IM11B03A03-02E - 020 (GC M-II Basic Operation Start - Up) PDF

User's
Manual
GC1000 Mark II
Process Gas Chromatograph
Basic Operation and Startup
IM 11B03A03-02E
IM 11B03A03-02E
2nd Edition
<Toc> <Ind> <Rev> <Introduction> i
◆ Notice
● Regarding This Manual
1. This Manual should be passed on to the end user.
2. Read this manual carefully and fully understand how to operate this product before
you start operation.
3. Yokogawa makes no warranty of any kind with regard to this material, but not limited
to, implied warranties of merchantability for particular purpose.
4. All rights reserved. No part of this manual may be reproduced in any form without
Yokogawa’s written permission.
5. Great effort has been expended to ensure that the descriptions in this manual are
correct. Should you, however, come across a questionable area or note an inconsis-
tency, a telephone call or letter to Yokogawa.co.,ltd. noting the questionable area
would be highly appreciated.
6. The contents of this manual are subject to change without prior notice.
● Regarding Protection, Safety, and Prohibition Against Unauthorized Modifica-

tion.
1. For the protection and safe use of the product and the system controlled by it, be sure
to follow the instructions on safety described in this manual when handling the prod-
uct. In addition, if you handle the product in contradiction to these instructions, our
company does not guarantee safety.
2. The following safety symbol marks are used on the product concerned or in this
Manual :
WARNING
A WARNING sign denotes a hazard. It calls attention to procedure, practice, condition
or the like, which, if not correctly performed or adhered to, could result in injury or
death of personnel.
CAUTION
A CAUTION sign denotes a hazard. It calls attention to a procedure, practice, condi-
tion or the like, which, if not correctly performed or adhered to, could result in damage
to or destruction of part or all of the product.
IMPORTANT:
Indicates that operating the hardware or software in this manner may damage it or
lead to system failure.
NOTE:
Draws attention to information essential for understanding the operation and features.
TIP:
Gives information that complements the present topic.
Media No. IM 11B03A03-02E 2nd Edition : July. 2002 (YK) IM 11B03A03-02E 2nd Edition : July. 1. 2002-00
All Rights Reserved Copyright © 2001, Yokogawa Electric Corporation
<Toc> <Ind> <Rev> <Introduction> ii
See Also:
Gives the reference locations for further information on the topic.
Protective ground terminal:

In order to provide protection against electrical shock in case of a fault. This symbo
indicates that the terminal must be connected to ground prior to operation of equip-
ment.
Function ground terminal:

In order to provide protection against noise. This symbol indicates that the terminal
must be connected to ground prior to operation of equipment.
Alternating current
Indicates the power switch state “ON”.
Indicates the power switch state “Stand - by”.
Indicate the power switch state “OFF”.
3. If protection / safety circuits are to be used for the product or the system controlled by
it, they should be installed outside of the product.
4. When you replace parts or consumables of the product, use those specified by our
company.
5. Do not modify the product.
● Exemption from Responsibility

1. Yokogawa Electric Corporation does not make any warranties regarding the product
except those mentioned in the WARRANTY that is provided separately.
2. Yokogawa Electric Corporation assumes no liability to any party for any loss or dam-
age, direct or indirect, caused by the use or any unpredictable defect of the product.
● Regarding Software and set including Software Supplied by YOKOGAWA

1. Yokogawa makes no other warranties expressed or implied except as provided in its
warranty clause for software supplied Yokogawa.
2. Use this software with one specified computer only.
You must purchase another copy of the software for use with each additional com-
puter.
3. Copying this software for purposes other than backup is strictly prohibited.
4. Store the streamer or floppy disk (original medium) in a secure place.
5. Reverse engineering such as the disassembly of software is strictly prohibited.
6. No portion of the software supplied by Yokogawa may be transferred, exchanged, or
sublet or leased for use by any third party without prior permission by Yokogawa.
IM 11B03A03-02E 1st Edition : Oct.30,2001-00

<Toc> <Ind> <Rev> <Introduction> iii
◆ Warning/Caution Labels
● To ensure safety operation of this equipment, warning/caution labels are at-
tached on the equipment as follows. Check these labels for your safety opera-
tion.
[Left side] [Front] [Right side] [Back]

F0001.EPS
A B
The inside of the enclosure is high temperature after turning off the power.
Don’t touch the inside of the enclosure or the compponents, the protective gas
should be suoolied for more than one hour after turning off the power.
D E
F0002.EPS

<Toc> <Ind> <Rev> <Introduction> iv
◆ Introduction
Thank you for purchasing the GC1000 Mark II process gas chromatograph.
This manual describes the technical information on basic operation and startup of Model
GC1000D / GC1000S / GC1000T / GC1000E / GC1000W / GC1000C (Hereafter, it is
abbreviated as GC1000 Mark II) Process Gas Chromatograph.
Please lead the following respective documents before installing and using the GC1000
Mark II system.
● Documents Related to the GC1000 Mark II Process Gas Chromatograph

1. Instruction manuals
The product comes with the following instruction manuals.
■ Instruction manuals that do not depend upon the specifications of the product
(1) Overview (IM 11B03A03-01E)
(2) Basic Operation and Startup (IM 11B03A03-02E)
(3) Maintenance and Inspection Manual (IM 11B03A03-04E)
(4) LCD Panel Operation Manual (IM 11B03A03-05E)
(5) Alarm Message Manual (IM 11B03A03-06E)
and Installation Manual (TI 11B03A03-03E)
■ Instruction manuals that depend upon the specifications of the product

(1) GCMT Gas Chromatograph Maintenance Terminal Software Package Operation
Guide (IM 11B03G03-03E)
(2) Capture It! Manual (IM 11B3G1-02E)
■ Instruction manuals for related products

(1) Model GCCU Computing Unit for a gas chromatograph (IM11B03S03-01E)
(2) GCCU Utility Software Manual (IM11B3S2-02E)
(3) Analyzer Server User's Manual (IM11B5B1-01E)
(4) ASMT Analyzer Server Maintenance Terminal Operation Guide
(IM11B05A03-01E)
(5) GCIU Interface Unit (IM 11B5B2-01E)
and Hub GCHUB Installation Manual (TI 11B5C1-01E)

<Toc> <Ind> <Rev> <Introduction> v
2. Operation Data
Operation data is supplied with the operation manuals in the delivered package and con-
tains the following required to use the gas chromatographs.
● Process conditions and measurement range
● Instrument specifications and operating conditions
● Standard sample for calibration
● Column system and column
● Miscellaneous data
Chromatogram, base line, repeatability, power supply voltage variation, etc.
● Analyzer flow diagram and installation
● Parts composition table
● General connection diagram
● Sampling system diagram (only if supplied by Yokogawa)
● Is the System Ready?

Before reading this manual, the following preparations must have been completed.
● The system must be unpacked and installed in the correct place.
● The piping for the utility gases such as carrier and calibration gases must be com-
pleted, followed by leak checking.
● The wiring for the power supply and others must be completed.
If these have not been completed yet, see the Installation Manual (TI 11B03A03-03E).
After completion, return to this manual and do the following:
● If the system power is on, turn off the power.
● Shut off all the gases at the flow control units.
Please read the following respective cautions (General Precautions, Caution of
using Explosion-Protection Instruments, on Piping Construction, and on Piping
Work) before installing and using the GC1000 system.
IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

<Toc> <Ind> <Rev> <Introduction> vi
● General Precautions
WARNING
(1) In order to analyze gases, process gas chromatographs use a sample of the process
gas and utility gases.
Since these gases are typically combustible, combustion-sustaining, toxic,
odorous, resolvable, polymerizing, or corrosive, refer to the “Safety Informa-
tion” in our approval drawings and others to ensure safety thoroughly before
using these analyzers.
(2) Up to two protection systems, each of which weighs approximately 10 kg, are installed
on top of the GC1000. Therefore, the center of gravity is higher than the center of the
analyzer body.
Take great care when carrying and installing (piping- wiring) the GC1000. The
GC1000 must be carried and installed very carefully (including piping and
wiring) by more than one person (at least four people are recommended).
(3) Since the GC1000 are precision instruments, take care when handling not to
jolt of knock them.
(4) Use the GC1000 within the range of your purchase specifications.
Yokogawa assumes no responsibility for problems resulting from use by the customer
outside the purchase specifications.
If the GC1000 need to be modified or repaired, please contact your nearest Yokogawa
representative. Yokogawa assumes no responsibility for results where the customer or
any third party has attempted to modify or repair these products.
(5) When touching LCD Panel switches
When touching LCD Panel switches, first, discharge Electro Static Charge of the body.
Then, touch the LCD Panel switches. If not, LCD display may be changed by Electro
Static Discharge.
IMPORTANT:
(1) Read the attached instruction manual before operating the GC1000
(2) The instruments must be installed and operated according to the installation manual,
instruction manual, approval drawings, and operation data.

