HYSYS Print PDF

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Case Name: SIMULACION.hsc

2 Company Name Not Available
3 Bedford, MA Unit Set: SI
4 USA
Date/Time: Wed May 15 13:35:17 2019
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7 Workbook: T-100 (COL1)
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Material Streams Fluid Pkg: All
11 Name 10 @COL1 9 @COL1 12 @COL1 11 @COL1

12 Vapour Fraction 0.0000 1.0000 1.0000 0.0000
13 Temperature (C) 60.62 120.0 77.12 92.95
14 Pressure (kPa) 101.3 199.3 202.6 202.6
15 Molar Flow (kgmole/h) 45.00 657.8 684.2 18.65
16 Mass Flow (kg/h) 817.9 1.949e+004 1.922e+004 1091
17 Liquid Volume Flow (m3/h) 0.8271 24.05 24.00 0.8749
18 Heat Flow (kJ/h) -1.267e+007 -4.533e+007 -5.128e+007 -6.728e+006
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Compositions Fluid Pkg: All
21 Name 10 @COL1 9 @COL1 12 @COL1 11 @COL1

22 Comp Mole Frac (n-Butane) 0.0040 0.0503 0.0484 0.0097
23 Comp Mole Frac (Oxygen) 0.0000 0.0144 0.0138 0.0000
24 Comp Mole Frac (Nitrogen) 0.0000 0.6754 0.6494 0.0000
25 Comp Mole Frac (MaleicAnhydr) 0.0000 0.0142 0.0000 0.5008
26 Comp Mole Frac (CO2) 0.0000 0.0420 0.0404 0.0000
27 Comp Mole Frac (CO) 0.0000 0.0420 0.0404 0.0000
28 Comp Mole Frac (Acetone) 0.0000 0.0000 0.0000 0.0000
29 Comp Mole Frac (H2O) 0.9960 0.1618 0.2077 0.4895
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Energy Streams Fluid Pkg: All
32 Name
33 Heat Flow (kJ/h)
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Unit Ops
36 Operation Name Operation Type Feeds Products Ignored Calc Level
37 10 @COL1 11 @COL1
Main Tower @COL1 Tower No 500.0 *
38 9 @COL1 12 @COL1
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40 Workbook: T-101 (COL2)
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44 Name Reflux @COL2 To Condenser @COL2 Boilup @COL2 To Reboiler @COL2 13 @COL2
45 Vapour Fraction 0.0000 1.0000 1.0000 0.0000 0.0000
46 Temperature (C) 21.53 99.49 201.5 196.2 21.53
47 Pressure (kPa) 101.3 101.3 101.3 101.3 101.3
48 Molar Flow (kgmole/h) 18.60 27.90 29.51 38.85 9.299
49 Mass Flow (kg/h) 349.5 524.3 2859 3775 174.8
50 Liquid Volume Flow (m3/h) 0.3652 0.5478 2.163 2.855 0.1826
51 Heat Flow (kJ/h) -5.254e+006 -6.612e+006 -1.101e+007 -1.638e+007 -2.627e+006
52 Name 14 @COL2 11 @COL2
53 Vapour Fraction 0.0000 0.0000
54 Temperature (C) 201.5 92.95
55 Pressure (kPa) 101.3 202.6
56 Molar Flow (kgmole/h) 9.347 18.65
57 Mass Flow (kg/h) 915.8 1091
58 Liquid Volume Flow (m3/h) 0.6923 0.8749
59 Heat Flow (kJ/h) -3.944e+006 -6.728e+006
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63 Aspen Technology Inc. Aspen HYSYS Version 10 Page 1 of 124
Licensed to: Company Name Not Available * Specified by user.
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7 Workbook: T-101 (COL2) (continued)
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11 Name Reflux @COL2 To Condenser @COL2 Boilup @COL2 To Reboiler @COL2 13 @COL2
12 Comp Mole Frac (n-Butane) 0.0194 0.0194 0.0000 0.0000 0.0194
13 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0000 0.0000 0.0000
14 Comp Mole Frac (Nitrogen) 0.0000 0.0000 0.0000 0.0000 0.0000
15 Comp Mole Frac (MaleicAnhydr) 0.0000 0.0000 0.9854 0.9887 0.0000
16 Comp Mole Frac (CO2) 0.0000 0.0000 0.0000 0.0000 0.0000
17 Comp Mole Frac (CO) 0.0000 0.0000 0.0000 0.0000 0.0000
18 Comp Mole Frac (Acetone) 0.0000 0.0000 0.0000 0.0000 0.0000
19 Comp Mole Frac (H2O) 0.9805 0.9805 0.0146 0.0113 0.9805
20 Name 14 @COL2 11 @COL2
21 Comp Mole Frac (n-Butane) 0.0000 0.0097
22 Comp Mole Frac (Oxygen) 0.0000 0.0000
23 Comp Mole Frac (Nitrogen) 0.0000 0.0000
24 Comp Mole Frac (MaleicAnhydr) 0.9990 0.5008
25 Comp Mole Frac (CO2) 0.0000 0.0000
26 Comp Mole Frac (CO) 0.0000 0.0000
27 Comp Mole Frac (Acetone) 0.0000 0.0000
28 Comp Mole Frac (H2O) 0.0010 0.4895
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31 Name QCT101 @COL2 QHT101 @COL2

32 Heat Flow (kJ/h) 1.269e+006 1.427e+006
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Unit Ops
36 To Reboiler @COL2 14 @COL2
Reboiler @COL2 Reboiler No 500.0 *
37 QHT101 @COL2 Boilup @COL2
38 Reflux @COL2 To Reboiler @COL2
39 Main Tower @COL2 Tower Boilup @COL2 To Condenser @COL2 No 500.0 *
40 11 @COL2
41 To Condenser @COL2 13 @COL2
42 Condenser @COL2 Total Condenser QCT101 @COL2 Reflux @COL2 No 500.0 *
43 QCT101 @COL2
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45 Workbook: Case (Main)
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49 Name 1 2 3 4 5
50 Vapour Fraction 1.0000 1.0000 1.0000 0.0000 1.0000
51 Temperature (C) 50.00 * 25.00 * 25.00 25.00 111.1
52 Pressure (kPa) 202.6 * 101.3 * 101.3 101.3 202.6 *
53 Molar Flow (kgmole/h) 56.24 * 562.4 562.4 0.0000 562.4
54 Mass Flow (kg/h) 3269 1.623e+004 1.623e+004 0.0000 1.623e+004
56 Heat Flow (kJ/h) -6.973e+006 -4578 -4578 -0.0000 1.419e+006
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7 Workbook: Case (Main) (continued)
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Material Streams (continued) Fluid Pkg: All
11 Name 6 7 8 9 10
12 Vapour Fraction 1.0000 1.0000 1.0000 1.0000 0.0000
13 Temperature (C) 93.97 150.0 * 399.9 * 120.0 * 60.62
14 Pressure (kPa) 202.6 202.6 199.3 199.3 101.3
15 Molar Flow (kgmole/h) 618.6 618.6 657.8 657.8 45.00 *
16 Mass Flow (kg/h) 1.949e+004 1.949e+004 1.949e+004 1.949e+004 817.9
19 Name 11 12 13 14 15
20 Vapour Fraction 0.0000 1.0000 0.0000 0.0000 0.0000
21 Temperature (C) 92.95 77.12 21.53 201.5 71.00 *
22 Pressure (kPa) 202.6 202.6 101.3 101.3 202.6 *
23 Molar Flow (kgmole/h) 18.65 684.2 9.299 9.347 35.70
24 Mass Flow (kg/h) 1091 1.922e+004 174.8 915.8 643.2
27 Name 16
28 Vapour Fraction 0.0000
29 Temperature (C) 21.56 *
30 Pressure (kPa) 101.3 *
31 Molar Flow (kgmole/h) 9.297 *
32 Mass Flow (kg/h) 174.7
33 Liquid Volume Flow (m3/h) 0.1826
34 Heat Flow (kJ/h) -2.626e+006
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37 Name 1 2 3 4 5
38 Comp Mole Frac (n-Butane) 1.0000 * 0.0000 * 0.0000 0.0000 0.0000
39 Comp Mole Frac (Oxygen) 0.0000 * 0.2100 * 0.2100 0.0584 0.2100
40 Comp Mole Frac (Nitrogen) 0.0000 * 0.7900 * 0.7900 0.9416 0.7900
41 Comp Mole Frac (MaleicAnhydr) 0.0000 * 0.0000 * 0.0000 0.0000 0.0000
42 Comp Mole Frac (CO2) 0.0000 * 0.0000 * 0.0000 0.0000 0.0000
43 Comp Mole Frac (CO) 0.0000 * 0.0000 * 0.0000 0.0000 0.0000
44 Comp Mole Frac (Acetone) 0.0000 * 0.0000 * 0.0000 0.0000 0.0000
45 Comp Mole Frac (H2O) 0.0000 * 0.0000 * 0.0000 0.0000 0.0000
46 Name 6 7 8 9 10
47 Comp Mole Frac (n-Butane) 0.0909 0.0909 0.0503 0.0503 0.0040
48 Comp Mole Frac (Oxygen) 0.1909 0.1909 0.0144 0.0144 0.0000
49 Comp Mole Frac (Nitrogen) 0.7182 0.7182 0.6754 0.6754 0.0000
50 Comp Mole Frac (MaleicAnhydr) 0.0000 0.0000 0.0142 0.0142 0.0000
51 Comp Mole Frac (CO2) 0.0000 0.0000 0.0420 0.0420 0.0000
52 Comp Mole Frac (CO) 0.0000 0.0000 0.0420 0.0420 0.0000
53 Comp Mole Frac (Acetone) 0.0000 0.0000 0.0000 0.0000 0.0000
54 Comp Mole Frac (H2O) 0.0000 0.0000 0.1618 0.1618 0.9960
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7 Workbook: Case (Main) (continued)
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Compositions (continued) Fluid Pkg: All
11 Name 11 12 13 14 15
12 Comp Mole Frac (n-Butane) 0.0097 0.0484 0.0194 0.0000 0.0000 *
13 Comp Mole Frac (Oxygen) 0.0000 0.0138 0.0000 0.0000 0.0000 *
14 Comp Mole Frac (Nitrogen) 0.0000 0.6494 0.0000 0.0000 0.0000 *
15 Comp Mole Frac (MaleicAnhydr) 0.5008 0.0000 0.0000 0.9990 0.0000 *
16 Comp Mole Frac (CO2) 0.0000 0.0404 0.0000 0.0000 0.0000 *
17 Comp Mole Frac (CO) 0.0000 0.0404 0.0000 0.0000 0.0000 *
18 Comp Mole Frac (Acetone) 0.0000 0.0000 0.0000 0.0000 0.0000 *
19 Comp Mole Frac (H2O) 0.4895 0.2077 0.9805 0.0010 1.0000 *
20 Name 16
21 Comp Mole Frac (n-Butane) 0.0194 *
22 Comp Mole Frac (Oxygen) 0.0000 *
23 Comp Mole Frac (Nitrogen) 0.0000 *
24 Comp Mole Frac (MaleicAnhydr) 0.0000 *
25 Comp Mole Frac (CO2) 0.0000 *
26 Comp Mole Frac (CO) 0.0000 *
27 Comp Mole Frac (Acetone) 0.0000 *
28 Comp Mole Frac (H2O) 0.9805 *
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31 Name QPFR100 QK100 QE100 QE101 QCT101

