CALCULATION

Activation Energy
1. Temperature goes up 2. Temperature goes down

t (s) T (K) ln t 1/T (K-1) t (s) T (K) ln t 1/T (K-1)

67.8 278.15 4.2165 0.00359 70,8 278,15 4,2598 0,003595
44 283.15 3.7841 0.00353 67,8 283,15 4,2166 0,003531
34 288.15 3.5264 0.00347 46 288,15 3,8286 0,00347
33 293.15 3.4965 0.00341 29 293,15 3,3673 0,00341
23 298.15 3.1355 0.00335 27 298,15 3,2958 0,00335

Activation Energy (In Activation Energy (In t

t vs 1/T) vs 1/T)
4.5 4.5
y = 4073.3x - 10.513 y = 4601.2x - 12.184
4 R² = 0.9411 4 R² = 0.9306
ln t

In t
3.5 3.5

3
3
0.00330.00340.00350.00360.0037
0.0033 0.0034 0.0035 0.0036 0.0037
1/T
1/T

Ea 1
ln t= ( ) +C Ea 1
R T ln t= ( ) +C
Ea R T
slope= Ea
R slope=
Ea=slope x R R
Ea=slope x R
R = 8.314 Joule/mol
R = 8.314 Joule/mol
Joule J
Ea=4073.3 x 8.314 =33,865.42 Joule J
mol mol Ea=4601.2 x 8.314 =38,254.38
mol mol
=33.86 kJ/mol
=38.25 kJ/mol
 ACTIVATION ENERGY

(33.86+38.25)kJ/mol
Average Ea= =36,05 kJ/mol
2

FREQUENCY FACTOR (A)

Addition of 1 mL 0.01 M Na2S2O3 (0.01 mmol)

S2O82- + 2 I-  2 SO42- + I2
initial 0.2 mmol 10 mmol
change 0.005 mmol 0.01 mmol 0.01 mmol 0.005 mmol
equilibrium 0.195 mmol 9.99 mmol 0.01 mmol 0.005 mmol

2 S2O32- + I2  2 I- + S4O62-
initial 0.01 mmol 0.005 mmol
change 0.01 mmol 0.005 mmol 0.01 mmol 0.005 mmol
equilibrium 0 0 0.01 mmol 0.005 mmol

[S2 O2-
8 ]o 0.2 1
= =
[S2 O2-
8 ]t 0.2-0.005 1-n

Where [S2O82-]o is the concentration of persulfate ions initially and [S2O82-]t is the
concentration of persulfate ions after reaction at certain time.
0.2 1
=
0.195 1- 1
n
1
1.025641=
1
1- n

n=40
From the graph

1 1
C= ln +ln ( )
A 1
1- n

C is the intercept of the previous graph

1st graph (Temperature goes up) 2nd graph (Temperature goes down)

1 1 1 1
-10.513= ln +ln ( ) =3.77 x 104 -12.184= ln +ln ( ) =2 x 105
A 1 A 1
1- 40 1- 40

(3.77 x 104 + 2 x 105 )

Average A= = 1,19 x 105
2