<Toc> <Ind> <Rev> <Introduction> vii
● CAUTIONS OF USING EXPLOSION-PROTECTION INSTRUMENTS
The GC1000 Process Gas Chromatographs are designed to protect against explosion.
When these analyzers are used in a hazardous area, observe the following precautions.
Since the applicable standard differs depending on the specifications of the analyzer to be
used, check the specifications of your analyzer.
(1) Kinds of explosion protection

To assure explosion protection, the GC1000 Process Gas Chromatographs have a pres-
surized and flameproof construction, or type X purging and explosionproof construction
meeting the following standards :
<GC1000D / GC1000S>
• JIS Expd IIB + H2 T1 (programmed-temperature oven 320˚C max., isothermal oven
225˚C max., liquid-sample valve 250˚C max.)
<GC1000W / GC1000C>
CENELEC (ATEX directive) certified : Group II Category 2G
• EEx pd II B +H2 T1 (programmed-temperature oven 320°C max, isothermal oven
225°C max., liquid-sample valve 250°C max.)
• EEx pd II B +H2 T4 (programmed-temperature oven 95°C max, isothermal oven 95°C
max., liquid-sample valve 95°C max.)
<GC1000T / GC1000E>
FM Type X purging and Explosionproof for CLI, DIV1, GPS B, C & D, NEMA3R.
Type Y purging and Type X purging for CLI, DIV1, GPS B, C & D, NEMA3R.
• T1 (programmed-temperature oven 320˚C max., isothermal oven 225˚C max., liquid-
sample valve 250˚C max.)

<Toc> <Ind> <Rev> <Introduction> viii
CSA Type X purging and Explosionproof for CLI, DIV1, GPS B, C & D, TYPE3R.
Type Y purging and Type X purging for CLI, DIV1, GPS B, C & D, TYPE3R.
(2) Precautions for Explosionproof section (The analyzer with optional code
"FM/CSA Type Y purging" does not have the explosionproof section.)
When handling the screws on the cover of the Protection system, note the following to
avoid damaging the screws since they cannot be repaired.
(1) The enclosure is pressurized. Before removing the cover, reduce the internal pres-
sure by loosening the sealing plug for wiring on the enclosure or relevant means.
(2) When removing the cover, prevent any dirt or foreign matter from contaminating the
screw part.
(3) When installing the cover, tighten the screws by hand ; never use tools.
(4) Since the screws are coated with MOLYKOTE, do not lubricate them.
(3) Precautions when using hydrogen gas

When using hydrogen gas as the carrier gas, the FID or FPD combustion gas, to ensure
safety, install the analyzer in a location equipped with a ventilator or where there is suffi-
cient ventilation. Make sure there are no gas leaks from the pipe joints and inspect for
leaks.
(4) Installation site and environment

The analyzer specifications allow it to be used in hazardous areas as defined by Zone1 IIB
+ H2T1, T2, T3, T4 (JIS / CENELEC) or DIV1, GPS B, C & D, T1, T2, T3, T4 (FM / CSA).
However, never install the analyzer in an area where the density of explosive gas persists
for a long time.
(5) Wiring works

Model GC1000D / GC1000S, analyzer obtains explosion proof authorization by the com-
plete set including metal fittings of the attachment.
When performing wiring, always use the attached sealing fittings and flameproof packing
adapter.

<Toc> <Ind> <Rev> <Introduction> ix
(6) Maintenance and inspection
During usual maintenance and inspection, it is not necessary to check the explosion-
protected section.
Before opening the door of the explosion-protected section for maintenance and inspec-
tion, be sure to turn off the power. After completing maintenance and checks, close the
door completely then turn on the power after checking that the specified explosion protec-
tion performance is guaranteed. The parts to be checked are described in the Maintenance
and Inspection Manual (IM 11B03A03 - 04E).
If any of the following damage occurs, contact a Yokogawa sales representative or the
Yokogawa sales division
(1) If the screws securing the Protection System (explosionproof construction) are dam-
aged
(2) If the exterior or light transmission section of the enclosures is damaged
(3) If packings are cracked or conspicuously deformed
(7) Override function (The analyzer with optional code "FM/CSA Type Y purg-
ing" does not have this function.)
WARNING
• When the override function is used, Analyzer becomes an ignition source and the high
temperature and the high voltage part will be exposed.
• Please confirm that in the ambient atmosphere, the concentration of explosive gases
is less than the allowable limit, by using a gas detector.
To return to the normal operation, turn off “the override switch” and then close the door as it
was before turning on power.
In this analyzer, if the pressure of the pressurized / type X purged enclosure system (oven,
electronic section) drops while the power is on, the pressurized explosion protection sec-
tion is activated to stop power supply. Therefore, in case of opening the door of the oven or
of the electronic section inadvertently, for maintenance, while the power is on, the protec-
tion system is activated to cut off the power.
The “override function” intensively releases this function of protection system.
The override switch is installed in section.
(8) Replacing parts

Always use parts specified by Yokogawa when replacing parts, for replacement, refer to the
Maintenance and Inspection Manual (IM 11B03A03 - 04E).

<Toc> <Ind> <Rev> <Introduction> x
(9) Operation
WARNING
<CENELEC>
* Only trained persons may use this instrument in a hazardous location.
* Do not open when energized.
<FM>
For type X purging:
* This equipment contains components that operate at high temperature. The equip-
ment shall be deenergized for 60 minutes to permit those components to cool before
the enclosure is opened unless the area is demonstrated to be nonhazardous at the
time.
* Enclosure shall not be opened unless the area is known to be nonhazardous, or
unless all devices within have been de-energized.
* Power shall not be restored after enclosure has been opened until enclosure has
been purged for 12 minutes. (When the internal pressure is restored, the system
automatically purges over the 12 minutes, then turns on the power again.)
For explosionproof enclosure:
* Seal all conduits within 18 inches
* Open circuit before removing cover.
For type Y purging:
* Enclosure shall not be opened unless the area is known to be non-hazardous, or
unless all devices within have been de-energized. Power shall not be restored after
enclosure has been opened until enclosure has been purged for 12 minutes at speci-
fied pressure indicated by the pressure gauge labeled “EL.BOX” in the pressure and
flow control section.
* Alarm shall be provided and connected to alarm contact output.
(a) The alarm shall generate a visual or audible signal that attracts attention
(b) The alarm shall be located at constantly attended location.
(c) Electrical alarms shall be approved for the location in which they are installed.

<Toc> <Ind> <Rev> <Introduction> xi
<CSA>
For type X purging:
* This equipment contains components that operate at high temperature. The equip-
ment shall be deenergized for 60 minutes to permit those components to cool before
the enclosure is opened unless the area is demonstrated to be nonhazardous at the
time.
unless all devices within the enclosure have been de-energized. Power must not be
restored after enclosure has been opened until enclosure has been purged for 12
minutes at a flow rate of 0.05m3/min.
* Power will automatically be removed when purge pressure falls below 40 mm (1.6 in)
of water column.
For explosionproof enclosure:
* A seal shall be installed within 50 cm of the enclosure.
* Open circuit before removing cover.
For type Y purging:
unless all devices within the enclosure have been de-energized. Power must not be
restored after enclosure has been opened until enclosure has been purged for 12
minutes at a flow rate of 0.05m3/minute min.
* Remove power below 40mm (1.6in) of water column.
Take care not to generate mechanical spark when accessing to the instrument and periph-
eral devices in hazardous locations.
Do not press prick the keyboard of LCD panel (operation and display section) using such
as knives and sticks.
(10) Maintenance and Repair

The instrument modification or parts replacement by other than authorized representative
of Yokogawa Electric Corporation is prohibited and will void the approval of Factory Mutual
Research Corporation and CSA certification and CENELEC certification .