32 Heat Flow (kJ/h) 3.376e+007 1.424e+006 1.329e+006 7.347e+006 1.269e+006
33 Name QHT101
34 Heat Flow (kJ/h) 1.427e+006
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Unit Ops
38 1 6
MIX-100 Mixer No 500.0 *
39 5
40 15 10
MIX-101 Mixer No 500.0 *
41 16
42 2 4
V-100 Separator No 500.0 *
43 3
44 3 5
K-100 Compressor No 500.0 *
45 QK100
46 SET-1 Set No 500.0 *
47 6 7
E-100 Heater No 500.0 *
48 QE100
49 7 8
PFR-100 Plug Flow Reactor No 500.0 *
50 QPFR100
51 8 9
E-101 Cooler No 500.0 *
52 QE101
53 10 11
T-100 Absorber No 2500 *
54 9 12
55 11 14
56 T-101 Distillation QHT101 13 No 2500 *
57 QCT101
58 RCY-1 Recycle 13 16 No 3500 *
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Fluid Package: Basis-1
7 Material Stream: 1 Property Package: NRTL - PR
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CONDITIONS
11 Overall Vapour Phase
12 Vapour / Phase Fraction 1.0000 1.0000
13 Temperature: (C) 50.00 * 50.00
14 Pressure: (kPa) 202.6 * 202.6
15 Molar Flow (kgmole/h) 56.24 * 56.24
16 Mass Flow (kg/h) 3269 3269
17 Std Ideal Liq Vol Flow (m3/h) 5.605 5.605
18 Molar Enthalpy (kJ/kgmole) -1.240e+005 -1.240e+005
19 Molar Entropy (kJ/kgmole-C) 129.6 129.6
20 Heat Flow (kJ/h) -6.973e+006 -6.973e+006
21 Liq Vol Flow @Std Cond (m3/h) 5.592 * 5.592
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PROPERTIES
25 Molecular Weight 58.12 58.12
26 Molar Density (kgmole/m3) 7.906e-002 7.906e-002
27 Mass Density (kg/m3) 4.595 4.595
28 Act. Volume Flow (m3/h) 711.4 711.4
29 Mass Enthalpy (kJ/kg) -2133 -2133
30 Mass Entropy (kJ/kg-C) 2.230 2.230
31 Heat Capacity (kJ/kgmole-C) 106.4 106.4
32 Mass Heat Capacity (kJ/kg-C) 1.831 1.831
33 LHV Molar Basis (Std) (kJ/kgmole) 2.660e+006 2.660e+006
34 HHV Molar Basis (Std) (kJ/kgmole) 2.865e+006 2.865e+006
35 HHV Mass Basis (Std) (kJ/kg) 4.929e+004 4.929e+004
36 CO2 Loading --- ---
37 CO2 App ML Con (kgmole/m3) --- ---
38 CO2 App WT Con (kgmol/kg) --- ---
39 LHV Mass Basis (Std) (kJ/kg) 4.576e+004 4.576e+004
40 Phase Fraction [Vol. Basis] 1.000 1.000
41 Phase Fraction [Mass Basis] 1.000 1.000
42 Phase Fraction [Act. Vol. Basis] 1.000 1.000
43 Mass Exergy (kJ/kg) 30.13 ---
44 Partial Pressure of CO2 (kPa) 0.0000 ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) 711.4 711.4
47 Avg. Liq. Density (kgmole/m3) 10.03 10.03
48 Specific Heat (kJ/kgmole-C) 106.4 106.4
49 Std. Gas Flow (STD_m3/h) 1330 1330
50 Std. Ideal Liq. Mass Density (kg/m3) 583.2 583.2
51 Act. Liq. Flow (m3/s) --- ---
52 Z Factor 0.9541 0.9541
53 Watson K 13.50 13.50
54 User Property --- ---
55 Partial Pressure of H2S (kPa) 0.0000 ---
56 Cp/(Cp - R) 1.085 1.085
57 Cp/Cv 1.101 1.101
58 Ideal Gas Cp/Cv 1.086 1.086
59 Ideal Gas Cp (kJ/kgmole-C) 104.8 104.8
60 Mass Ideal Gas Cp (kJ/kg-C) 1.802 1.802
61 Heat of Vap. (kJ/kgmole) 2.118e+004 ---
62 Kinematic Viscosity (cSt) 1.725 1.725
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7 Material Stream: 1 (continued) Property Package: NRTL - PR
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PROPERTIES
12 Liq. Mass Density (Std. Cond) (kg/m3) 584.5 584.5
13 Liq. Vol. Flow (Std. Cond) (m3/h) 5.592 5.592
14 Liquid Fraction 0.0000 0.0000
15 Molar Volume (m3/kgmole) 12.65 12.65
16 Mass Heat of Vap. (kJ/kg) 364.5 ---
17 Phase Fraction [Molar Basis] 1.0000 1.0000
18 Surface Tension (dyne/cm) --- ---
19 Thermal Conductivity (W/m-K) 1.807e-002 1.807e-002
20 Bubble Point Pressure (kPa) 496.7 ---
21 Viscosity (cP) 7.925e-003 7.925e-003
22 Cv (Semi-Ideal) (kJ/kgmole-C) 98.09 98.09
23 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.688 1.688
24 Cv (kJ/kgmole-C) 96.62 96.62
25 Mass Cv (kJ/kg-C) 1.662 1.662
26 Cv (Ent. Method) (kJ/kgmole-C) --- ---
27 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
28 Cp/Cv (Ent. Method) --- ---
29 Reid VP at 37.8 C (kPa) 356.5 356.5
30 True VP at 37.8 C (kPa) 356.5 356.5
31 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 5.592 5.592
32 Viscosity Index -34.87 ---
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COMPOSITION
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Overall Phase Vapour Fraction 1.0000
37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 n-Butane 56.2390 * 1.0000 * 3268.8357 * 1.0000 * 5.6048 * 1.0000 *
40 Oxygen 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
41 Nitrogen 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
42 MaleicAnhydr 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
43 CO2 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
44 CO 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
45 Acetone 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
46 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
47 Total 56.2390 1.0000 3268.8357 1.0000 5.6048 1.0000
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Vapour Phase Phase Fraction 1.000
52 n-Butane 56.2390 1.0000 3268.8357 1.0000 5.6048 1.0000
53 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 Total 56.2390 1.0000 3268.8357 1.0000 5.6048 1.0000
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K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 n-Butane --- --- ---
13 Oxygen --- --- ---
14 Nitrogen --- --- ---
15 MaleicAnhydr --- --- ---
16 CO2 --- --- ---
17 CO --- --- ---
18 Acetone --- --- ---
19 H2O --- --- ---
20
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UNIT OPERATIONS
22 FEED TO PRODUCT FROM LOGICAL CONNECTION
23 Mixer: MIX-100 Set: SET-1
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UTILITIES
26 ( No utilities reference this stream )
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PROCESS UTILITY
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DYNAMICS
32 Pressure Specification (Active): 202.6 kPa *
33 Flow Specification (Active) Molar: 56.24 kgmole/h * Mass: 3269 kg/h Std Ideal Liq Volume: 5.605 m3/h
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User Variables
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NOTES
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Description
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CONDITIONS
49 Temperature: (C) 25.00 * 25.00
50 Pressure: (kPa) 101.3 * 101.3
52 Mass Flow (kg/h) 1.623e+004 1.623e+004
54 Molar Enthalpy (kJ/kgmole) -8.140 -8.140
56 Heat Flow (kJ/h) -4578 -4578
57 Liq Vol Flow @Std Cond (m3/h) --- ---
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PROPERTIES
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PROPERTIES
13 Act. Volume Flow (m3/h) 1.375e+004 1.375e+004
14 Mass Enthalpy (kJ/kg) -0.2821 -0.2821
18 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000
19 HHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000
20 HHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000
24 LHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000
28 Mass Exergy (kJ/kg) -2.896e-006 ---
31 Act. Gas Flow (ACT_m3/h) 1.375e+004 1.375e+004
34 Std. Gas Flow (STD_m3/h) 1.330e+004 1.330e+004
36 Act. Liq. Flow (m3/s) --- ---
37 Z Factor 0.9995 0.9995
38 Watson K 6.042 6.042
41 Cp/(Cp - R) 1.398 1.398
42 Cp/Cv 1.401 1.401
46 Heat of Vap. (kJ/kgmole) 5952 ---
48 Liq. Mass Density (Std. Cond) (kg/m3) --- ---
49 Liq. Vol. Flow (Std. Cond) (m3/h) --- ---
56 Bubble Point Pressure (kPa) --- ---
57 Viscosity (cP) 1.883e-002 1.883e-002
60 Cv (kJ/kgmole-C) 20.84 20.84
61 Mass Cv (kJ/kg-C) 0.7223 0.7223
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PROPERTIES
14 Reid VP at 37.8 C (kPa) --- ---
15 True VP at 37.8 C (kPa) --- ---
17 Viscosity Index --- ---
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COMPOSITION
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24 n-Butane 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
25 Oxygen 118.1019 * 0.2100 * 3779.2608 * 0.2329 * 3.3219 * 0.1771 *
26 Nitrogen 444.2881 * 0.7900 * 12445.8428 * 0.7671 * 15.4343 * 0.8229 *
27 MaleicAnhydr 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
28 CO2 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 CO 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 Acetone 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
32 Total 562.3900 1.0000 16225.1036 1.0000 18.7562 1.0000
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37 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 Oxygen 118.1019 0.2100 3779.2608 0.2329 3.3219 0.1771
39 Nitrogen 444.2881 0.7900 12445.8428 0.7671 15.4343 0.8229
40 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 Total 562.3900 1.0000 16225.1036 1.0000 18.7562 1.0000
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K VALUE
49 n-Butane --- --- ---
50 Oxygen --- --- ---
51 Nitrogen --- --- ---
53 CO2 --- --- ---
54 CO --- --- ---
55 Acetone --- --- ---
56 H2O --- --- ---
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UNIT OPERATIONS
60 Separator: V-100 Set: SET-1
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UTILITIES
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PROCESS UTILITY
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DYNAMICS
18 Flow Specification (Inactive) Molar: 562.4 kgmole/h Mass: 1.623e+004 kg/h Std Ideal Liq Volume: 18.76 m3/h
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User Variables
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NOTES
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Description
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CONDITIONS
32 Overall Vapour Phase Liquid Phase
33 Vapour / Phase Fraction 1.0000 1.0000 0.0000
34 Temperature: (C) 25.00 25.00 25.00
35 Pressure: (kPa) 101.3 101.3 101.3
36 Molar Flow (kgmole/h) 562.4 562.4 0.0000
37 Mass Flow (kg/h) 1.623e+004 1.623e+004 0.0000
38 Std Ideal Liq Vol Flow (m3/h) 18.76 18.76 0.0000
39 Molar Enthalpy (kJ/kgmole) -8.140 -8.140 -577.9
40 Molar Entropy (kJ/kgmole-C) 151.7 151.7 147.8
41 Heat Flow (kJ/h) -4578 -4578 0.0000
42 Liq Vol Flow @Std Cond (m3/h) --- --- 0.0000
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PROPERTIES
46 Molecular Weight 28.85 28.85 28.25
47 Molar Density (kgmole/m3) 4.090e-002 4.090e-002 4.090e-002
48 Mass Density (kg/m3) 1.180 1.180 1.155
49 Act. Volume Flow (m3/h) 1.375e+004 1.375e+004 0.0000
50 Mass Enthalpy (kJ/kg) -0.2821 -0.2821 -20.46
51 Mass Entropy (kJ/kg-C) 5.258 5.258 5.233
52 Heat Capacity (kJ/kgmole-C) 29.20 29.20 65.00
53 Mass Heat Capacity (kJ/kg-C) 1.012 1.012 2.301
54 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000 0.0000
55 HHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000 0.0000
56 HHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000 0.0000
57 CO2 Loading --- --- ---
58 CO2 App ML Con (kgmole/m3) --- --- ---
59 CO2 App WT Con (kgmol/kg) --- --- ---
60 LHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000 0.0000
61 Phase Fraction [Vol. Basis] 1.000 1.000 ---
62 Phase Fraction [Mass Basis] 1.000 1.000 0.0000
1
4 USA
5
6
8
9
10
PROPERTIES
12 Phase Fraction [Act. Vol. Basis] 1.000 1.000 0.0000
13 Mass Exergy (kJ/kg) -2.896e-006 --- ---
14 Partial Pressure of CO2 (kPa) 0.0000 --- ---
15 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
16 Act. Gas Flow (ACT_m3/h) 1.375e+004 1.375e+004 ---
17 Avg. Liq. Density (kgmole/m3) 29.98 29.98 29.11
18 Specific Heat (kJ/kgmole-C) 29.20 29.20 65.00
19 Std. Gas Flow (STD_m3/h) 1.330e+004 1.330e+004 0.0000
20 Std. Ideal Liq. Mass Density (kg/m3) 865.1 865.1 822.2
21 Act. Liq. Flow (m3/s) --- --- ---
22 Z Factor --- 0.9995 0.9995
23 Watson K 6.042 6.042 6.309
24 User Property --- --- ---
25 Partial Pressure of H2S (kPa) 0.0000 --- ---
26 Cp/(Cp - R) 1.398 1.398 1.147
27 Cp/Cv 1.401 1.401 1.147
28 Ideal Gas Cp/Cv 1.399 1.399 1.399
29 Ideal Gas Cp (kJ/kgmole-C) 29.14 29.14 29.14
30 Mass Ideal Gas Cp (kJ/kg-C) 1.010 1.010 1.032
31 Heat of Vap. (kJ/kgmole) 5952 --- ---
32 Kinematic Viscosity (cSt) 15.96 15.96 0.5799
33 Liq. Mass Density (Std. Cond) (kg/m3) --- --- ---
34 Liq. Vol. Flow (Std. Cond) (m3/h) --- --- 0.0000
35 Liquid Fraction 0.0000 0.0000 1.000
36 Molar Volume (m3/kgmole) 24.45 24.45 24.45
37 Mass Heat of Vap. (kJ/kg) 206.3 --- ---
38 Phase Fraction [Molar Basis] 1.0000 1.0000 0.0000
39 Surface Tension (dyne/cm) --- --- 0.0000
40 Thermal Conductivity (W/m-K) 2.592e-002 2.592e-002 4.586e-002
41 Bubble Point Pressure (kPa) --- --- ---
42 Viscosity (cP) 1.883e-002 1.883e-002 6.698e-004
43 Cv (Semi-Ideal) (kJ/kgmole-C) 20.88 20.88 56.69
44 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.7239 0.7239 2.007
45 Cv (kJ/kgmole-C) 20.84 20.84 56.69
46 Mass Cv (kJ/kg-C) 0.7223 0.7223 2.007
47 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
48 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
49 Cp/Cv (Ent. Method) --- --- ---
50 Reid VP at 37.8 C (kPa) --- --- ---
51 True VP at 37.8 C (kPa) --- --- ---
52 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 0.0000 0.0000 0.0000
53 Viscosity Index --- --- ---
54
55
COMPOSITION
56
57
60 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Oxygen 118.1019 0.2100 3779.2608 0.2329 3.3219 0.1771
62 Nitrogen 444.2881 0.7900 12445.8428 0.7671 15.4343 0.8229
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
Overall Phase (continued) Vapour Fraction 1.0000
15 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Total 562.3900 1.0000 16225.1036 1.0000 18.7562 1.0000
21
22
25 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 Oxygen 118.1019 0.2100 3779.2608 0.2329 3.3219 0.1771
27 Nitrogen 444.2881 0.7900 12445.8428 0.7671 15.4343 0.8229
28 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 Total 562.3900 1.0000 16225.1036 1.0000 18.7562 1.0000
34
35
Liquid Phase Phase Fraction 0.0000
38 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 Oxygen 0.0000 0.0584 0.0000 0.0661 0.0000 0.0478
40 Nitrogen 0.0000 0.9416 0.0000 0.9339 0.0000 0.9522
41 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
46 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
47
48
K VALUE
50 n-Butane --- --- ---
51 Oxygen 3.598 3.598 ---
52 Nitrogen 0.8390 0.8390 ---
54 CO2 --- --- ---
55 CO --- --- ---
56 Acetone --- --- ---
57 H2O --- --- ---
58
59
UNIT OPERATIONS
61 Compressor: K-100 Separator: V-100
62
1
4 USA
5
6
8
9
10
UTILITIES
12
13
PROCESS UTILITY
14
15
16
DYNAMICS
17 Pressure Specification (Inactive): 101.3 kPa
19
20
User Variables
21
22
NOTES
23
24
25
Description
26
27
29
30
31
CONDITIONS
34 Temperature: (C) 25.00 25.00 25.00
35 Pressure: (kPa) 101.3 101.3 101.3
37 Mass Flow (kg/h) 0.0000 0.0000 0.0000
41 Heat Flow (kJ/h) -0.0000 0.0000 0.0000
42 Liq Vol Flow @Std Cond (m3/h) 0.0000 * 0.0000 0.0000
43
44
PROPERTIES
48 Mass Density (kg/m3) 1.155 1.180 1.155
49 Act. Volume Flow (m3/h) 0.0000 0.0000 0.0000
57 CO2 Loading --- --- ---
61 Phase Fraction [Vol. Basis] --- --- 1.000
1
4 USA
5
6
8
9
10
PROPERTIES
12 Phase Fraction [Act. Vol. Basis] --- --- ---
13 Mass Exergy (kJ/kg) -6.391e-003 --- ---
16 Act. Gas Flow (ACT_m3/h) --- --- ---
17 Avg. Liq. Density (kgmole/m3) --- --- ---
19 Std. Gas Flow (STD_m3/h) 0.0000 0.0000 0.0000
21 Act. Liq. Flow (m3/s) 0.0000 --- 0.0000
22 Z Factor --- 0.9995 0.9995
23 Watson K 6.309 6.042 6.309
26 Cp/(Cp - R) 1.147 1.398 1.147
27 Cp/Cv 1.147 1.401 1.147
28 Ideal Gas Cp/Cv 1.399 1.399 1.399
31 Heat of Vap. (kJ/kgmole) 5688 --- ---
34 Liq. Vol. Flow (Std. Cond) (m3/h) 0.0000 0.0000 0.0000
35 Liquid Fraction 1.000 0.0000 1.000
39 Surface Tension (dyne/cm) --- --- ---
42 Viscosity (cP) 6.698e-004 1.883e-002 6.698e-004
45 Cv (kJ/kgmole-C) 56.69 20.84 56.69
46 Mass Cv (kJ/kg-C) 2.007 0.7223 2.007
49 Cp/Cv (Ent. Method) --- --- ---
50 Reid VP at 37.8 C (kPa) --- --- ---
51 True VP at 37.8 C (kPa) --- --- ---
54
55
COMPOSITION
56
57
60 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Oxygen 0.0000 0.0584 0.0000 0.0661 0.0000 0.0478
62 Nitrogen 0.0000 0.9416 0.0000 0.9339 0.0000 0.9522
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
21
22
25 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 Oxygen 0.0000 0.2100 0.0000 0.2329 0.0000 0.1771
27 Nitrogen 0.0000 0.7900 0.0000 0.7671 0.0000 0.8229
28 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
34
35
38 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 Oxygen 0.0000 0.0584 0.0000 0.0661 0.0000 0.0478
40 Nitrogen 0.0000 0.9416 0.0000 0.9339 0.0000 0.9522
41 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
46 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
47
48
K VALUE
50 n-Butane --- --- ---
51 Oxygen 3.598 3.598 ---
52 Nitrogen 0.8390 0.8390 ---
54 CO2 --- --- ---
55 CO --- --- ---
56 Acetone --- --- ---
57 H2O --- --- ---
58
59
UNIT OPERATIONS
61 Separator: V-100
62
1
4 USA
5
6
8
9
10
UTILITIES
12
13
PROCESS UTILITY
14
15
16
DYNAMICS
18 Flow Specification (Inactive) Molar: 0.0000 kgmole/h Mass: 0.0000 kg/h Std Ideal Liq Volume: 0.0000 m3/h
19
20
User Variables
21
22
NOTES
23
24
25
Description
26
27
29
30
31
CONDITIONS
34 Temperature: (C) 93.97 93.97
35 Pressure: (kPa) 202.6 202.6
37 Mass Flow (kg/h) 1.949e+004 1.949e+004
39 Molar Enthalpy (kJ/kgmole) -8978 -8978
41 Heat Flow (kJ/h) -5.554e+006 -5.554e+006
43
44
PROPERTIES
49 Act. Volume Flow (m3/h) 9308 9308
56 HHV Mass Basis (Std) (kJ/kg) 8264 8264
60 LHV Mass Basis (Std) (kJ/kg) 7673 7673
1
4 USA
5
6
8
9
10
PROPERTIES
16 Act. Gas Flow (ACT_m3/h) 9308 9308
21 Act. Liq. Flow (m3/s) --- ---
22 Z Factor 0.9989 0.9989
23 Watson K 7.138 7.138
26 Cp/(Cp - R) 1.284 1.284
27 Cp/Cv 1.288 1.288
42 Viscosity (cP) 2.090e-002 2.090e-002
45 Cv (kJ/kgmole-C) 29.17 29.17
46 Mass Cv (kJ/kg-C) 0.9255 0.9255
50 Reid VP at 37.8 C (kPa) --- ---
51 True VP at 37.8 C (kPa) --- ---
54
55
COMPOSITION
56
57
60 n-Butane 56.2390 0.0909 3268.8357 0.1677 5.6048 0.2301
61 Oxygen 118.1019 0.1909 3779.2608 0.1939 3.3219 0.1364
62 Nitrogen 444.2881 0.7182 12445.8428 0.6384 15.4343 0.6336
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Total 618.6290 1.0000 19493.9392 1.0000 24.3610 1.0000
21
22
25 n-Butane 56.2390 0.0909 3268.8357 0.1677 5.6048 0.2301
26 Oxygen 118.1019 0.1909 3779.2608 0.1939 3.3219 0.1364
27 Nitrogen 444.2881 0.7182 12445.8428 0.6384 15.4343 0.6336
28 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 Total 618.6290 1.0000 19493.9392 1.0000 24.3610 1.0000
34
35
K VALUE
37 n-Butane --- --- ---
38 Oxygen --- --- ---
39 Nitrogen --- --- ---
41 CO2 --- --- ---
42 CO --- --- ---
43 Acetone --- --- ---
44 H2O --- --- ---
45
46
UNIT OPERATIONS
48 Heater: E-100 Mixer: MIX-100
49
50
UTILITIES
52
53
PROCESS UTILITY
54
55
56
DYNAMICS
59
60
User Variables
61
62
NOTES
1
4 USA
5
6
8
9
10
11
Description
12
13
15
16
17
CONDITIONS
20 Temperature: (C) 111.1 111.1
21 Pressure: (kPa) 202.6 * 202.6
23 Mass Flow (kg/h) 1.623e+004 1.623e+004
25 Molar Enthalpy (kJ/kgmole) 2523 2523
27 Heat Flow (kJ/h) 1.419e+006 1.419e+006
29
30
PROPERTIES
36 Mass Enthalpy (kJ/kg) 87.46 87.46
58 Act. Liq. Flow (m3/s) --- ---
59 Z Factor 1.000 1.000
60 Watson K 6.042 6.042
1
4 USA
5
6
8
9
10
PROPERTIES
12 Cp/(Cp - R) 1.388 1.388
13 Cp/Cv 1.391 1.391
17 Heat of Vap. (kJ/kgmole) 5724 ---
28 Viscosity (cP) 2.267e-002 2.267e-002
31 Cv (kJ/kgmole-C) 21.38 21.38
32 Mass Cv (kJ/kg-C) 0.7412 0.7412
36 Reid VP at 37.8 C (kPa) --- ---
37 True VP at 37.8 C (kPa) --- ---
40
41
COMPOSITION
42
43
46 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
47 Oxygen 118.1019 0.2100 3779.2608 0.2329 3.3219 0.1771
48 Nitrogen 444.2881 0.7900 12445.8428 0.7671 15.4343 0.8229
49 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Total 562.3900 1.0000 16225.1036 1.0000 18.7562 1.0000
55
56
59 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 Oxygen 118.1019 0.2100 3779.2608 0.2329 3.3219 0.1771
61 Nitrogen 444.2881 0.7900 12445.8428 0.7671 15.4343 0.8229
62 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000
15 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 562.3900 1.0000 16225.1036 1.0000 18.7562 1.0000
20
21
K VALUE
23 n-Butane --- --- ---
24 Oxygen --- --- ---
25 Nitrogen --- --- ---
27 CO2 --- --- ---
28 CO --- --- ---
29 Acetone --- --- ---
30 H2O --- --- ---
31
32
UNIT OPERATIONS
34 Mixer: MIX-100 Compressor: K-100
35
36
UTILITIES
38
39
PROCESS UTILITY
40
41
42
DYNAMICS
45
46
User Variables
47
48
NOTES
49
50
51
Description
52
53
55
56
57
CONDITIONS
60 Temperature: (C) 150.0 * 150.0
61 Pressure: (kPa) 202.6 202.6
1
4 USA
5
6
8
9
10
CONDITIONS
12 Mass Flow (kg/h) 1.949e+004 1.949e+004
14 Molar Enthalpy (kJ/kgmole) -6830 -6830
16 Heat Flow (kJ/h) -4.225e+006 -4.225e+006
18
19
PROPERTIES
47 Act. Liq. Flow (m3/s) --- ---
48 Z Factor 0.9997 0.9997
49 Watson K 7.138 7.138
52 Cp/(Cp - R) 1.270 1.270
53 Cp/Cv 1.273 1.273
1
4 USA
5
6
8
9
10
PROPERTIES
17 Viscosity (cP) 2.322e-002 2.322e-002
20 Cv (kJ/kgmole-C) 30.74 30.74
21 Mass Cv (kJ/kg-C) 0.9754 0.9754
25 Reid VP at 37.8 C (kPa) --- ---
26 True VP at 37.8 C (kPa) --- ---
29
30
COMPOSITION
31
32
35 n-Butane 56.2390 0.0909 3268.8357 0.1677 5.6048 0.2301
36 Oxygen 118.1019 0.1909 3779.2608 0.1939 3.3219 0.1364
37 Nitrogen 444.2881 0.7182 12445.8428 0.6384 15.4343 0.6336
38 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 Total 618.6290 1.0000 19493.9392 1.0000 24.3610 1.0000
44
45
48 n-Butane 56.2390 0.0909 3268.8357 0.1677 5.6048 0.2301
49 Oxygen 118.1019 0.1909 3779.2608 0.1939 3.3219 0.1364
50 Nitrogen 444.2881 0.7182 12445.8428 0.6384 15.4343 0.6336
51 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 Total 618.6290 1.0000 19493.9392 1.0000 24.3610 1.0000
