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Infrared Physics & Technology 44 (2003) 125–132

www.elsevier.com/locate/infrared

An analytical model of a double-heterostructure


mid-infrared photodetector
R.K. Lal, M. Jain, S. Gupta, P. Chakrabarti *

Department of Electronics Engineering, Institute of Technology, Banaras Hindu University, Varanasi 221005, India
Received 21 February 2002

Abstract

A complete analytical model of a mid-infrared (MIR) double heterostructure (DH) photodetector has been devel-
oped. The model is physics based and takes into account all the dominant mechanisms that shape the characteristics of
room temperature MIR DH photodetectors. It can be used to characterize theoretically the performance of narrow
bandgap III–V based semiconductor MIR photodetectors for non-telecommunication applications. The model has been
applied to estimate the detectivity, photoresponse and quantum efficiency of an Pþ –As0:55 Sb0:15 P0:30 /n0 –InAs0:89 Sb0:11 /
Nþ –InAs0:55 Sb0:15 P0:30 DH MIR photodetector. The results obtained on the basis of the model are in good agreement
with reported experimental findings. The simulation code developed can be used as a tool by the design engineers for
useful fabrication guidelines.
Ó 2002 Elsevier Science B.V. All rights reserved.

Keywords: MIR detector; InAsSb; Responsivity; Detectivity; Double heterostructure

1. Introduction length region. Currently the dominant infrared


detector materials appropriate for 2–5 lm appli-
Mid-infrared (MIR) photodetectors operating cations are PbSe, HgCdTe and InSb related ma-
beyond 2 lm wavelength have a variety of appli- terials. However, both PbSe and HgCdTe-based
cations such as in gas sensors based on optical detectors are normally used in photoconductive
absorption, process control monitor, temperature mode and therefore result in slow response speed.
sensors, pulsed laser monitor and power meters PbSe also suffers from undesirable 1=f -noise
[1,2]. In particular, there is a great demand for problems, while HgCdTe normally requires ther-
efficient and reliable photodetectors, which can be moelectric cooling below room temperature in
used for detection of several gases in environment order to achieve a sufficiently high detectivity for
and process control applications in 2–6 lm wave- successful instrumentation. Photovoltaic detectors
based on InAsSb related materials on the other
hand are faster and can operate beyond 5 lm
*
Corresponding author. Tel.: +91-542-307011; fax: +91-542-
wavelength. However, these devices require cryo-
317074. genic cooling to 77 K in order to obtain satisfac-
E-mail address: pchakra@bhu.ac.in (P. Chakrabarti). tory detector performance. There is therefore, a

1350-4495/02/$ - see front matter Ó 2002 Elsevier Science B.V. All rights reserved.
PII: S 1 3 5 0 - 4 4 9 5 ( 0 2 ) 0 0 1 9 0 - 1
126 R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132

Nomenclature

Lp hole diffusion length in n0 region nin intrinsic carrier concentration on the n0


Dp hole diffusion coefficient in n0 region side
Sp surface recombination velocity for holes v1 electron affinity of the larger bandgap
on the n0 side at the n0 –Pþ hetero- Pþ material
interface v2 electron affinity of the smaller bandgap
xp width of the depletion region at Pþ –n0 n0 material
heterointerface on Pþ side ap absorption coefficient of Pþ material
Ln electron diffusion length in Pþ region an absorption coefficient of n0 material
Dn electron diffusion coefficient in the Pþ Eg1 bandgap of the larger bandgap Pþ ma-
region terial
Sn surface recombination velocity of elec- Eg2 bandgap of the smaller bandgap n0
tron in Pþ side at the n0 –Pþ hetero- material
interface DEc conduction band-edge discontinuity at
xn width of the depletion region at Pþ –n0 the n0 –Pþ heterointerface
heterointerface on n0 side DEv valance band-edge discontinuity at the
t width of the Pþ region n0 –Pþ heterointerface
d width of the n0 region DEg bandgap difference between the mate-
r trap capture cross-section rial forming the heterointerface
Nf trap density at the n0 –Pþ heterointerface Vdp built-in potential at the heterointerface
q electronic charge on the larger bandgap Pþ side
k BoltzmannÕs constant Vdn built-in potential at the heterointerface
T detector temperature on the smaller bandgap n0 side
h PlanckÕs constant dp separation between the Fermi level and
c velocity of light in free space the top of the valance band on the Pþ
rp reflectance of the Pþ entrance face side
rn reflectance at the n0 –Pþ heterointerface dn separation between the Fermi level and
mpp effective mass of holes on Pþ side the bottom of the conduction band on
mnn effective mass of electrons on n0 side the n0 side
nip intrinsic carrier concentration on the Pþ A effective RichardsonÕs constant
side