<Toc> <Ind> <Rev> <Introduction> xii
● Precautions Against Electrostatic Problems
The GC1000 system uses numerous IC components. When handling cards with IC
components mounted on them for maintenance or setting changes, take full precau-
tions against electrostatic problems.
These precautions are summarized below.
(a) When storing or carrying cards, enclose them in a conductive bag or antistatic
bag. (Cards as shipped by Yokogawa are enclosed in a conductive bag or
antistatic bag labeled with cautions against electrostatic problems.)
(b) Whenever mounting or demounting cards into or from a product, wear a wrist
strap grounded via a 1 MΩ resistance. Connect the wrist strap to any ground
terminal near the ground wire or to any unpainted part of the grounded frame.
Gard List strap

Sheet
List strap
1M‰
F0003.EPS
Using a wrist strap and conductive sheet Using a Conductive Sheet
(c) When servicing cards on the bench, place them on a conductive sheet
grounded via a 1 MΩ resistance, wearing a wrist strap as in (2) above. Keep
easily-chargeable plastic materials away from the bench.
(d) Never touch components mounted on the cards, the pattern side, connectors,
pin components, etc. with bare hands, unless using a wrist strap and a conduc-
tive sheet.
(e) Wrist straps and conductive sheets are available from Yokogawa Engineering
Service (YSV).

<Int> <Ind> <Rev> Toc-1
GC1000 Mark II Process Gas Chromatograph

Basic Operation and Startup
IM 11B03A03-02E 2nd Edition
CONTENTS
◆ Notice ............................................................................................................ i
◆ Warning/Caution Labels ............................................................................... iii
◆ Introduction.................................................................................................. iv
1. How to Set, Measure, and Check the Statuses of the Analyzer .................. 1-1
1.1 How to Check the Status Indication of the Protection System ............................ 1-1
1.2 How to Operate the LCD Panel ................................................................. 1-4
1.3 How to Check the Temperature at Each Part ..................................................... 1-6
1.4 How to Check the Operating Status of the Detector ........................................... 1-8
1.4.1 TCD .................................................................................................. 1-8
1.4.2 FID ................................................................................................... 1-9
1.4.3 FID with Methane Converter ............................................................. 1-9
1.4.4 FPD ................................................................................................ 1-10
1.5 How to Measure/Set the Pressure and Flow Rate of Various Gases ................. 1-11
1.6 How to Check the Analysis Result ................................................................... 1-12
1.7 How to Check the Alarm .................................................................................. 1-14
1.8 How to Check the Chromatogram ................................................................... 1-16
2. Startup ........................................................................................................... 2-1
2.1 Preparations and Checks Before Supplying Power ........................................... 2-1
2.1.1 Preparations and Checks of Miscellaneous Equipment ..................... 2-1
2.1.2 External Piping Check ...................................................................... 2-1
2.1.3 External Wiring Check ...................................................................... 2-1
2.1.4 Air Supply ......................................................................................... 2-1
2.1.5 Steam Supply ................................................................................... 2-1
2.1.6 Supply of Various Cylinder Gases ..................................................... 2-2
2.1.7 In case of GC1000T Type Y Purging and GC1000E Type Y Purging . 2-2
2.2 Operation After Power Delivery ......................................................................... 2-3
2.2.1 Power Supply ................................................................................... 2-3
2.2.2 Date/Time Setting ............................................................................. 2-3
2.2.3 Checking the Set Values ................................................................... 2-4
2.2.4 Supply of Combustion Hydrogen or Makeup Gas, and Combustion Air2-4
2.3 Detector ON/OFF Operation ............................................................................. 2-5
2.3.1 TCD .................................................................................................. 2-5

<Int> <Ind> <Rev> Toc-2
2.3.2 FID and FID with Methane Converter ................................................ 2-6
2.3.3 FPD .................................................................................................. 2-7
2.3.4 Base Line Check .............................................................................. 2-7
2.4 Standard Sample (Gas or Liquid) Measurement ................................................ 2-8
2.4.1 Connection of the Standard Gas Cylinder or Standard Liquid Tank ... 2-8
2.4.2 Displacement of the Standard Sample Line ...................................... 2-8
2.4.3 Measurement of a Standard Sample ................................................. 2-9
2.5 Calibration ...................................................................................................... 2-10
2.5.1 Types of Calibration Methods .......................................................... 2-10
2.5.2 Calibration Method ......................................................................... 2-12
2.5.3 Confirmation of Parameter Settings ................................................ 2-12
2.5.4 Calibration Command ..................................................................... 2-14
3. Normal Operation (Continuous Measurement of Process Samples) .......... 3-1
3.1 Setting of Stream Sequence ............................................................................. 3-1
3.2 Setting of Process Sample Pressure/Flow Rate ................................................ 3-1
3.3 Starting the Operation ....................................................................................... 3-2
3.4 Ending the Operation ........................................................................................ 3-2
3.5 Precautions for Long-term Shutdown ................................................................ 3-2
◆ Revision Record ............................................................................................ i

<Toc> <Ind> <1. How to Set, Measure, and Check the Statuses of the Analyzer > 1-1
1. How to Set, Measure, and Check the

Statuses of the Analyzer
1.1 How to Check the Status Indication of the

Protection System
(1) GC1000D/T Type X Purging/W and GC1000S/E Type X Purging/C
Figure 1.1 shows the status indicators of the GC1000D/T/W and the GC1000S/E/C.
Window
LED lighting status
can be checked.
C. OVEN PRESS.
I. OVEN PRESS. POWER EL. BOX PRESS.

PURGING
GC1000D/T/W
Window
LED lighting status
can be checked.
I. OVEN PRESS. POWER EL. BOX PRESS.

PURGING
GC1000S/E/C
F0101.EPS
Figure 1.1 Status Indicators
By the status (lit/unlit) of the LEDs, which are visible through the window on the protection
system, conditions of power supply, internal pressure of the electrical box, isothermal oven
and column oven, and purging, can be checked.

The meaning of each LED is described below.
C. OVEN PRESS: Lit when the internal pressure of the column oven is the specified
pressure (approximately 400Pa) or greater.
I. OVEN PRESS: Lit when the internal pressure of the isothermal oven is the specified
EL. BOX PRESS: Lit when the internal pressure of the electrical box is the specified
POWER: Lit when power is supplied. However, power is supplied to the electri-
cal box after purging.
PURGING: Lit during purging. After the LED has been lit for about 12 minutes,
purging is completed. The LED turns off and power is automatically
supplied to the electrical box.
Operation of the protection system

Enclosures with a general pressurized explosion-proof structure, which does not allow
flammable gases to enter the enclosure, are purged or pressurized with a protection gas
such as air, nitrogen, and carbon dioxide so that no external gas or vapor can penetrate to
the inside, preventing an explosion to occur inside the enclosure.
As for the GC1000 Mark II, flammable gases such as a carrier gas, FID combustion gas,
and sample gas may enter the enclosure (i.e., the isothermal and column ovens), so a
special pressurized explosion-proof structure is provided. Penetration of external gases is
prevented by purging the enclosure with a specified amount of air (i.e., a protection gas).
Explosion inside the enclosure is also prevented by reducing the concentration of a flam-
mable gas to or below the specified value (1/4 of the lower explosive limit) if the flammable
gas leaks from the piping inside the enclosure.
The protection system is designed to monitor the status of air supply by measuring the
internal pressure of the enclosure so that it can determine whether the power should be cut
off or not, maintaining the pressurized explosion-proof integrity.
The protection system functions as follows:
(1) Starts measuring the internal pressure of each enclosure (i.e., the electrical box,
isothermal oven, and column oven) when power is supplied. During this measure-
ment, power is not supplied to the electrical box.
(2) Starts purging for about 12 minutes when the internal pressure of each enclosure
reaches the specified pressure (approximately 500Pa) after air is delivered at the
specified flow rate (approximately 100 to 150 L/min for GC1000S/E/C, 150 to 500 L/
min for GC1000D/T/W). Purging is to displace the contents of the enclosure with air
and is conducted by feeding air the volume of which is five times larger than the
enclosure capacity to the enclosure. The timer in the protection system automatically
measures the purging time.
(3) Automatically starts supplying power to the electrical box when purging is completed
with the internal pressure maintained. If the internal pressure decreases as a result of
interruption of the air supply during purging or of opening of the enclosure door,
purging is aborted. When the internal pressure increases again, purging is restarted.
(4) Shuts off power supply to the electrical box if the internal pressure decreases as a
result of interruption of the air supply or of opening of the enclosure door after power
has been supplied to the electrical box (i.e. normal operation status). When the
internal pressure increases, purging is restarted and upon the completion of purging,
power supply to the electrical box is started .