57
58
K VALUE
60 n-Butane --- --- ---
61 Oxygen --- --- ---
62 Nitrogen --- --- ---
1
4 USA
5
6
8
9
10
K VALUE
13 CO2 --- --- ---
14 CO --- --- ---
15 Acetone --- --- ---
16 H2O --- --- ---
17
18
UNIT OPERATIONS
20 Plug Flow Reactor: PFR-100 Heater: E-100
21
22
UTILITIES
24
25
PROCESS UTILITY
26
27
28
DYNAMICS
31
32
User Variables
33
34
NOTES
35
36
37
Description
38
39
41
42
43
CONDITIONS
46 Temperature: (C) 399.9 * 399.9 399.9
47 Pressure: (kPa) 199.3 199.3 199.3
49 Mass Flow (kg/h) 1.949e+004 1.949e+004 0.0000
51 Molar Enthalpy (kJ/kgmole) -5.774e+004 -5.774e+004 -2.217e+005
53 Heat Flow (kJ/h) -3.798e+007 -3.798e+007 0.0000
54 Liq Vol Flow @Std Cond (m3/h) --- --- 0.0000
55
56
PROPERTIES
60 Mass Density (kg/m3) 1.055 1.055 2.006
61 Act. Volume Flow (m3/h) 1.847e+004 1.847e+004 0.0000
62 Mass Enthalpy (kJ/kg) -1948 -1948 -3937
1
4 USA
5
6
8
9
10
PROPERTIES
15 LHV Molar Basis (Std) (kJ/kgmole) 1.654e+005 1.654e+005 1.227e+006
16 HHV Molar Basis (Std) (kJ/kgmole) 1.829e+005 1.829e+005 1.313e+006
17 HHV Mass Basis (Std) (kJ/kg) 6173 6173 2.331e+004
18 CO2 Loading --- --- ---
21 LHV Mass Basis (Std) (kJ/kg) 5581 5581 2.179e+004
22 Phase Fraction [Vol. Basis] 1.000 1.000 ---
25 Mass Exergy (kJ/kg) 204.5 --- ---
28 Act. Gas Flow (ACT_m3/h) 1.847e+004 1.847e+004 ---
31 Std. Gas Flow (STD_m3/h) 1.555e+004 1.555e+004 0.0000
33 Act. Liq. Flow (m3/s) --- --- ---
34 Z Factor --- 1.000 1.000
35 Watson K 7.251 7.251 9.474
38 Cp/(Cp - R) 1.244 1.244 1.052
39 Cp/Cv 1.245 1.245 1.052
40 Ideal Gas Cp/Cv 1.244 1.244 1.074
43 Heat of Vap. (kJ/kgmole) 2.344e+004 --- ---
45 Liq. Mass Density (Std. Cond) (kg/m3) --- --- 923.0
46 Liq. Vol. Flow (Std. Cond) (m3/h) --- --- 0.0000
47 Liquid Fraction 0.0000 0.0000 1.000
51 Surface Tension (dyne/cm) --- --- 34.66
54 Viscosity (cP) 2.967e-002 2.967e-002 1.421e-003
57 Cv (kJ/kgmole-C) 34.07 34.07 159.4
58 Mass Cv (kJ/kg-C) 1.150 1.150 2.830
61 Cp/Cv (Ent. Method) --- --- ---
62 Reid VP at 37.8 C (kPa) --- --- ---
1
4 USA
5
6
8
9
10
PROPERTIES
12 True VP at 37.8 C (kPa) --- --- ---
15
16
COMPOSITION
17
18
21 n-Butane 33.0897 0.0503 1923.3074 0.0987 3.2977 0.1371
22 Oxygen 9.4564 0.0144 302.6037 0.0155 0.2660 0.0111
23 Nitrogen 444.2881 0.6754 12445.8428 0.6384 15.4343 0.6417
24 MaleicAnhydr 9.3379 0.0142 915.6542 0.0470 0.6921 0.0288
25 CO2 27.6239 0.0420 1215.7203 0.0624 1.4730 0.0612
26 CO 27.6239 0.0420 773.7708 0.0397 0.9680 0.0402
27 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 H2O 106.4105 0.1618 1916.9967 0.0983 1.9209 0.0799
29 Total 657.8305 1.0000 19493.8958 1.0000 24.0520 1.0000
30
31
34 n-Butane 33.0897 0.0503 1923.3074 0.0987 3.2977 0.1371
35 Oxygen 9.4564 0.0144 302.6037 0.0155 0.2660 0.0111
36 Nitrogen 444.2881 0.6754 12445.8428 0.6384 15.4343 0.6417
37 MaleicAnhydr 9.3379 0.0142 915.6542 0.0470 0.6921 0.0288
38 CO2 27.6239 0.0420 1215.7203 0.0624 1.4730 0.0612
39 CO 27.6239 0.0420 773.7708 0.0397 0.9680 0.0402
40 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 H2O 106.4105 0.1618 1916.9967 0.0983 1.9209 0.0799
42 Total 657.8305 1.0000 19493.8958 1.0000 24.0520 1.0000
43
44
47 n-Butane 0.0000 0.3114 0.0000 0.3213 0.0000 0.4872
48 Oxygen 0.0000 0.0006 0.0000 0.0004 0.0000 0.0003
49 Nitrogen 0.0000 0.0622 0.0000 0.0309 0.0000 0.0339
50 MaleicAnhydr 0.0000 0.2857 0.0000 0.4975 0.0000 0.3325
51 CO2 0.0000 0.0863 0.0000 0.0674 0.0000 0.0722
52 CO 0.0000 0.0073 0.0000 0.0036 0.0000 0.0040
53 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 H2O 0.0000 0.2465 0.0000 0.0788 0.0000 0.0699
55 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
56
57
K VALUE
59 n-Butane 0.1616 0.1616 ---
60 Oxygen 22.82 22.82 ---
61 Nitrogen 10.85 10.85 ---
62 MaleicAnhydr 4.968e-002 4.968e-002 ---
1
4 USA
5
6
8
9
10
K VALUE
12 CO2 0.4869 0.4869 ---
13 CO 5.728 5.728 ---
14 Acetone --- --- ---
15 H2O 0.6563 0.6563 ---
16
17
UNIT OPERATIONS
19 Cooler: E-101 Plug Flow Reactor: PFR-100
20
21
UTILITIES
23
24
PROCESS UTILITY
25
26
27
DYNAMICS
30
31
User Variables
32
33
NOTES
34
35
36
Description
37
38
40
41
42
CONDITIONS
45 Temperature: (C) 120.0 * 120.0
46 Pressure: (kPa) 199.3 199.3
48 Mass Flow (kg/h) 1.949e+004 1.949e+004
52 Heat Flow (kJ/h) -4.533e+007 -4.533e+007
54
55
PROPERTIES
1
4 USA
5
6
8
9
10
PROPERTIES
32 Act. Liq. Flow (m3/s) --- ---
33 Z Factor 0.9978 0.9978
34 Watson K 7.251 7.251
37 Cp/(Cp - R) 1.288 1.288
38 Cp/Cv 1.293 1.293
53 Viscosity (cP) 1.967e-002 1.967e-002
56 Cv (kJ/kgmole-C) 28.77 28.77
57 Mass Cv (kJ/kg-C) 0.9708 0.9708
61 Reid VP at 37.8 C (kPa) --- ---
62 True VP at 37.8 C (kPa) --- ---
1
4 USA
5
6
8
9
10
PROPERTIES
14
15
COMPOSITION
16
17
20 n-Butane 33.0897 0.0503 1923.3074 0.0987 3.2977 0.1371
21 Oxygen 9.4564 0.0144 302.6037 0.0155 0.2660 0.0111
22 Nitrogen 444.2881 0.6754 12445.8428 0.6384 15.4343 0.6417
23 MaleicAnhydr 9.3379 0.0142 915.6542 0.0470 0.6921 0.0288
24 CO2 27.6239 0.0420 1215.7203 0.0624 1.4730 0.0612
25 CO 27.6239 0.0420 773.7708 0.0397 0.9680 0.0402
26 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
27 H2O 106.4105 0.1618 1916.9967 0.0983 1.9209 0.0799
28 Total 657.8305 1.0000 19493.8958 1.0000 24.0520 1.0000
29
30
33 n-Butane 33.0897 0.0503 1923.3074 0.0987 3.2977 0.1371
34 Oxygen 9.4564 0.0144 302.6037 0.0155 0.2660 0.0111
35 Nitrogen 444.2881 0.6754 12445.8428 0.6384 15.4343 0.6417
36 MaleicAnhydr 9.3379 0.0142 915.6542 0.0470 0.6921 0.0288
37 CO2 27.6239 0.0420 1215.7203 0.0624 1.4730 0.0612
38 CO 27.6239 0.0420 773.7708 0.0397 0.9680 0.0402
39 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 H2O 106.4105 0.1618 1916.9967 0.0983 1.9209 0.0799
41 Total 657.8305 1.0000 19493.8958 1.0000 24.0520 1.0000
42
43
K VALUE
45 n-Butane --- --- ---
46 Oxygen --- --- ---
47 Nitrogen --- --- ---
49 CO2 --- --- ---
50 CO --- --- ---
51 Acetone --- --- ---
52 H2O --- --- ---
53
54
UNIT OPERATIONS
56 Absorber: T-100 Cooler: E-101
57
58
UTILITIES
60
61
PROCESS UTILITY
62
1
4 USA
5
6
8
9
10
DYNAMICS
13
14
User Variables
15
16
NOTES
17
18
19
Description
20
21
23
24
25
CONDITIONS
26 Overall Aqueous Phase
28 Temperature: (C) 60.62 60.62
29 Pressure: (kPa) 101.3 101.3
31 Mass Flow (kg/h) 817.9 817.9
35 Heat Flow (kJ/h) -1.267e+007 -1.267e+007
37
38
PROPERTIES
41 Molar Density (kgmole/m3) 53.59 53.59
44 Mass Enthalpy (kJ/kg) -1.549e+004 -1.549e+004
52 CO2 App ML Con (kgmole/m3) 5.096e-004 5.096e-004
53 CO2 App WT Con (kgmol/kg) 5.231e-007 5.231e-007
58 Mass Exergy (kJ/kg) -239.4 ---
61 Act. Gas Flow (ACT_m3/h) --- ---
1
4 USA
5
6
8
9
10
PROPERTIES
13 Std. Gas Flow (STD_m3/h) 1064 1064
15 Act. Liq. Flow (m3/s) 2.332e-004 2.332e-004
16 Z Factor 6.813e-004 6.813e-004
17 Watson K 13.48 13.48
20 Cp/(Cp - R) 1.123 1.123
21 Cp/Cv 1.171 1.171
27 Liq. Mass Density (Std. Cond) (kg/m3) 1009 1009
30 Molar Volume (m3/kgmole) 1.866e-002 1.866e-002
31 Mass Heat of Vap. (kJ/kg) 2237 ---
33 Surface Tension (dyne/cm) 65.62 65.62
34 Thermal Conductivity (W/m-K) 0.6503 0.6503
36 Viscosity (cP) 0.4867 0.4867
39 Cv (kJ/kgmole-C) 65.06 65.06
40 Mass Cv (kJ/kg-C) 3.579 3.579
44 Reid VP at 37.8 C (kPa) 369.7 369.7
45 True VP at 37.8 C (kPa) 30.80 30.80
48
49
COMPOSITION
50
51
54 n-Butane 0.1805 0.0040 10.4939 0.0128 0.0180 0.0218
55 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
56 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
57 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 CO2 0.0004 0.0000 0.0188 0.0000 0.0000 0.0000
59 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
60 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 H2O 44.8189 0.9960 807.4168 0.9871 0.8090 0.9782
62 Total 45.0000 1.0000 817.9335 1.0000 0.8271 1.0000
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
Aqueous Phase Phase Fraction 1.000
15 n-Butane 0.1805 0.0040 10.4939 0.0128 0.0180 0.0218
16 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
17 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
18 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 CO2 0.0004 0.0000 0.0188 0.0000 0.0000 0.0000
20 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
21 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 H2O 44.8189 0.9960 807.4168 0.9871 0.8090 0.9782
23 Total 45.0000 1.0000 817.9335 1.0000 0.8271 1.0000
24
25
K VALUE
27 n-Butane 0.0000 --- 0.0000
28 Oxygen 0.0000 --- 0.0000
29 Nitrogen 0.0000 --- 0.0000
30 MaleicAnhydr 0.0000 --- 0.0000
31 CO2 0.0000 --- 0.0000
32 CO 0.0000 --- 0.0000
33 Acetone --- --- ---
34 H2O 0.0000 --- 0.0000
35
36
UNIT OPERATIONS
38 Absorber: T-100 Mixer: MIX-101
39
40
UTILITIES
42
43
PROCESS UTILITY
44
45
46
DYNAMICS
48 Flow Specification (Active) Molar: 45.00 kgmole/h * Mass: 817.9 kg/h Std Ideal Liq Volume: 0.8271 m3/h
49
50
User Variables
51
52
NOTES
53
54
55
Description
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
CONDITIONS
11 Overall Liquid Phase
13 Temperature: (C) 92.95 92.95
14 Pressure: (kPa) 202.6 202.6
16 Mass Flow (kg/h) 1091 1091
19 Molar Entropy (kJ/kgmole-C) -113.8 -113.8
20 Heat Flow (kJ/h) -6.728e+006 -6.728e+006
22
23
PROPERTIES
27 Mass Density (kg/m3) 1158 1158
30 Mass Entropy (kJ/kg-C) -1.946 -1.946
49 Std. Gas Flow (STD_m3/h) 440.9 440.9
50 Std. Ideal Liq. Mass Density (kg/m3) 1247 1247
51 Act. Liq. Flow (m3/s) 2.617e-004 2.617e-004
52 Z Factor 3.364e-003 3.364e-003
53 Watson K 7.238 7.238
56 Cp/(Cp - R) 1.065 1.065
57 Cp/Cv 1.171 1.171
1
4 USA
5
6
8
9
10
PROPERTIES
21 Viscosity (cP) 0.7785 0.7785
24 Cv (kJ/kgmole-C) 116.7 116.7
25 Mass Cv (kJ/kg-C) 1.996 1.996
26 Cv (Ent. Method) (kJ/kgmole-C) -2548 -2548
27 Mass Cv (Ent. Method) (kJ/kg-C) -43.56 -43.56
28 Cp/Cv (Ent. Method) -5.365e-002 -5.365e-002
29 Reid VP at 37.8 C (kPa) 6.506 6.506
30 True VP at 37.8 C (kPa) 323.5 323.5
33
34
COMPOSITION
35
36
39 n-Butane 0.1806 0.0097 10.4958 0.0096 0.0180 0.0206
40 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
41 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
42 MaleicAnhydr 9.3379 0.5008 915.6543 0.8396 0.6921 0.7911
43 CO2 0.0004 0.0000 0.0188 0.0000 0.0000 0.0000
44 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
45 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
46 H2O 9.1268 0.4895 164.4197 0.1508 0.1648 0.1883
47 Total 18.6458 1.0000 1090.5924 1.0000 0.8749 1.0000
48
49
52 n-Butane 0.1806 0.0097 10.4958 0.0096 0.0180 0.0206
53 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
54 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
55 MaleicAnhydr 9.3379 0.5008 915.6543 0.8396 0.6921 0.7911
56 CO2 0.0004 0.0000 0.0188 0.0000 0.0000 0.0000
57 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
58 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 H2O 9.1268 0.4895 164.4197 0.1508 0.1648 0.1883
60 Total 18.6458 1.0000 1090.5924 1.0000 0.8749 1.0000
61
62
1
4 USA
5
6
8
9
10
K VALUE
12 n-Butane 0.0000 0.0000 ---
13 Oxygen 0.0000 0.0000 ---
14 Nitrogen 0.0000 0.0000 ---
15 MaleicAnhydr 0.0000 0.0000 ---
16 CO2 0.0000 0.0000 ---
17 CO 0.0000 0.0000 ---
18 Acetone --- --- ---
19 H2O 0.0000 0.0000 ---
20
21
UNIT OPERATIONS
23 Distillation: T-101 Absorber: T-100
24
25
UTILITIES
27
28
PROCESS UTILITY
29
30
31
DYNAMICS
33 Flow Specification (Inactive) Molar: 18.65 kgmole/h Mass: 1091 kg/h Std Ideal Liq Volume: 0.8749 m3/h
34
35
User Variables
36
37
NOTES
38
39
40
Description
41
42
44
45
46
CONDITIONS
49 Temperature: (C) 77.12 77.12
50 Pressure: (kPa) 202.6 202.6
52 Mass Flow (kg/h) 1.922e+004 1.922e+004
56 Heat Flow (kJ/h) -5.128e+007 -5.128e+007
58
59
PROPERTIES
1
4 USA
5
6
8
9
10
PROPERTIES
36 Act. Liq. Flow (m3/s) --- ---
37 Z Factor 0.9963 0.9963
38 Watson K 7.256 7.256
41 Cp/(Cp - R) 1.312 1.312
42 Cp/Cv 1.320 1.320
57 Viscosity (cP) 1.709e-002 1.709e-002
60 Cv (kJ/kgmole-C) 26.47 26.47
61 Mass Cv (kJ/kg-C) 0.9423 0.9423
1
4 USA
5
6
8
9
10
PROPERTIES
14 Reid VP at 37.8 C (kPa) --- ---
15 True VP at 37.8 C (kPa) --- ---
18
19
COMPOSITION
20
21
24 n-Butane 33.0897 0.0484 1923.3055 0.1001 3.2977 0.1374
25 Oxygen 9.4564 0.0138 302.6037 0.0157 0.2660 0.0111
26 Nitrogen 444.2881 0.6494 12445.8428 0.6475 15.4343 0.6430
27 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 CO2 27.6239 0.0404 1215.7203 0.0632 1.4730 0.0614
29 CO 27.6239 0.0404 773.7708 0.0403 0.9680 0.0403
30 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 H2O 142.1027 0.2077 2559.9938 0.1332 2.5652 0.1069
32 Total 684.1847 1.0000 19221.2369 1.0000 24.0041 1.0000
33
34
37 n-Butane 33.0897 0.0484 1923.3055 0.1001 3.2977 0.1374
38 Oxygen 9.4564 0.0138 302.6037 0.0157 0.2660 0.0111
39 Nitrogen 444.2881 0.6494 12445.8428 0.6475 15.4343 0.6430
40 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 CO2 27.6239 0.0404 1215.7203 0.0632 1.4730 0.0614
42 CO 27.6239 0.0404 773.7708 0.0403 0.9680 0.0403
43 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 H2O 142.1027 0.2077 2559.9938 0.1332 2.5652 0.1069
45 Total 684.1847 1.0000 19221.2369 1.0000 24.0041 1.0000
46
47
K VALUE
49 n-Butane --- --- ---
50 Oxygen --- --- ---
51 Nitrogen --- --- ---
53 CO2 --- --- ---
54 CO --- --- ---
55 Acetone --- --- ---
56 H2O --- --- ---
57
58
UNIT OPERATIONS
60 Absorber: T-100
61
62
1
4 USA
5
6
8
9
10
UTILITIES
12
13
PROCESS UTILITY
14
15
16
DYNAMICS
19
20
User Variables
21
22
NOTES
23
24
25
Description
26
27
29
30
31
CONDITIONS
34 Temperature: (C) 21.53 21.53
35 Pressure: (kPa) 101.3 101.3
37 Mass Flow (kg/h) 174.8 174.8
41 Heat Flow (kJ/h) -2.627e+006 -2.627e+006
43
44
PROPERTIES
1
4 USA
5
6
8
9
10
PROPERTIES
21 Act. Liq. Flow (m3/s) 4.937e-005 4.937e-005
22 Z Factor 7.905e-004 7.905e-004
23 Watson K 13.48 13.48
26 Cp/(Cp - R) 1.121 1.121
27 Cp/Cv 1.154 1.154
42 Viscosity (cP) 0.9117 0.9117
45 Cv (kJ/kgmole-C) 66.71 66.71
46 Mass Cv (kJ/kg-C) 3.550 3.550
50 Reid VP at 37.8 C (kPa) 369.7 369.7
51 True VP at 37.8 C (kPa) 122.6 122.6
53 Viscosity Index 2.192 ---
54
55
COMPOSITION
56
57
60 n-Butane 0.1806 0.0194 10.4958 0.0601 0.0180 0.0986
61 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
62 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 CO2 0.0004 0.0000 0.0188 0.0001 0.0000 0.0001
17 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
18 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 H2O 9.1174 0.9805 164.2513 0.9398 0.1646 0.9013
20 Total 9.2986 1.0000 174.7698 1.0000 0.1826 1.0000
21
22
25 n-Butane 0.1806 0.0194 10.4958 0.0601 0.0180 0.0986
26 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
27 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
28 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 CO2 0.0004 0.0000 0.0188 0.0001 0.0000 0.0001
30 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
31 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 H2O 9.1174 0.9805 164.2513 0.9398 0.1646 0.9013
33 Total 9.2986 1.0000 174.7698 1.0000 0.1826 1.0000
34
35
K VALUE
37 n-Butane 0.0000 --- 0.0000
38 Oxygen 0.0000 --- 0.0000
39 Nitrogen 0.0000 --- 0.0000
40 MaleicAnhydr 0.0000 --- 0.0000
41 CO2 0.0000 --- 0.0000
42 CO 0.0000 --- 0.0000
43 Acetone --- --- ---
44 H2O 0.0000 --- 0.0000
45
46
UNIT OPERATIONS
48 Recycle: RCY-1 Distillation: T-101
49
50
UTILITIES
52
53
PROCESS UTILITY
54
55
56
DYNAMICS
59
60
User Variables
61
62
NOTES
1
4 USA
5
6
8
9
10
11
Description
12
13
15
16
17
CONDITIONS
20 Temperature: (C) 201.5 201.5
21 Pressure: (kPa) 101.3 101.3
23 Mass Flow (kg/h) 915.8 915.8
26 Molar Entropy (kJ/kgmole-C) -213.2 -213.2
27 Heat Flow (kJ/h) -3.944e+006 -3.944e+006
29
30
PROPERTIES
34 Mass Density (kg/m3) 1118 1118
37 Mass Entropy (kJ/kg-C) -2.176 -2.176
57 Std. Ideal Liq. Mass Density (kg/m3) 1323 1323
58 Act. Liq. Flow (m3/s) 2.275e-004 2.275e-004
59 Z Factor 2.249e-003 2.249e-003
60 Watson K 7.161 7.161
1
4 USA
5
6
8
9
10
PROPERTIES
12 Cp/(Cp - R) 1.040 1.040
13 Cp/Cv 1.529 1.529
28 Viscosity (cP) 0.3881 0.3881
31 Cv (kJ/kgmole-C) 141.5 141.5
32 Mass Cv (kJ/kg-C) 1.444 1.444
36 Reid VP at 37.8 C (kPa) 0.1159 0.1159
37 True VP at 37.8 C (kPa) 0.1223 0.1223
40
41
COMPOSITION
42
43
46 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
47 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 MaleicAnhydr 9.3379 0.9990 915.6542 0.9998 0.6921 0.9998
50 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 H2O 0.0093 0.0010 0.1684 0.0002 0.0002 0.0002
54 Total 9.3472 1.0000 915.8226 1.0000 0.6923 1.0000
55
56
59 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 MaleicAnhydr 9.3379 0.9990 915.6542 0.9998 0.6921 0.9998
1
4 USA
5
6
8
9
10
COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 1.000
15 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 H2O 0.0093 0.0010 0.1684 0.0002 0.0002 0.0002
19 Total 9.3472 1.0000 915.8226 1.0000 0.6923 1.0000
20
21
K VALUE
23 n-Butane 0.0000 0.0000 ---
24 Oxygen --- --- ---
25 Nitrogen --- --- ---
26 MaleicAnhydr 0.0000 0.0000 ---
27 CO2 0.0000 0.0000 ---
28 CO --- --- ---
29 Acetone --- --- ---
30 H2O 0.0000 0.0000 ---
31
32
UNIT OPERATIONS
34 Distillation: T-101
35
36
UTILITIES
38
39
PROCESS UTILITY
40
41
42
DYNAMICS
45
46
User Variables
47
48
NOTES
49
50
51
Description
52
53
55
56
57
CONDITIONS
60 Temperature: (C) 71.00 * 71.00
61 Pressure: (kPa) 202.6 * 202.6
1
4 USA
5
6
8
9
10
CONDITIONS
12 Mass Flow (kg/h) 643.2 643.2
16 Heat Flow (kJ/h) -1.005e+007 -1.005e+007
18
19
PROPERTIES
33 CO2 App ML Con (kgmole/m3) 0.0000 0.0000
34 CO2 App WT Con (kgmol/kg) 0.0000 0.0000
47 Act. Liq. Flow (m3/s) 1.839e-004 1.839e-004
48 Z Factor 1.313e-003 1.313e-003
49 Watson K --- ---
52 Cp/(Cp - R) 1.123 1.123
53 Cp/Cv 1.175 1.175
1
4 USA
5
6
8
9
10
PROPERTIES
17 Viscosity (cP) 0.3950 0.3950
20 Cv (kJ/kgmole-C) 64.39 64.39
21 Mass Cv (kJ/kg-C) 3.574 3.574
25 Reid VP at 37.8 C (kPa) --- ---
26 True VP at 37.8 C (kPa) --- ---
29
30
COMPOSITION
31
32
35 n-Butane 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
36 Oxygen 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
37 Nitrogen 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
38 MaleicAnhydr 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
39 CO2 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
40 CO 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
41 Acetone 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
42 H2O 35.7032 * 1.0000 * 643.1976 * 1.0000 * 0.6445 * 1.0000 *
43 Total 35.7032 1.0000 643.1976 1.0000 0.6445 1.0000
44
45
48 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 H2O 35.7032 1.0000 643.1976 1.0000 0.6445 1.0000
56 Total 35.7032 1.0000 643.1976 1.0000 0.6445 1.0000
57
58
K VALUE
60 n-Butane --- --- ---
61 Oxygen --- --- ---
62 Nitrogen --- --- ---
1
4 USA
5
6
8
9
10
K VALUE
13 CO2 --- --- ---
14 CO --- --- ---
15 Acetone --- --- ---
16 H2O 0.0000 --- 0.0000
17
18
UNIT OPERATIONS
20 Mixer: MIX-101
21
22
UTILITIES
24
25
PROCESS UTILITY
26
27
28
DYNAMICS
31
32
User Variables
33
34
NOTES
35
36
37
Description
38
39
41
42
43
CONDITIONS
46 Temperature: (C) 21.56 * 21.56
47 Pressure: (kPa) 101.3 * 101.3
49 Mass Flow (kg/h) 174.7 174.7
53 Heat Flow (kJ/h) -2.626e+006 -2.626e+006
55
56
PROPERTIES
1
4 USA
5
6
8
9
10
PROPERTIES
33 Act. Liq. Flow (m3/s) 4.937e-005 4.937e-005
34 Z Factor 7.905e-004 7.905e-004
35 Watson K 13.48 13.48
38 Cp/(Cp - R) 1.121 1.121
39 Cp/Cv 1.154 1.154
54 Viscosity (cP) 0.9112 0.9112
57 Cv (kJ/kgmole-C) 66.71 66.71
58 Mass Cv (kJ/kg-C) 3.549 3.549
62 Reid VP at 37.8 C (kPa) 369.7 369.7
1
4 USA
5
6
8
9
10
PROPERTIES
12 True VP at 37.8 C (kPa) 122.6 122.6
14 Viscosity Index 2.185 ---
15
16
COMPOSITION
17
18
21 n-Butane 0.1805 * 0.0194 * 10.4939 * 0.0601 * 0.0180 * 0.0986 *
22 Oxygen 0.0000 * 0.0000 * 0.0003 * 0.0000 * 0.0000 * 0.0000 *
23 Nitrogen 0.0001 * 0.0000 * 0.0030 * 0.0000 * 0.0000 * 0.0000 *
24 MaleicAnhydr 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
25 CO2 0.0004 * 0.0000 * 0.0188 * 0.0001 * 0.0000 * 0.0001 *
26 CO 0.0000 * 0.0000 * 0.0006 * 0.0000 * 0.0000 * 0.0000 *
27 Acetone 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
28 H2O 9.1156 * 0.9805 * 164.2192 * 0.9398 * 0.1646 * 0.9013 *
29 Total 9.2968 1.0000 174.7359 1.0000 0.1826 1.0000
30
31
34 n-Butane 0.1805 0.0194 10.4939 0.0601 0.0180 0.0986
35 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
36 Nitrogen 0.0001 0.0000 0.0030 0.0000 0.0000 0.0000
37 MaleicAnhydr 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 CO2 0.0004 0.0000 0.0188 0.0001 0.0000 0.0001
39 CO 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
40 Acetone 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 H2O 9.1156 0.9805 164.2192 0.9398 0.1646 0.9013
42 Total 9.2968 1.0000 174.7359 1.0000 0.1826 1.0000
43
44
K VALUE
46 n-Butane 0.0000 --- 0.0000
47 Oxygen 0.0000 --- 0.0000
48 Nitrogen 0.0000 --- 0.0000
49 MaleicAnhydr 0.0000 --- 0.0000
50 CO2 0.0000 --- 0.0000
51 CO 0.0000 --- 0.0000
52 Acetone --- --- ---
53 H2O 0.0000 --- 0.0000
54
55
UNIT OPERATIONS
57 Mixer: MIX-101 Recycle: RCY-1
58
59
UTILITIES
61
62
1
4 USA
5
6
8
9
10
PROCESS UTILITY
11
12
13
DYNAMICS
14 Pressure Specification (Inactive): 101.3 kPa *
15 Flow Specification (Inactive) Molar: 9.297 kgmole/h * Mass: 174.7 kg/h Std Ideal Liq Volume: 0.1826 m3/h
16
17
User Variables
18
19
NOTES
20
21
22
Description
23
24
25 Heater: E-100
26
27
28
CONNECTIONS
29
30
Inlet Stream
31 STREAM NAME FROM UNIT OPERATION
32 6 Mixer MIX-100
33
34
Outlet Stream
35 STREAM NAME TO UNIT OPERATION
36 7 Plug Flow Reactor PFR-100
37
38
Energy Stream
40 QE100
41
42
PARAMETERS