need for improved MIR detectors and specifically models and simulation codes for analysis of room
for use in portable gas sensor instruments. A fast temperature MIR photodetectors based on narrow
photovoltaic detector based on narrow bandgap bandgap III–V semiconductors. As the technology
III–V materials operating at room temperature of these materials is not yet fully mature and the
beyond 4 lm would be a major advantage and cost of experimental investigations is high, there is
would have wide ranging applications. a need for further theoretical studies in the area
Although much work has already been done in to advance the existing knowledge. The results
the general area of modelling semiconductor pho- of theoretical studies will provide useful design
todetectors for the near-infrared region [3–5], guidelines for development of device prototypes.
comparatively less work has been done on the de- The modelling of detectors based on narrow
velopment models for MIR detectors. It is there- bandgap materials needs special attention. These
fore, necessary to develop both generic and specific models should take into consideration various ad-
R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132 127

ditional mechanisms such as tunneling and surface Pþ regions considering the effect of surface re-
recombination at various interfaces in addition to combination at the heterointerface. The other
Auger and radiative mechanisms. It is also neces- mechanisms considered in the model include the
sary to explore theoretically the ways and means G–R mechanism in the depletion region and tun-
for improving and optimizing the performance neling at the Pþ –n0 interface (TUN). The specific
of the existing devices in respect of quantum effi- detectivity of the heterojunction photodetector
ciency, responsivity and detectivity. In this paper a under consideration can be calculated from John-
complete physics based model of a double hetero- son noise limited equation as
structure (DH) photodetector based on narrow rffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
bandgap InSb related material for application in  ðR0 AÞnet
D ¼ SðkÞ ð1Þ
the MIR region has been presented. 4kT
The photoresponsivity SðkÞ is given by
qgk
2. Theoretical model SðkÞ ¼ ð2Þ
hc
The narrow bandgap ternary III–V alloys are where g the net quantum efficiency, k the operating
promising materials for making MIR optoelec- wavelength. The effective value of the zero-bias
tronic devices. The performances of these devices resistance area product ðR0 AÞnet can be written as
can be greatly improved by using heterostructure. 1 1 1 1
In a DH MIR photodetector, the lightly doped ¼ þ þ
ðR0 AÞnet ðR0 AÞAU ðR0 AÞRAD ðR0 AÞGR
narrow bandgap active layer is generally sand-
1
wiched between two heavily doped lattice matched þ ð3Þ
cladding layers. The DH is used for carrier con- ðR0 AÞTUN
finement in the active region. The higher energy where R0 A is the zero-bias resistance-area product
bandgap of the upper cladding layer also acts as a of the detector which is related to the saturated
window for the incident optical signal. The basic current density as
mechanism of operation of a DH MIR photode- kT
tector is same irrespective of the material combi- ðR0 AÞx ¼ ð4Þ
qJsx
nations used for realising the structure.
Here the suffix x represents the component (AU,
2.1. Specific detectivity RAD, GR or TUN) and Js is saturated current
density for the corresponding component.
One of the most important figures of merit of Each component of R0 A product further com-
the MIR photodetector is the specific detectivity prises contributions from both n and p regions.
D , which depends on the wavelength of the inci- The net R0 A product for each component (e.g. AU,
dent light k, the quantum efficiency g and the zero- RAD, G–R and TUN) is calculated using the
bias resistance-area product R0 A. The detectivity following relation
of the heterojunction photodetector under con- 1 1 1
sideration depends on four dominant mechanisms ¼ þ ð5Þ
R0 A ðR0 AÞp ðR0 AÞn
that control the zero-bias resistance area product.
These include radiative and Auger recombination
(AU) in the neutral n and Pþ regions, generation– 2.1.1. Auger mechanism and radiative mechanism
recombination (G–R) in the depletion region, Among the various noise mechanisms in narrow
and tunneling of carriers from n to Pþ regions and bandgap III–V materials, the Auger and radiative
vice versa. In our modelling we consider the effect recombination are the most important mecha-
of both the recombination mechanisms e.g. AU nisms that affect the performance of a MIR
and radiative recombination (RAD) in the com- photovoltaic detector working at or near room
putation of diffusion current in the neutral n0 and temperature. In this model we have assumed that
128 R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132