(2) GC1000T Type Y Purging and GC1000E Type Y Purging
The GC1000 Mark II with the Type Y purging version is not equipped with the protection
system. If the internal pressure decreases or during purging, the following alarms are
generated.
No.36 ELEC PRESS DOWN Decrease of the internal pressure of the electrical box
No.37 C-OVEN PRESS DOWN Decrease of the internal pressure of the column oven
No.38 I-OVEN PRESS DOWN Decrease of the internal pressure of the isothermal oven
No.39 PURGING Purging
Each status can be checked on the alarm display screen of the LCD panel.

1.2 How to Operate the LCD Panel

Screens described in this manual are based on the statuses after the power has been
turned on. After some operations taken on the LCD panel, screens may appear differently.
For details on the operating method, refer to the LCD Panel Operation Manual, IM
11B03A03-05E.
Figure 1.2 shows the LCD panel status after the power is turned on. The GC1000 Mark II
has two modes: REMOTE and LOCAL. In the REMOTE mode, various statuses and
settings can be checked but not changed. Select the LOCAL mode to change the statuses
and settings. To select the LOCAL mode, take the following procedure:
(1) Press the LOCAL/REMOTE key. (The screen shown in Figure 1.3 appears.)
(2) Enter the password.
(3) Press the SET/ENT key. (The screen shown in Figure 1.4 appears and the LOCAL
LED lights.)
Mark II PROCESS GAS

CHROMATOGRAPH
A B C D E F G H I
ALARM LOCAL POWER 1 2 3

J K L M N O P Q R
4 5 6
S T U V W X Y Z ∗
7 8 9
( ) + # $ : < > %
0
/ SP ,
BACK
CANCEL
SPACE
SET / ENT
F1 F2 F3 F4 F5 F6
STATUS RESULT ALARM TEMP CHROM
DISPLAY LOCAL/
OPERATION TABLE PREV NEXT
RESET REMOTE
F0102.EPS
Figure 1.2 Operation Screen
F0103.EPS
Figure 1.3 Communication Mode Switching Screen

F0104.EPS
Figure 1.4 Communication Mode Switching Screen

1.3 How to Check the Temperature at Each Part

After the power is applied to the GC1000 Mark II, the heater is turned on to start tempera-
ture control. When the TEMP key is pressed, the Temperature Status screen shown in
Figure 1.5 appears. The set temperature, present temperature, and heater ON/OFF status
of the column oven, isothermal oven, LSV, and detector, can be checked.
F0105.EPS
Figure 1.5 Temperature Status Screen
The terms used on the screen are explained below.

SV: Set temperature
PV: Present temperature
State/Remark
Temp stable: Heater is turned on to control the temperature of the isothermal oven at a
constant temperature (“Temp Stable” is also indicated during the tem-
perature rise after the power is turned on)
Ready: Heater is turned off
Temp Up: Heater is turned on to raise and control the temperature of the column
oven
ON: Heater is turned on
OFF: Heater is turned off
None: Not equipped
Turning on and off the heater is not required during the normal operation, startup, and other
occasions of the GC1000 Mark II. For your reference, the procedure for turning on and off
the heater is described below.
(1) Select the LOCAL mode. (Refer to Section 1.2, “How to Operate the LCD Panel”.)
(2) Press the OPERATION key. (The screen shown in Figure 1.6 appears.)
(3) Press the F3 key (Manual). (The screen shown in Figure 1.7 appears.)
(4) Press the NEXT key. (The screen shown in Figure 1.8 appears.)
(5) Move the cursor (>) to the item of interest.
(6) Press the SET/ENT key. The status changes from ON to OFF, or vice versa.
(7) Press the F2 key (Ope) to return to the Operation screen (Figure 1.6).

F0106.EPS
Figure 1.6 Operation Screen
F0107.EPS
Figure 1.7 Manual Operation Screen
F0108.EPS
Figure 1.8 Manual Operation Screen

1.4 How to Check the Operating Status of the Detector

The Operation screen shown in Figure 1.2 shows the types of detectors and their ON/OFF
statuses . There are four types of detectors: TCD, FID, FID with methane converter (re-
ferred to as “FI-CONV” on the screen), and FPD.
When the STATUS key and then the F2 key (Signal) are pressed, the Detector Status
screen (Figure 1.9) appears.
1.4.1 TCD
Figure 1.9 shows the Detector Status screen for the TCD.
F0109.EPS
Figure 1.9 Detector Status Screen (TCD)
Input signal: Indicates the value obtained by A-D converting the detector’s analog
signal sampled every 20 to 80 msec (depending on the sample rate)
and averaging the converted value with the value specified as a
sample rate.
Filter signal: Indicates the value obtained by filtering the input signal with the value
specified for “Filtering constant” of the “Detector Signal Set” screen.
Std deviation: Indicates the standard deviation of the past 20 input signals.
Input signal, filter signal and standard deviation are common items for all detectors.
Note: If the operation mode is in Stop, these items read 0.000 mV.
Voltage: Indicates the bridge voltage (V) of the TCD.

Current: Indicates the bridge current (mA) of the TCD.
The typical current by the carrier gas is as follows:
H2: 260 mA
He: 240 mA
N2: 120 mA
Ar: 100 mA

1.4.2 FID
Figure 1.10 shows the Detector Status screen for the FID.
F0110.EPS
Figure 1.10 Detector Status Screen (FID)
Input signal to Std deviation: See Section 1.4.1, “TCD”.

Flame level: The FID measures the flame temperature with a thermocouple and
identifies flame on/out using this value. As a typical value, 2 mV is set.
Therm signal: Output value of the thermocouple used to measure the flame tem-
perature of the FID (flame out: 0 mV, flame on: 3 to 6 mV).
Flame status: If the Therm signal is below the Flame level, “Flame Out” is indicated,
and if at or above the Flame level, “ Flame On “ is indicated.
1.4.3 FID with Methane Converter

Figure 1.11 shows the Detector Status screen for the FID with methane converter.
F0111.EPS
Figure 1.11 Detector Status Screen (FID with methane converter)

Flame level to Flame status: See Section 1.4.2, “FID”.
Voltage of metha-con: Indicates the voltage applied to the heater of the methane con-
verter. The voltage depends on the temperature of the isothermal
oven (normally 10 to 20 V).

1.4.4 FPD
Figure 1.12 shows the Detector Status screen for the FPD.
F0112.EPS
Figure 1.12 Detector Status Screen (FPD)

Flame level: The FPD measures the flame temperature with a thermocouple and
identifies flame on/out using this value. As a typical value, 1 mV is set.
Therm signal: Output value of the thermocouple used to measure the flame tem-
perature of the FPD. In normal burning, it is 2.5 to 3.5 mV. If the flow
rate of a carrier gas is greater than 50 ml/min, it may be 3 to 5 mV.
Flame status: See Section 1.4.2, “FID”.

1.5 How to Measure/Set the Pressure and Flow Rate of

Various Gases
The GC1000 Mark II uses gases such as a carrier gas, combustion gas for FID/FPD, and
combustion air for FID/FPD. Normal analysis cannot be expected unless the specified
value is set for each gas. Set the values according to the “Operational Condition Setting” of
the attached “Operation Data.”
The flow rate of each gas can be adjusted by the pressure regulator or restrictor. While
measuring the flow rate in a way described below, set the values according to the “Opera-
tion Data.”
The pressure of each gas can be checked by pressure gauges on the Flow Control unit.
Measure the flow rate of each gas by using a flow meter at each vent.
NOTE
Measure the pressure and flow rate of each gas after the temperatures of the isothermal
oven and column oven have fully stabilized. If the temperature is low, the pressure is likely
to be higher. The time required for the temperature to stabilize depends on the set tem-
perature: the isothermal oven with the temperature of below 146°C requires 2 to 4 hours,
and the one with the temperature of at or above 146°C requires 4 to 8 hours. For the FID
or FPD detector, the “Therm signal” on the Detector Status screen becomes 0 mV after the
temperature of the isothermal oven has stabilized (see Figure 1.10). This screen can be
viewed by pressing the STATUS key and F2 key (Signal) in order. See Section 1.4, “How
to Check the Operating Status of the Detector”.
For the FID and FPD, a carrier gas, combustion gas, and combustion air are discharged
together from the DET vent. Therefore, before measurement close the primary valves of
cylinders of gases that are not to be measured. For the FID and FPD, supplying the gas
may simply result in natural ignition. In the Flame on status, condensation forms on the
vent line and the “Therm signal” on the Detector Status screen indicates 2 to 6 mV. Mea-
sure the gas flow rate under the condition that the “Therm signal” is 0 mV.