43 Pressure Drop: 0.0000 kPa * Duty: 1.329e+006 kJ/h Volume: 0.1000 m3
44 Function: Not Selected Zones: 1
45
46
User Variables
47
48
RATING
49
50
NOZZLE PARAMETERS
51 Base Elevation Relative to Ground Level 0.0000 m *
52 6 7
53 Diameter (m) 5.000e-002 5.000e-002
54 Elevation (Base) (m) 0.0000 0.0000
55 Elevation (Ground) (m) 0.0000 * 0.0000 *
56
57
CONDITIONS
58 Name 6 7 QE100
59 Vapour 1.0000 1.0000 ---
60 Temperature (C) 93.9716 150.0000 * ---
61 Pressure (kPa) 202.6500 202.6500 ---
62 Molar Flow (kgmole/h) 618.6290 618.6290 ---
1
4 USA
5
6
7 Heater: E-100 (continued)
8
9
10
CONDITIONS
11 Mass Flow (kg/h) 19493.9392 19493.9392 ---
12 Std Ideal Liq Vol Flow (m3/h) 24.3610 24.3610 ---
13 Molar Enthalpy (kJ/kgmole) -8978 -6830 ---
14 Molar Entropy (kJ/kgmole-C) 153.8 159.3 ---
15 Heat Flow (kJ/h) -5.5543e+06 -4.2251e+06 1.3292e+06
16
17
PROPERTIES
18 Name 6 7
22 Act. Volume Flow (m3/h) 9308 1.074e+004
31 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
32 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
37 Mass Exergy (kJ/kg) 62.52 79.20
38 Partial Pressure of CO2 (kPa) 0.0000 0.0000
40 Act. Gas Flow (ACT_m3/h) 9308 1.074e+004
45 Act. Liq. Flow (m3/s) --- ---
46 Z Factor 0.9989 0.9997
47 Watson K 7.138 7.138
49 Partial Pressure of H2S (kPa) 0.0000 0.0000
50 Cp/(Cp - R) 1.284 1.270
51 Cp/Cv 1.288 1.273
55 Heat of Vap. (kJ/kgmole) 1.626e+004 1.626e+004
61 Mass Heat of Vap. (kJ/kg) 515.9 515.9
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name 6 7
15 Viscosity (cP) 2.090e-002 2.322e-002
18 Cv (kJ/kgmole-C) 29.17 30.74
19 Mass Cv (kJ/kg-C) 0.9255 0.9754
23 Reid VP at 37.8 C (kPa) --- ---
24 True VP at 37.8 C (kPa) --- ---
27
28
PERFORMANCE PROFILES
29 Zone Pressure Temperature Vapour Fraction Enthalpy
30 (kPa) (C) (kJ/kgmole)
31 Inlet 202.65 93.97 1.0000 -8978.36
32 0 202.65 150.00 1.0000 -6829.77
33
34
PERFORMANCE PLOT
35
36
37 207,0
38
206,0
39
40 205,0
41
42 204,0
Pressure (kPa)
43
203,0
44
45 202,0
46
47 201,0
48
200,0
49
50 199,0
51
52 198,0
53
197,0
54
90,00 100,0 110,0 120,0 130,0 140,0 150,0
55
56 Temperature (C)
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
PERFORMANCE TABLE
11
12
Overall Phase
13 Temperature Pressure Heat Flow Enthalpy
14 (C) (kPa) (kJ/h) (kJ/kgmole)
15 93.97 202.65 0.00 -8978.36
16 99.57 202.65 130496.59 -8767.42
17 105.18 202.65 261538.11 -8555.59
18 110.78 202.65 393122.05 -8342.89
19 116.38 202.65 525245.89 -8129.31
20 121.99 202.65 657907.06 -7914.87
21 127.59 202.65 791102.99 -7699.56
22 133.19 202.65 924831.09 -7483.39
23 138.79 202.65 1059088.74 -7266.37
24 144.40 202.65 1193873.31 -7048.49
25 150.00 202.65 1329182.18 -6829.77
26 Vapour Fraction Vap Phase Mass Frac Heat of Vap
27 (kJ/kgmole)
28 1.0000 1.0000 ---
29 1.0000 1.0000 ---
30 1.0000 1.0000 ---
31 1.0000 1.0000 ---
32 1.0000 1.0000 ---
33 1.0000 1.0000 ---
34 1.0000 1.0000 ---
35 1.0000 1.0000 ---
36 1.0000 1.0000 ---
37 1.0000 1.0000 ---
38 1.0000 1.0000 ---
39
40
Vapour Phase
41 Mass Flow Molecular Wt Density Mass Sp Heat Viscosity Thermal Cond
42 (kg/h) (kg/m3) (kJ/kg-C) (cP) (W/m-K)
43 19493.94 31.51 2.09 1.19 0.02 0.03
44 19493.94 31.51 2.06 1.20 0.02 0.03
45 19493.94 31.51 2.03 1.20 0.02 0.03
46 19493.94 31.51 2.00 1.21 0.02 0.03
47 19493.94 31.51 1.97 1.21 0.02 0.03
48 19493.94 31.51 1.95 1.22 0.02 0.03
49 19493.94 31.51 1.92 1.22 0.02 0.03
50 19493.94 31.51 1.89 1.23 0.02 0.03
51 19493.94 31.51 1.87 1.23 0.02 0.03
52 19493.94 31.51 1.84 1.24 0.02 0.03
53 19493.94 31.51 1.82 1.24 0.02 0.03
54 Std Gas Flow Z Factor Pseudo Pc Pseudo Tc Pseudo Zc Pseudo Omega
55 (STD_m3/h) (kPa) (C)
56 14627.13 1.00 3752.74 -114.32 0.29 0.05
57 14627.13 1.00 3752.74 -114.32 0.29 0.05
58 14627.13 1.00 3752.74 -114.32 0.29 0.05
59 14627.13 1.00 3752.74 -114.32 0.29 0.05
60 14627.13 1.00 3752.74 -114.32 0.29 0.05
61 14627.13 1.00 3752.74 -114.32 0.29 0.05
62 14627.13 1.00 3752.74 -114.32 0.29 0.05
1
4 USA
5
6
8
9
10
PERFORMANCE TABLE
11
12
Vapour Phase
14 (STD_m3/h) (kPa) (C)
15 14627.13 1.00 3752.74 -114.32 0.29 0.05
16 14627.13 1.00 3752.74 -114.32 0.29 0.05
17 14627.13 1.00 3752.74 -114.32 0.29 0.05
18 14627.13 1.00 3752.74 -114.32 0.29 0.05
19
20
Light Liquid Phase
21 Mass Flow Density Mass Sp Heat Viscosity Thermal Cond Surface Tens
22 (kg/h) (kg/m3) (kJ/kg-C) (cP) (W/m-K) (dyne/cm)
23 --- --- --- --- --- ---
24 --- --- --- --- --- ---
25 --- --- --- --- --- ---
26 --- --- --- --- --- ---
27 --- --- --- --- --- ---
28 --- --- --- --- --- ---
29 --- --- --- --- --- ---
30 --- --- --- --- --- ---
31 --- --- --- --- --- ---
32 --- --- --- --- --- ---
33 --- --- --- --- --- ---
34 Molecular Wt Sp Gravity Pseudo Pc Pseudo Tc Pseudo Zc Pseudo Omega
35 (kPa) (C)
36 --- --- --- --- --- ---
37 --- --- --- --- --- ---
38 --- --- --- --- --- ---
39 --- --- --- --- --- ---
40 --- --- --- --- --- ---
41 --- --- --- --- --- ---
42 --- --- --- --- --- ---
43 --- --- --- --- --- ---
44 --- --- --- --- --- ---
45 --- --- --- --- --- ---
46 --- --- --- --- --- ---
47
48
Heavy Liquid Phase
51 --- --- --- --- --- ---
52 --- --- --- --- --- ---
53 --- --- --- --- --- ---
54 --- --- --- --- --- ---
55 --- --- --- --- --- ---
56 --- --- --- --- --- ---
57 --- --- --- --- --- ---
58 --- --- --- --- --- ---
59 --- --- --- --- --- ---
60 --- --- --- --- --- ---
61 --- --- --- --- --- ---
62
1
4 USA
5
6
8
9
10
PERFORMANCE TABLE
11
12
Heavy Liquid Phase
14 (kPa) (C)
15 --- --- --- --- --- ---
16 --- --- --- --- --- ---
17 --- --- --- --- --- ---
18 --- --- --- --- --- ---
19 --- --- --- --- --- ---
20 --- --- --- --- --- ---
21 --- --- --- --- --- ---
22 --- --- --- --- --- ---
23 --- --- --- --- --- ---
24 --- --- --- --- --- ---
25 --- --- --- --- --- ---
26
27
Mixed Liquid Phase
30 --- --- --- --- --- ---
31 --- --- --- --- --- ---
32 --- --- --- --- --- ---
33 --- --- --- --- --- ---
34 --- --- --- --- --- ---
35 --- --- --- --- --- ---
36 --- --- --- --- --- ---
37 --- --- --- --- --- ---
38 --- --- --- --- --- ---
39 --- --- --- --- --- ---
40 --- --- --- --- --- ---
42 (kPa) (C)
43 --- --- --- --- --- ---
44 --- --- --- --- --- ---
45 --- --- --- --- --- ---
46 --- --- --- --- --- ---
47 --- --- --- --- --- ---
48 --- --- --- --- --- ---
49 --- --- --- --- --- ---
50 --- --- --- --- --- ---
51 --- --- --- --- --- ---
52 --- --- --- --- --- ---
53 --- --- --- --- --- ---
54
55
DYNAMICS
56
57
Model Details: Supplied Duty
58 Zone 1* Delta P (kPa) 0.0000 *
59 Volume (m3) 0.1000 * Overall K (kg/hr/sqrt(kPa-kg/m3)) 3.600e-003 *
60 Duty (kJ/h) 1.329e+006
61
62
Holdup Details
1
4 USA
5
6
8
9 Phase Accumulation Moles Volume
10 (kgmole/h) (kgmole) (m3)
11 Vapour 0.0000 0.0000 0.0000
12 Liquid 0.0000 0.0000 0.0000
13 Aqueous 0.0000 0.0000 0.0000
14 Total 0.0000 0.0000 0.0000
15
16
Individual Zone Holdups: Zone 0
17
18
Delta P Specs and Duties
19 Zone dP Value dP Option Duty
20 (kPa) (kJ/h)
21 0 * 0.0000 * not specified -5.709e+004 *
22
23
Zone Conductance Specifications
24 Zone k Specification
25 (kg/hr/sqrt(kPa-kg/m3))
26 0 * 3.600e-003 Disabled
27
28
NOTES
29
30
31 Cooler: E-101
32
33
34
CONNECTIONS
35
36
Inlet Stream
38 8 Plug Flow Reactor PFR-100
39
40
Outlet Stream
42 9 Absorber T-100
43
44
Energy Stream
46 QE101
47
48
PARAMETERS
49 Pressure Drop: 0.0000 kPa * Duty: 7.347e+006 kJ/h Volume: 0.1000 m3
50 Function: Not Selected Zones: 1
51
52
User Variables
53
54
NOZZLE PARAMETERS
56 8 9
57 Diameter (m) 5.000e-002 5.000e-002
58 Elevation (Base) (m) 0.0000 0.0000
59 Elevation (Ground) (m) 0.0000 * 0.0000 *
60
61
CONDITIONS
62 Name 8 9 QE101
1
4 USA
5
6
7 Cooler: E-101 (continued)
8
9
10
CONDITIONS
11 Vapour 1.0000 1.0000 ---
12 Temperature (C) 399.8500 * 120.0000 * ---
13 Pressure (kPa) 199.3142 199.3142 ---
15 Mass Flow (kg/h) 19493.8958 19493.8958 ---
17 Molar Enthalpy (kJ/kgmole) -5.774e+004 -6.891e+004 ---
19 Heat Flow (kJ/h) -3.7983e+07 -4.5330e+07 7.3469e+06
20
21
PROPERTIES
22 Name 8 9
49 Act. Liq. Flow (m3/s) --- ---
50 Z Factor --- 0.9978
51 Watson K 7.251 7.251
54 Cp/(Cp - R) 1.244 1.288
55 Cp/Cv 1.245 1.293
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name 8 9
19 Viscosity (cP) 2.967e-002 1.967e-002
22 Cv (kJ/kgmole-C) 34.07 28.77
23 Mass Cv (kJ/kg-C) 1.150 0.9708
27 Reid VP at 37.8 C (kPa) --- ---
28 True VP at 37.8 C (kPa) --- ---
31
32
PERFORMANCE PROFILES
33 Zone Pressure Temperature Vapour Fraction Enthalpy
34 (kPa) (C) (kJ/kgmole)
35 Inlet 199.31 399.85 1.0000 -57740.28
36 0 199.31 120.00 1.0000 -68908.73
37
38
PERFORMANCE PLOT
39
40
41 204,0
42
203,0
43
44 202,0
45
46 201,0
Pressure (kPa)
47
200,0
48
49 199,0
50
51 198,0
52
197,0
53
54 196,0
55
56 195,0
57
194,0
58
100,0 150,0 200,0 250,0 300,0 350,0 400,0
59
60 Temperature (C)
61
62
1
4 USA
5
6
8
9
10
PERFORMANCE TABLE
11
12
Overall Phase
13 Temperature Pressure Heat Flow Enthalpy
14 (C) (kPa) (kJ/h) (kJ/kgmole)
15 399.85 199.31 0.00 -57740.28
16 371.87 199.31 -776521.41 -58920.71
17 343.88 199.31 -1544315.59 -60087.87
18 315.89 199.31 -2303181.47 -61241.46
19 287.91 199.31 -3052913.55 -62381.16
20 259.93 199.31 -3793249.96 -63506.59
21 231.94 199.31 -4524058.79 -64617.52
22 203.96 199.31 -5245073.58 -65713.57
23 175.97 199.31 -5956057.50 -66794.37
24 147.99 199.31 -6656765.08 -67859.55
25 120.00 199.31 -7346943.81 -68908.73
26 Vapour Fraction Vap Phase Mass Frac Heat of Vap
27 (kJ/kgmole)
28 1.0000 1.0000 ---
29 1.0000 1.0000 ---
30 1.0000 1.0000 ---
31 1.0000 1.0000 ---
32 1.0000 1.0000 ---
33 1.0000 1.0000 ---
34 1.0000 1.0000 ---
35 1.0000 1.0000 ---
36 1.0000 1.0000 ---
37 1.0000 1.0000 ---
38 1.0000 1.0000 ---
39
40
Vapour Phase
41 Mass Flow Molecular Wt Density Mass Sp Heat Viscosity Thermal Cond
42 (kg/h) (kg/m3) (kJ/kg-C) (cP) (W/m-K)
43 19493.90 29.63 1.06 1.43 0.03 0.05
44 19493.90 29.63 1.10 1.42 0.03 0.05
45 19493.90 29.63 1.15 1.40 0.03 0.05
46 19493.90 29.63 1.21 1.38 0.03 0.04
47 19493.90 29.63 1.27 1.37 0.03 0.04
48 19493.90 29.63 1.33 1.35 0.03 0.04
49 19493.90 29.63 1.41 1.33 0.02 0.04
50 19493.90 29.63 1.49 1.31 0.02 0.04
51 19493.90 29.63 1.58 1.29 0.02 0.03
52 19493.90 29.63 1.69 1.27 0.02 0.03
53 19493.90 29.63 1.81 1.26 0.02 0.03
55 (STD_m3/h) (kPa) (C)
56 15554.03 1.00 6694.38 -31.01 0.28 0.11
57 15554.03 1.00 6694.38 -31.01 0.28 0.11
58 15554.03 1.00 6694.38 -31.01 0.28 0.11
59 15554.03 1.00 6694.38 -31.01 0.28 0.11
60 15554.03 1.00 6694.38 -31.01 0.28 0.11
61 15554.03 1.00 6694.38 -31.01 0.28 0.11
62 15554.03 1.00 6694.38 -31.01 0.28 0.11
1
4 USA
5
6
8
9
10
PERFORMANCE TABLE
11
12
Vapour Phase
14 (STD_m3/h) (kPa) (C)
15 15554.03 1.00 6694.38 -31.01 0.28 0.11
16 15554.03 1.00 6694.38 -31.01 0.28 0.11
17 15554.03 1.00 6694.38 -31.01 0.28 0.11
18 15554.03 1.00 6694.38 -31.01 0.28 0.11
19
20
Light Liquid Phase
23 0.00 2.01 2.98 0.00 0.05 34.66
24 0.00 2.27 4.85 0.00 0.06 72.82
25 0.00 2.56 3.09 0.00 0.08 124.66
26 0.00 2.85 2.82 0.00 0.11 186.61
27 0.00 3.17 2.63 0.00 0.13 257.56
28 0.00 3.52 2.49 0.00 0.14 335.15
29 0.00 3.89 2.38 0.01 0.15 416.98
30 0.00 3.14 2.52 0.01 0.23 323.30
31 0.00 3.52 2.41 0.01 0.24 396.91
32 0.00 3.97 2.31 0.01 0.25 476.32
33 0.00 4.47 2.23 0.02 0.24 558.49
35 (kPa) (C)
36 56.32 0.00 9589.91 259.95 0.26 0.33
37 61.16 0.00 10219.22 312.79 0.26 0.37
38 65.87 0.00 10444.15 348.32 0.26 0.40
39 70.03 0.00 10545.15 374.91 0.26 0.43
40 74.15 0.00 10456.26 395.55 0.25 0.46
41 78.17 0.00 10210.62 411.44 0.25 0.48
42 82.01 0.00 9841.59 423.21 0.25 0.50
43 62.42 0.00 13098.38 396.07 0.26 0.44
44 65.93 0.00 12747.50 406.58 0.25 0.45
45 69.59 0.00 12295.95 415.37 0.25 0.47
46 73.22 0.00 11749.46 421.74 0.25 0.48
47
48
Heavy Liquid Phase
51 --- --- --- --- --- ---
52 --- --- --- --- --- ---
53 --- --- --- --- --- ---
54 --- --- --- --- --- ---
55 --- --- --- --- --- ---
56 --- --- --- --- --- ---
57 --- --- --- --- --- ---
58 --- --- --- --- --- ---
59 --- --- --- --- --- ---
60 --- --- --- --- --- ---
61 --- --- --- --- --- ---
62
1
4 USA
5
6
8
9
10
PERFORMANCE TABLE
11
12
Heavy Liquid Phase
14 (kPa) (C)
15 --- --- --- --- --- ---
16 --- --- --- --- --- ---
17 --- --- --- --- --- ---
18 --- --- --- --- --- ---
19 --- --- --- --- --- ---
20 --- --- --- --- --- ---
21 --- --- --- --- --- ---
22 --- --- --- --- --- ---
23 --- --- --- --- --- ---
24 --- --- --- --- --- ---
25 --- --- --- --- --- ---
26
27
Mixed Liquid Phase
30 --- --- --- --- --- ---
31 --- --- --- --- --- ---
32 --- --- --- --- --- ---
33 --- --- --- --- --- ---
34 --- --- --- --- --- ---
35 --- --- --- --- --- ---
36 --- --- --- --- --- ---
37 --- --- --- --- --- ---
38 --- --- --- --- --- ---
39 --- --- --- --- --- ---
40 --- --- --- --- --- ---
42 (kPa) (C)
43 --- --- --- --- --- ---
44 --- --- --- --- --- ---
45 --- --- --- --- --- ---
46 --- --- --- --- --- ---
47 --- --- --- --- --- ---
48 --- --- --- --- --- ---
49 --- --- --- --- --- ---
50 --- --- --- --- --- ---
51 --- --- --- --- --- ---
52 --- --- --- --- --- ---
53 --- --- --- --- --- ---
54
55
DYNAMICS
56
57
Model Details: Supplied Duty
58 Zone 1* Delta P (kPa) 0.0000 *
59 Volume (m3) 0.1000 * Overall K (kg/hr/sqrt(kPa-kg/m3)) 3.600e-003 *
60 Duty (kJ/h) 7.347e+006
61
62
Holdup Details
1
4 USA
5
6
8
11 Vapour 0.0000 0.0000 0.0000
12 Liquid 0.0000 0.0000 0.0000
13 Aqueous 0.0000 0.0000 0.0000
14 Total 0.0000 0.0000 0.0000
15
16
Individual Zone Holdups: Zone 0
17
18
Delta P Specs and Duties
19 Zone dP Value dP Option Duty
20 (kPa) (kJ/h)
21 0 * 0.0000 * not specified -7.347e+006 *
22
23
Zone Conductance Specifications
24 Zone k Specification
25 (kg/hr/sqrt(kPa-kg/m3))
26 0 * 3.600e-003 Disabled
27
28
NOTES
29
30
31
32
Feeder Block: FeederBlock_1
33 ( No Datasheets exist for this unit operation )
34
35
36
38
39
40
42
43 Compressor: K-100
44
45
DESIGN
46
47
Connections
48
49
Inlet Stream
50
52 3 Separator V-100
53
Outlet Stream
54
56 5 Mixer MIX-100
57
Energy Stream
58
60 QK100
61
62
1
4 USA
5
6
7 Compressor: K-100 (continued)
8
9
Parameters
10
11 Speed: --- Duty: 3.9545e+02 kW
12 Adiabatic Eff.: 75.00 PolyTropic Eff.: 77.26
13 Adiabatic Head: 6710 m Polytropic Head: 6913 m
14 Adiabatic Fluid Head: 65.81 kJ/kg Polytropic Fluid Head: 67.79 kJ/kg
15 Polytropic Exp. 1.579 Isentropic Exp. 1.397 Poly Head Factor 1.000
16
User Variables
17
18
RATING
19
20
Curves
21
22 Compressor Speed: --- Efficiency: Adiabatic Curves Enabled: Yes
23 Head Offset: 0.0000 m Efficiency Offset: 0.00 %
24 Speed:
25 Flow Head Efficiency (%)
26
Flow Limits
27
28 Surge Curve: Inactive
29 Speed Flow Speed Flow Speed Flow
30 Stone Wall Curve: Inactive
31 Speed Flow Speed Flow Speed Flow
32 Surge Flow Rate --- Field Flow Rate
1.375e+004 ACT_m3/h Stone Wall Flow --- Compressor Volume 0.0000 m3
33
Nozzle Paramaters
34
36 3 5
37 Diameter (m) 5.000e-002 5.000e-002
38 Elevation (Base) (m) 0.0000 0.0000
39 Elevation (Ground) (m) 0.0000 0.0000
40
Inertia
41
42 Rotational inertia (kg-m2) 6.000 Radius of gyration (m) 0.2000
43 Mass (kg) 150.0 Friction loss factor (rad/min) (kg-m2/s) 6.000e-003
44
WORKSHEET
45
46
Conditions
47
48 Name 3 5 QK100
49 Vapour 1.0000 1.0000 ---
50 Temperature (C) 25.0000 111.0895 ---
51 Pressure (kPa) 101.3250 202.6500 * ---
53 Mass Flow (kg/h) 16225.1036 16225.1036 ---
55 Molar Enthalpy (kJ/kgmole) -8.140 2523 ---
57 Heat Flow (kJ/h) -4.5777e+03 1.4190e+06 1.4236e+06
58
Properties
59
60 Name 3 5
1
4 USA
5
6
8
9
Properties
10
11 Name 3 5
13 Act. Volume Flow (m3/h) 1.375e+004 8866
14 Mass Enthalpy (kJ/kg) -0.2821 87.46
28 Mass Exergy (kJ/kg) -2.896e-006 70.23
31 Act. Gas Flow (ACT_m3/h) 1.375e+004 8866
36 Act. Liq. Flow (m3/s) --- ---
37 Z Factor --- 1.000
38 Watson K 6.042 6.042
41 Cp/(Cp - R) 1.398 1.388
42 Cp/Cv 1.401 1.391
46 Heat of Vap. (kJ/kgmole) 5952 5724
57 Viscosity (cP) 1.883e-002 2.267e-002
60 Cv (kJ/kgmole-C) 20.84 21.38
61 Mass Cv (kJ/kg-C) 0.7223 0.7412
1
4 USA
5
6
8
9
Properties
10
11 Name 3 5
14 Reid VP at 37.8 C (kPa) --- ---
15 True VP at 37.8 C (kPa) --- ---
18
PERFORMANCE
19
20
Results
21
22 Adiabatic Head (m) 6710 Power Consumed (kW) 395.4
23 Polytropic Head (m) 6913 Polytropic Head Factor 1.000
24 Adiabatic Fluid Head (kJ/kg) 65.81 Polytropic Exponent 1.579
25 Polytropic Fluid Head (kJ/kg) 67.79 Isentropic Exponent 1.397
26 Adiabatic Efficiency 75 Speed (rpm) ---
27 Polytropic Efficiency 77 ---
28
Power/Torque
29
30 Total Rotor Power (kW) 395.4 Total Rotor Torque (N-m) ---
31 Transient Rotor Power (kW) 0.0000 Transient Rotor Torque (N-m) ---
32 Friction Power Loss (kW) 0.0000 Friction Torque Loss (N-m) ---
33 Fluid Power (kW) 395.4 Fluid Torque (N-m) ---
34
DYNAMICS
35
36
Dynamic Specifications
37
38 Duty (kJ/h) 1.424e+006 Active Head (m) 6913 Not Active
39 Adiabatic Efficiency 75 Not Active Fluid Head (kJ/kg) 67.79 Not Active
40 Polytropic Efficiency 77 Active Capacity (ACT_m3/h) 1.375e+004 Not Active
41 Pressure Increase (kPa) 101.3 Not Active Speed (rpm) --- Not Active
42 --- Use Characteristic Curves No
43
Holdup Details
44
47 Vapour 0.0000 0.0000 0.0000
48 Liquid 0.0000 0.0000 0.0000
49 Aqueous 0.0000 0.0000 0.0000
50 Total 0.0000 0.0000 0.0000
51
NOTES
52
53
54
55 Simulation Case: Case
56
57
STATUS MESSAGES
58
59 Tag: Main Minimum Severity: ---
60
Object Status
61
62 Severity Source Messages
1
4 USA
5
6
7 Simulation Case: Case (continued)
8
9 Required Info Set-2 Reaction set is not complete
10 Warning Set-2 Reaction set is not complete
11 Required Info Rxn-4 Rxn is not complete
14 Required Info Internals-1@Main Tower@COL1 No Sections
15 Warning Internals-1@Main Tower@COL1 Calculate
16 Required Info Internals-1@Main Tower@COL2 No Sections
17 Warning Internals-1@Main Tower@COL2 Calculate
18 Warning All reactions sets are not complete
19
Calculation Levels
20
21 Name Active Calculation Level
22 1 Yes 500.0 *
23 2 Yes 500.0 *
24 3 Yes 500.0 *
25 4 Yes 500.0 *
26 5 Yes 500.0 *
27 6 Yes 500.0 *
28 7 Yes 500.0 *
29 8 Yes 500.0 *
30 9 Yes 500.0 *
31 10 Yes 500.0 *
32 11 Yes 500.0 *
33 12 Yes 500.0 *
34 13 Yes 500.0 *
35 14 Yes 500.0 *
36 15 Yes 500.0 *
37 16 Yes 500.0 *
38 FeederBlock_1 Yes 500.0 *
40 ProductBlock_4 Yes 500.0 *
44 MIX-100 Yes 500.0 *
45 MIX-101 Yes 500.0 *
46 QPFR100 Yes 500.0 *
47 QK100 Yes 500.0 *
48 QE100 Yes 500.0 *
49 QE101 Yes 500.0 *
50 QCT101 Yes 500.0 *
51 QHT101 Yes 500.0 *
52 V-100 Yes 500.0 *
53 K-100 Yes 500.0 *
54 SET-1 Yes 500.0 *
55 E-100 Yes 500.0 *
56 PFR-100 Yes 500.0 *
57 E-101 Yes 500.0 *
58 T-100 Yes 2500 *
59 T-101 Yes 2500 *
60 RCY-1 Yes 3500 *
61
Exported Connections, Exported Variables and Initial Input Expert Only Available in Template View
62
1
4 USA
5
6
7 Simulation Case: Case (continued)
8
9
OVERALL MASS BALANCE
10
11 In Stream Count Mass Flow Out Stream Count Mass Flow
12
13 Total In MassFlow --- Total Out MassFlow ---
14 Mass Imbalance --- Rel Mass Imbalance Pct (%) ---
15
OVERALL ENERGY BALANCE
16
17 InStream Count Energy Flow OutStream Count Energy Flow
18
19 Total In EnergyFlow (kJ/h) --- Total Out EnergyFlow (kJ/h) ---
20 Energy Imbalance (kJ/h) --- Rel Energy Imbalance Pct (%) ---
21
OVERALL UTILITY BALANCE
22
23 Utility Name Usage Info Energy Flow Mass Flow Cost
24
25
Hot Utility Summary Cold Utility Summary
26
27 Utility Flow --- Utility Flow ---
28 Utility Cost --- Utility Cost ---
29 Carbon Emiss. --- Carbon Emiss. ---
30 Carbon Fees --- Carbon Fees ---
31
PROCESS CO2 EMISSIONS
32
33 Inlet Stream Count IFPP (1995) IFPP (2007) EPA (2009)
34
35 Total from Inlets --- --- ---
36 Total Carbon Fees
--- --- ---
37 from Inlets (Cost/hr)
38 Outlet Stream Count IFPP (1995) IFPP (2007) EPA (2009)
39
40 Total from Outlets --- --- ---
41 Total Carbon Fees
--- --- ---
42 from Outlets (Cost/hr)
43
User Variables
44
45
46 Mixer: MIX-100
47
48
49
CONNECTIONS
50
51
Inlet Stream
53 1
54 5 Compressor K-100
55
56
Outlet Stream
58 6 Heater E-100
59
60
PARAMETERS
61
62
User Variables
1
4 USA
5
6
7 Mixer: MIX-100 (continued)
8
9
10
NOZZLE PARAMETERS
12 1 5 6
13 Diameter (m) 5.000e-002 5.000e-002 5.000e-002
14 Elevation (Base) (m) 0.0000 0.0000 0.0000
15 Elevation (Ground) (m) 0.0000 0.0000 0.0000
16
17
CONDITIONS
18 Name 1 5 6
19 Vapour 1.0000 1.0000 1.0000
20 Temperature (C) 50.0000 * 111.0895 93.9716
21 Pressure (kPa) 202.6500 * 202.6500 * 202.6500
22 Molar Flow (kgmole/h) 56.2390 * 562.3900 618.6290
23 Mass Flow (kg/h) 3268.8357 16225.1036 19493.9392
25 Molar Enthalpy (kJ/kgmole) -1.240e+005 2523 -8978
27 Heat Flow (kJ/h) -6.9733e+06 1.4190e+06 -5.5543e+06
28
29
PROPERTIES
30 Name 1 5 6
33 Mass Density (kg/m3) 4.595 1.830 2.094
34 Act. Volume Flow (m3/h) 711.4 8866 9308
35 Mass Enthalpy (kJ/kg) -2133 87.46 -284.9
39 LHV Molar Basis (Std) (kJ/kgmole) 2.660e+006 0.0000 2.418e+005
40 HHV Molar Basis (Std) (kJ/kgmole) 2.865e+006 0.0000 2.604e+005
41 HHV Mass Basis (Std) (kJ/kg) 4.929e+004 0.0000 8264
42 CO2 Loading --- --- ---
43 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
44 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
45 LHV Mass Basis (Std) (kJ/kg) 4.576e+004 0.0000 7673
46 Phase Fraction [Vol. Basis] 1.000 1.000 1.000
49 Mass Exergy (kJ/kg) 30.13 70.23 62.52
50 Partial Pressure of CO2 (kPa) 0.0000 0.0000 0.0000
52 Act. Gas Flow (ACT_m3/h) 711.4 8866 9308
55 Std. Gas Flow (STD_m3/h) 1330 1.330e+004 1.463e+004
57 Act. Liq. Flow (m3/s) --- --- ---
58 Z Factor 0.9541 1.000 0.9989
59 Watson K 13.50 6.042 7.138
61 Partial Pressure of H2S (kPa) 0.0000 0.0000 0.0000
62 Cp/(Cp - R) 1.085 1.388 1.284
