CHEMISTRY

46. The percentage by volume of C3H8 in a 3) 0.5 107 M 3 4) 5 107 M 3

gaseous mixture of C3H8, CH4 and CO is 20.
When 100 mL of the mixture is burnt in excess 53. In the spinal structure, oxides ions are cubical-
of O2, the volume of CO2 produced is: closest packed whereas 1/8th of tetrahedral
1) 90 mL 2) 160 mL
voids are occupied by A 2 cation and 1/2 of
3) 140 mL 4) none of these
47. The angular momentum of electron of H-atom octahedral voids are occupied by B3 cations.
is proportional to: (r = radius of orbit ) The general formula of the compound having
1 1 spinal structure is:
1) r 2 2) 3) r 4)
r r 1) A 2 B2O 4 2) AB2 O4
48. 1 mole of each of x1, x2, x3 with van der Waals 3) A 2 B4O 2 4) A 4 B2O 2
constants ‘a’ (in atm L3 mol-2) 1.0, 3.8, 2.1
respectively is kept separately in three 54. If Raoult’s law is obeyed, the vapour pressure
different vessels of equal volume at identical of the solvent in a solution is directly
temperature. Their pressures are observed to proportional to:
P1, P2 and P3 respectively. On the basis of this 1) Mole fraction of the solvent
data alone, select the correct option is (neglect 2) Mole fraction of the solute
the effect of ‘b’)
3) Mole fraction of the solvent and solute
1) P1  P2  P3 2) P2  P1  P3
4) The volume of the solution
3) P2  P3  P1 4) P1  P2  P3
55. P t Cl4 .6H 2 O can exist as a hydrated complex.
49. Determine the enthalpy of formation of
B2H6(g) in kJ/mol of the following reaction: Its 1 molal aq. solution has depression in
B2 H6  g   3O2 (g)  B2 O3  s   3H 2 O  g  ; freezing point of 3.72. Assume 100%
ionisation and K f  H 2 O   1.860 C mol1 kg ,
Given :  r H 0  1941kJ / mol;
then complex is:
H0f  B2 O3 ,s   1273 kJ / mol;
1)  Pt  H 2O 6  Cl4
H0f  H2 O, g   241.8 kJ / mol
1) 75.6 2) 75.6 2)  Pt  H 2O  4 Cl2  Cl 2 .2H 2O
3) 57.4 4) 28.4
3)  Pt  H 2O 3 Cl3  Cl.3H 2O
50. In a system A  s   2B  g   3C  g  , if the
4)  Pt  H 2O  2 Cl4  .4H 2O
concentration of C at equilibrium is increased
by a factor of 2, it will cause the equilibrium 56. Consider the following equations for a cell
concentration of B to change to: reaction
1) two times the original value  C  D;
A  B  E0  x volt, K eq  K1
2) one half of its original value
 2C  2D; E0  y volt, K eq  K 2
2A  2B 
3) 2 2 times to the original value
Then:
1
4) times the original value 1) x  y, K1  K 2 2) x  2y, K1  2K 2
2 2
3) x  y, K12  K 2 4) x 2  y, K12  K 2
51. The pH of a solution containing 0.4 M HCO3
57. The equilibrium constant for the following
and 0.2 M CO32 is:
general reaction is 1030.E0 for the cell at 298 K
 1  2

 K a  H 2CO3   4  10 7 ; K a HCO3  4 10 11 
 is:
1) 10.4 2) 10.1 2X 2  s   3Y 2  aq   2X32  aq   3Y  s 
3) 6.1 4) 10.7 1)  0.105 V 2)  0.2955 V
H
52. p of Ba  OH 2 solution is 12. Its solubility 3) 0.0985 V 4)  0.2955 V
product is

1) 106 M 3 2) 3 × 10 -5 M3
58. For a homogeneous gaseous reaction A  3B , 67. Which of the following equations depict the
if pressure after time t was Pt and after oxidising nature of H2O2?
completion of reaction, pressure was P then 1) 2MnO 4  6H   5H 2 O2 
select correct relation 2Mn 2  8H 2O  5O 2