1.6 How to Check the Analysis Result

Press the RESULT key to view the Latest Result screen shown in Figure 1.13.
F0113.EPS
Figure 1.13 Latest Result Screen
When the keys are pressed, the following items are displayed:
# (peak number), Composition (name), Conc. (concentration), R. Time (retention time),
Det# (detector number), S. Time. (peak on time), R. Time (retention time), E. Time (peak off
time), Gate on (time), Gate off (time), Tracking (gate tracking function), S. Level (peak on
signal level), T. Level (peak height), E. Level (peak off signal level), Area (peak area),
Shape (peak shape), H. width (peak half width), Tail (tailing coefficient), Varifactor (variation
factor), Calc. method (peak processing method)
For details on each item, refer to the LCD Panel Operation Manual, IM 11B03A03-05E, or
the Technical Guide, IM 11B03A03-03E.
When the F2 key (Conc) or F3 key (R.Time) is pressed on the Latest Result screen, the
Concentration Record (Figure 1.14) or R. Time Record (Figure 1.15) screen appears.
When the F6 key (Strm#) is pressed and a stream number is specified, the analysis result
of each stream is displayed.
F0114.EPS
Figure 1.14 Concentration Record Screen

F0115.EPS
Figure 1.15 Retention Time Record Screen

1.7 How to Check the Alarm

There are three levels of alarms for the GC1000 Mark II. These three levels are explained
below. For details, refer to the Alarm Message Manual, IM 11B03A03-06E.
• Level 1: An alarm if a system or hardware failure occurs. Once the alarm is gener-
ated, the alarm status will be held until the alarm is reset.
If a level-1 alarm is generated during the Run or Lab mode, the operation
mode changes to Stop after an ongoing measurement has been com-
pleted.
• Level 2: An alarm if a failure in the measurement conditions occurs. Once the alarm
is generated, the alarm status will be held until the alarm is reset.
• Component: An alarm if a measurement result such as concentration and retention time
becomes out of the specified range. Once the alarm is generated, the
alarm status will be held until the alarm is reset.
• Level 3: An alarm for signalling a minor error besides level-1 and level-2 alarms or
for information. The alarm status is not be held.
When the ALARM key is pressed, the Alarm Status screen (Figure 1.16) appears.
F0116.EPS
Figure 1.16 Alarm Status Screen
The screen shows the Total (i.e., total number of level-1, level-2, and Component alarms
that are currently occurring), ALM# (alarm number), Contents, and Date and Time of alarm
occurrence.
When the F2 key (Histry) is pressed on the Alarm Status screen, the Alarm Historical
Record screen shown in Figure 1.17 appears.
F0117.EPS
Figure 1.17 Alarm Historical Record Screen

The screen shows the Total (i.e., total number of alarms that have occurred), Date and
Time, “1” or “0” (“1”: alarm occurrence, “0”: alarm release), ALM# (alarm number), and
Contents. Up to 32 alarms can be displayed. When the number of alarms is more than 32,
the oldest alarm is deleted from the alarm historical record.

1.8 How to Check the Chromatogram

When the CHROM key is pressed, the Chromatogram screen shown in Figure 1.18 ap-
pears.
F0118.EPS
Figure 1.18 Chromatogram Screen
The F1 to F6 keys are used to manipulate the chromatogram display as follows.

F1 key (Det#): To switch between detector 1 and 2
F2 key (Scale#): To change the time scale
F3 key (Auto): If the time to be displayed is changed by pressing the

key, the chromatogram is not automatically updated. By pressing the
F3 key, automatic updating is restored.
F4 key (A.zero): To change the current position of the base line upward by one scale.
F5 key (Again): To change to the auto gain mode
F6 key (Mgain): To change the gain o chromatogram. When the gain is changed,
manual gain mode is set.

<Toc> <Ind> <2. Startup > 2-1
2. Startup
2.1 Preparations and Checks Before Supplying Power

Before turning on the power, prepare and check the following items.
For details on wiring, piping, and setting of operating conditions, refer to the supplied
“Operation Data.”
2.1.1 Preparations and Checks of Miscellaneous Equipment

Check the necessary miscellaneous equipment such as gas cylinders (carrier gas, com-
bustion hydrogen or makeup gas, standard gas), air, and steam, for operation. For the
carrier gas, combustion hydrogen, or makeup gas, prepare a new cylinder if the cylinder
charging pressure is 1 MPa or lower. For the standard gas, prepare a new cylinder if the
charging pressure is 5% or less of the maximum value.
2.1.2 External Piping Check

Make sure that all pipes are connected correctly according to the “Operation Data.” By
using soap water or a relevant means, make sure that there is no leak from each joint.
IMPORTANT
Do not use a pipe or joint that may be stained with oil or other dirt. Since dirt such as metal
powder may adhere inside the piping immediately after construction, perform full purging
with air before connecting to the GC1000 Mark II.
2.1.3 External Wiring Check

Make sure that all wires are connected correctly according to the “Operation Data.”
WARNING
Make sure that the supplied sealing fitting or packing adapter is used for wiring. If the
supplied fitting or adapter is not used, the explosion-proof structure cannot be maintained.
2.1.4 Air Supply

Start supplying the instrument air.
2.1.5 Steam Supply

If steam is to be used in the sampling system, start supplying the steam. Set the steam
pressure according to the “Operation Data.”

2.1.6 Supply of Various Cylinder Gases

Start supplying various cylinder gases (carrier gas, combustion hydrogen or makeup gas,
etc.). Set the pressure according to Section 1.5, “How to Measure/Set the Pressure and
Flow Rate of Various Gases”. The pressure and flow rate should be finally set after the
temperature of the isothermal oven has stabilized.
NOTE
According to the explosion-proof standard, hydrogen gas supply to the isothermal oven is
stopped while the power is turned off. If hydrogen is used as a carrier gas, set the pressure
after turning on the power.
IMPORTANT
If a pressure of 1 MPa or higher is applied directly to the GC1000 Mark II, a failure may
occur. To avoid this, take the following procedure when supplying the cylinder gas.
(1) Fully close the pressure regulator of the cylinder.
(2) Make sure that the secondary pressure of the pressure regulator is zero.
(3) Open the primary valve of the cylinder.
(4) Set the secondary pressure of the pressure regulator to 700 kPa.
2.1.7 In case of GC1000T Type Y Purging and GC1000E Type Y

Purging
Supply the power following the procedure below.
(1) Confirm that the pressure gauge for the electronic section in the flow control unit
indicates the specified pressure.
(2) Wait 12 minutes in this condition.
(3) After 12 minutes passed, supply the power
CAUTION
Routine inspection: Confirm that the pressure gauge for the electronic section in the flow
control unit indicates the specified pressure.

2.2 Operation After Power Delivery

This section explains preparations required before the measurement of a process sample
or standard sample.
2.2.1 Power Supply

When the power is turned on, purging is performed for about 12 minutes, then the power is
supplied to the electrical box. For details on the operation of the protection system, see
Section 1.1, “How to Check the Status Indication of the Protection System”.
2.2.2 Date/Time Setting

Since the GC1000 Mark II does not allow the date/time to be backed up because of the
explosion-proof standard, set the date/time after turning on the power. The setting proce-
dure is explained below. For details on LCD panel operation, refer to the LCD Panel
Operation Manual, IM 11B03A03-05E.
(2) Press the TABLE key. (The screen shown in Figure 2.1 appears.)
(3) Move the cursor (>) to “System Set.”
(4) Press the SET/ENT key. (The screen shown in Figure 2.2 appears.)
(5) Move the cursor (>) to “Current date” or “Current time.”
(6) Press the SET/ENT key. Entry is now allowed.
(7) Enter the date in the format of “year-month-day” or the time in the format of “hours (24-
hour format)-minute-second.”
F0201.EPS
Figure 2.1 Table Menu Screen
F0202.EPS
Figure 2.2 System Set Screen

2.2.3 Checking the Set Values

The “Operation Data” shows the set values for the items on the Table Menu screen (Figure
2.1). Make sure that all the items are set according to the “Operation Data.”
2.2.4 Supply of Combustion Hydrogen or Makeup Gas, and

Combustion Air
This section is applicable to the FID, FID with methane converter, and FPD, but not to the
TCD.
Start supplying combustion hydrogen or makeup gas and combustion air. Set the pressure
according to Section 1.5, “How to Measure/Set the Pressure and Flow Rate of Various
Gases”. Set the pressure and flow rate finally after the temperature of the isothermal oven
has stabilized.
NOTE
According to the explosion-proof standard, the supply of hydrogen gas to the isothermal
oven is stopped when the power is turned off.
IMPORTANT
If a pressure of 1 MPa or higher is applied directly to the GC1000 Mark II, a failure may
occur. To avoid this, take the following procedure when supplying the cylinder gas.
(1) Fully close the pressure regulator of the cylinder.
(2) Make sure that the secondary pressure of the pressure regulator is zero.
(3) Open the primary valve of the cylinder.
(4) Set the secondary pressure of the pressure regulator to 700 kPa.
When the instrument air is to be used as combustion air, set the pressure for supplying the
instrument air to the GC1000 Mark II to at least 100 kPa more than the set pressure of
combustion air described in the “Operation Data.”