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name 1 5 6
12 Cp/Cv 1.101 1.391 1.288
13 Ideal Gas Cp/Cv 1.086 1.389 1.285
16 Heat of Vap. (kJ/kgmole) 2.118e+004 5724 1.626e+004
18 Liq. Mass Density (Std. Cond) (kg/m3) 584.5 --- ---
19 Liq. Vol. Flow (Std. Cond) (m3/h) 5.592 --- ---
20 Liquid Fraction 0.0000 0.0000 0.0000
22 Mass Heat of Vap. (kJ/kg) 364.5 198.4 515.9
26 Bubble Point Pressure (kPa) 496.7 --- ---
27 Viscosity (cP) 7.925e-003 2.267e-002 2.090e-002
30 Cv (kJ/kgmole-C) 96.62 21.38 29.17
31 Mass Cv (kJ/kg-C) 1.662 0.7412 0.9255
34 Cp/Cv (Ent. Method) --- --- ---
35 Reid VP at 37.8 C (kPa) 356.5 --- ---
36 True VP at 37.8 C (kPa) 356.5 --- ---
38 Viscosity Index -34.87 --- ---
39
40
DYNAMICS
41 Pressure Specification: Set Outlet to Lowest Inlet
42
43
Holdup Details
46 Vapour 0.0000 0.0000 0.0000
47 Liquid 0.0000 0.0000 0.0000
48 Aqueous 0.0000 0.0000 0.0000
49 Total 0.0000 0.0000 0.0000
50
51
NOTES
52
53
54 Mixer: MIX-101
55
56
57
CONNECTIONS
58
59
Inlet Stream
61 15
62 16 Recycle RCY-1
1
4 USA
5
6
8
9
10
CONNECTIONS
11
12
Outlet Stream
14 10 Absorber T-100
15
16
PARAMETERS
17
18
User Variables
19
20
NOZZLE PARAMETERS
22 15 16 10
23 Diameter (m) 5.000e-002 5.000e-002 5.000e-002
24 Elevation (Base) (m) 0.0000 0.0000 0.0000
26
27
CONDITIONS
28 Name 15 16 10
29 Vapour 0.0000 0.0000 0.0000
30 Temperature (C) 71.0000 * 21.5586 * 60.6191
31 Pressure (kPa) 202.6500 * 101.3250 * 101.3250
32 Molar Flow (kgmole/h) 35.7032 9.2968 * 45.0000 *
33 Mass Flow (kg/h) 643.1976 174.7359 817.9335
35 Molar Enthalpy (kJ/kgmole) -2.814e+005 -2.825e+005 -2.816e+005
37 Heat Flow (kJ/h) -1.0047e+07 -2.6263e+06 -1.2673e+07
38
39
PROPERTIES
40 Name 15 16 10
42 Molar Density (kgmole/m3) 53.94 52.31 53.59
43 Mass Density (kg/m3) 971.7 983.2 974.1
45 Mass Enthalpy (kJ/kg) -1.562e+004 -1.503e+004 -1.549e+004
49 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 5.165e+004 1.067e+004
51 HHV Mass Basis (Std) (kJ/kg) 2276 5099 2879
52 CO2 Loading --- --- ---
53 CO2 Apparent Mole Conc. (kgmole/m3) 0.0000 2.408e-003 5.096e-004
54 CO2 Apparent Wt. Conc. (kgmol/kg) 0.0000 2.449e-006 5.231e-007
55 LHV Mass Basis (Std) (kJ/kg) 0.0000 2748 587.1
59 Mass Exergy (kJ/kg) -204.7 26.64 -239.4
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name 15 16 10
14 Std. Gas Flow (STD_m3/h) 844.2 219.8 1064
16 Act. Liq. Flow (m3/s) 1.839e-004 4.937e-005 2.332e-004
17 Z Factor 1.313e-003 7.905e-004 6.813e-004
18 Watson K --- 13.48 13.48
21 Cp/(Cp - R) 1.123 1.121 1.123
22 Cp/Cv 1.175 1.154 1.171
23 Ideal Gas Cp/Cv 1.325 1.314 1.323
26 Heat of Vap. (kJ/kgmole) 3.894e+004 4.524e+004 4.066e+004
28 Liq. Mass Density (Std. Cond) (kg/m3) 1015 988.2 1009
30 Liquid Fraction 1.000 1.000 1.000
31 Molar Volume (m3/kgmole) 1.854e-002 1.912e-002 1.866e-002
32 Mass Heat of Vap. (kJ/kg) 2162 2407 2237
34 Surface Tension (dyne/cm) 63.98 71.52 65.62
35 Thermal Conductivity (W/m-K) 0.6631 0.5902 0.6503
36 Bubble Point Pressure (kPa) 32.56 95.98 51.61
37 Viscosity (cP) 0.3950 0.9112 0.4867
40 Cv (kJ/kgmole-C) 64.39 66.71 65.06
41 Mass Cv (kJ/kg-C) 3.574 3.549 3.579
44 Cp/Cv (Ent. Method) --- --- ---
45 Reid VP at 37.8 C (kPa) --- 369.7 369.7
46 True VP at 37.8 C (kPa) --- 122.6 30.80
48 Viscosity Index -13.34 2.185 -8.487
49
50
DYNAMICS
51 Pressure Specification: Set Outlet to Lowest Inlet
52
53
Holdup Details
56 Vapour 0.0000 0.0000 0.0000
57 Liquid 0.0000 0.0000 0.0000
58 Aqueous 0.0000 0.0000 0.0000
59 Total 0.0000 0.0000 0.0000
60
61
NOTES
62
1
4 USA
5
6
7 Plug Flow Reactor: PFR-100
8
9
CONNECTIONS
10
11
Inlet Stream
12
14 7 Heater E-100
15
Outlet Stream
16
18 8 Cooler E-101
19
Energy Stream
20
22 QPFR100
23
PARAMETERS
24
25
Physical Parameters
26
27 Type : Ergun Equation Pressure Drop: 3.336 kPa
28
Heat Transfer
29
30 Type : Direct Q Value Energy Stream : QPFR100 Duty : 3.376e+007 kJ/h
31
Dimensions
32
33 Total Volume: 170.1 m3 Length: 15.00 m * Diameter: 3.800 m * Number of Tubes: 1*
34 Wall Thickness: 5.000e-003 m * Void Fraction: 0.8000 * Void Volume: 136.1 m3
35
Reaction Info
36
37 Reaction Set: Set-1 Initialize From: Current
38
Integration Information
39
40 Number of Segments: 20 * Minimum Step Fraction: 1.0e-06 * Minimum Step Length: 1.5e-05 m
41
Catalyst Data
42
43 Particle Diameter: 1.000e-003 m * Particle Spericity: 1.0000 * Solid Density: 2500 kg/m3 *
44 Bulk Density: 500.0 kg/m3 Solid Heat Capacity: 250.0 kJ/kg-C *
45
User Variables
46
47
RATING
48
49
Sizing
50
51 Tube Dimensions
52 Total Volume 170.1 m3 Length 15.00 m * Diameter 3.800 m * Number of Tubes 1* Wall Thickness 5.000e-003 m *
53 Tube Packing
54 Void Fraction 0.8000 * Void Volume 136.1 m3
55
Nozzle Parameters
56
57 Base Elevation Relative to Ground Level 0.0000 m Diameter 3.800 m * Length 15.00 *
58 8 7
59 Diameter (m) 5.000e-002 5.000e-002
60 Elevation (Base) (m) 0.0000 0.0000
61 Elevation (Ground) (m) 0.0000 0.0000
62
1
4 USA
5
6
7 Plug Flow Reactor: PFR-100 (continued)
8
9
Conditions
10
11 Length Temperature Pressure Vapour Fraction Duty
12 (m) (C) (kPa) (kJ/h)
13 0.375 162.5 202.53 1.0000 -303254
14 1.125 175.0 202.41 1.0000 -305336
15 1.875 187.5 202.28 1.0000 -306824
16 2.625 200.0 202.15 1.0000 -307061
17 3.375 212.5 202.01 1.0000 -304823
18 4.125 225.0 201.87 1.0000 -297824
19 4.875 237.4 201.72 1.0000 -281942
20 5.625 249.9 201.57 1.0000 -249977
21 6.375 262.4 201.41 1.0000 -189762
22 7.125 274.9 201.25 1.0000 -81727
23 7.875 287.4 201.08 1.0000 105693
24 8.625 299.9 200.91 1.0000 418281
25 9.375 312.4 200.73 1.0000 918378
26 10.125 324.9 200.54 1.0000 1678149
27 10.875 337.4 200.35 1.0000 2754883
28 11.625 349.9 200.16 1.0000 4137251
29 12.375 362.4 199.96 1.0000 5666264
30 13.125 374.9 199.75 1.0000 6967493
31 13.875 387.4 199.54 1.0000 7441054
32 14.625 399.9 199.31 1.0000 6299310
33 Length Enthalpy Entropy Inside HTC Overall HTC
34 (m) (kJ/kgmole) (kJ/kgmole-C) (kJ/h-m2-C) (kJ/h-m2-C)
35 0.375 -6340 160.44 --- ---
36 1.125 -5846 161.57 --- ---
37 1.875 -5350 162.67 --- ---
38 2.625 -4854 163.75 --- ---
39 3.375 -4361 164.82 --- ---
40 4.125 -3879 165.87 --- ---
41 4.875 -3424 166.91 --- ---
42 5.625 -3019 167.93 --- ---
43 6.375 -2712 168.95 --- ---
44 7.125 -2579 169.97 --- ---
45 7.875 -2749 171.00 --- ---
46 8.625 -3422 172.05 --- ---
47 9.375 -4896 173.13 --- ---
48 10.125 -7581 174.26 --- ---
49 10.875 -11960 175.47 --- ---
50 11.625 -18467 176.78 --- ---
51 12.375 -27237 178.22 --- ---
52 13.125 -37784 179.76 --- ---
53 13.875 -48742 181.33 --- ---
54 14.625 -57740 182.77 --- ---
55
Flows
56
57 Length Molar Flow Mass Flow Volumetric Flow Heat Flow
58 (m) (kgmole/h) (kg/h) (m3/h) (kJ/h)
59 0.375 618.629 19493.94 11061.275 -3.922e+006
60 1.125 618.630 19493.94 11386.535 -3.617e+006
61 1.875 618.631 19493.94 11712.403 -3.310e+006
62 2.625 618.633 19493.95 12038.927 -3.003e+006
1
4 USA
5
6
8
9
Flows
10
11 Length Molar Flow Mass Flow Volumetric Flow Heat Flow
12 (m) (kgmole/h) (kg/h) (m3/h) (kJ/h)
13 3.375 618.638 19493.95 12366.173 -2.698e+006
14 4.125 618.649 19493.96 12694.235 -2.400e+006
15 4.875 618.670 19493.97 13023.273 -2.118e+006
16 5.625 618.714 19493.99 13353.558 -1.868e+006
17 6.375 618.798 19494.02 13685.572 -1.678e+006
18 7.125 618.954 19494.01 14020.144 -1.597e+006
19 7.875 619.244 19494.01 14358.785 -1.702e+006
20 8.625 619.764 19494.01 14704.061 -2.121e+006
21 9.375 620.675 19494.00 15060.234 -3.039e+006
22 10.125 622.222 19494.00 15434.011 -4.717e+006
23 10.875 624.746 19493.98 15835.074 -7.472e+006
24 11.625 628.650 19493.97 16275.465 -1.161e+007
25 12.375 634.269 19493.94 16766.378 -1.728e+007
26 13.125 641.616 19493.94 17311.180 -2.424e+007
27 13.875 650.034 19493.92 17894.892 -3.168e+007
28 14.625 657.830 19493.90 18472.127 -3.798e+007
29
Segment Overall Reaction Rates (kgmole/m3-s)
30
31 Length (m) Rxn-1 Rxn-2 Rxn-3
32 0.3750 9.307e-009 7.627e-010 3.399e-013
33 1.125 2.236e-008 2.105e-009 2.472e-012
34 1.875 5.122e-008 5.495e-009 1.306e-011
35 2.625 1.123e-007 1.364e-008 5.976e-011
36 3.375 2.363e-007 3.229e-008 2.483e-010
37 4.125 4.791e-007 7.321e-008 9.542e-010
38 4.875 9.375e-007 1.593e-007 3.423e-009
39 5.625 1.775e-006 3.338e-007 1.153e-008
40 6.375 3.256e-006 6.744e-007 3.663e-008
41 7.125 5.791e-006 1.315e-006 1.099e-007
42 7.875 9.985e-006 2.476e-006 3.115e-007
43 8.625 1.666e-005 4.495e-006 8.341e-007
44 9.375 2.680e-005 7.838e-006 2.100e-006
45 10.13 4.131e-005 1.305e-005 4.939e-006
46 10.88 6.040e-005 2.055e-005 1.073e-005
47 11.63 8.268e-005 3.020e-005 2.125e-005
48 12.38 1.042e-004 4.074e-005 3.771e-005
49 13.13 1.182e-004 4.935e-005 5.873e-005
50 13.88 1.163e-004 5.175e-005 7.806e-005
51 14.63 9.016e-005 4.263e-005 8.329e-005
52
Component Production Rates (kgmole/m3-s)
53
54 Length (m) n-Butane Oxygen Nitrogen MaleicAnhydr
55 0.3750 -1.007e-008 -3.677e-008 0.0000 9.307e-009
56 1.125 -2.446e-008 -8.984e-008 0.0000 2.236e-008
57 1.875 -5.671e-008 -2.095e-007 0.0000 5.120e-008
58 2.625 -1.259e-007 -4.681e-007 0.0000 1.122e-007
59 3.375 -2.686e-007 -1.005e-006 0.0000 2.361e-007
60 4.125 -5.523e-007 -2.081e-006 0.0000 4.781e-007
61 4.875 -1.097e-006 -4.165e-006 0.0000 9.341e-007
62 5.625 -2.109e-006 -8.072e-006 0.0000 1.763e-006
1
4 USA
5
6
8
9
Component Production Rates (kgmole/m3-s)
10
12 6.375 -3.930e-006 -1.518e-005 0.0000 3.219e-006
13 7.125 -7.106e-006 -2.772e-005 0.0000 5.681e-006
14 7.875 -1.246e-005 -4.919e-005 0.0000 9.673e-006
15 8.625 -2.115e-005 -8.470e-005 0.0000 1.583e-005
16 9.375 -3.464e-005 -1.411e-004 0.0000 2.470e-005
17 10.13 -5.436e-005 -2.262e-004 0.0000 3.637e-005
18 10.88 -8.095e-005 -3.459e-004 0.0000 4.967e-005
19 11.63 -1.129e-004 -4.980e-004 0.0000 6.143e-005
20 12.38 -1.449e-004 -6.641e-004 0.0000 6.647e-005
21 13.13 -1.675e-004 -8.024e-004 0.0000 5.942e-005
22 13.88 -1.681e-004 -8.478e-004 0.0000 3.824e-005
23 14.63 -1.328e-004 -7.166e-004 0.0000 6.875e-006
24 Length (m) CO2 CO Acetone H2O
25 0.3750 1.526e-009 1.526e-009 0.0000 4.104e-008
26 1.125 4.214e-009 4.214e-009 0.0000 9.996e-008
27 1.875 1.102e-008 1.102e-008 0.0000 2.324e-007
28 2.625 2.740e-008 2.740e-008 0.0000 5.174e-007
29 3.375 6.509e-008 6.509e-008 0.0000 1.107e-006
30 4.125 1.483e-007 1.483e-007 0.0000 2.283e-006
31 4.875 3.255e-007 3.255e-007 0.0000 4.550e-006
32 5.625 6.907e-007 6.907e-007 0.0000 8.781e-006
33 6.375 1.422e-006 1.422e-006 0.0000 1.643e-005
34 7.125 2.850e-006 2.850e-006 0.0000 2.985e-005
35 7.875 5.576e-006 5.576e-006 0.0000 5.263e-005
36 8.625 1.066e-005 1.066e-005 0.0000 8.995e-005
37 9.375 1.988e-005 1.988e-005 0.0000 1.485e-004
38 10.13 3.598e-005 3.598e-005 0.0000 2.354e-004
39 10.88 6.256e-005 6.256e-005 0.0000 3.551e-004
40 11.63 1.029e-004 1.029e-004 0.0000 5.030e-004
41 12.38 1.569e-004 1.569e-004 0.0000 6.581e-004
42 13.13 2.162e-004 2.162e-004 0.0000 7.781e-004
43 13.88 2.596e-004 2.596e-004 0.0000 8.020e-004
44 14.63 2.518e-004 2.518e-004 0.0000 6.571e-004
45
Transport
46
47 Length Viscosity Moleular Weight Mass Density Heat Capacity Surface Tension Z Factor
48 (m) (cP) (kg/m3) (kJ/kgmole-C) (dyne/cm)
49 0.3750 2.371e-002 31.51 1.762 39.447 --- 0.9998
50 1.125 2.419e-002 31.51 1.712 39.777 --- 0.9999
51 1.875 2.467e-002 31.51 1.664 40.103 --- 1.000
52 2.625 2.515e-002 31.51 1.619 40.425 --- 1.000
53 3.375 2.561e-002 31.51 1.576 40.743 --- 1.000
54 4.125 2.607e-002 31.51 1.536 41.058 --- 1.000
55 4.875 2.653e-002 31.51 1.497 41.368 --- 1.000
56 5.625 2.698e-002 31.51 1.460 41.674 --- 1.000
57 6.375 2.743e-002 31.50 1.424 41.976 --- 1.000
58 7.125 2.786e-002 31.50 1.390 42.271 --- 1.000
59 7.875 2.827e-002 31.48 1.358 42.558 --- 1.000
60 8.625 2.866e-002 31.45 1.326 42.832 --- 1.000
61 9.375 2.901e-002 31.41 1.294 43.082 --- 1.000
62 10.13 2.930e-002 31.33 1.263 43.292 --- 1.000
1
4 USA
5
6
8
9
Transport
10
11 Length Viscosity Moleular Weight Mass Density Heat Capacity Surface Tension Z Factor
12 (m) (cP) (kg/m3) (kJ/kgmole-C) (dyne/cm)
13 10.88 2.952e-002 31.20 1.231 43.437 --- 1.000
14 11.63 2.964e-002 31.01 1.198 43.479 --- 1.000
15 12.38 2.967e-002 30.73 1.163 43.383 --- 1.000
16 13.13 2.964e-002 30.38 1.126 43.136 --- 1.000
17 13.88 2.961e-002 29.99 1.089 42.773 --- 1.000
18 14.63 2.967e-002 29.63 1.055 42.414 --- 1.000
19
Component Molar Flowrates (kgmole/h)
20
22 0.3750 56.2388 118.1010 444.2881 0.0002
23 1.125 56.2382 118.0988 444.2881 0.0008
24 1.875 56.2368 118.0937 444.2881 0.0021
25 2.625 56.2337 118.0822 444.2881 0.0048
26 3.375 56.2271 118.0576 444.2881 0.0106
27 4.125 56.2136 118.0066 444.2881 0.0224
28 4.875 56.1867 117.9046 444.2881 0.0453
29 5.625 56.1350 117.7068 444.2881 0.0886
30 6.375 56.0388 117.3350 444.2881 0.1675
31 7.125 55.8647 116.6559 444.2881 0.3067
32 7.875 55.5594 115.4509 444.2881 0.5436
33 8.625 55.0412 113.3760 444.2881 0.9313
34 9.375 54.1926 109.9191 444.2881 1.5364
35 10.13 52.8611 104.3774 444.2881 2.4273
36 10.88 50.8781 95.9045 444.2881 3.6439
37 11.63 48.1128 83.7047 444.2881 5.1487
38 12.38 44.5628 67.4361 444.2881 6.7769
39 13.13 40.4596 47.7801 444.2881 8.2326
40 13.88 36.3428 27.0116 444.2881 9.1695
41 14.63 33.0897 9.4564 444.2881 9.3379
43 0.3750 0.0000 0.0000 0.0000 0.0010
44 1.125 0.0001 0.0001 0.0000 0.0035
45 1.875 0.0004 0.0004 0.0000 0.0093
46 2.625 0.0011 0.0011 0.0000 0.0220
47 3.375 0.0027 0.0027 0.0000 0.0492
48 4.125 0.0064 0.0064 0.0000 0.1053
49 4.875 0.0144 0.0144 0.0000 0.2171
50 5.625 0.0314 0.0314 0.0000 0.4326
51 6.375 0.0663 0.0663 0.0000 0.8356
52 7.125 0.1361 0.1361 0.0000 1.5669
53 7.875 0.2727 0.2727 0.0000 2.8562
54 8.625 0.5338 0.5338 0.0000 5.0597
55 9.375 1.0207 1.0207 0.0000 8.6974
56 10.13 1.9021 1.9021 0.0000 14.4642
57 10.88 3.4347 3.4347 0.0000 23.1623
58 11.63 5.9558 5.9558 0.0000 35.4841
59 12.38 9.7994 9.7994 0.0000 51.6060
60 13.13 15.0946 15.0946 0.0000 70.6665
61 13.88 21.4545 21.4545 0.0000 90.3134
62 14.63 27.6239 27.6239 0.0000 106.4105
1
4 USA
5
6
8
9
Component Mole Fractions
10
12 0.3750 0.0909 0.1909 0.7182 0.0000
13 1.125 0.0909 0.1909 0.7182 0.0000
14 1.875 0.0909 0.1909 0.7182 0.0000
15 2.625 0.0909 0.1909 0.7182 0.0000
16 3.375 0.0909 0.1908 0.7182 0.0000
17 4.125 0.0909 0.1907 0.7182 0.0000
18 4.875 0.0908 0.1906 0.7181 0.0001
19 5.625 0.0907 0.1902 0.7181 0.0001
20 6.375 0.0906 0.1896 0.7180 0.0003
21 7.125 0.0903 0.1885 0.7178 0.0005
22 7.875 0.0897 0.1864 0.7175 0.0009
23 8.625 0.0888 0.1829 0.7169 0.0015
24 9.375 0.0873 0.1771 0.7158 0.0025
25 10.13 0.0850 0.1677 0.7140 0.0039
26 10.88 0.0814 0.1535 0.7111 0.0058
27 11.63 0.0765 0.1331 0.7067 0.0082
28 12.38 0.0703 0.1063 0.7005 0.0107
29 13.13 0.0631 0.0745 0.6925 0.0128
30 13.88 0.0559 0.0416 0.6835 0.0141
31 14.63 0.0503 0.0144 0.6754 0.0142
33 0.3750 0.0000 0.0000 0.0000 0.0000
34 1.125 0.0000 0.0000 0.0000 0.0000
35 1.875 0.0000 0.0000 0.0000 0.0000
36 2.625 0.0000 0.0000 0.0000 0.0000
37 3.375 0.0000 0.0000 0.0000 0.0001
38 4.125 0.0000 0.0000 0.0000 0.0002
39 4.875 0.0000 0.0000 0.0000 0.0004
40 5.625 0.0001 0.0001 0.0000 0.0007
41 6.375 0.0001 0.0001 0.0000 0.0014
42 7.125 0.0002 0.0002 0.0000 0.0025
43 7.875 0.0004 0.0004 0.0000 0.0046
44 8.625 0.0009 0.0009 0.0000 0.0082
45 9.375 0.0016 0.0016 0.0000 0.0140
46 10.13 0.0031 0.0031 0.0000 0.0232
47 10.88 0.0055 0.0055 0.0000 0.0371
48 11.63 0.0095 0.0095 0.0000 0.0564
49 12.38 0.0154 0.0154 0.0000 0.0814
50 13.13 0.0235 0.0235 0.0000 0.1101
51 13.88 0.0330 0.0330 0.0000 0.1389
52 14.63 0.0420 0.0420 0.0000 0.1618
53
PROPERTIES
54
55 Name 7 8
60 Mass Enthalpy (kJ/kg) -216.7 -1948
1
4 USA
5
6
8
9
PROPERTIES
10
11 Name 7 8
31 Act. Liq. Flow (m3/s) --- ---
32 Z Factor 0.9997 ---
33 Watson K 7.138 7.251
36 Cp/(Cp - R) 1.270 1.244
37 Cp/Cv 1.273 1.245
52 Viscosity (cP) 2.322e-002 2.967e-002
55 Cv (kJ/kgmole-C) 30.74 34.07
56 Mass Cv (kJ/kg-C) 0.9754 1.150
60 Reid VP at 37.8 C (kPa) --- ---
61 True VP at 37.8 C (kPa) --- ---
1
4 USA
5
6
8
9
PROPERTIES
10
11 Name 7 8
13
DYNAMICS
14
15
Vessel Parameters: Initialize from Product
16
17 Single Phase: Not Activated Lag Rxn Temperature: Not Activated
18 Laminar Flow Activated Fixed Delta P Not Activated
19 Flow Equation Activated PFR Elevation (m) 0 *
20
Pressure Flow Relation Segmented Holdup Details
21
22 Segment Pressure-Flow K (kg/hr/sqrt(kPa-kg/m3)) View Holdup
23 1.000 * --- PFR-100:Seg-1 Holdup
24 2.000 * --- PFR-100:Seg-2 Holdup
25 3.000 * --- PFR-100:Seg-3 Holdup
26 4.000 * --- PFR-100:Seg-4 Holdup
27 5.000 * --- PFR-100:Seg-5 Holdup
28 6.000 * --- PFR-100:Seg-6 Holdup
29 7.000 * --- PFR-100:Seg-7 Holdup
30 8.000 * --- PFR-100:Seg-8 Holdup
31 9.000 * --- PFR-100:Seg-9 Holdup
32 10.00 * --- PFR-100:Seg-10 Holdup
33 11.00 * --- PFR-100:Seg-11 Holdup
34 12.00 * --- PFR-100:Seg-12 Holdup
35 13.00 * --- PFR-100:Seg-13 Holdup
36 14.00 * --- PFR-100:Seg-14 Holdup
37 15.00 * --- PFR-100:Seg-15 Holdup
38 16.00 * --- PFR-100:Seg-16 Holdup
39 17.00 * --- PFR-100:Seg-17 Holdup
40 18.00 * --- PFR-100:Seg-18 Holdup
41 19.00 * --- PFR-100:Seg-19 Holdup
42 20.00 * --- PFR-100:Seg-20 Holdup
43
Overall Holdup Details
44
47 Vapour 0.0000 0.0000 0.0000
48 Liquid 0.0000 0.0000 0.0000
49 Aqueous 0.0000 0.0000 0.0000
50 Total 0.0000 0.0000 0.0000
51
Direct Q
52
53 SP (kJ/h) 3.376e+007 Max. Available (kJ/h) ---
54 Min. Available (kJ/h) 0.0000
55
Heat Flow into the PFR: Cooling
56
57
NOTES
58
59
60
61
62
1
4 USA
5
6
7
8
Feeder Block: ProductBlock_12
10
11
12
14
15
16
18
19 Energy Stream: QCT101 Property Package: NRTL - PR
20
21
22
CONDITIONS
23 Duty Type: Direct Q Duty Calculation Operation: Condenser @COL2
24 Duty SP: 1.269e+006 kJ/h Minimum Available Duty: --- Maximum Available Duty: ---
25
26
COMPOSITION
27 ( Not a material stream - No compositions exist )
28
29
UNIT OPERATIONS
32
33
UTILITIES
35
36
PROCESS UTILITY
37
38
39
DYNAMICS
40 Pressure Specification (Inactive): ---
41 Flow Specification (Inactive) Molar: --- Mass: --- Std Ideal Liq Volume: ---
42
43
User Variables
44
45
NOTES
46
47
48
Description
49
50
51 Energy Stream: QE100 Property Package: NRTL - PR
52
53
54
CONDITIONS
55 Duty Type: Direct Q Duty Calculation Operation: E-100
56 Duty SP: 1.329e+006 kJ/h Minimum Available Duty: 0.0000 kJ/h Maximum Available Duty: ---
57
58
COMPOSITION
60
61
62
1
4 USA
5
6
7 Energy Stream: QE100 (continued) Property Package: NRTL - PR
8
9
10
UNIT OPERATIONS
12 Heater: E-100
13
14
UTILITIES
16
17
PROCESS UTILITY
18
19
20
DYNAMICS
23
24
User Variables
25
26
NOTES
27
28
29
Description
30
31
32 Energy Stream: QE101 Property Package: NRTL - PR
33
34
35
CONDITIONS
36 Duty Type: Direct Q Duty Calculation Operation: E-101
38
39
COMPOSITION
41
42
UNIT OPERATIONS
44 Cooler: E-101
45
46
UTILITIES
48
49
PROCESS UTILITY
50
51
52
DYNAMICS
55
56
User Variables
57
58
NOTES
59
60
61
Description
62
1
4 USA
5
6
7 Energy Stream: QHT101 Property Package: NRTL - PR
8
9
10
CONDITIONS
11 Duty Type: Direct Q Duty Calculation Operation: Reboiler @COL2
13
14
COMPOSITION
16
17
UNIT OPERATIONS
20
21
UTILITIES
23
24
PROCESS UTILITY
25
26
27
DYNAMICS
30
31
User Variables
32
33
NOTES
34
35
36
Description
37
38
39 Energy Stream: QK100 Property Package: NRTL - PR
40
41
42
CONDITIONS
43 Duty Type: Direct Q Duty Calculation Operation: K-100
45
46
COMPOSITION
48
49
UNIT OPERATIONS
51 Compressor: K-100
52
53
UTILITIES
55
56
PROCESS UTILITY
57
58
59
DYNAMICS
62
1
4 USA
5
6
7 Energy Stream: QK100 (continued) Property Package: NRTL - PR
8
9
10
User Variables
11
12
NOTES
13
14
15
Description
16
17
18 Energy Stream: QPFR100 Property Package: NRTL - PR
19
20
21
CONDITIONS
22 Duty Type: Direct Q Duty Calculation Operation: PFR-100
24
25
COMPOSITION
27
28
UNIT OPERATIONS
30 Plug Flow Reactor: PFR-100
31
32
UTILITIES
34
35
PROCESS UTILITY
36
37
38
DYNAMICS
41
42
User Variables
43
44
NOTES
45
46
47
Description
48
49
50 Recycle: RCY-1
51
52
53
CONNECTIONS
54
55
Inlet Stream
56 Stream Name From Unit Operation
57 13 Distillation T-101
58
59
Outlet Stream
60 Stream Name To Unit Operation
61 16 Mixer MIX-101
62
1
4 USA
5
6
7 Recycle: RCY-1 (continued)
8
9
10
TOLERANCE
11 Vapour Fraction: 10.00 * Temperature: 10.00 * Pressure: 10.00 *
12 Flow: 10.00 * Enthalpy: 10.00 * Composition: 10.00 *
13
14
NUMERICAL
15 Acceleration Type: Wegstein Iteration Type: Nested
16 Maximum Iterations: 10 * Iteration Count: 1
17 Wegstein Count: 3* Q Minimum: -20.00 * Q Maximum: 0.0000 *
18
19
Iteration History
20 Iteration Variable Outlet Value Inlet Value
21 1 * Converged --- ---
22
23
User Variables
24
25
CONDITIONS
26 Name 13 16
27 Vapour 0.0000 0.0000
28 Temperature (C) 21.5330 21.5586 *
29 Pressure (kPa) 101.3250 101.3250 *
30 Molar Flow (kgmole/h) 9.2986 9.2968 *
31 Mass Flow (kg/h) 174.7698 174.7359
35 Heat Flow (kJ/h) -2.6269e+06 -2.6263e+06
36
37
PROPERTIES
38 Name 13 16
51 CO2 Apparent Mole Conc. (kgmole/m3) 2.408e-003 2.408e-003
52 CO2 Apparent Wt. Conc. (kgmol/kg) 2.449e-006 2.449e-006
1
4 USA
5
6
7 Recycle: RCY-1 (continued)
8
9
10
PROPERTIES
11 Name 13 16
14 Act. Liq. Flow (m3/s) 4.937e-005 4.937e-005
15 Z Factor 7.905e-004 7.905e-004
16 Watson K 13.48 13.48
19 Cp/(Cp - R) 1.121 1.121
20 Cp/Cv 1.154 1.154
30 Mass Heat of Vap. (kJ/kg) 2407 2407
34 Bubble Point Pressure (kPa) 95.94 95.98
35 Viscosity (cP) 0.9117 0.9112
38 Cv (kJ/kgmole-C) 66.71 66.71
39 Mass Cv (kJ/kg-C) 3.550 3.549
43 Reid VP at 37.8 C (kPa) 369.7 369.7
44 True VP at 37.8 C (kPa) 122.6 122.6
46 Viscosity Index 2.192 2.185
47
Heterogeneous Catalytic: Rxn-1