the Auger processes involved in this device follow rffiffiffiffiffiffi  


kTn0 sp qðVdp  Ev Þ
those observed in InSb like band structure. For ðR0 AÞp ¼ exp
q2 n2in Dp kT
sake of simplicity we have considered three most    
Lp Sp
dominant Auger mechanisms only e.g. Auger 1 (A- Dp
sinh tx Lp
n
þ cosh tx Lp
n

1), Auger 7 (A-7) and Auger S (A-S). The effective      ð12Þ


Lp Sp
carrier lifetime due to Auger recombination can be Dp
cosh tx Lp
n
þ sinh tx Lp
n

written as [4]
where t is the width of the Pþ region and d is the
1 1 1 1 width of the n0 region, Vdn and Vdp are the built-in
¼ þ þ ð6Þ
sAU sA-1 sA-7 sA-S potentials at the Pþ –n0 heterojunction on the n0
and Pþ side respectively.
where sAU corresponds to the overall value of the The components of R0 A corresponding to
mean lifetime of the carriers due to AU and Auger mechanism and radiative mechanism can be
the other suffixes indicate the components of s for obtained separately by substituting the values of
the corresponding Auger transitions. the respective lifetime (sAU or sRAD ) of carriers in
The lifetimes for the A-1, A-7 and A-S mecha- Eqs. (11) and (12).
nisms can be obtained as [4]
2siA-1 2.1.2. G–R mechanism in the depletion region
sA-1 ¼ ð7Þ The carriers generated in the depletion region
1 þ n0 =p0
are generally separated out under the action of the
2siA-7 existing electric field. These carriers contribute to
sA-7 ¼ ð8Þ the total current flowing through the detector. The
1 þ p0 =n0
transport of carriers across the heterojunction
2siA-S under consideration is strongly affected by the trap
sA-S ¼ ð9Þ levels at the heterointerface inside the depletion
1 þ p0 =n0
region. The electron and the hole component of
where p0 and n0 are the hole and electron con- the R0 A product arising from the G–R in the de-
centration at equilibrium in the active n0 -InAsSb pletion region can be obtained as
region and si indicates the intrinsic value of re- rffiffiffiffiffiffiffiffi
Vdn mnn
combination lifetime of the corresponding Auger ðR0 AÞGRn ¼ ð13Þ
2qnin xn rNf 3kT
transitions [4]. For the radiative recombination,
the lifetime of the carriers can be computed di- rffiffiffiffiffiffiffiffi
Vdp mpp
rectly from ðR0 AÞGRp ¼ ð14Þ
2qnip xp rNf 3kT
1
sRAD ¼ ð10Þ where mnn and mpp are the effective mass of elec-
Br ðn0 þ p0 Þ
trons and holes in the n0 and Pþ region respec-
where Br is the recombination coefficient for elec- tively, Vdn and Vdp are barriers due to band bending
trons and holes in the active region. of n0 region and Pþ region respectively at the Pþ –
The electron and hole components of R0 A n0 heterointerface.
product arising from diffusion mechanisms (Auger
and radiative mechanisms) can be obtained as 2.1.3. Tunneling mechanism
In the present heterojunction photodetector
rffiffiffiffiffiffi  
kTp0 sn qðVdn þ DEc Þ both electrons and holes are separated on both
ðR0 AÞn ¼ exp sides of the heterointerface. The electrons and
q2 n2ip Dn kT
    holes having energy below the barrier can cross the
Ln Sn dxp dxp
Dn
sinh Ln
þ cosh Ln heterointerface by quantum mechanical tunnel-
     ð11Þ ing process when the width of the barrier is suffi-
Ln Sn dxp dxp
Dn
cosh Ln
þ sinh Ln ciently thin. As tunneling is a quantum mechanical
R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132 129