2.3 Detector ON/OFF Operation

For the GC1000 Mark II, the detector is turned off after the power is turned on. However, if
“Auto start set” in “System Set” screen (Figure 2.2) is set to “Yes,” the detector is turned on
automatically upon power startup. The precautions on turning each detector on and off are
described below.
Only the TCD allows the detector’s turning-off operation. For the FID and FPD, combustion
stops and the detector is turned off when the supply of the combustion hydrogen or com-
bustion air is stopped, but a “DET1 FIRE OFF” or “DET2 FIRE OFF” alarm occurs.
2.3.1 TCD
If the TCD is turned on with the carrier gas line filled with air, the TCD filament may be burnt
out. Before turning on the TCD, feed the carrier gas for at least 10 minutes. The TCD
output cannot stabilize (i.e., the base line drifts) until some time after the temperature has
stabilized. Allow at least 12 hours to pass after the TCD has been turned on, and then start
normal operation and calibration.
The procedure for turning the TCD on and off is explained below.
(3) Press the F3 key. (The screen shown in Figure 1.7 appears.)
(4) Move the cursor (>) to the detector of interest.
(5) Press the SET/ENT key. The indication changes from On to Off, or vice versa.
(6) Press the F2 key to return to the Operation screen (Figure 1.6).

2.3.2 FID and FID with Methane Converter

Turn on (i.e., ignite) the FID after the temperature of the isothermal oven has fully stabi-
lized. The time required for the temperature to stabilize depends on the set temperature,
but the required time is 2 to 4 hours if the temperature of the isothermal oven is below
146°C, and 4 to 8 hours if the temperature is 146°C or higher. When the temperature of the
isothermal oven has stabilized, the “Therm signal” (Figures 1.10, 1.11) on the Detector
Status screen becomes 0 mV. After the power is turned on, the “Therm signal” changes
from 0 mV to -2 to -3 mV, and then returns to 0 mV as the temperature of the isothermal
oven rises and then stabilizes. If the FID is turned on (i.e., ignited) when the “Therm signal”
is -2 to -3 mV, the “Therm signal” does not exceed the “Flame level” but the flame out state
is identified although combustion is still in progress and a “DET1 FIRE OFF” or “DET2
FIRE OFF” alarm occurs.
The FID performs ignition by using a platinum coil. With this platinum coil as catalyst,
simply supplying a carrier gas, combustion hydrogen or makeup gas, and combustion air
may result in natural ignition, which can be confirmed by condensation forming on the vent
line. If the FID is turned on after natural ignition, the chromatogram may not show the peak
but output the base line only. If natural ignition occurs, set “Flame level” in the Detector
Status Set screen to the value of “Therm signal” plus 0.5 mV, and then turn on the FID. The
procedure for turning on the FID is described below.
(1) Make sure that the temperature of the isothermal oven has stabilized.
(3) Make sure that “Therm signal” on the Detector Status screen (Figures 1.10, 1.11) is
0±0.1 mV.
(4) If natural ignition occurs (i.e., “Therm signal” becomes 2 to 3 mV or higher), set “Flame
level” to the value of the “Therm signal” value plus 0.5 mV. For the setting method,
refer to the LCD Panel Operation Manual, IM 11B03A03-05E.
(7) Move the cursor (>) to the detector of interest.
(8) Press the SET/ENT key. The OFF indication remains until “Flame On” is indicated for
the FID. If the ignition fails, a “DET1 FIRE OFF” or “DET2 FIRE OFF” alarm occurs. If
this alarm occurs, retry from step (1).
(9) When “Flame On” is indicated for the FID, the indication changes from OFF to ON.

2.3.3 FPD
Turn on (i.e., ignite) the FPD after the temperature of the isothermal oven has fully stabi-
lized. The time required for the temperature to stabilize depends on the set temperature,
but the required time is 2 to 4 hours (For the FPD, the maximum temperature of the isother-
mal oven is 145°C). When the temperature of the isothermal oven has stabilized, the
“Therm signal” on the Detector Status screen (Figure 1.12) becomes 0 mV. After the power
is turned on, the “Therm signal” changes from 0 mV to -2 to -3 mV and then returns to 0 mV
as the temperature of the isothermal oven rises and stabilizes. If the FPD is turned on (i.e.,
ignited) when the “Therm signal” is -2 to -3 mV, the “Therm signal” does not exceed the
“Flame level” but the flame out state is identified although combustion is still in progress
and a “DET1 FIRE OFF” alarm occurs.
The FPD performs ignition by using a platinum coil. With this platinum coil as catalyst,
simply supplying a carrier gas, combustion hydrogen, and combustion air may result in
natural ignition. If the FPD is turned on after natural ignition, the chromatogram may not
show the peak but output the base line only. If natural ignition occurs, change the “Flame
level” in the “Detector Status Set” screen according to the ignition procedure, and then turn
on the FPD. The procedure for turning on the FPD is described below.
(1) Make sure that the temperature of the isothermal oven has stabilized.
(2) Set the pressure of the combustion air to the value twice the one shown in “Operation
Condition Set” of the “Operation Data.”
(4) Make sure that the “Therm signal” on the Detector Status screen (Figure 1.12) is
0±0.1 mV.
(5) If natural ignition occurs (i.e., “Therm signal” becomes 2 to 3 mV or higher), set the
“Flame level” to the value of the “Therm signal” plus 0.5 mV. For the setting method,
refer to the LCD Panel Operation Manual, IM 11B03A03-05E.
(8) Move the cursor (>) to “Det 1 operation.”
(9) Press the SET/ENT key. The OFF indication remains until “Flame On” is indicated for
the FPD. If the ignition fails, a “DET1 FIRE OFF” alarm occurs. If this alarm occurs,
retry from step (1).
(10) When “Flame On” is indicated for the FPD, the indication changes from OFF to ON.
(11) Reset the “Flame detection” to the value shown in “Operation Condition Set” of the
“Operation Data.”
(12) One minute after “Flame On” has been indicated for the FPD, reset the pressure of
the combustion air to the value shown in “Operation Condition Set” of the “Operation
Data.”
2.3.4 Base Line Check

To make sure that the detector is correctly operating, check the base line on the Chromato-
gram screen (Figure 1.18) and compare it with the one in the chromatogram in the “Opera-
tion Data.” If the signal level and noise of the base line are significantly different from those
in the chromatogram shown in the “Operation Data,” a failure of the detector, detector card,
or wiring may have occurred.

2.4 Standard Sample (Gas or Liquid) Measurement

To verify that no conformity has occurred during transportation and installation, the mea-
surement of a standard sample must be performed after installation. The results should be
compared with those obtained at factory before shipment that are described in the “Opera-
tion Data.”
2.4.1 Connection of the Standard Gas Cylinder or Standard Liquid

Tank
Connect a standard gas cylinder or standard liquid tank to the standard sample line. If
there are two or more standard sample lines, connect the standard gas cylinder correctly
according to “Stream Set” and “Individual Peak Set” in the “Operation Data.” If a small
liquid tank is used, connection to the standard sample line may result in a shortage of the
standard liquid. In this case, remove the joint for the piping between the sampling system
and the isothermal oven, and then connect the standard liquid tank.
2.4.2 Displacement of the Standard Sample Line

Before the measurement of a standard sample, inside the sample lines should be fully
displaced as following the procedures below.
• In case of an automatic stream valve:

(4) Move the cursor (>) to “Str valve.”
(5) Press the SET/ENT key. A stream number can now be entered.
(6) Enter the stream number for a standard sample.
(7) The stream valve opens.
(8) Adjust the restrictor of the sampling system so that the standard sample flows into the
line for displacement.
(9) After the displacement has been completed, press the F2 key to return to the Opera-
tion screen (Figure 1.6).
• In case of a manual stream valve:

(6) Enter “0.”
(7) All stream valves close.
(8) Open the stream valve of the sampling system manually.
(10) After the displacement has been completed, press the F2 key to return to the Opera-
tion screen (Figure 1.6).