48
49
50
51
STOICHIOMETRY
52 Component Molecular Weight Stoich Coeff Forward Order Reverse Order
53 n-Butane 58.12 -1 * 1.000 0.0000
54 Oxygen 32.00 -4 * 0.5000 * 0.0000
55 MaleicAnhydr 98.06 1* 0.0000 1.000
56 H2O 18.02 4* 0.0000 4.000
57
58 Balance Error : 0.0000 Reaction Heat (25 C) : -1.239e+006 kJ/kgmole
59
60
61
62
1
4 USA
5
6
Heterogeneous Catalytic: Rxn-1 (continued)

7
8
9
10
BASIS
11 Min. Temp Max. Temp
Basis Base Component Rxn Phase
12 (C) (C)
13 Partial Pres n-Butane VapourPhase -273.1 3000
14
15
PARAMETERS
16 Forward Reaction Reverse Reaction
17 A: 3840 * A' : ---
18 E: 1.140e+005 * E' : ---
19

20
21
22
23
STOICHIOMETRY
25 n-Butane 58.12 -1 * 1.000 0.0000
26 Oxygen 32.00 -6 * 0.5000 * 0.0000
27 CO2 44.01 2* 0.0000 2.000
28 CO 28.01 2* 0.0000 2.000
29 H2O 18.02 5* 0.0000 5.000
30
32
33
BASIS
35 (C) (C)
36 Partial Pres n-Butane VapourPhase -273.1 3000
37
38
PARAMETERS
40 A: 4.530e+004 * A' : ---
41 E: 1.320e+005 * E' : ---
42