1  P  2) 2Fe3  H 2O 2  2Fe 2  2H   O 2
1) k  ln  1  2P 
  2) k  ln   3) 2I   2H   H 2O2  I 2  2H 2O
t  3  P  Pt   t  3  P  Pt  
4) KIO4  H 2 O2  KIO3  H 2O  O 2
1  3P  1  2P 
3) k  ln   4) k  ln   68. On dissolving moderate amount of sodium
t  2  P  Pt   t  3  P  Pt   metal in liquid NH3 at low temperature, which
59. Which of the following process is not one of the following does not occur?
responsible for the presence of electric charge 1) Na+ ions are formed in the solution
2) Blue coloured solution is obtained
on the sol particles?
3) Liquid NH3 becomes good conductor of
1) Electron capture by sol particles electricity
2) Adsorption of ionic species from solution 4) Liquid NH3 remains diamagnetic
3) Formation of Helmholtz electrical double 69. Amorphous boron is extracted from borax by
layer. following steps:
X  Y
4) Absorption of ionic species from solution Borax  H3BO3   B2 O3  Boron
60. Ionic radii of: Then X and Y are:
1) Ti 4  Mn 7  2) Cr 6   Cr 3 1) H 2SO 4 , Mg 2) HCl, C

3) K  Cl 
4) P 3  P5 3) HCl, Fe 4) H 2SO 4 , H 2
61. In which of the following molecule/ion all the 70. Which of the following can not evolve
bonds are not equal? phosphine?
1) XeF4 2) BF4 1) white P4  Ca  OH 2  2) AlP  H 2 O 
3) C 2 H 4 4) SiF4 
3) H 3PO 4   4) PH 4 I  NaOH 
62. Which of the following order of bond angle is A B
not correct? 71. XeF6  SbF5  Cation  anion

1) NH3  NF3  PF3 2) N  SiH 3 3  N  CH 3 3 Incorrect statement for above changes is:
3) O  CH3 2  OCl2  NO 2 1) XeF6 act as F donar
4) All are correct 2) Hybridisation state of central atom in
63. Back bonding is present in dimer of: cationic part is sp 3 d 2
1) BF3 2) NO 2 3) anionic part is isostructural with  PCl6 


3) AlF3 4) BeCl2
4) Both cation and anion have identical shape
64. Select in which both have sea-saw shape?
72. Gadolinium belongs to 4f series. It’s atomic
1) XeO 2 F2 ,SiF4 2) XeO2 F2 , SF4
number is 64. Which of the following is the
3) TeCl 4 , ICl4 4) TeCl4 , XeOF2 correct electronic configuration of
65. Which one of the following complexes exhibit Gadolinium?
chirality?
3
1)  Xe 4f 7 5d1 6s2 2)  Xe 4f 6 5d 2 6s2
1) Cr  ox 3  2) cis   PtCl2  en  
3)  Xe 4f 8 6s2 4)  Xe 4f 9 6s1

3) cis   RhCl2  NH 3  2 
73. MnO24 (1 mole) in acidic medium
4) mer  Co  NO 2 3  NH3 3  disproportionate to:
66. In the extraction of copper from its sulphide 1) 2/3 mole of MnO 4 and 1/3 mole of MnO 2
ore, the metal is formed by the reduction of
Cu 2O with 2) 1/3 mole of MnO 4 and 2/3 mole of MnO 2
1) FeS 2) CO 3) 1/3 mole of Mn 2 O7 and 1/3 mole of MnO 2
3) Cu2S 4) SO2 4) 2/3 mole of Mn 2 O7 and 1/3 mole of MnO2
74. Which of the following has longest C – O COO K
bond? COO K
O O

1) COO K 2)
1) 2)
O

O
3) 4)
78. The major product formed in the reaction:
CH2 O
3) 4) Conc. HNO 3  H 2SO 4
C O 
75. Consider the following reaction and statements