2.4.3 Measurement of a Standard Sample

Perform the measurement of a standard sample as following the procedure below. If the
operation mode is in a mode other than Stop, change the operation mode to Stop, and then
take the following procedure.
(4) Move the cursor (>) to “Str (cont) select.”
(6) Enter the stream number for a standard sample.
(7) Move the cursor (>) to “Ope mode.”
(8) Press the SET/ENT key. An item for “Ope mode” can now be selected.
(9) Select Run using the ~ ` keys, and then press the SET/ENT key. The operation
mode turns to Run to start measuring the standard sample.
(10) After the measurement of the standard sample has been completed, press the SET/
ENT key while the cursor is pointing to “Ope mode.” An item for “Ope mode” can now
be selected.
(11) Select Stop using the ~ ` keys, and then press the SET/ENT key. The operation
mode turns to Stop to end measuring the standard sample.
F0203.EPS
Figure 2.3 Stream Command Screen

2.5 Calibration
Although calibration with a standard sample is normally performed at the factory before
shipping, it is recommended that calibration should be performed again with the standard
gas upon startup. Once the continuous process measurement is started, it is recom-
mended that calibration be performed once in one to six months.
2.5.1 Types of Calibration Methods

For calculation of concentrations using the area or height obtained from the chromatogram,
refer to the Technical Guide, IM 11B03A03-03E. The method of calculating concentrations
depends on “Process assign” in “Individual Peak Set.”
Calibration with a standard sample is performed when “Process assign” is set to “External
3rd” (external standard). The formula used for calculating concentrations of “External 3rd”
is shown below.
C=RK( α Si/Sb)(A( α Si/Sb)2+B( α Si/Sb)+1)
C: Concentration
α : Calibration factor
Sb: Standard area or height
Si: Measured area or height
R: Measurement range
K: Coefficient
A: Coefficient
B: Coefficient
If it is confirmed that the concentration is proportional to the area or height, the following
formula can be applied:
Assuming K=1, A=0, and B=0,
C=R α Si/Sb
Calibration is allowed by obtaining the calibration factor or standard area (or height) from
the area (or height) as a result of measuring the standard sample and the formula shown
above, and then entering the obtained value in “Individual Peak Set” (Figure 2.4) of the
calibration stream. For the entry method, see the LCD Panel Operation Manual, IM
11B03A03-05E.
F0204.EPS
Figure 2.4 Individual Peak Set Screen
The GC1000 Mark II provides two automatic calibration methods. According to the value
set for “Calib coef range” in “Peak Common Set” (Figure 2.5), “Std area” or “Calib factor” is
changed automatically.

F0205.EPS
Figure 2.5 Peak Common Set Screen
Calibration by changing “Std area”

If “Calib coef range” is set to “0,” after the calibration the GC1000 Mark II changes “Calib
factor” to “1” and “Std area ” to a value obtained by calculation, in “Individual Peak Set”
(Figure 2.4). In this method these changes are made regardless of the value obtained. So
even if the measurement result of the standard sample is abnormal, the automatic calibra-
tion is finished as normal. To avoid this problem, the GC1000 Mark II determines whether
or not to execute automatic calibration from the following method based on the setpoints of
“Set calib range ” and “Calib coef vari range.”
If “Set calib range” is set to “ α ,” the GC1000 Mark II displays an alarm message and does
not execute automatic calibration when the result of measuring the standard sample falls
outside the range of “Std conc ± measurement range “ α .” Likewise, if “Calib repeat range”
is set to “ α ,” the GC1000 Mark II displays an alarm message and does not execute auto-
matic calibration when a variation coefficient resulting from n -time measurements of the
standard sample is greater than “ α .” The variation coefficient here refers to a value ob-
tained by dividing the standard deviation by the measurement range. For details on the
calculation formula, refer to the Technical Guide, IM 11B03A03-03E.
The calibration method based on a change in “Std area” is not suited for purposes such as
calibration history management. As a regular calibration method, the method based on a
change in “Calib factor” described below is recommended. Factory calibration is performed
using the method based on a change in “Std area.”
Calibration by changing “Calib factor”

If “Calib coef range” is set to a value other than “0,” after the calibration the GC1000 Mark II
changes “Calib factor” to a value obtained through calculation without changing the
setpoint of “Std area” in “Individual Peak Set” (Figure 2.4). In this method, the GC1000
Mark II determines whether or not to execute automatic calibration from the following
method based on the obtained value of “Calib factor.” At this point, the GC1000 Mark II also
uses “Calib range ” and “Calib repeat range” to make the determination.
That is:
• If “Calib coef range” is set to “ α ,” the GC1000 Mark II executes automatic calibration
when the obtained value of “Calib factor” falls within a range from “1- α ” to “1+ α .”
• If the obtained value of “Calib factor ” is smaller than “1- α ” or greater than “1+ α ,” the
GC1000 Mark II displays an alarm message and does not execute automatic calibra-
tion.
For example, if “Calib coef range ” is set to “0.1,” the GC1000 Mark II executes automatic
calibration when the obtained value of “Calib factor ” falls within a range from “0.9” to “1.1.”

2.5.2 Calibration Method

When an automatic stream valve is used for the stream of a standard sample, either
automatic or semiautomatic calibration can be selected, while when a manual stream valve
is used, only manual calibration is available. For each calibration method, refer to the
Overview, IM 11B03A03-01E.
2.5.3 Confirmation of Parameter Settings

Before executing a calibration command, previously specified settings such as number of
calibration stream, frequency, and combination with validation, should be checked.
(1)Calibration/Validation Set Screen (Figure 2.6)

When the power is turned off and on, “Cal (Val) method” turns to Manual. When the power
is turned off and on, reset the calibration (validation) method. For detains on the entry
method, see the LCD Panel Operation Manual, IM 11B03A03-05E.
(2) Move the cursor (>) to “Cal/Val Set.”
(4) Automatic, semiautomatic, or manual is set for “Cal (Val) method.”
(5) “Auto start time” indicates the time to start calibration in the 24-hour format. (valid only
for automatic calibration.)
(6) “Time interval” indicates a calibration cycle. (valid only for automatic calibration.)
When automatic calibration is selected, automatic calibration according to the settings

when “Cal (Val) method” is specified, is performed. Setting for the automatic calibration
should be set after the other settings have been completed. Changes in “Auto start time”
and other settings after “Cal (Val) method” is set to Auto, are not reflected. If other settings
are changed, set “Cal (Val) method” to the one other than Auto once, and then set it again
to Auto.
F0206.EPS
Figure 2.6 Cal/Val Set (Main) Screen

(2)Calibration Set Screen (Figure 2.7)
(1) From the “Cal/Val Set (Main)” screen (Figure 2.6), press the F5 key (Cal). (The
screen shown in Figure 2.7 appears.)
(2) For “Cal stream,” set the calibration stream to be used for this calibration.
(3) For “Cal times,” set the number of measurements of the calibration stream.
(4) “Auto cal” is for setting whether or not to conduct the calibration of the stream with the
number set for “Cal stream” during automatic calibration. (valid only for automatic
calibration.)
(5) “Val Stream” indicates the validation stream to be measured after the calibration.
F0207.EPS
Figure 2.7 Calibration Set Screen

2.5.4 Calibration Command

After the parameter settings has been checked as following the procedures in the previous
section, a calibration command can be executed. The following shows the procedure.
(1)Automatic Calibration
(1) Connect the cylinder or tank to the standard sample stream as referring Section 2.4.1,
“Standard Gas Cylinder or Standard Liquid Tank Connection”.
(4) Move the cursor (>) to “Cal/Val Set.”
(6) Press the SET/ENT key. An item for “Cal (Val) method” can now be selected.
(7) Select “Auto” using the ~ ` keys, and then press the SET/ENT key.
(8) When the time set for “Auto start time” comes, measurements of the calibration
stream and validation stream according to the settings starts. After the completion,
the calibration stops.
(9) Press the OPERATION key to return to the Operation screen (Figure 1.6).
IMPORTANT
If the time set for “Auto start time” comes while the operation mode is in Run, the calibration
will start after the ongoing measurement of the stream has been completed. After the
calibration the operation mode turns to Run, i.e., the previous operation is retrieved to
continue the measurement. (If the operation mode is in Stop or in Pause, the calibration
during that time is not performed.)
(2)Semiautomatic Calibration
(5) Move the cursor (>) to “Cal (Val) select.”
(6) Press the SET/ENT key. An item for “Cal (Val) select” can now be selected.
(7) Select one from among “Calibration 1 to 3” using the ~ ` keys, and then press the
SET/ENT key. The operation mode turns to Run to start calibration. (If the operation
mode is in Run at the selection, the calibration will start after the ongoing measure-
ment of the stream has been completed.)
NOTE
To cancel the calibration (validation) command, move the cursor (>) to “Selection cancel”
and then press the SET/ENT key. Note that “Selection cancel” is not valid after the mea-
surement of the calibration stream has started.