43
44
45
46
STOICHIOMETRY
48 MaleicAnhydr 98.06 -1 * 1.000 0.0000
49 Oxygen 32.00 -2 * 0.2500 * 0.0000
50 CO2 44.01 2* 0.0000 2.000
51 CO 28.01 2* 0.0000 2.000
52 H2O 18.02 1* 0.0000 1.000
53
55
56
BASIS
58 (C) (C)
59 Partial Pres MaleicAnhydr VapourPhase -273.1 3000
60
61
62
1
4 USA
5
6
Heterogeneous Catalytic: Rxn-3 (continued)

7
8
9
10
PARAMETERS
12 A: 780.0 * A' : ---
13 E: 9.700e+004 * E' : ---
14
15 Set: SET-1
16
17
18
Target
19 OBJECT VARIABLE
20 2 Molar Flow
21
22
Source
23 OBJECT VARIABLE
24 1 Molar Flow
25
26
Equation Parameters
27 MULTIPLIER OFFSET
28 10.00 * 0.0000 kgmole/h
29
30
User Variables
31
32
NOTES
33
34
35 Absorber: T-100
36
37
CONNECTIONS
38
39 Inlet Stream
40 STREAM NAME Stage FROM UNIT OPERATION
41 10 1__Main Tower Mixer MIX-101
42 9 10__Main Tower Cooler E-101
43 Outlet Stream
44 STREAM NAME Stage TO UNIT OPERATION
45 12 1__Main Tower
46 11 10__Main Tower Distillation T-101
47
MONITOR
48
49 Specifications Summary
50 Specified Value Current Value Wt. Error
51
52 Wt. Tol. Abs. Tol. Active Estimate Used
53
54
SPECS
55
56 Column Specification Parameters
57
58
59 Fix/Rang: Prim/Alter: Lower Bnd: Upper Bnd:
60
SUBCOOLING
61
62
1
4 USA
5
6
7 Absorber: T-100 (continued)
8
9
SUBCOOLING
10
11 Degrees of Subcooling
12 Subcool to
13
User Variables
14
15
PROFILES
16
17 General Parameters
18 Sub-Flow Sheet: T-100 (COL1) Number of Stages: 10 *
19 Profile Estimates
20 Temperature Net Liquid Net Vapour
21 (C) (kgmole/h) (kgmole/h)
22 1__Main Tower 77.12 46.52 684.2
23 2__Main Tower 77.26 46.54 685.7
24 3__Main Tower 77.26 46.54 685.7
25 4__Main Tower 77.26 46.54 685.7
26 5__Main Tower 77.26 46.53 685.7
27 6__Main Tower 77.26 46.52 685.7
28 7__Main Tower 77.28 46.37 685.7
29 8__Main Tower 77.52 44.78 685.6
30 9__Main Tower 79.95 35.94 684.0
31 10__Main Tower 92.95 18.65 675.1
32
EFFICIENCIES
33
34 Stage Efficiencies
35 Stages Overall n-Butane Oxygen Nitrogen MaleicAnhydr
36 1__Main Tower 1.000 1.000 1.000 1.000 1.000
37 2__Main Tower 1.000 1.000 1.000 1.000 1.000
38 3__Main Tower 1.000 1.000 1.000 1.000 1.000
39 4__Main Tower 1.000 1.000 1.000 1.000 1.000
40 5__Main Tower 1.000 1.000 1.000 1.000 1.000
41 6__Main Tower 1.000 1.000 1.000 1.000 1.000
42 7__Main Tower 1.000 1.000 1.000 1.000 1.000
43 8__Main Tower 1.000 1.000 1.000 1.000 1.000
44 9__Main Tower 1.000 1.000 1.000 1.000 1.000
45 10__Main Tower 1.000 1.000 1.000 1.000 1.000
46 Stages Overall CO2 CO Acetone H2O
47 1__Main Tower 1.000 1.000 1.000 1.000 1.000
48 2__Main Tower 1.000 1.000 1.000 1.000 1.000
49 3__Main Tower 1.000 1.000 1.000 1.000 1.000
50 4__Main Tower 1.000 1.000 1.000 1.000 1.000
51 5__Main Tower 1.000 1.000 1.000 1.000 1.000
52 6__Main Tower 1.000 1.000 1.000 1.000 1.000
53 7__Main Tower 1.000 1.000 1.000 1.000 1.000
54 8__Main Tower 1.000 1.000 1.000 1.000 1.000
55 9__Main Tower 1.000 1.000 1.000 1.000 1.000
56 10__Main Tower 1.000 1.000 1.000 1.000 1.000
57
SOLVER
58
59 Column Solving Algorithm: HYSIM Inside-Out
60 Solving Options Acceleration Parameters
61 Maximum Iterations: 10000 Accelerate K Value & H Model Parameters: Off
62 Equilibrium Error Tolerance: 1.000e-05
1
4 USA
5
6
8
10 Heat/Spec Error Tolerance: 5.000e-004
11 Save Solutions as Initial Estimate: On
12 Super Critical Handling Model: Simple K
13 Trace Level: Low
14 Init from Ideal K's: Off Damping Parameters
15 Initial Estimate Generator Parameters Azeotrope Check: Off
16 Iterative IEG (Good for Chemicals): Off Fixed Damping Factor: 1
17
18
19
SIDE STRIPPERS
20
21
SIDE RECTIFIERS
22
23
PUMP AROUNDS
24
25
VAP BYPASSES
26
27
RATING
28
29
Tray Sections
30
31 Tray Section Main Tower @COL1
32 Tray Diameter (m) 1.500
33 Weir Height (m) 5.000e-002 *
34 Weir Length (m) 1.200 *
35 Tray Space (m) 0.5000
36 Tray Volume (m3) 0.8836
37 Disable Heat Loss Calculations No
38 Heat Model None
39 Rating Calculations No
40 Tray Hold Up (m3) 8.836e-002
41
Vessels
42
43 Vessel
44 Diameter
45 Length
46 Volume
47 Orientation
48 Vessel has a Boot
49 Boot Diameter
50 Boot Length
51 Hold Up
52
Other Equipment In Column Flowsheet
53
54
55
Pressure Profile
56
57 Pressure (kPa) Pressure Drop (kPa)
58 1__Main Tower 202.6 kPa * 0.0000 kPa
59 2__Main Tower 202.6 kPa 0.0000 kPa
1
4 USA
5
6
8
13 10__Main Tower 202.6 kPa * ---
14
Pressure Solving Options
15
16 Pressure Tolerance 1.000e-004 Pressure Drop Tolerance 1.000e-004
17 Damping Factor 1.000 Max Press Iterations 100
18
CONDITIONS
19
20 Name 10 9 11 12
21 Vapour 0.0000 1.0000 0.0000 1.0000
22 Temperature (C) 60.6191 120.0000 * 92.9529 77.1214
23 Pressure (kPa) 101.3250 199.3142 202.6500 202.6500
24 Molar Flow (kgmole/h) 45.0000 * 657.8305 18.6458 684.1847
25 Mass Flow (kg/h) 817.9335 19493.8958 1090.5924 19221.2369
26 Std Ideal Liq Vol Flow (m3/h) 0.8271 24.0520 0.8749 24.0041
27 Molar Enthalpy (kJ/kgmole) -2.816e+005 -6.891e+004 -3.608e+005 -7.494e+004
28 Molar Entropy (kJ/kgmole-C) 53.34 161.4 -113.8 162.4
29 Heat Flow (kJ/h) -1.2673e+07 -4.5330e+07 -6.7283e+06 -5.1275e+07
30
PROPERTIES
31
32 Name 10 9 11 12
33 Molecular Weight 18.18 29.63 58.49 28.09
34 Molar Density (kgmole/m3) 53.59 6.111e-002 19.79 6.984e-002
35 Mass Density (kg/m3) 974.1 1.811 1158 1.962
36 Act. Volume Flow (m3/h) 0.8397 1.076e+004 0.9420 9796
37 Mass Enthalpy (kJ/kg) -1.549e+004 -2325 -6169 -2668
38 Mass Entropy (kJ/kg-C) 2.934 5.448 -1.946 5.781
39 Heat Capacity (kJ/kgmole-C) 76.16 37.20 136.7 34.94
40 Mass Heat Capacity (kJ/kg-C) 4.190 1.255 2.337 1.244
41 LHV Molar Basis (Std) (kJ/kgmole) 1.067e+004 1.654e+005 7.216e+005 1.401e+005
42 HHV Molar Basis (Std) (kJ/kgmole) 5.234e+004 1.829e+005 7.642e+005 1.585e+005
43 HHV Mass Basis (Std) (kJ/kg) 2879 6173 1.307e+004 5641
44 CO2 Loading --- --- --- ---
45 CO2 Apparent Mole Conc. (kgmole/m3) 5.096e-004 --- 4.543e-004 ---
46 CO2 Apparent Wt. Conc. (kgmol/kg) 5.231e-007 --- 3.924e-007 ---
47 LHV Mass Basis (Std) (kJ/kg) 587.1 5581 1.234e+004 4985
48 Phase Fraction [Vol. Basis] 0.0000 1.000 0.0000 1.000
49 Phase Fraction [Mass Basis] 0.0000 1.000 0.0000 1.000
50 Phase Fraction [Act. Vol. Basis] 0.0000 1.000 0.0000 1.000
51 Mass Exergy (kJ/kg) -239.4 42.18 -111.0 31.31
52 Partial Pressure of CO2 (kPa) 0.0000 8.370 0.0000 8.182
53 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000 0.0000
54 Act. Gas Flow (ACT_m3/h) --- 1.076e+004 --- 9796
55 Avg. Liq. Density (kgmole/m3) 54.41 27.35 21.31 28.50
56 Specific Heat (kJ/kgmole-C) 76.16 37.20 136.7 34.94
57 Std. Gas Flow (STD_m3/h) 1064 1.555e+004 440.9 1.618e+004
58 Std. Ideal Liq. Mass Density (kg/m3) 989.0 810.5 1247 800.7
59 Act. Liq. Flow (m3/s) 2.332e-004 --- 2.617e-004 ---
60 Z Factor 6.813e-004 0.9978 3.364e-003 0.9963
61 Watson K 13.48 7.251 7.238 7.256
62 User Property --- --- --- ---
1
4 USA
5
6
8
9
PROPERTIES
10
11 Name 10 9 11 12
12 Partial Pressure of H2S (kPa) 0.0000 0.0000 0.0000 0.0000
13 Cp/(Cp - R) 1.123 1.288 1.065 1.312
14 Cp/Cv 1.171 1.293 1.171 1.320
15 Ideal Gas Cp/Cv 1.323 1.289 1.111 1.314
16 Ideal Gas Cp (kJ/kgmole-C) 34.09 37.06 82.90 34.76
17 Mass Ideal Gas Cp (kJ/kg-C) 1.876 1.251 1.417 1.237
18 Heat of Vap. (kJ/kgmole) 4.066e+004 2.344e+004 5.362e+004 2.258e+004
19 Kinematic Viscosity (cSt) 0.4997 10.86 0.6724 8.711
20 Liq. Mass Density (Std. Cond) (kg/m3) 1009 --- 1240 ---
21 Liq. Vol. Flow (Std. Cond) (m3/h) 0.8105 --- 0.8796 ---
22 Liquid Fraction 1.000 0.0000 1.000 0.0000
23 Molar Volume (m3/kgmole) 1.866e-002 16.36 5.052e-002 14.32
24 Mass Heat of Vap. (kJ/kg) 2237 791.1 916.8 803.7
25 Phase Fraction [Molar Basis] 0.0000 1.0000 0.0000 1.0000
26 Surface Tension (dyne/cm) 65.62 --- 458.4 ---
27 Thermal Conductivity (W/m-K) 0.6503 3.017e-002 0.3304 2.718e-002
28 Bubble Point Pressure (kPa) 51.61 --- 187.5 ---
29 Viscosity (cP) 0.4867 1.967e-002 0.7785 1.709e-002
30 Cv (Semi-Ideal) (kJ/kgmole-C) 67.84 28.89 128.4 26.63
31 Mass Cv (Semi-Ideal) (kJ/kg-C) 3.732 0.9748 2.195 0.9479
32 Cv (kJ/kgmole-C) 65.06 28.77 116.7 26.47
33 Mass Cv (kJ/kg-C) 3.579 0.9708 1.996 0.9423
34 Cv (Ent. Method) (kJ/kgmole-C) --- --- -2548 ---
35 Mass Cv (Ent. Method) (kJ/kg-C) --- --- -43.56 ---
36 Cp/Cv (Ent. Method) --- --- -5.365e-002 ---
37 Reid VP at 37.8 C (kPa) 369.7 --- 6.506 ---
38 True VP at 37.8 C (kPa) 30.80 --- 323.5 ---
39 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 0.8105 0.0000 0.8796 0.0000
40 Viscosity Index -8.487 --- -2.827 ---
41
SUMMARY
42
43 Flow Basis: Molar The composition option is selected
44 Feed Composition
45 10 9
46 Flow Rate (kgmole/h) 45.0000 657.8305
47 --- ---
48 n-Butane 0.0040 0.0503
49 Oxygen 0.0000 0.0144
50 Nitrogen 0.0000 0.6754
51 MaleicAnhydr 0.0000 0.0142
52 CO2 0.0000 0.0420
53 CO 0.0000 0.0420
54 Acetone 0.0000 0.0000
55 H2O 0.9960 0.1618
57 Feed Flows
58 10 9
60 --- ---
61 n-Butane (kgmole/h) 0.1805 33.0897
62 Oxygen (kgmole/h) 0.0000 9.4564
1
4 USA
5
6
8
9
SUMMARY
10
11 10 9
12 Nitrogen (kgmole/h) 0.0001 444.2881
13 MaleicAnhydr (kgmole/h) 0.0000 9.3379
14 CO2 (kgmole/h) 0.0004 27.6239
15 CO (kgmole/h) 0.0000 27.6239
16 Acetone (kgmole/h) 0.0000 0.0000
17 H2O (kgmole/h) 44.8189 106.4105
18 Products
20 Product Compositions
21 12 11
23 --- ---
24 n-Butane 0.0484 0.0097
25 Oxygen 0.0138 0.0000
26 Nitrogen 0.6494 0.0000
28 CO2 0.0404 0.0000
29 CO 0.0404 0.0000
30 Acetone 0.0000 0.0000
31 H2O 0.2077 0.4895
33 Product Flows
34 12 11
35 Flow Rate (kgmole/h) 684.1847 * 18.6458 *
36 --- ---
37 n-Butane (kgmole/h) 33.0897 * 0.1806 *
38 Oxygen (kgmole/h) 9.4564 * 0.0000 *
39 Nitrogen (kgmole/h) 444.2881 * 0.0001 *
40 MaleicAnhydr (kgmole/h) 0.0000 * 9.3379 *
41 CO2 (kgmole/h) 27.6239 * 0.0004 *
42 CO (kgmole/h) 27.6239 * 0.0000 *
43 Acetone (kgmole/h) 0.0000 * 0.0000 *
44 H2O (kgmole/h) 142.1027 * 9.1268 *
46 Product Recoveries
47 12 11
49 --- ---
50 n-Butane (%) 99.4572 0.5428
51 Oxygen (%) 99.9999 0.0001
52 Nitrogen (%) 100.0000 0.0000
53 MaleicAnhydr (%) 0.0000 100.0000
54 CO2 (%) 99.9985 0.0015
55 CO (%) 99.9999 0.0001
56 Acetone (%) 0.0000 0.0000
57 H2O (%) 93.9650 6.0350
58
COLUMN PROFILES
59
60 Reflux Ratio: 6.800e-002 Reboil Ratio: --- The Flows Option is Selected Flow Basis: Molar
61 Column Profiles Flows
62
1
4 USA
5
6
8
9
COLUMN PROFILES
10
11 Temp Pres Net Liq Net Vap Net Feed Net Draws Duty
12 (C) (kPa) (kgmole/h) (kgmole/h) (kgmole/h) (kgmole/h) (kJ/h)
13 1__Main Tower 77.1 202.6 46.52 --- 45.00 684.2 ---
14 2__Main Tower 77.3 202.6 46.54 685.7 --- --- ---
15 3__Main Tower 77.3 202.6 46.54 685.7 --- --- ---
16 4__Main Tower 77.3 202.6 46.54 685.7 --- --- ---
17 5__Main Tower 77.3 202.6 46.53 685.7 --- --- ---
18 6__Main Tower 77.3 202.6 46.52 685.7 --- --- ---
19 7__Main Tower 77.3 202.6 46.37 685.7 --- --- ---
20 8__Main Tower 77.5 202.6 44.78 685.6 --- --- ---
21 9__Main Tower 79.9 202.6 35.94 684.0 --- --- ---
22 10__Main Tower 93.0 202.6 --- 675.1 657.8 18.65 ---
23 Column Profiles Energy
24 Temperature Liq Enthalpy Vap Enthalpy Heat Loss
25 (C) (kJ/kgmole) (kJ/kgmole) (kJ/h)
26 1__Main Tower 77.12 -2.792e+005 -7.494e+004 ---
27 2__Main Tower 77.26 -2.792e+005 -7.524e+004 ---
28 3__Main Tower 77.26 -2.792e+005 -7.524e+004 ---
29 4__Main Tower 77.26 -2.792e+005 -7.524e+004 ---
30 5__Main Tower 77.26 -2.792e+005 -7.524e+004 ---
31 6__Main Tower 77.26 -2.792e+005 -7.524e+004 ---
32 7__Main Tower 77.28 -2.793e+005 -7.524e+004 ---
33 8__Main Tower 77.52 -2.811e+005 -7.520e+004 ---
34 9__Main Tower 79.95 -2.980e+005 -7.484e+004 ---
35 10__Main Tower 92.95 -3.608e+005 -7.304e+004 ---
36
FEEDS / PRODUCTS
37
38 Flow Basis: Molar
39 Stream Type Duty State Flows Enthalpy Temp
40 (kJ/h) (kgmole/h) (kJ/kgmole) (C)
41 10 Feed --- Liquid 45.0 * -2.8e+005 * 60.62*
1__Main Tower
42 12 Draw --- Vapour 684 * -7.5e+004 * 77.12*
43 2__Main Tower
44 3__Main Tower
45 4__Main Tower
46 5__Main Tower
47 6__Main Tower
48 7__Main Tower
49 8__Main Tower
50 9__Main Tower
51 9 Feed --- Vapour 658 * -6.9e+004 * 120.00
*
10__Main Tower
52 11 Draw --- Liquid 18.6 * -3.6e+005 * 92.95*
53
SETUP
54
55 Sub-Flowsheet
56 Internal Feed Stream External Feed Stream Transfer Basis
57 10 10 P-H Flash
58 9 9 P-H Flash
59 Internal Prod Stream External Prod Stream Transfer Basis
60 12 12 P-H Flash
61 11 11 P-H Flash
62
1
4 USA
5
6
8
9
VARIABLES
10
11 Column Flowsheet Vars Available as Parameters
12 Data Source Variable Component Description
13
14
COMPONENT MAPS
15
16 Feed Streams
17 Feed Name In to SubFlowSheet Out of SubFlowSheet
18 10
19
20 Product Stream
21 Product Name In to SubFlowSheet Out of SubFlowSheet
22 12
23
24
DYNAMICS
25
26
Vessel Dynamic Specifications
27
28 Vessel
29 Diameter (m)
30 Height.0 (m)
31 Volume.0 (m3)
32 Liquid Volume Percent (%)
33 Level Calculator
34 Fraction Calculator
35 Vessel Delta P (kPa)
36 Fixed Vessel P Spec (kPa)
37 Fixed P Spec Active
38
Other Equipment in Column Flowsheet
39
40
41
Holdup Details
42
43 Pressure Volume Bulk Liquid Volume
44 (kPa) (m3) (m3)
45 1__Main Tower 0.0000 0.0000 * ---
46 2__Main Tower 0.0000 0.0000 * ---
47 3__Main Tower 0.0000 0.0000 * ---
48 4__Main Tower 0.0000 0.0000 * ---
49 5__Main Tower 0.0000 0.0000 * ---
50 6__Main Tower 0.0000 0.0000 * ---
51 7__Main Tower 0.0000 0.0000 * ---
52 8__Main Tower 0.0000 0.0000 * ---
53 9__Main Tower 0.0000 0.0000 * ---
54 10__Main Tower 0.0000 0.0000 * ---
55
COLUMN REFINERY ASSAY PLOTS
56
57 Single Tray : Single Tray :
58
59
60
61
62
1
4 USA
5
6
8
9
10
11
12
Boiling Point Properties Molecular Weight Properties
13 10,00 10,00
14
15
16 8,00 8,00
17
Molecular Weight
18
Temperature
19
6,00 6,00
20
21
22
23 4,00 4,00
24
25
26 2,00 2,00
27
28
29
0,00 0,00
30
0,00 2,00 4,00 6,00 8,00 10,00 0,00 2,00 4,00 6,00 8,00 10,00
31
32 Percent Composition Percent Composition
33
34 Single Tray :
35
36
Density Properties
37 10,00
38
39
40 8,00
41
42
43
6,00
Density
44
45
46
47 4,00
48
49
50 2,00
51
52
53
0,00
54
0,00 2,00 4,00 6,00 8,00 10,00
55
56 Percent Composition
57
58
COLUMN REFINERY ASSAY TABLES
59
60
Boiling Point Assay
61
62 Single Tray : Assay Basis : Molar
1
4 USA
5
6
8
9
10
11
Boiling Point Assay
12
13 Assay Percent
14
15 0.0 %
16 1.0 %
17 2.0 %
18 3.5 %
19 5.0 %
20 7.5 %
21 10.0 %
22 12.5 %
23 15.0 %
24 17.5 %
25 20.0 %
26 25.0 %
27 30.0 %
28 35.0 %
29 40.0 %
30 45.0 %
31 50.0 %
32 55.0 %
33 60.0 %
34 65.0 %
35 70.0 %
36 75.0 %
37 80.0 %
38 85.0 %
39 90.0 %
40 92.5 %
41 95.0 %
42 96.5 %
43 98.0 %
44 99.0 %
45 100.0 %
46
Molecular Weight Assay
47
49 Assay Percent
50
51 0.0 %
52 1.0 %
53 2.0 %
54 3.5 %
55 5.0 %
56 7.5 %
57 10.0 %
58 12.5 %
59 15.0 %
60 17.5 %
61 20.0 %
62 25.0 %
1
4 USA
5
6
8
9
10
11
12
13 Assay Percent
14
15 30.0 %
16 35.0 %
17 40.0 %
18 45.0 %
19 50.0 %
20 55.0 %
21 60.0 %
22 65.0 %
23 70.0 %
24 75.0 %
25 80.0 %
26 85.0 %
27 90.0 %
28 92.5 %
29 95.0 %
30 96.5 %
31 98.0 %
32 99.0 %
33 100.0 %
34
Density Assay
35
37 Assay Percent
38
39 0.0 %
40 1.0 %
41 2.0 %
42 3.5 %
43 5.0 %
44 7.5 %
45 10.0 %
46 12.5 %
47 15.0 %
48 17.5 %
49 20.0 %
50 25.0 %
51 30.0 %
52 35.0 %
53 40.0 %
54 45.0 %
55 50.0 %
56 55.0 %
57 60.0 %
58 65.0 %
59 70.0 %
60 75.0 %
61 80.0 %
62 85.0 %
1
4 USA
5
6
8
9
10
11
Density Assay
12
13 Assay Percent
14
15 90.0 %
16 92.5 %
17 95.0 %
18 96.5 %
19 98.0 %
20 99.0 %
21 100.0 %
22
User Properties
23
24 Assay Percent
25
26 0.0 %
27 1.0 %
28 2.0 %
29 3.5 %
30 5.0 %
31 7.5 %
32 10.0 %
33 12.5 %
34 15.0 %
35 17.5 %
36 20.0 %
37 25.0 %
38 30.0 %
39 35.0 %
40 40.0 %
41 45.0 %
42 50.0 %
43 55.0 %
44 60.0 %
45 65.0 %
46 70.0 %
47 75.0 %
48 80.0 %
49 85.0 %
50 90.0 %
51 92.5 %
52 95.0 %
53 96.5 %
54 98.0 %
55 99.0 %
56 100.0 %
57
58
59
60
61
62
1
4 USA
5
6
8
9
TRAY by TRAY PROPERTIES PLOTS
10
11
12 Temperature vs. Tray Position from Top
13 94,0
14
92,0
15
16
90,0
17
18
Temperature (C)
88,0
19
20 86,0
21
22 84,0
23
24 82,0
25
26 80,0
27
28 78,0
29
76,0
30
0 1 2 3 4 5 6 7 8 9
31
32
33
34
35 Pressure vs. Tray Position from Top
36 207
37
206
38
39 205
40
41 204
Pressure (kPa)
42
203
43
44 202
45
46 201
47
200
48
49 199
50
51 198
52
197
53
0 1 2 3 4 5 6 7 8 9
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
11
12 Flow vs. Tray Position from Top
13 700
Vapour
14
Liquid
15 600
16
Net Molar Flow (kgmole/h)
17
500
18
19
20 400
21
22
300
23
24
25 200
26
27 100
28
29
0,000
30
0 1 2 3 4 5 6 7 8 9
31
32
33
34
35 Column Properties vs. Tray Position from Top
36 1,20e+003 60,0
Density(Light)
37
Mol Weight(Light) 55,0
38
1,15e+003
39
50,0
40
41
Density (kg/m3)
1,10e+003 45,0
42
43 40,0
44 1,05e+003
45 35,0
46
47 1,00e+003 30,0
48
49 25,0
50 950
51 20,0
52
900 15,0
53
0 1 2 3 4 5 6 7 8 9
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
11
12 Composition vs. Tray Position from Top
13 0,600
n-Butane (Light)
14
Oxygen (Light)
15
0,500 Nitrogen (Light)
16
MaleicAnhydr (Light)
17
18
0,400
Mole Fraction
19
20
21 0,300
22
23
24 0,200
25
26
27 1,00e-001
28
29
0,000
30
0 1 2 3 4 5 6 7 8 9
31
32
33
34
35 K-Value vs. Tray Position from Top
36 1,20e+005
n-Butane
37
Oxygen
38
1,00e+005 Nitrogen
39
MaleicAnhydr
40
41
8,00e+004
42
K Value
43
44 6,00e+004
45
46
47 4,00e+004
48
49
50 2,00e+004
51
52
0,000
53
0 1 2 3 4 5 6 7 8 9
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
11
12 Component Ratio vs. Tray Position from Top
13 2,50e+004
Light
14
15
16 2,00e+004
17
Mole Fraction Ratio
18
19
1,50e+004
20
21
22
23 1,00e+004
24
25
26 5,00e+003
27
28
29
0,000
30
0 1 2 3 4 5 6 7 8 9
31
32
33
34
TRAY by TRAY PROPERTIES TABLES
35
36
Column Temperature / Pressure Profile
37
38 Column Stage Temperature Pressure
39 (C) (kPa)
40 1__Main Tower 77.12 202.6
41 2__Main Tower 77.26 202.6
42 3__Main Tower 77.26 202.6
43 4__Main Tower 77.26 202.6
44 5__Main Tower 77.26 202.6
45 6__Main Tower 77.26 202.6
46 7__Main Tower 77.28 202.6
47 8__Main Tower 77.52 202.6
48 9__Main Tower 79.95 202.6
49 10__Main Tower 92.95 202.6
50
Column Flow Profile
51
52 Options Selected
53 Molar flow is selected Net is selected as flow basis
54 Tray Number Vapour Bulk Liquid
55 (kgmole/h) (kgmole/h)
56 1__Main Tower 684.2 46.52
57 2__Main Tower 685.7 46.54
58 3__Main Tower 685.7 46.54
59 4__Main Tower 685.7 46.54
60 5__Main Tower 685.7 46.53
61 6__Main Tower 685.7 46.52
62 7__Main Tower 685.7 46.37
1
4 USA
5
6
8
9
10
13 8__Main Tower 685.6 44.78
14 9__Main Tower 684.0 35.94
15 10__Main Tower 675.1 18.65
16
Column Properties Profile
17
18 Options Selected
19 Mass basis is selected
20 Stage Surf Tens Mol Wt Dens Visc Therm Con Heat Cap
21 L-Liq L-Liq L-Liq L-Liq L-Liq
22 (dyne/cm) (kg/m3) (cP) (W/m-K) (kJ/kg-C)
23 1__Main Tower 62.2 18.5 949 0.373 0.656 4.14