process, one has to take help of quantum me- e.g. neutral n0 and Pþ regions and the depletion
chanics to model the tunneling current component. region at the heterointerface.
Following the numerical model based on WKB The net quantum efficiency can be written as
approximation proposed by Yang et al. [7] the
compo-nents of R0 A arising from quantum me- g ¼ gn þ gp þ gdep ð17Þ
chanical tunneling can be obtained as where the gn , gp and gdep are the components of the
 
k Vdn þ dn quantum efficiency contributed by the n0 , Pþ and
ðR0 AÞTUNn ¼  exp ð15Þ
qA TPp kT the depletion region respectively. If an optical
  power Popt is incident on the surface of the wide
k Vdp þ dp bandgap Pþ material, the generation rate of the
ðR0 AÞTUNp ¼ exp ð16Þ
qA TPn kT electron–hole pairs in the Pþ region as a function
of distance x from the surface can be written as
where A is the effective RichardsonÕs constant, Pn
and Pp are tunneling factors for the n0 and Pþ -side ð1  rp ÞPopt
Gp ¼ ap ðkÞ expðap ðkÞxÞ ð18Þ
respectively. Ahm
The generation in the n0 region can be written as
2.2. Quantum efficiency
ð1  rp Þð1  rn ÞPopt
Gn ¼ an ðkÞ expðap ðkÞtÞ
The quantum efficiency of a photodetector is Ahm
defined as the number of electron–hole pairs gen-  expðap ðkÞxÞ ð19Þ
erated per incident photon. The incident optical
radiation on the detector is absorbed in the de- The three components of quantum efficiency can
pletion region as well as in the bulk regions of both be obtained as follows.
the materials. The wavelength of the incident ra-
diation is selected to match the bandgap of the (i) The net quantum efficiency due to the contribu-
narrow bandgap active material so that the larger tion of the photogenerated carriers in the de-
bandgap material behaves essentially as a window. pletion region can be written as

In the present analysis we have however assumed gdep ¼ ð1  rn Þð1  rp Þ expð  ap ðt  xp ÞÞ
that the absorption takes place in both the mate-

 expð  ðap t þ an xn ÞÞ ð20Þ


rials. The photocurrent generated due to the ab-
sorption of the incident radiation in the various (ii) The quantum efficiency component contrib-
regions contributes to the total quantum efficiency. uted by the neutral n0 and P regions can be ob-
In the present detector we have three regions tained as

2 h 
txp
 
txp
i 3
ð1  rp Þap Ln 4 ap L n þ c n  exp  a p ðt  x p Þ c n cosh Ln
þ sinh Ln
gp ¼      ap Ln exp  ap ðt  xp Þ 5
a2p L2n  1 txp
cn sinh Ln þ cosh Ln
txp