(8) After the completion of measurements of the calibration stream and validation stream
according to the settings, the calibration stops.
NOTE
If the measurement status before the calibration is in Stream Sequence or in Stream

(continuous) and the operation mode is in Run, after the calibration the previous measure-
ment status is retrieved and the operation mode turns to Run to continue the measure-
ment. If the operation mode before the calibration is in Stop or in Pause, after the calibra-
tion the previous measurement status is retrieved and the operation mode turns to Stop.
F0208.EPS
Figure 2.8 Cal (Val) Command Screen
(3)Manual Calibration
(3) Press the F5 key (Cmd). (The screen shown in Figure 2.9 appears.)
(4) Move the cursor (>) to “Cal (Val) select.”
(5) Press the SET/ENT key. An item for “Cal (Val) select” can now be selected.
(6) Select one from among “Calibration 1 to 3” using the ~ ` keys, and then press the
SET/ENT key. In 0 to 20 seconds, sample displacement becomes ready.
(7) Open the stream valve for the standard sample stream of the sampling system manu-
ally.

NOTE
To cancel the calibration (validation) command by this time, move the cursor (>) to “Selec-
tion cancel” and then press the SET/ENT key.
(9) After the displacement has been completed, move the cursor (>) to “Cal (Val) start/
stop.”
(10) Press the SET/ENT key. An item for “Cal (Val) start/stop” can now be selected.
(11) Select “Start” using the ~ ` keys, and then press the SET/ENT key. In 0 to 20 sec-
onds, the calibration starts.
(12) After the completion of measurements of the calibration stream and validation stream
according to the settings, sample displacement becomes ready.
(13) Close the stream valve for the standard sample stream of the sampling system manu-
ally.
(14) Press the SET/ENT key while the cursor (>) is pointing to “Cal start/stop.” An item for
“Cal start/stop” can now be selected.
(15) Select “Stop” using the ~ ` keys, and then press the SET/ENT key. In 0 to 20 sec-
onds, the previous measurement status before the calibration is retrieved and the
operation mode turns to Stop.
F0209.EPS
Figure 2.9 Cal (Val) Command Screen

<Toc> <Ind> <3. Normal Operation (Continuous Measurement of Process Samples) > 3-1
3. Normal Operation (Continuous

Measurement of Process Samples)
A normal operation should be performed after startup procedures described in Chapter 2,
“Startup”, have been completed successfully.
3.1 Setting of Stream Sequence

Upon shipment, unless otherwise specified, streams are set in order from Stream 1 for
Stream Sequence 1. To change the specified parameters, such as the number of mea-
surement times and order of streams to be measured, change settings in “Stream Se-
quence” as referring the LCD Panel Operation Manual, IM 11B03A03-05E.
3.2 Setting of Process Sample Pressure/Flow Rate

Set the pressure and flow rate of a sample in each stream as following the procedure
below. For the values of pressure and flow rate to be set, refer to the “Operation Data.”
• In case of an automatic stream valve:

(6) Enter the stream number (normally in order from 1) for the process sample.
(7) The stream valve opens.
(8) Adjust the restrictor of the sampling system to set the pressure and flow rate of the
process sample.
Repeat steps (5) through (8) to set the pressure and flow rate for all process sample
streams.
• In case of a manual stream valve:

(6) Enter “0.”
(7) All stream valves close.
(8) Open the stream valve of the sampling system for the stream to be measured manu-
ally.
(9) Adjust the restrictor of the sampling system to set the pressure and flow rate of the
process sample.

<Toc> <Ind> <3. Normal Operation (Continuous Measurement of Process Samples) > 3-2
3.3 Starting the Operation

Start the operation as following the procedure below. If the operation mode is in a mode
other than Stop, change the mode to Stop before taking the following procedure.
(4) Move the cursor (>) to “Str seq select.”
(5) Press the SET/ENT key. A stream sequence number can now be entered.
(6) Enter the stream sequence number.
(7) Move the cursor (>) to “Ope mode.”
(9) Select “Run” using the ~ ` keys, and then press the SET/ENT key. The operation
mode turns to “Run” to start measuring the process sample.
3.4 Ending the Operation

Stop the operation as following the procedure below.
(4) Select “Stop” using the ~ ` keys, and then press the SET/ENT key. After an ongoing
measurement has been completed, the operation mode turns to Stop and the mea-
surement of the process sample is ended.
IMPORTANT
To turn off the power after the operation is stopped, follow the procedure described below.
Failure to follow the procedure when turning off the power could result in malfunction of
components, such as a detector and a column.
(1) For the FID, FID with methane converter, or FPD, stop supplying the combustion
hydrogen or nitrogen and combustion air (i.e., close the primary valves of the gas
cylinders). After the detector indicates “Flame Out,” leave the equipment standing for
at least 4 hours.
(2) If the carrier gas is hydrogen, turn off the heaters for the isothermal oven and column
oven. For the procedure for turning off the heaters, see Section 1.3, “How to Check
the Temperature at Each Part”. Leave the ovens standing for at least one hour until
the temperatures of the isothermal oven and column oven fall.
(3) Turn off the power supply.
Keep on supplying the carrier gas.
3.5 Precautions for Long-term Shutdown

When stopping the operation for a long period, turn off the power supply and then stop the
air supply according to Section 3.4, “Ending the Operation”. Keep on supplying the carrier
gas at a reduced pressure to approximately 1/10. To stop supplying the carrier gas, seal
each vent line so that the equipment is pressurized with the carrier gas, and then close the
primary valve of the carrier gas cylinder.

<Int> <Toc> i
◆ Revision Record
● Manual No. : IM 11B03A03-02E
● Title : GC1000 Mark II Process Gas Chromatograph Basic Operation and Startup
Oct. 2001/1st Edition

Newly published
July/2002/2nd Edition
Introduction modified below;

Added “(5) When touching LCD Panel switches” to “WARNING”;
Corrected a part of “CENELEC (ATEX directive) certification”;
Corrected a part of “Installation site and environment”;
Added “Explanation for type Y purging” to “WARNING of explosionproof enclosure” of FM
and CSA certification;

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User's

● Regarding Protection, Safety, and Prohibition Against Unauthorized Modifica-

Protective ground terminal:

Function ground terminal:

Indicates the power switch state “Stand - by”.

Indicate the power switch state “OFF”.

● Exemption from Responsibility

● Regarding Software and set including Software Supplied by YOKOGAWA

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

[Left side] [Front] [Right side] [Back]

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

● Documents Related to the GC1000 Mark II Process Gas Chromatograph

■ Instruction manuals that depend upon the specifications of the product

■ Instruction manuals for related products

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

● Is the System Ready?

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

(1) Kinds of explosion protection

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

(3) Precautions when using hydrogen gas

(4) Installation site and environment

(5) Wiring works

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

(8) Replacing parts

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

(10) Maintenance and Repair

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

Gard List strap

Using a wrist strap and conductive sheet Using a Conductive Sheet

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

GC1000 Mark II Process Gas Chromatograph

IM 11B03A03-02E 2nd Edition

IM 11B03A03-02E 2nd Edition : July. 1. 2002-00

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

1. How to Set, Measure, and Check the

1.1 How to Check the Status Indication of the

I. OVEN PRESS. POWER EL. BOX PRESS.

I. OVEN PRESS. POWER EL. BOX PRESS.

Figure 1.1 Status Indicators

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

Operation of the protection system

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

1.2 How to Operate the LCD Panel

Mark II PROCESS GAS

ALARM LOCAL POWER 1 2 3

STATUS RESULT ALARM TEMP CHROM

Figure 1.2 Operation Screen

Figure 1.3 Communication Mode Switching Screen

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

Figure 1.4 Communication Mode Switching Screen

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

1.3 How to Check the Temperature at Each Part

Figure 1.5 Temperature Status Screen

The terms used on the screen are explained below.

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

Figure 1.6 Operation Screen

Figure 1.7 Manual Operation Screen

Figure 1.8 Manual Operation Screen

IM 11B03A03-02E 1st Edition : Oct.30,2001-00

1.4 How to Check the Operating Status of the Detector