24 2__Main Tower 62.1 18.5 948 0.372 0.656 4.14
25 3__Main Tower 62.1 18.5 948 0.372 0.656 4.14
26 4__Main Tower 62.1 18.5 948 0.372 0.656 4.14
27 5__Main Tower 62.1 18.5 948 0.372 0.656 4.14
28 6__Main Tower 62.2 18.5 949 0.372 0.656 4.14
29 7__Main Tower 62.9 18.6 950 0.373 0.655 4.13
30 8__Main Tower 71.6 19.4 961 0.387 0.647 4.01
31 9__Main Tower 156 27.6 1.04e+003 0.513 0.570 3.26
32 10__Main Tower 458 58.5 1.16e+003 0.778 0.330 2.34
33
34
35
Column Composition Profile
36
37 Options Selected
38 Fraction is selected as the composition basis Net is selected as flow basis
39 Molar basis is selected
40 Stage n-Butane Oxygen Nitrogen MaleicAnhydr
41 L-Liq L-Liq L-Liq L-Liq
42 1__Main Tower 0.0124 0.0000 0.0000 0.0000
43 2__Main Tower 0.0125 0.0000 0.0000 0.0000
44 3__Main Tower 0.0125 0.0000 0.0000 0.0000
45 4__Main Tower 0.0125 0.0000 0.0000 0.0000
46 5__Main Tower 0.0125 0.0000 0.0000 0.0000
47 6__Main Tower 0.0125 0.0000 0.0000 0.0001
48 7__Main Tower 0.0125 0.0000 0.0000 0.0010
49 8__Main Tower 0.0125 0.0000 0.0000 0.0114
50 9__Main Tower 0.0120 0.0000 0.0000 0.1142
51 10__Main Tower 0.0097 0.0000 0.0000 0.5008
52
Heavy/Light Key Component Ratios
53
54 Options Selected
56
Key Components
57
58 Light Key Chosen Heavy Key Chosen
59 n-Butane On n-Butane Off
60 Oxygen On Oxygen Off
61 Nitrogen On Nitrogen Off
62 MaleicAnhydr On MaleicAnhydr Off
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8
9
10
11
12
13
Key Components
14
16 CO2 Off CO2 On
17 CO Off CO On
18 Acetone Off Acetone Off
19 H2O Off H2O Off
20 Stage Light Liq
21 1__Main Tower 524.2
28 8__Main Tower 1011
29 9__Main Tower 5366
30 10__Main Tower 2.124e+004
31
Column K-Values Profile
32
33 Tray Number n-Butane Oxygen Nitrogen MaleicAnhydr
34 1__Main Tower 3.885 2.877e+004 4.932e+004 5.700e-003
35 2__Main Tower 3.895 2.875e+004 4.925e+004 5.741e-003
36 3__Main Tower 3.895 2.875e+004 4.924e+004 5.741e-003
37 4__Main Tower 3.895 2.875e+004 4.924e+004 5.741e-003
38 5__Main Tower 3.895 2.875e+004 4.925e+004 5.741e-003
39 6__Main Tower 3.895 2.875e+004 4.926e+004 5.742e-003
40 7__Main Tower 3.897 2.878e+004 4.942e+004 5.748e-003
41 8__Main Tower 3.914 2.907e+004 5.134e+004 5.815e-003
42 9__Main Tower 4.090 3.134e+004 6.991e+004 6.561e-003
43 10__Main Tower 5.099 3.184e+004 1.140e+005 1.214e-002
44
NOTES
45
46
47
49
50
CONNECTIONS
51
52 Inlet Stream
53 STREAM NAME Stage FROM UNIT OPERATION
54 QHT101 Reboiler
55 11 5__Main Tower Absorber T-100
56 Outlet Stream
57 STREAM NAME Stage TO UNIT OPERATION
58 QCT101 Condenser
59 13 Condenser Recycle RCY-1
60 14 Reboiler
61
MONITOR
62
1
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5
6
7 Distillation: T-101 (continued)
8
9 Specifications Summary
10 Specified Value Current Value Wt. Error
11 Reflux Ratio 2.000 * 2.000 -6.762e-009
12 Distillate Rate --- 9.299 kgmole/h ---
13 Reflux Rate --- 18.60 kgmole/h ---
14 Btms Prod Rate --- 9.347 kgmole/h ---
15 Comp Fraction 0.9990 * 0.9990 3.653e-005
16 Wt. Tol. Abs. Tol. Active Estimate Used
17 Reflux Ratio 1.000e-002 1.000e-002 On On On
18 Distillate Rate 1.000e-002 1.000 kgmole/h Off On Off
19 Reflux Rate 1.000e-002 1.000 kgmole/h Off On Off
20 Btms Prod Rate 1.000e-002 1.000 kgmole/h Off On Off
21 Comp Fraction 1.000e-002 1.000e-003 On On On
22
SPECS
23
24 Column Specification Parameters
25
Reflux Ratio
26
27 Fix/Rang: Fixed Prim/Alter: Primary Lower Bnd: --- Upper Bnd: ---
28 Stage: Condenser Flow Basis: Molar Liquid Spec: ---
29
Distillate Rate
30
32 Stream: 13 @COL2 Flow Basis: Molar
33
Reflux Rate
34
36 Stage: Condenser Flow Basis: Molar Liquid Spec: ---
37
Btms Prod Rate
38
40 Stream: 14 @COL2 Flow Basis: Molar
41
Comp Fraction
42
44 Stage: Flow Basis: Mole Fraction Phase: Liquid
45 Components: MaleicAnhydr
46
SUBCOOLING
47
48 Condenser
49 Degrees of Subcooling ---
50 Subcool to ---
51
User Variables
52
53
PROFILES
54
55 General Parameters
56 Sub-Flow Sheet: T-101 (COL2) Number of Stages: 10
57 Profile Estimates
60 Condenser 21.53 18.60 2.530e-007
61 1__Main Tower 99.49 21.22 27.90
62 2__Main Tower 99.81 21.22 30.52
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5
6
8
9 Profile Estimates
12 3__Main Tower 99.85 21.20 30.52
13 4__Main Tower 100.3 20.92 30.50
14 5__Main Tower 107.4 40.68 30.21
15 6__Main Tower 107.6 40.66 31.33
16 7__Main Tower 108.3 40.21 31.31
17 8__Main Tower 118.4 36.78 30.86
18 9__Main Tower 163.2 35.31 27.44
19 10__Main Tower 196.2 38.85 25.97
20 Reboiler 201.5 9.347 29.51
21
EFFICIENCIES
22
23 Stage Efficiencies
24 Stages Overall n-Butane Oxygen Nitrogen MaleicAnhydr
25 Condenser 1.000 1.000 1.000 1.000 1.000
26 1__Main Tower 1.000 1.000 1.000 1.000 1.000
27 2__Main Tower 1.000 1.000 1.000 1.000 1.000
28 3__Main Tower 1.000 1.000 1.000 1.000 1.000
29 4__Main Tower 1.000 1.000 1.000 1.000 1.000
30 5__Main Tower 1.000 1.000 1.000 1.000 1.000
31 6__Main Tower 1.000 1.000 1.000 1.000 1.000
32 7__Main Tower 1.000 1.000 1.000 1.000 1.000
33 8__Main Tower 1.000 1.000 1.000 1.000 1.000
34 9__Main Tower 1.000 1.000 1.000 1.000 1.000
35 10__Main Tower 1.000 1.000 1.000 1.000 1.000
36 Reboiler 1.000 1.000 1.000 1.000 1.000
37 Stages Overall CO2 CO Acetone H2O
38 Condenser 1.000 1.000 1.000 1.000 1.000
39 1__Main Tower 1.000 1.000 1.000 1.000 1.000
40 2__Main Tower 1.000 1.000 1.000 1.000 1.000
41 3__Main Tower 1.000 1.000 1.000 1.000 1.000
42 4__Main Tower 1.000 1.000 1.000 1.000 1.000
43 5__Main Tower 1.000 1.000 1.000 1.000 1.000
44 6__Main Tower 1.000 1.000 1.000 1.000 1.000
45 7__Main Tower 1.000 1.000 1.000 1.000 1.000
46 8__Main Tower 1.000 1.000 1.000 1.000 1.000
47 9__Main Tower 1.000 1.000 1.000 1.000 1.000
48 10__Main Tower 1.000 1.000 1.000 1.000 1.000
49 Reboiler 1.000 1.000 1.000 1.000 1.000
50
SOLVER
51
53 Solving Options Acceleration Parameters
54 Maximum Iterations: 10000 Accelerate K Value & H Model Parameters: Off
55 Equilibrium Error Tolerance: 1.000e-05
56 Heat/Spec Error Tolerance: 5.000e-004
57 Save Solutions as Initial Estimate: On
58 Super Critical Handling Model: Simple K
59 Trace Level: Low
60 Init from Ideal K's: Off Damping Parameters
61 Initial Estimate Generator Parameters Azeotrope Check: Off
62 Iterative IEG (Good for Chemicals): Off Fixed Damping Factor: 1
1
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10
11
12
SIDE STRIPPERS
13
14
SIDE RECTIFIERS
15
16
PUMP AROUNDS
17
18
VAP BYPASSES
19
20
RATING
21
22
Tray Sections
23
24 Tray Section Main Tower @COL2
25 Tray Diameter (m) 1.500
26 Weir Height (m) 5.000e-002 *
27 Weir Length (m) 1.200 *
28 Tray Space (m) 0.5500 *
29 Tray Volume (m3) 0.9719
30 Disable Heat Loss Calculations No
31 Heat Model None
32 Rating Calculations No
33 Tray Hold Up (m3) 8.836e-002
34
Vessels
35
36 Vessel Reboiler @COL2 Condenser @COL2
37 Diameter (m) 1.193 1.193
38 Length (m) 1.789 1.789
39 Volume (m3) 2.000 * 2.000 *
40 Orientation Horizontal Horizontal
41 Vessel has a Boot No No
42 Boot Diameter (m) --- ---
43 Boot Length (m) --- ---
44 Hold Up (m3) 1.000 1.000
45
Other Equipment In Column Flowsheet
46
47
48
Pressure Profile
49
50 Pressure (kPa) Pressure Drop (kPa)
51 Condenser 101.3 kPa * 0.0000 kPa
61 10__Main Tower 101.3 kPa ---
62 Reboiler 101.3 kPa * -0.0000 kPa
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6
8
9
Pressure Solving Options
10
11 Pressure Tolerance 1.000e-004 Pressure Drop Tolerance 1.000e-004
12 Damping Factor 1.000 Max Press Iterations 100
13
CONDITIONS
14
15 Name 11 14 13 QHT101
16 Vapour 0.0000 0.0000 0.0000 ---
17 Temperature (C) 92.9529 201.5142 21.5330 ---
18 Pressure (kPa) 202.6500 101.3250 101.3250 ---
19 Molar Flow (kgmole/h) 18.6458 9.3472 9.2986 ---
20 Mass Flow (kg/h) 1090.5924 915.8226 174.7698 ---
21 Std Ideal Liq Vol Flow (m3/h) 0.8749 0.6923 0.1826 ---
22 Molar Enthalpy (kJ/kgmole) -3.608e+005 -4.219e+005 -2.825e+005 ---
23 Molar Entropy (kJ/kgmole-C) -113.8 -213.2 27.92 ---
24 Heat Flow (kJ/h) -6.7283e+06 -3.9436e+06 -2.6269e+06 1.4267e+06
25
PROPERTIES
26
27 Name 11 14 13
29 Molar Density (kgmole/m3) 19.79 11.41 52.31
30 Mass Density (kg/m3) 1158 1118 983.2
32 Mass Enthalpy (kJ/kg) -6169 -4306 -1.503e+004
33 Mass Entropy (kJ/kg-C) -1.946 -2.176 1.486
36 LHV Molar Basis (Std) (kJ/kgmole) 7.216e+005 1.388e+006 5.165e+004
38 HHV Mass Basis (Std) (kJ/kg) 1.307e+004 1.459e+004 5099
39 CO2 Loading --- --- ---
40 CO2 Apparent Mole Conc. (kgmole/m3) 4.543e-004 1.930e-028 2.408e-003
41 CO2 Apparent Wt. Conc. (kgmol/kg) 3.924e-007 1.726e-031 2.449e-006
42 LHV Mass Basis (Std) (kJ/kg) 1.234e+004 1.417e+004 2748
46 Mass Exergy (kJ/kg) -111.0 -124.5 26.84
52 Std. Gas Flow (STD_m3/h) 440.9 221.0 219.9
53 Std. Ideal Liq. Mass Density (kg/m3) 1247 1323 957.1
54 Act. Liq. Flow (m3/s) 2.617e-004 2.275e-004 4.937e-005
55 Z Factor 3.364e-003 2.249e-003 7.905e-004
56 Watson K 7.238 7.161 13.48
59 Cp/(Cp - R) 1.065 1.040 1.121
60 Cp/Cv 1.171 1.529 1.154
61 Ideal Gas Cp/Cv 1.111 1.059 1.314
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8
9
PROPERTIES
10
11 Name 11 14 13
13 Heat of Vap. (kJ/kgmole) 5.362e+004 4.708e+004 4.524e+004
15 Liq. Mass Density (Std. Cond) (kg/m3) 1240 1344 988.2
17 Liquid Fraction 1.000 1.000 1.000
18 Molar Volume (m3/kgmole) 5.052e-002 8.761e-002 1.912e-002
19 Mass Heat of Vap. (kJ/kg) 916.8 480.6 2407
21 Surface Tension (dyne/cm) 458.4 599.0 71.52
22 Thermal Conductivity (W/m-K) 0.3304 0.1120 0.5902
23 Bubble Point Pressure (kPa) 187.5 101.3 95.94
24 Viscosity (cP) 0.7785 0.3881 0.9117
27 Cv (kJ/kgmole-C) 116.7 141.5 66.71
28 Mass Cv (kJ/kg-C) 1.996 1.444 3.550
29 Cv (Ent. Method) (kJ/kgmole-C) -2548 --- ---
30 Mass Cv (Ent. Method) (kJ/kg-C) -43.56 --- ---
31 Cp/Cv (Ent. Method) -5.365e-002 --- ---
32 Reid VP at 37.8 C (kPa) 6.506 0.1159 369.7
33 True VP at 37.8 C (kPa) 323.5 0.1223 122.6
35 Viscosity Index -2.827 -17.90 2.192
36
SUMMARY
37
39 Feed Composition
40 11
41 Flow Rate (kgmole/h) 18.6458
42 ---
43 n-Butane 0.0097
44 Oxygen 0.0000
45 Nitrogen 0.0000
46 MaleicAnhydr 0.5008
47 CO2 0.0000
48 CO 0.0000
49 Acetone 0.0000
50 H2O 0.4895
52 Feed Flows
53 11
54 Flow Rate (kgmole/h) 18.6458
55 ---
56 n-Butane (kgmole/h) 0.1806
57 Oxygen (kgmole/h) 0.0000
58 Nitrogen (kgmole/h) 0.0001
59 MaleicAnhydr (kgmole/h) 9.3379
60 CO2 (kgmole/h) 0.0004
61 CO (kgmole/h) 0.0000
62 Acetone (kgmole/h) 0.0000
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5
6
8
9
SUMMARY
10
11 11
12 H2O (kgmole/h) 9.1268
13 Products
15 Product Compositions
16 13 14
18 --- ---
19 n-Butane 0.0194 0.0000
20 Oxygen 0.0000 0.0000
21 Nitrogen 0.0000 0.0000
23 CO2 0.0000 0.0000
24 CO 0.0000 0.0000
25 Acetone 0.0000 0.0000
26 H2O 0.9805 0.0010
28 Product Flows
29 13 14
30 Flow Rate (kgmole/h) 9.2986 * 9.3472 *
31 --- ---
32 n-Butane (kgmole/h) 0.1806 * 0.0000 *
33 Oxygen (kgmole/h) 0.0000 * 0.0000 *
34 Nitrogen (kgmole/h) 0.0001 * 0.0000 *
35 MaleicAnhydr (kgmole/h) 0.0000 * 9.3379 *
36 CO2 (kgmole/h) 0.0004 * 0.0000 *
37 CO (kgmole/h) 0.0000 * 0.0000 *
38 Acetone (kgmole/h) 0.0000 * 0.0000 *
39 H2O (kgmole/h) 9.1174 * 0.0093 *
41 Product Recoveries
42 13 14
44 --- ---
45 n-Butane (%) 100.0000 0.0000
46 Oxygen (%) 99.9080 0.0000
47 Nitrogen (%) 99.8249 0.0000
48 MaleicAnhydr (%) 0.0000 100.0000
49 CO2 (%) 99.9965 0.0000
50 CO (%) 99.8741 0.0000
51 Acetone (%) 0.0000 0.0000
52 H2O (%) 99.8976 0.1024
53
COLUMN PROFILES
54
55 Reflux Ratio: 2.000 Reboil Ratio: 3.157 The Flows Option is Selected Flow Basis: Molar
56 Column Profiles Flows
59 Condenser 21.5 101.3 18.60 --- --- 9.299 1.27e+006 *
60 1__Main Tower 99.5 101.3 21.22 27.90 --- --- ---
61 2__Main Tower 99.8 101.3 21.22 30.52 --- --- ---
62 3__Main Tower 99.9 101.3 21.20 30.52 --- --- ---
1
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5
6
8
9
COLUMN PROFILES
10
13 4__Main Tower 100.3 101.3 20.92 30.50 --- --- ---
14 5__Main Tower 107.4 101.3 40.68 30.21 18.65 --- ---
15 6__Main Tower 107.6 101.3 40.66 31.33 --- --- ---
16 7__Main Tower 108.3 101.3 40.21 31.31 --- --- ---
17 8__Main Tower 118.4 101.3 36.78 30.86 --- --- ---
18 9__Main Tower 163.2 101.3 35.31 27.44 --- --- ---
19 10__Main Tower 196.2 101.3 38.85 25.97 --- --- ---
20 Reboiler 201.5 101.3 --- 29.51 --- 9.347 1.43e+006 *
21 Column Profiles Energy
22 Temperature Liq Enthalpy Vap Enthalpy Heat Loss
23 (C) (kJ/kgmole) (kJ/kgmole) (kJ/h)
24 Condenser 21.53 -2.825e+005 -4.587e+004 ---
25 1__Main Tower 99.49 -2.790e+005 -2.370e+005 ---
26 2__Main Tower 99.81 -2.791e+005 -2.385e+005 ---
27 3__Main Tower 99.85 -2.793e+005 -2.386e+005 ---
28 4__Main Tower 100.3 -2.817e+005 -2.387e+005 ---
29 5__Main Tower 107.4 -3.174e+005 -2.399e+005 ---
30 6__Main Tower 107.6 -3.176e+005 -2.406e+005 ---
31 7__Main Tower 108.3 -3.206e+005 -2.409e+005 ---
32 8__Main Tower 118.4 -3.550e+005 -2.437e+005 ---
33 9__Main Tower 163.2 -4.131e+005 -2.802e+005 ---
34 10__Main Tower 196.2 -4.215e+005 -3.550e+005 ---
35 Reboiler 201.5 -4.219e+005 -3.730e+005 ---
36
FEEDS / PRODUCTS
37
38 Flow Basis: Molar
39 Stream Type Duty State Flows Enthalpy Temp
40 (kJ/h) (kgmole/h) (kJ/kgmole) (C)
41 QCT101 Energy 1.3e+006 * --- --- ---
Condenser
42 13 Draw --- Liquid 9.30 * -2.8e+005 * 21.53*
43 1__Main Tower
44 2__Main Tower
45 3__Main Tower
46 4__Main Tower
47 5__Main Tower 11 Feed --- Liquid 18.6 * -3.6e+005 * 92.95*
48 6__Main Tower
49 7__Main Tower
50 8__Main Tower
51 9__Main Tower
52 10__Main Tower
53 QHT101 Energy 1.4e+006 * --- --- ---
Reboiler
54 14 Draw --- Liquid 9.35 * -4.2e+005 * 201.51
*
55
SETUP
56
57 Sub-Flowsheet
58 Internal Feed Stream External Feed Stream Transfer Basis
59 QHT101 QHT101 None Req'd
60 11 11 P-H Flash
61 Internal Prod Stream External Prod Stream Transfer Basis
62 QCT101 QCT101 None Req'd
1
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5
6
8
9 Sub-Flowsheet
10 13 13 P-H Flash
11 14 14 P-H Flash
12
13
VARIABLES
14
15 Column Flowsheet Vars Available as Parameters
16 Data Source Variable Component Description
17
18
COMPONENT MAPS
19
20 Feed Streams
21 Feed Name In to SubFlowSheet Out of SubFlowSheet
22 QHT101
23
24 Product Stream
25 Product Name In to SubFlowSheet Out of SubFlowSheet
26 QCT101
27 13
28
29
DYNAMICS
30
31
Vessel Dynamic Specifications
32
33 Vessel Reboiler @COL2 Condenser @COL2
34 Diameter (m) 1.193 1.193
35 Height.0 (m) 1.789 1.789
36 Volume.0 (m3) 2.000 * 2.000 *
37 Liquid Volume Percent (%) 50.00 50.00
38 Level Calculator Horizontal cylinder Horizontal cylinder
39 Fraction Calculator Use levels and nozzles Use levels and nozzles
40 Vessel Delta P (kPa) 0.0000 0.0000
41 Fixed Vessel P Spec (kPa) 101.3 101.3
42 Fixed P Spec Active Not Active Not Active
43
Other Equipment in Column Flowsheet
44
45
46
Holdup Details
47
48 Pressure Volume Bulk Liquid Volume
49 (kPa) (m3) (m3)
50 Condenser 0.0000 0.0000 * ---
51 1__Main Tower 0.0000 0.0000 * ---
52 2__Main Tower 0.0000 0.0000 * ---
53 3__Main Tower 0.0000 0.0000 * ---
54 4__Main Tower 0.0000 0.0000 * ---
55 5__Main Tower 0.0000 0.0000 * ---
56 6__Main Tower 0.0000 0.0000 * ---
57 7__Main Tower 0.0000 0.0000 * ---
58 8__Main Tower 0.0000 0.0000 * ---
59 9__Main Tower 0.0000 0.0000 * ---
60 10__Main Tower 0.0000 0.0000 * ---
61 Reboiler 0.0000 0.0000 * ---
62
1
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5
6
8
9
10
11 Single Tray : Single Tray :
12
13
Boiling Point Properties Molecular Weight Properties
14 10,00 10,00
15
16
17 8,00 8,00
18
Molecular Weight
19
Temperature
20
6,00 6,00
21
22
23
24 4,00 4,00
25
26
27 2,00 2,00
28
29
30
0,00 0,00
31
0,00 2,00 4,00 6,00 8,00 10,00 0,00 2,00 4,00 6,00 8,00 10,00
32
33 Percent Composition Percent Composition
34
35 Single Tray :
36
37
Density Properties
38 10,00
39
40
41 8,00
42
43
44
6,00
Density
45
46
47
48 4,00
49
50
51 2,00
52
53
54
0,00
55
0,00 2,00 4,00 6,00 8,00 10,00
56
57 Percent Composition
58
59
60
61
62
1
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5
6
8
9
10
11
Boiling Point Assay
12
14 Assay Percent
15
16 0.0 %
17 1.0 %
18 2.0 %
19 3.5 %
20 5.0 %
21 7.5 %
22 10.0 %
23 12.5 %
24 15.0 %
25 17.5 %
26 20.0 %
27 25.0 %
28 30.0 %
29 35.0 %
30 40.0 %
31 45.0 %
32 50.0 %
33 55.0 %
34 60.0 %
35 65.0 %
36 70.0 %
37 75.0 %
38 80.0 %
39 85.0 %
40 90.0 %
41 92.5 %
42 95.0 %
43 96.5 %
44 98.0 %
45 99.0 %
46 100.0 %
47
48
50 Assay Percent
51
52 0.0 %
53 1.0 %
54 2.0 %
55 3.5 %
56 5.0 %
57 7.5 %
58 10.0 %
59 12.5 %
60 15.0 %
61 17.5 %
62 20.0 %
1
4 USA
5
6
8
9
10
11
12
13 Assay Percent
14
15 25.0 %
16 30.0 %
17 35.0 %
18 40.0 %
19 45.0 %
20 50.0 %
21 55.0 %
22 60.0 %
23 65.0 %
24 70.0 %
25 75.0 %
26 80.0 %
27 85.0 %
28 90.0 %
29 92.5 %
30 95.0 %
31 96.5 %
32 98.0 %
33 99.0 %
34 100.0 %
35
Density Assay
36
38 Assay Percent
39
40 0.0 %
41 1.0 %
42 2.0 %
43 3.5 %
44 5.0 %
45 7.5 %
46 10.0 %
47 12.5 %
48 15.0 %
49 17.5 %
50 20.0 %
51 25.0 %
52 30.0 %
53 35.0 %
54 40.0 %
55 45.0 %
56 50.0 %
57 55.0 %
58 60.0 %
59 65.0 %
60 70.0 %
61 75.0 %
62 80.0 %
1
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5
6
8
9
10
11
Density Assay
12
13 Assay Percent
14
15 85.0 %
16 90.0 %
17 92.5 %
18 95.0 %
19 96.5 %
20 98.0 %
21 99.0 %
22 100.0 %
23
User Properties
24
25 Assay Percent
26
27 0.0 %
28 1.0 %
29 2.0 %
30 3.5 %
31 5.0 %
32 7.5 %
33 10.0 %
34 12.5 %
35 15.0 %
36 17.5 %
37 20.0 %
38 25.0 %
39 30.0 %
40 35.0 %
41 40.0 %
42 45.0 %
43 50.0 %
44 55.0 %
45 60.0 %
46 65.0 %
47 70.0 %
48 75.0 %
49 80.0 %
50 85.0 %
51 90.0 %
52 92.5 %
53 95.0 %
54 96.5 %
55 98.0 %
56 99.0 %
57 100.0 %
58
59
60
61
62
1
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5
6
8
9
10
11
12 Temperature vs. Tray Position from Top
13 220
14
200
15
16 180
17
18 160
Temperature (C)
19
140
20
21 120
22
23 100
24
80,0
25
26 60,0
27
28 40,0
29
20,0
30
0 2 4 6 8 10 12
31
32
33
34
35 Pressure vs. Tray Position from Top
36 106
37
105
38
39 104
40
41 103
Pressure (kPa)
42
102
43
44 101
45
46 100
47
99,0
48
49 98,0
50
51 97,0
52
96,0
53
0 2 4 6 8 10 12
54
55
56
57
58
59
60
61
62
1
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5
6
8
9
10
11
12 Flow vs. Tray Position from Top
13 45,0
Vapour
14
40,0 Liquid
15
16
Net Molar Flow (kgmole/h)
35,0
17
18
30,0
19
20 25,0
21
22 20,0
23
24 15,0
25
26 10,0
27
28 5,00
29
0,000
30
0 2 4 6 8 10 12
31
32
33
34
35 Column Properties vs. Tray Position from Top
36 1,20e+003 100
Density(Light)
37
Mol Weight(Light) 90,0
38
1,15e+003
39
80,0
40
41
Density (kg/m3)
1,10e+003 70,0
42
43 60,0
44 1,05e+003
45 50,0
46
47 1,00e+003 40,0
48
49 30,0
50 950
51 20,0
52
900 10,0
53
0 2 4 6 8 10 12
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
11
12 Composition vs. Tray Position from Top
13 1,00
n-Butane (Light)
14
0,900 Oxygen (Light)
15
Nitrogen (Light)
16 0,800
MaleicAnhydr (Light)
17
18 0,700
Mole Fraction
19
0,600
20
21 0,500
22
23 0,400
24
0,300
25
26 0,200
27
28 1,00e-001
29
0,000
30
0 2 4 6 8 10 12
31
32
33
34
35 K-Value vs. Tray Position from Top
36 1,80e+005
n-Butane
37
1,60e+005 Oxygen
38
Nitrogen
39
1,40e+005 MaleicAnhydr
40
41
1,20e+005
42
K Value
43 1,00e+005
44
45 8,00e+004
46
47 6,00e+004
48
49 4,00e+004
50
51 2,00e+004
52
0,000
53
0 2 4 6 8 10 12
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
10
11
12 Component Ratio vs. Tray Position from Top
13 6,00e+028
Light
14
15
5,00e+028
16
17
Mole Fraction Ratio
18
4,00e+028
19
20
21 3,00e+028
22
23
24 2,00e+028
25
26
27 1,00e+028
28
29
0,000
30
0 2 4 6 8 10 12
31
32
33
34
35
36
Column Temperature / Pressure Profile
37
38 Column Stage Temperature Pressure
39 (C) (kPa)
40 Condenser 21.53 101.3
41 1__Main Tower 99.49 101.3
42 2__Main Tower 99.81 101.3
43 3__Main Tower 99.85 101.3
44 4__Main Tower 100.3 101.3
45 5__Main Tower 107.4 101.3
46 6__Main Tower 107.6 101.3
47 7__Main Tower 108.3 101.3
48 8__Main Tower 118.4 101.3
49 9__Main Tower 163.2 101.3
50 10__Main Tower 196.2 101.3
51 Reboiler 201.5 101.3
52
Column Flow Profile
53
54 Options Selected
55 Molar flow is selected Net is selected as flow basis
58 Condenser 2.530e-007 18.60
59 1__Main Tower 27.90 21.22
60 2__Main Tower 30.52 21.22
61 3__Main Tower 30.52 21.20
62 4__Main Tower 30.50 20.92
1
4 USA
5
6
8
9
10
13 5__Main Tower 30.21 40.68
14 6__Main Tower 31.33 40.66
15 7__Main Tower 31.31 40.21
16 8__Main Tower 30.86 36.78
17 9__Main Tower 27.44 35.31
18 10__Main Tower 25.97 38.85
19 Reboiler 29.51 9.347
20
Column Properties Profile
21
22 Options Selected
23 Mass basis is selected
24 Stage Surf Tens Mol Wt Dens Visc Therm Con Heat Cap
25 L-Liq L-Liq L-Liq L-Liq L-Liq
26 (dyne/cm) (kg/m3) (cP) (W/m-K) (kJ/kg-C)
27 Condenser 71.5 18.8 983 0.912 0.590 4.10
28 1__Main Tower 58.6 18.1 946 0.276 0.681 4.19
29 2__Main Tower 58.6 18.0 947 0.280 0.681 4.19
30 3__Main Tower 59.2 18.1 948 0.276 0.681 4.19
31 4__Main Tower 70.7 19.3 963 0.294 0.669 4.02
32 5__Main Tower 239 37.1 1.09e+003 0.498 0.499 2.83
33 6__Main Tower 240 37.2 1.09e+003 0.498 0.498 2.83
34 7__Main Tower 254 38.7 1.09e+003 0.511 0.485 2.78
35 8__Main Tower 409 56.3 1.13e+003 0.602 0.348 2.41
36 9__Main Tower 620 89.3 1.15e+003 0.523 0.154 2.18
37 10__Main Tower 606 97.2 1.12e+003 0.404 0.116 2.20
38 Reboiler 599 98.0 1.12e+003 0.388 0.112 2.21
39
40
41
Column Composition Profile
42
43 Options Selected
44 Fraction is selected as the composition basis Net is selected as flow basis
46 Stage n-Butane Oxygen Nitrogen MaleicAnhydr
47 L-Liq L-Liq L-Liq L-Liq
48 Condenser 0.0194 0.0000 0.0000 0.0000
49 1__Main Tower 0.0017 0.0000 0.0000 0.0000
50 2__Main Tower 0.0006 0.0000 0.0000 0.0000
51 3__Main Tower 0.0006 0.0000 0.0000 0.0008
52 4__Main Tower 0.0006 0.0000 0.0000 0.0156
53 5__Main Tower 0.0005 0.0000 0.0000 0.2380
54 6__Main Tower 0.0001 0.0000 0.0000 0.2391
55 7__Main Tower 0.0000 0.0000 0.0000 0.2583
56 8__Main Tower 0.0000 0.0000 0.0000 0.4779
57 9__Main Tower 0.0000 0.0000 0.0000 0.8903
58 10__Main Tower 0.0000 0.0000 0.0000 0.9887
59 Reboiler 0.0000 0.0000 0.0000 0.9990
60
61
62 Options Selected
1
4 USA
5
6
8
9
10
11
12
14
Key Components
15
17 n-Butane On n-Butane Off
18 Oxygen On Oxygen Off
19 Nitrogen On Nitrogen Off
20 MaleicAnhydr On MaleicAnhydr Off
21 CO2 Off CO2 On
22 CO Off CO On
23 Acetone Off Acetone Off
24 H2O Off H2O Off
25 Stage Light Liq
26 Condenser 403.2
27 1__Main Tower 1.652e+005
28 2__Main Tower 2.109e+005
29 3__Main Tower 4.157e+005
30 4__Main Tower 5.064e+006
31 5__Main Tower 6.695e+007
32 6__Main Tower 2.074e+011
33 7__Main Tower 6.849e+014
34 8__Main Tower 3.557e+018
35 9__Main Tower 1.459e+022
36 10__Main Tower 3.063e+025
37 Reboiler 5.579e+028
38
Column K-Values Profile
39
40 Tray Number n-Butane Oxygen Nitrogen MaleicAnhydr
41 Condenser 2.044 3.386e+004 6.451e+004 3.854e-004
42 1__Main Tower 11.22 6.401e+004 1.085e+005 3.236e-002
43 2__Main Tower 11.27 6.484e+004 1.103e+005 3.281e-002
44 3__Main Tower 11.28 6.488e+004 1.105e+005 3.287e-002
45 4__Main Tower 11.35 6.467e+004 1.142e+005 3.346e-002
46 5__Main Tower 12.58 5.948e+004 1.542e+005 4.536e-002
47 6__Main Tower 12.62 5.962e+004 1.548e+005 4.572e-002
48 7__Main Tower 12.75 5.903e+004 1.569e+005 4.715e-002
49 8__Main Tower 14.56 5.078e+004 1.622e+005 7.097e-002
50 9__Main Tower 20.84 2.754e+004 1.727e+004 0.3374
51 10__Main Tower 26.33 3.385 1.000 0.8609
52 Reboiler 27.24 1.000 1.000 0.9864
53
NOTES
54
55
56
57 Separator: V-100
58
59
60
CONNECTIONS
61
62
Inlet Stream
1
4 USA
5
6
7 Separator: V-100 (continued)
8
10 2
11
12
Outlet Stream
13 Stream Name To Unit Operation
14 3 Compressor: K-100
15 4
16
17
Energy Stream
19
20
21
PARAMETERS
22 Vessel Volume: --- Level SP: 50.00 % Liquid Volume: ---
23 Vessel Pressure: 101.3 kPa Pressure Drop: 0.0000 kPa Duty: 0.0000 kJ/h Heat Transfer Mode: Heating
24
25
User Variables
26
27
RATING
28
29
Sizing
30 Cylinder Vertical Separator has a Boot: No
31 Volume: --- Diameter: --- Height: ---
32
33
Nozzles
34 Base Elevation Relative to Ground Level 0.0000 m * Diameter --- Height ---
35 2 3 4
36 Diameter (m) 5.000e-002 5.000e-002 5.000e-002
37 Elevation (Base) (m) 0.0000 0.0000 0.0000
39 Elevation (% of Height) (%) --- --- ---
40
41
Level Taps: Level Tap Specification
42 Level Tap PV High PV Low OP High OP Low
43
44
Level Taps: Calculated Level Tap Values
45 Level Tap Liquid Level Aqueous Level
46
47
Options
48 PV Work Term Contribution (%) 100.00 *
49
50
CONDITIONS
51 Name 2 4 3
52 Vapour 1.0000 0.0000 1.0000
53 Temperature (C) 25.0000 * 25.0000 25.0000
54 Pressure (kPa) 101.3250 * 101.3250 101.3250
56 Mass Flow (kg/h) 16225.1036 0.0000 16225.1036
60 Heat Flow (kJ/h) -4.5777e+03 -0.0000e-01 -4.5777e+03
61
62
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name 2 4 3
14 Mass Density (kg/m3) 1.180 1.155 1.180
15 Act. Volume Flow (m3/h) 1.375e+004 0.0000 1.375e+004
23 CO2 Loading --- --- ---
24 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
25 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
27 Phase Fraction [Vol. Basis] 1.000 --- 1.000
29 Phase Fraction [Act. Vol. Basis] 1.000 --- 1.000
30 Mass Exergy (kJ/kg) -2.896e-006 -6.391e-003 -2.896e-006
33 Act. Gas Flow (ACT_m3/h) 1.375e+004 --- 1.375e+004
34 Avg. Liq. Density (kgmole/m3) 29.98 --- 29.98
36 Std. Gas Flow (STD_m3/h) 1.330e+004 0.0000 1.330e+004
38 Act. Liq. Flow (m3/s) --- 0.0000 ---
39 Z Factor 0.9995 --- ---
40 Watson K 6.042 6.309 6.042
43 Cp/(Cp - R) 1.398 1.147 1.398
44 Cp/Cv 1.401 1.147 1.401
45 Ideal Gas Cp/Cv 1.399 1.399 1.399
48 Heat of Vap. (kJ/kgmole) 5952 5688 5952
51 Liq. Vol. Flow (Std. Cond) (m3/h) --- 0.0000 ---
52 Liquid Fraction 0.0000 1.000 0.0000
54 Mass Heat of Vap. (kJ/kg) 206.3 201.4 206.3
59 Viscosity (cP) 1.883e-002 6.698e-004 1.883e-002
62 Cv (kJ/kgmole-C) 20.84 56.69 20.84
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name 2 4 3
12 Mass Cv (kJ/kg-C) 0.7223 2.007 0.7223
15 Cp/Cv (Ent. Method) --- --- ---
16 Reid VP at 37.8 C (kPa) --- --- ---
17 True VP at 37.8 C (kPa) --- --- ---
20
21
DYNAMICS
22
23
Vessel Parameters: Initialize from Product
24 Vessel Volume (m3) --- Level Calculator Vertical cylinder
25 Vessel Diameter (m) --- Fraction Calculator Use levels and nozzles
26 Vessel Height (m) --- Feed Delta P (kPa) 0.0000
27 Liquid Level Percent (%) 50.00 Vessel Pressure (kPa) 101.3
28
29
Holdup: Vessel Levels
30 Phase Level Percent Volume
31 (m) (%) (m3)
32 Vapour --- --- 0.0000
33 Liquid --- --- 0.0000
34 Aqueous --- --- 0.0000
35
36
Holdup: Details
39 Vapour 0.0000 0.0000 0.0000
40 Liquid 0.0000 0.0000 0.0000
41 Aqueous 0.0000 0.0000 0.0000
42 Total 0.0000 0.0000 0.0000
43
44
NOTES
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62

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1

Case Name: SIMULACION.hsc

11 Name 10 @COL1 9 @COL1 12 @COL1 11 @COL1

21 Name 10 @COL1 9 @COL1 12 @COL1 11 @COL1

31 Name QCT101 @COL2 QHT101 @COL2

31 Name QPFR100 QK100 QE100 QE101 QCT101

Heterogeneous Catalytic: Rxn-1

Heterogeneous Catalytic: Rxn-1 (continued)

Heterogeneous Catalytic: Rxn-2

Heterogeneous Catalytic: Rxn-3

Heterogeneous Catalytic: Rxn-3 (continued)

23 1__Main Tower 62.2 18.5 949 0.373 0.656 4.14

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