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SMKBA
A. Acids and Bases
Learning Objectives: In this lesson, you are able to
state the meaning of acid, base and alkali,
state uses of acids, bases and alkalis in daily life,
explain the role of water in the formation of hydrogen ions to show the properties of acids,
explain the role of water in the formation of hydroxide ions to show the properties of alkalis,
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Read textbook Chapter 7 page 117-119 and answer the following questions.
Q5. Based on your understanding, state the ion which take in charge to show properties of
a) acid :
b) alkali :
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
Q6. State the uses of acids, bases and alkalis in daily life by filling the table below.
Uses
1
2
3 3
4 4
5 5
6 6
Advanced:
Q7.
P Q R
HCl molecule ionises to form H+ (or H3O+) ions and Cl- ions when it dissolves in water.
a) In the experiment above, what method is using to test the properties of acid?
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Q8.
○ Light ○ Light
Switch Switch
bulb bulb
a) In the experiment above, what method is using to test the properties of acid?
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Monobasic
Definition: 1 molecule produce 1 H+ ion upon dissociation
Example: HCl, HNO3
Dissociation Equation: HCl(aq) –> H+(aq) + Cl-(aq)
Dibasic
Definition: 1 molecule produce 2 H+ ion upon dissociation
Example: H2SO4
Dissociation Equation: Figure it out yourself!!
Tribasic
Definition: 1 molecule produce 3 H+ ion upon dissociation
Example: H3PO4
Dissociation Equation: H3PO4(aq) –> 3H+(aq) + PO4 3-
(aq)
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B.
7.1 Synthesising the Concepts of Strong Acids, Weak Acids, Strong Alkalis and Weak Alkalis
state the use of a pH scale,
relate pH value with acidic or alkaline properties of a substance,
relate concentration of hydrogen ions with pH value,
relate concentration of hydroxide ions with pH value,
relate strong or weak acid with degree of dissociation,
relate strong or weak alkali with degree of dissociation,
conceptualise qualitatively strong and weak acids,
conceptualise qualitatively strong and weak alkalis.
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1. pH scale
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
Definition:
i) Strong acid : An acid that ionises completely in water to produce high concentration of hydrogen ion, H+
ii) Weak acid : An acid that ionises partially in water to produce low concentration of hydrogen ion, H+
iii) Strong alkali: A base that ionises completely in water to produce high concentration of hydroxide ions, OH-
iv) Weak alkali : A base that ionises partially in water to produce low concentration of hydroxide ions, OH-
7.2 Analysing Concentration of Acids and Alkalis
state the meaning of concentration,
state the meaning of molarity,
state the relationship between the number of moles with molarity and volume of a solution,
describe methods for preparing standard solutions,
describe the preparation of a solution with a specified concentration using dilution method,
relate pH value with molarity of acid and alkali,
solve numerical problems involving molarity of acids and alkalis.
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1. meaning of concentration
Unit - …………………………….. / ……………………………. [1 dm3 = 1000 cm3]
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2. meaning of molarity: the amount of dissolved substance in 1dm-3 of solvent to form a solution.
** molarity ≠ strong or weak acid
Prepare 100cm3 of 1.0 mol dm-3 sodium hydroxide solution from 1 Calculate & weigh the mass
solid of solid sodium hydroxide
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3 Rinse the beaker and filter
funnel
Add washings into flask
4 Add distilled water til
calibration mark
5 Shake well
Prepare 250cm3 of 0.05 mol dm-3 sodium hydroxide solution 1 Calculate & measure the V1 cm3 of
from 1.0 mol dm-3 sodium hydroxide solution 1.0 mol dm-3 sodium hydroxide solution
by using pipette
2 Transfer the solution into a 250cm3
volumetric flask which containing a
little distilled water
[never add water into concentrated acid
/ alkali]
3 Rinse the pipette
Add washings into flask
Add distilled water til calibration mark
4 Shake well
Reason [ H+ ions]per unit volume is high [ H+ ions] per unit volume is high [ H+ ions] per unit volume is lower
7.3 Analysing Neutralisation
explain the meaning of neutralisation,
explain the application of neutralisation in daily life,
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write equations for neutralisation reactions,
describe acid-base titration,
determine the end point of titration during neutralisation,
solve numerical problems involving neutralisation reactions to calculate either concentration or volume of solutions.
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1. Neutralisation: reaction between …………… and …………… to produce salt & water.
…………………. from acid reacts with …………………. from alkali to form water molecules.
Ionic equation: ……… + ……… …………
Agriculture
Industries
Health
4. Acid-base titration : a quantitative analysis methode to determine the volume of an acid to neutralise an alkali
Method: …………………………………
Reaction: …………………………………
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
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Exercises:
1. A student dissolves 50.0 g of anhydrous copper(II) sulphate in water to make a 250 cm3 of solution. What is
the concentration of the solution in g dm3?
