023 atoms of carbon

16. Avogadro number of helium atom weighs


a) 1 g b) 4 g
c) 8 g d) 4 × 6.02 × 1023g

17. Prove from the following results that mercury


molecules are monoatomic.
a) 10 g of mercury combine with 0.8 g of oxygen to
form an oxide.
b) 1000 mL of vapour of Hg at NTP weigh 8.923 g.
c) The specific heat of the metal is 0.033.

18. Natural hydrogen gas is a mixture of 1H and 2H


in the ratio of 5000: 1. Calculate the atomic mass of
the hydrogen.

19. Calculate how many methane molecules and how


many hydrogen and carbon atoms are there in 25.0 g
of methane.

20. Calculate the number of g-moles of CaO that


could be obtained from 42.54g of CaCO3 and convert
the number of g-moles to grams.

21. How many moles are there in 1 m3 of any gas at


NTP?
Answer :
1. a 2. b 3. c 4. d 5. c
6. a 7. b 8. c 9. c 10. d
11. b 12. c 13. c 14. d 15. b
16. b
17. 100, 199.879, 
~ 1
18. 1.000199
19. 9.41 × 1023 CH4 molecules, 9.41 × 1023 carbon
atoms and 37.64 × 1023 hydrogen atoms
42.54
20. No. of g-moles = = 0.4254, Mass of CaO
100
= 0.4254 ×56 = 23.8g
21. 44.6 moles

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