ð21Þ

2  h    i 3
dxn dxn
ð1  rp Þð1  rn Þan Lp   cp  an Lp exp f  an ðd  xn Þg  cp cosh Lp þ sinh Lp
gn ¼ exp  ap t þ an wn 4     þ an Lp 5
a2n L2p  1 c sinh dxn þ cosh dxn
p Lp Lp

ð22Þ
130 R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132

Sp Lp lm) buffer layer with an intermediate composition


where cn ¼ SDn Lnn and cn ¼ Dp
.
of InAs0:94 Sb0:06 is used to relieve the misfit dislo-
cation density in the active region due to large
3. Results and discussion mismatch between InAs and the InAs0:89 Sb0:11
substrate. The undoped thick InAs0:89 Sb0:11 active
In order to characterise a DH MIR detector layer sandwiched between two InAs0:55 Sb0:15 P0:30
theoretically on the basis of the above model it is regions forms the DH. The DH is used for carrier
necessary to consider a typical structure. The type confinement in the active region. Due to higher
of the energy band diagram (type I or II) and some bandgap, the upper cladding layer acts as an ef-
of the associated parameters play key roles in fective transparent window layer for transmission
shaping the characteristics of the detector. In the of light incident on it.
present work, a DH InAs0:89 Sb0:11 photodiode The energy band diagram of the DH Pþ –
supposed to operate at room temperature in the InAsSbP/n0 –InAsSb/Nþ InAsSbP is shown in Fig.
2.0–5.0 lm MIR wavelength range has been con- 1b. The energy bandgaps of the two semiconduc-
sidered. The photodetector structure under con- tors, their conduction and valance band-edge dis-
sideration is shown in Fig. 1a and is similar to one continuities and the built-in potentials at the
studied experimentally by Gao et al. [6]. In order heterointerface after formation of the heterojunc-
to accommodate the large lattice mismatch be- tion are interrelated as follows.
tween the InAs0:89 Sb0:11 active region and the InAs
substrate, buffer layers of InAs0:55 Sb0:15 P0:30 and Vd ¼ Vdn þ Vdp ð23Þ
InAs0:94 Sb0:06 are introduced in the structure. The
structure consists of a heavily doped Pþ -type In- DEc ¼ v1  v2 ð24Þ
As0:55 Sb0:15 P0:30 followed by a lightly doped n0 -type
InAs0:89 Sb0:11 active layer. The single thick (
4 DEg ¼ Eg1  Eg2 ð25Þ

Fig. 1. (a) Structure of the DH photodetector and (b) energy band diagram.
R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132 131

DEg ¼ DEc þ DEv ð26Þ

dp þ dn þ Vd þ DEc ¼ Eg1 ð27Þ


where, Vd is the total built-in potential, DEg is the
total band-edge discontinuity, DEc and DEv are the
conduction and valence band-edge discontinuities
respectively at the heterointerface.
Computations have been carried out for an
InAs0:55 Sb0:15 P0:30 /InAs0:89 Sb0:11 /InAs0:55 Sb0:15 P0:30
double heterojunction MIR photodetector at 300
K. The doping concentrations on Pþ and n0 sides
are taken to be 4  1024 m3 and 1021 m3 re- Fig. 2. Variation of quantum efficiency of the detector with
spectively. The thickness of the active n0 region wavelength.
has been assumed to be 1 lm. The thickness of the
cladding layers has been taken to be 3 lm each. rapidly above 4.4 lm. The device has a moderately
The optical absorption coefficients of the active high value of quantum efficiency in the 2.4–4.4 lm
layer and the window layer have been computed wavelength range. The value of the quantum effi-
theoretically as a function of the wavelength of the ciency is found to be 35% at k ¼ 2:3 lm which is in
incident radiation. In the present computation free close agreement with the value of the quantum
carrier absorption and intra-valence band ab- efficiency (
35.2 %) obtained experimentally at the
sorption have been neglected. Various parameters same wavelength by Gao et al. [6] for a similar
used in the computation have been taken from structure. It is also observed that at room tem-
Refs. [6,8]. Some of the parameters of the quater- perature the detector exhibits a quantum efficiency
nary material (InAsSbP) used for the cladding of more than 30% up to a wavelength of 3.5 lm
layers had to be computed from the parameters of wavelength.
the corresponding ternary materials using linear Fig. 3 shows the variation of the photorespon-
interpolation. The major parameters used in the sivity of the device with the operating wavelength.
computation are listed in Table 1. In the present It is seen that the responsivity of the device is
computation we assumed Sn ¼ Sp ¼ 0. nearly constant (
0.83 A/W) in the wavelength
Fig. 2 shows the variation of the quantum effi- range of 2.4–4.4 lm. The responsivity of the de-
ciency of the photodetector with the operating vice falls steeply near the cut-off wavelength. The
wavelength. The quantum efficiency of the device
is found to increase sharply near 2 lm and falls