2. 28.0 g of potassium hydroxide is dissolved in water to make 200 cm3 of solution. Calculate the molarity of
potassium hydroxide solution obtained. (Ar: H, 1; O, 16; K, 39)
3. A potassium chloride solution has a concentration of 14.9 g dm3. What is the molarity of this solution?
(Ar: Cl, 35.5; K, 39)
4. Calculate the mass of calcium hydroxide in 50 cm3 of 0.01 mol dm3 calcium hydroxide solution.
(Ar: H, 1; O, 16; Ca, 40)
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5. A 0.5 mol dm3 lithium hydroxide solution contains 6.0 g lithium hydroxide. Calculate the volume of this
solution. (Ar: H, 1; Li, 7; O, 16)
6. What is the volume of 2.0 mol dm3 nitric acid needed to be diluted with distilled water to make 250 cm3 of 0.5
mol dm3 nitric acid?
7. 50 cm3 of water is added to 200 cm3 of a 2 mol dm3 solution of sodium hydroxide. Determine the molarity of
the diluted solution.
8. A student pipetted 25.0 cm3 of sodium hydroxide, NaOH solution into a conical flask and filled a burette with
0.10 mol dm-3 hydrochloric acid, HCl to carry out a titration. He obtained an average volume of 22.0 cm3
hydrochloric acid, HCl. What was the molarity of the sodium hydroxide, NaOH solution?
9. What is the volume of 0.5 mol dm -3 sulphuric acid, H2SO4 needed to neutralise 25.0 cm3 of 0.8 mol dm-3
ammonia, NH3 solution?
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10. The following result were obtained when 20 cm3 of sodium hydroxide solution (0.5 mol dm-3) was titrated
against dilute sulphuric acid of unknown concentration.
Titration
I II III
Volume of acid
End reading (cm3)
21.00 29.95 21.00
3
Initial reading (cm )
0.00 10.00 1.00
Volume of acid used cm3)
i) Fill in the volume of acid used for each titration in the table given above.
ii) Find the average volume of sulphuric acid used in the titration.
iii) Write the chemical equation of the reaction between sulphuric acid and sodium hydroxide.
…………………………………………………………………………………………………………………………………...
iv) Calculate the concentration of dilute sulphuric acid used in the titration in mol dm-3.
11.
Solution K L M N O
pH 1 4 7 10 13
a) State one solution which is,
i) a strong acid :………………………………………………………………………… (1 mark)
ii) a strong alkali :………………………………………………………………….. …... (1 mark)
iii) Which solution is likely to be ammonia solution?
…………………………………………………………………………………………………………………………………...
(1 mark)
iv) Explain why solution K has a lower pH value than solution L
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
(2 marks)
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v) State one example of solution M
…………………………………………………………………………………………………………………………………...
(1 mark)
vi) Explain briefly why the pH value of solution O changes when solution K is added to it drop by drop until K is in
excess.
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
(2 marks)
v) State two solutions which can produce a neutral solution when mixed together
…………………………………………………………………………………………………………………………………...
(2 marks)
12. The table below shows the pH values of five solutions A,B,C,D and E.
Solution pH
A 2
B 5
C 7
D 8
E 14
a) Which of the solution produce hydrogen ions in aqueous solution?
…………………………………………………………………………………………………………………………………...
(1 mark)
b) (i) Compare the concentration of hydrogen ion in solution A and B
…………………………………………………………………………………………………………………………………...
(1 mark)
b) (ii) Explain why solution A has lower pH value than solution B.
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
(4 marks)
c) State the reaction of solution C on moist litmus paper.
…………………………………………………………………………………………………………………………………...
(1 mark)
d) Give the formula of the common ion produced in aqueous solution of
i) A and B……………………………………… ii) D and E…………………………………………… (2 marks)
e) Write the ionic equation for the reaction between solution A and solution E
…………………………………………………………………………………………………………………………………...
(1 mark)
f) Which solution, when added to solution E will not change the pH of solution E
…………………………………………………………………………………………………………………………………...
(1 mark)
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13. a)
Experiment Result
I blue litmus paper in ethanoic acid + distilled water blue litmus paper turns red
II blue litmus paper in glacial ethanoic acid no change
Explain the result above. [4 marks]
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
b)
Substance pH
25cm3 of 1.0 mol dm-3 hydrochloric acid 1
25cm3 of 1.0 mol dm-3 ethanoic acid 3
Explain the result above. [4 marks]
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
13. An experiment is carried out to determine the volume of acid for neutralisation between 25 cm3 of
2 mol dm–3 sodium hydroxide, NaOH solution and 2 mol dm–3 sulphuric acid, H2SO4 solution by using
titration method. Phenolphthalein is used as indicator.
The experiment is repeated three times and the reading of volume of sulphuric acid is shown in Diagram 1.
Diagram 1
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(a) Record the readings of volume of sulphuric acid in the space provided in Diagram 1.
(b) Construct a table to record the data from these experiments. Your table should include initial reading, final
reading and volume of sulphuric acid used in the titration.
(c) Based on table on (c), calculate the average volume of 2 mol dm–3 sulphuric acid, H2SO4 needed to neutralise 25
cm3 of 2 mol dm–3 sodium hydroxide, NaOH solution.
(d) What is the type of salt produced, a soluble or insoluble salt? Name the salt.
…………………………………………………………………………………………………………………………………...
(e) What is the colour change in the sodium hydroxide, NaOH solution at the end point?