 Co  NH 3 4 Br2   Br    Co  NH 3 3 Br3   NH 3
1)
I) Two isomers are produced if the reactant O
complex ion is a cis-isomer
C O
II) Two isomers are produced if the reactant
complex ion is a trans-isomer
III) Only one isomer is produced if the reactant NO2
complex ion is a trans-isomer O
IV) Only one isomer is produced if the reactant O2N C O
complex ion is a cis-isomer
2) 3)
The correct statement are
O
1) I and III 2) III and IV
3) II and IV 4) I and II C O
76. The absolute configuration of
HO C CO2H NO2
2
O
HO OH C O NO2
H H
4)
is:
1) S, S 2) R, R 79. Match the column I with column II and mark
3) R, S 4) S, R the appropriate choice.
77. Column – I Column – II
COOH Finkelstein C 6 H 5 N 2Cl  Cu 2 Cl 2
A) i)
reaction  HCl
KOH
CH3 CH CH CH3 
Electrolysis
 Pr oduct : B) Insecticides ii) Aniline+NaNO2 + HCl
COOH C) Diazotisation iii) CH3Cl + NaI
Sandmeyer’s
D) iv) DDT
reaction

A B C D
1) ii iii iv i
2) iii iv ii i
3) i ii iv iii
4) iv i iii ii
80. Which of the following is most basic? H3C CH3
CH 3
OH
CH 3
2)
CH3
1)
H 3C CH 3 OH
3)
H 3C CH3
H 3C OH
4)
2)
83. Arrange the following compounds in
decreasing order of nucleophilic addition
reaction:
O O
3)
CH3 C CH3 ; CH3 C Cl ;
I II
O O

CH3 C NH2 ; CH3 C OH ;

III IV
4) O O

CH3 C O C CH3
V
81. In the given reaction,
1) II > V > I > IV > III
H /H 2O 
2) III > IV > I > V > II
O CH 2 CH 3  P 3) II > I > V > III > IV
4) IV > III > V > I > II
P will be: 84. The oxidation states of Cr in
Cr  H 2O  6  Cl3 , Cr  C6 H 6 2  , and
OH O K 2 Cr  CN  2  O  2  O2  NH 3   respectively
1) 2) are
1) +3, +2 and +4 2) +3, 0 and +6
3) +3, 0 and +4 4) +3, +4 adn +6
CH2 OH
85. Which of the following is not a surfactant?
3) 4)
1) CH 3   CH 2 15  N   CH 3 3 Br 
82. Identify the product in the following reaction,
CH3 2) CH3   CH 2 14  CH 2 NH 2
H 3C
BH3 in THF
 3) CH3   CH 2 10  CH 2OSO3 Na 
H3C H 2 O2 /alkaline medium

CH 2 4) CH3  CH 2 11 C6 H 4SO3 Na 

H 3C CH3

H3C OH
CH 3
1)
86. NH 2
O Br Br Br Br

O and
LiAlH 4

CH3 CH 3

O
O OH 3)
NH 2
Br Br Br Br
O O
and

OH OH Br Br
1) 2)
4)
OH
NH 2
O Br Br
OH
and
O

OH CH 3 CH3
3) 4)
87. 88. Riboflavin deficiency causes:
NH 2 1) scurvy 2) pellagra
3) beri-beri 4) cheilosis
89. The numbers of chiral centers present in
Excess Br2 (i) NaNO 2 / HCl

 X  Y
H2 O (ii ) H 3PO2+H2O
glucopyranose and fructofuranose are:
1) 4 and 3 2) 5 and 4
3) 4 in each 4) 5 in each
CH 3 90. Given the polymers,
I = Nylon 6,6 II – Buna S
The compounds X and Y are: III = Polyethene
1) Arrange these in increasing order of inter
NH 2 molecular forces (lower to higher)
1) I > II > III 2) II < III< I
3) II > III > I 4) III < I < II
and
Br Br

CH 3 CH 3

2)