Table 1
Major parameters used in the computation
Parameter Value Remark
Eg1 0.278 eV [8]
Eg2 0.484 eV Computed
v1 4.876 eV [8]
v2 4.737 eV Computed
DEc 0.139 eV Computed
DEv 0.067 eV Computed
Nf 1020 /m3 [3]
r 1019 m2 [3]
an (at k ¼ 3 lm) 1:2  106 /m Computed
mnn 0.019 m0 [8] Fig. 3. Variation of responsivity of the detector with wave-
e (InAsSb) 15.33 e0 [8] length.
132 R.K. Lal et al. / Infrared Physics & Technology 44 (2003) 125–132

double heterojunction photodetector has been de-


veloped. The model has been applied to a reported
DH MIR detector structure. The maximum quan-
tum efficiency, peak detectivity and responsivity of
the detector estimated on the basis of the model
closely match with the experimentally reported
values. The simulation code developed can be used
to optimize the performance of DH MIR photo-
detectors for specific non-telecommunication ap-
plications. The model is expected to provide useful
guidelines for fabrication of device prototypes and
thereby cut down the cost of expensive experi-
mental investigations significantly. The model can
Fig. 4. Variation of detectivity of the detector with wavelength. be used as a tool for exploring the potential of
other similar DH room temperature MIR photo-
detector has a high responsivity as compared to detectors based on other narrow bandgap III–V
HgCdTe detectors. The value of the responsivity materials.
obtained on the basis of the present model also
matches closely with the measured value of the
responsivity (0.8 A/W at k ¼ 4:6 lm) reported by
Gao et al. [6] for a similar structure. References
Fig. 4 depicts the variation of the room tem-
[1] X.Y. Gong, T. Yamaguchi, H. Kan, T. Makino, T. Iida, T.
perature detectivity of the device with the op- Kato, M. Aoyama, Y. Hayakama, M. Kumagawa,
erating wavelength. The device exhibits a peak Room temperature InAsx P1xy Sby /InAs photodetectors
detectivity of 1:18  107 mHz1=2 W1 at k ¼ 4:4 with large quantum efficiency, Jpn. J. Appl. Phys. 36 (1997)
lm. The device has a relatively high value of the 2614–2616.
[2] A. Rakovska, V. Berger, X. Marcodet, B. Vinter, G.
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Glastre, T. Oksenhendler, D. Kapler, Room temperature
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detector in the mid-infrared region. The room Phys. Lett. 7 (2000) 397–399.
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experimentally measured value of detectivity re-
1891.
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component and G–R component in the depletion Opt. Eng. 37 (1998) 1754–1762.
[5] Y. Tian, B. Zhang, T. Zhan, H. Jiang, Y. Jin, Theoretical
region. The R0 A product thus follows mainly the
analysis of the detectivity in N–p and P–n GaSb/GaInAsSb
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