…………………………………………………………………………………………………………………………………...
(g) Before the burette is filled with sulphuric acid, it is rinsed with some sulphuric acid. Explain why.
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
(h) State the operational definition for end point.
…………………………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………………………...
(i) Predict the volume of acid needed to complete the neutralization reaction if replace the sulphuric acid with
hydrochloric acid which has same concentration.
…………………………………………………………………………………………………………………………………...
(j) Suggest another substance which can be used to replace the phenolphthalein and predict its colour change.
…………………………………………………………………………………………………………………………………...
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
14.
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
15. The Figure 1 below shows the apparatus set-up of an activity to determine the end point
in the titration of sulphuric acid and sodium hydroxide solution.
Figure 1
Titration 1 2 3
Final burette reading ( cm3) 15.85 16.10 16.20
Initial burette reading ( cm3) 0.80 1.10 1.25
Volume of sulphuric acid( cm3 )
………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………[ 2 marks]
c) Describe the colour change in the sodium hydroxide solution at the end point.
………………………………………………………………………………………………………………………….[ 2 marks]
d) The burette is rinsed with a small amount of dilute sulphuric acid before it is filled with dilute
sulphuric acid. Explain why.
…………………………………………………………………………………………………………………………………………..
………………………………………………………………………………………………………………………….[ 2 marks]
………………………………………………………………………………………………………………………..[ 2 marks]
f) Based on the results, calculate the average volume of the dilute sulphuric acid used.
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
[ 2 marks]
[ 3 marks]
h) Predict the volume of nitric acid needed to achieve the end point if the dilute sulphuric acid
is replaced with acid of the same concentration. Why ?
…………………………………………………………………………………………………………………………………………..
[ 2 marks]
16. Dilute sulphuric acid is added slowly from a burette to barium hydroxide solution in a beaker
as shown in Figure 2
Figure 2
……………………………………………………………………………………………………………………………[ 2 marks]
……………………………………………………………………………………………………………………………[ 2 marks]
c) What can be seen in the barium hydroxide solution when the dilute sulphuric acid is added ?
……………………………………………………………………………………………………………………………………………
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
…………………………………………………………………………………………………………………………….[ 2 marks]
Sketch a graph show how the brightness of the bulb changes with the volume of dilute
sulphuric acid added
[ 3 marks]
.
…………………………………………………………………………………………………………………………………………..
…………………………………………………………………………………………………………………………………………….
……………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………… ………….
……………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………
[ 6 marks]
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
17. 0.1 mol dm-3 hydrochloric acid from a burette is added little by little into a conical flask
containing 10.0 cm3 of barium hydroxide and a few drops of methyl orange until the end
point is reached. The burette readings of the hydrochloric acid before and after the titration
are shown in Figure 3.
Figure 3
a) Based on Figure 3, record the initial and final readings into the table below:
[ 2 marks]
b) State the change in colour of the methyl orange at the end point of titration.
…………………………………………………………………………………………………………………………….[ 2 marks]
c) Name a suitable apparatus used to measure 10.0 cm3 of barium hydroxide solution.
……………………………………………………………………………………………………………………………….[ 1 mark]
…………………………………………………………………………………………………………………………….[ 1 mark]
e) What precaution must be taken when hydrochloric acid from the burette is added to the
barium hydroxide solution in the conical flask ?
…………………………………………………………………………………………………………………………….[ 1 mark]
[ 4 marks]
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
18. A student added 1 cm3 portion of an acid HA to 25 cm3 of 0.10 mol dm-3 sodium hydroxide .
After each addition of acid , the student measured the pH of the mixture by using a
pH meter. From the results, the student drew the titration curve shown below.
Figure 4
…………………………………………………………………………………………………………………………[ 1 mark]
……………………………………………………………………………………………………………………….[ 1 mark]
………………………………………………………………………………………………………………………….[ 1 mark]
d) Suggest a suitable acid for HA.
…………………………………………………………………………………………………………………………..[ 1 mark]
e) i) What is the volume of acid needed to neutralize the alkali ?
………………………………………………………………………………………………………………………….[ 1 mark]
ii) Write a balance equation for the reaction between HA and sodium hydroxide ?
…………………………………………………………………………………………………………………………….[ 2 marks]
iii) Calculate the concentration in moldm-3 of acid HA.
[ 3 marks]
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
Answers :
d) To remove any water on the inner surface of the burette to prevent the sulphuric acid
being diluted.
f) 15.00 cm3
g) 0.2 moldm-3
h) 30 cm3. Sulphuric acid is a strong diprotic acid whereas nitric acid is a strong monoprotic acid.
b) H+, SO42-
c) A pipette
d) Neutralization
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CHAPTER 7: ACIDS AND BASES Keeping W. SMKBA
e) The conical flask is swirled continuously to allow the mixture to mix thoroughly.
f) 0.04925 moldm-3
18. a) Neutralization
b) 7
c) Strong acid
d) Hydrochloric acid
e) i) 7 cm3
19. Essay: Describe the experiment how to prepare 100cm3 of 0.1 mol dm-3 sodium hydroxide solution. [10m]
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