Mole Concept

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JEELIVE
Example What weight of AgCl will be precipitated when a solution containing 4.77g of
NaCl is added to a solution of 5.77g of AgNO3?

A. 4.87 g C. 6.23 g

B. 11.62 g D. 3.86 g
Example What is the number of moles of Fe(OH)3 that can be produced by allowing 1
mole of FeS3, 2 moles of H2O and 3 moles of O2 to react?
Example Equal weights of P and O are heated in a closed vessel producing P2O3 and
P2O5 in a 1:1 mole ratio. If the limiting component is exhausted, find which
component and what fraction of it is left over?
Principle of Atom Conservation - POAC
Example 27.6g of K2CO3 was treated by a series of reagents so as to convert all of its
carbon to K2Zn3[Fe(CN)6]2. Calculate the weight of the product.
Expressing Concentration of Solution

The amount of solute dissolved in per unit amount of solvent or solution is

called strength of solution.

There are various methods of measuring strength of a

solution
Mole fraction (X) Molality, m

Mass by Percent (% w/w) Molarity, M

Volume by Percent (% v/v)

Mass by Volume Percent (% w/v)

Parts per million (ppm)

Mole fraction (X)

Moles of
Mole fraction, = solute
X Total moles in
solution
Mass by Percent (% w/w)

Mass of solute
% w/w = × 100
Mass of solution
Volume by Percent (% v/v)

Vsolute
% v/v = × 100
Vsolution
Mass by Volume Percent (% w/v)

Wsolute
% w/v = × 100
Vsolution
Example Explain what does 20% w/w glucose in H2O, 35% v/v ethylene glycol in H2O
means

Solution:

20g glucose
a) 100g solution

80g H2O

35 ml of glycol
b) 100ml
solution
65 ml of H2O
Example Calculate the mass percentage of benzene (C6H6) and carbon tetrachloride
(CCl4), if 22 g of C6H6 is dissolved in 122 g of CCl4 .

Solution: