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B. Marking Scheme:
6. For each question in Section A(i) you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1)
mark will be awarded.
7. For each question in Section A(ii), you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1)
mark will be awarded.
8. For each question in Section A(iii), you will be awarded 4 marks if you darken the bubble(s) corresponding to the
correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded.
9. For each question in Section B, you will be awarded 2 marks for each row in which you have darkened the
bubble(s) corresponding to the correct answer. Thus, each question in this section carries a maximum of 8 marks.
There is no negative marking for incorrect answer(s) for this section.
Enrolment No. :
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-2
Chemistry PART – I
SECTION – A
Single Correct Choice Type
This section contains 9 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
1. Arrange the following compounds in the decreasing order of the basic strength
Aniline(I) , o-methylaniline(II) , m-methylaniline(III) , p-methylaniline(IV)
(A) (I)>(II)>(III)>(IV) (B) (IV)>(III)>(II)>(I)
(C) (IV)>(III)>(I)>(II) (D) (II)>(I)>(III)>(IV)
2. The equivalent weight of HNO3 (Mol. wt. = 63) in the following reaction is
3Cu 8HNO3 3Cu(NO3 )2 2NO 4H2 O
4 63 63
(A) (B)
3 5
63 63
(C) (D)
3 8
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-3
6. Excess of solid AgCl is added to a 0.1 M solution of Br – ions, Eo for half cell:
AgBr e Ag Br Eo 0.095 V
AgCl e Ag Cl Eo 0.222 V
–
the value of Br ion concentration at equilibrium is [Given – antilog (2.152) = 142].
(A) [Br – ] = 0.0317 V (B) [Br – ] = 0.013 V
–
(C) [Br ] = 0.99 V (D) [Br – ] = 0.099 V
7. Oxide ions are arranged in ccp (Cubic Close Packing) in a spinel-structure. One eighth of tetrahedral
+2 +3
holes occupied by A ions and one half of the octahedral holes are occupied by B . What is the
volume unoccupied in unit cell of this spinel?
(A) 28% (B) 76%
(C) 74 % (D) 22%
8.
A B C
O
O HO
(A)
O
(B)
O
(C) O (D) O
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-4
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion) and
STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
10. STATEMENT-1: If equilibrium is reached, when the molar concentration of each reactant and product
is the same, Keq. must be equal to one.
and
STATEMENT-2: The coefficients of each reactant and product are need to be equal to one, as
required condition for Keq = 1.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement -2 is False.
(D) Statement-1 is False, Statement-2 is True.
11. STATEMENT-1: α- glucopyranose is oxidized by HIO4 more readily than the β-anomer at the
1, 2- bond.
and
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-5
12. STATEMENT-1: PhCONHCH3 does not undergo the Hofmann amine preparation reaction with
Br2 and KOH.
and
+
STATEMENT-2: PhCONHCH3 cannot form intermediates [PhCONBr] K and PhNCO.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement -2 is False.
(D) Statement-1 is False, Statement-2 is True.
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-6
Comprehension Type
This section contains 2 groups of questions. Each group has 3 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.
15. What would be the pH if more of NaH2A is added to the titration mixture at point ‘C’?
(A) 11.0 (B) 10.2
(C) 9.69 (D) 7.69
16. What will be the change in pH from point ‘B’ to print ‘C’?
(A) 2.8 (B) 3.2
(C) 4.6 (D) none of these
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-7
Pinacols (1, 2 diols) on treatment with acids undergo a rearrangement to Ketones (Pinacolones, the
rearranged interemediate is a carbocation. A further observation is that with unsymmetrical glycols the
product formation depends mainly by which OH is lost to leave behind the more stable of the two
carbocations, and thereafter by which is the better migrating groups (order of migratory aptitude is
Ar > H > Alkyl).
e.g.
CH3 CH3 CH3 CH3 CH3 CH3 CH3
Ph C C H
Ph H2 O
Ph C C Ph
Ph C C Ph Ph C C CH3
OH OH OH2OH OH Ph OH
CH3 CH3
Ph C C CH3 Ph C C CH3
Ph O Ph O H
OH OH
H
17. C CH3 Major product is
Ph
Ph O CH3 O
(A) C (B) C
CH3 Ph
O O
CH3 Ph
(C) Ph (D)
CH3
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-8
OMe Me
18.
14 H
Ph C C Ph Pr oduct is
OH OH
OMe
OMe Me
14
(A) Ph C C Ph (B)
O
Ph C C O
Ph
Me
OMe
OMe Me
14
(C) Ph C C Ph (D)
O 14
C C Ph
O Ph
Me
CH2
19.
(i) HOCl
(ii) NH
Pr oduct is
3
(iii) NaNO2 / HCl
O O CH3
CHO
Cl NO2
(A) (B) (C) (D)
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-9
SECTION – B
Matrix – Match Type
This section contains 3 questions. Each question contains statements given in p q r s t
two columns, which have to be matched. The statements in Column I are
A p q r s t
labelled A, B, C and D, while the statements in Column II are labelled p, q, r, s
and t. Any given statement in Column I can have correct matching with ONE OR B p q r s t
MORE statement(s) in Column II. The appropriate bubbles corresponding to the
answers to these questions have to be darkened as illustrated in the following C p q r s t
example:
D p q r s t
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s and
t; then the correct darkening of bubbles will look like the following:
O
O
(D) (s) NH3
R C Cl
(t) NaCN
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-10
Mathematics PART – II
SECTION – A
Single Correct Choice Type
This section contains 9 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
1. The normal to the curve at P(x, y) meets the x-axis at G. If the distance of G from the origin is twice
the abscissa of P, then what is the nature of the curve?
(A) Circle (B) Parabola
(C) Ellipse (D) Hyperbola
2. If [x] denotes the greatest integer function of x, then what is the value of
1/ 2
4. Let f(x) = x3 + 3x2 – 10x so that f(1) = –6 and f(2) = 0 by the mean value theorem, there exists a
number y in the open interval (0, 1) such that f(1 + y) = 6. The value of y turns out to be
3 1 3
(A) greater than (B) between and
4 2 4
1 1 1
(C) between and (D) less than
4 2 4
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-11
5. The vertices of a triangle are A(m, n), B(12, 19) and C(23, 20), where m and n are integers. If its area
is 70 and the slope of the median through A is –5, then the last digit of (m + n) is
(A) 3 (B) 5
(C) 7 (D) 8
6. What is the equation of the curve whose tangent at any point (x, y) makes an angle tan–1(2x + 3y) with
x-axis and which passes through (1, 2)?
(A) 4 + 8x + 10y = 32e2(x – 1) (B) 2 + 6x + 9y = 26e3(x – 1)
3(x – 1)
(C) 2x + 3y = 8e (D) none of these
sin(x – [x]) cosx
7. If f(x) = e , then f(x) is ([x] denotes greatest integer function)
(A) non-periodic (B) periodic with no fundamental period
(C) periodic with period 2 (D) periodic with period
8. Numbers are selected at random, one at a time, from the two digit numbers 00, 01, 02, ...., 99 with
replacement. An event E occurs if and only if the product of the two digits of a selected number is 18.
If four numbers are selected, the probability that the event E occurs at least 3 times is
(A) 2.4832 10–4 (B) 2.481 10–4
–4
(C) 2.47 10 (D) none of these
9. The equation 4 sin x cos x a2 3 sin 2x – cos 2x have solution, when
3 6
(A) |a| 2 (B) |a| 2
(C) |a| 1 (D) |a| 1
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-12
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion) and
STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
10. Statement –1: If a 3iˆ k, ˆ c ˆi ˆj kˆ and d 2iˆ ˆj , then there exist real numbers ,
ˆ b ˆi 2ˆj k,
, such that a b c d .
and
Statement –2: a,b,c,d are four vectors in a 3 – dimensional space. If b, c, d are non-coplanar, then
there exists real numbers , , such that a b c d .
(A) Statement-1 is True, Statement -2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement -1 is True, Statement -2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement -1 is True, Statement -2 is False
(D) Statement -1 is False, Statement -2 is True
11. Statement –1: If x + y + z = xyz then at most one of the number can be negative.
and
Statement –2: In a triangle ABC, tanA + tanB + tanC = tanA tanB tanC and there can be at most one
obtuse angle in a triangle.
(A) Statement-1 is True, Statement -2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement -1 is True, Statement -2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement -1 is True, Statement -2 is False
(D) Statement -1 is False, Statement -2 is True
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-13
12. Statement –1: If I is incentre of ABC and I1 excentre opposite to A and P is the intersection of II1 and
BC, then IP . I1P = BP . PC.
and
Statement –2: In a ABC, I is incentre and I1 is excentre opposite to A, then IBI1 C must be square.
(A) Statement-1 is True, Statement -2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement -1 is True, Statement -2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement -1 is True, Statement -2 is False
(D) Statement -1 is False, Statement -2 is True
13. Statement –1: The internal angle bisector of angle C of a triangle ABC with sides AB, AC and BC are
y = 0, 3x + 2y = 0 and 2x + 3y + 6 = 0 respectively, is 5x + 5y + 6 = 0.
and
Statement –2: Image of point A with respect to 5x + 5y + 6 = 0 lies on side BC of the triangle.
(A) Statement-1 is True, Statement -2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement -1 is True, Statement -2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement -1 is True, Statement -2 is False
(D) Statement -1 is False, Statement -2 is True
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-14
Comprehension Type
This section contains 2 groups of questions. Each group has 3 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.
Define a function : N N as follows. (1) = 1, (rn) = rn – 1 (r – 1), if r is prime and n N, (ln) = () (n), if
H.C.F (, n) = 1.
14. (1672) =
(A) 720 (B) 836
(C) 832 (D) 729
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-15
Let f(x) be defined as, f(x) = max {a, b, c}, where a = lim lim
n sin x cos x n ,
n 1 n n
b = lim lim
n
sin x cos x and c =
n
cos(n 1)
n 1 n n
lim
n
4n
1 cos
2n
....
2n , then
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-16
SECTION – B
Matrix – Match Type
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-17
2. Given x = z1 + z2 + z3, y = z1 + z2w + z3w2, z = z1 + z2w2 + z3w; where w is cube root of unity then
Column I Column II
2
(A) |x| (p) |z1|2 + z1 (z2w + z2w2) + z2 (z3w + z1w2) + z3 (z1w + z2w2)
2
(B) |y| (q) |z1|2 + z1 (z2w2 + z3w) + z2 (z3w2 + z1w) + z3 (z1w2 + z2w)
2
(C) |z| (r) 3 |z1|2
2 2
(D) |x| (s) |z1| + z1 (z2 + z3) + z2 (z3 + z1) + z3 (z1 + z2)
(t) (|z1| + |z2| + |z3|)2
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-18
This section contains 9 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
2
1. A flat coil of area A and n turns is placed at the centre of a ring of radius r(r >> A) and resistance R.
The coil and the ring are coplanar. When the current in the coil increases from zero to i, the total
charge circulating in the ring is
nAi nAi
(A) 0 (B) 02
2rR rR
nAi n 2i
(C) 0 (D) 0
2r 4rR
2. An engine whistling at a constant frequency n0 and moving with a constant velocity goes part a
stationary observer. As the engine crosses him, the frequency of the sound heard by him changes by
a factor f. The actual difference in the frequencies of sound heard by him before and after the engine
crosses him is
1 1 1 f 2
2
(A) n0 1 f 2 (B) n0
2 f
1 f 1 1 f
(C) n0 (D) n0
1 f 2 1 f
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-19
t
(A) v (B) v
t t
(C) v (D) v
t t
5. Two conducting spheres of unequal radii are given charge such that they have the same charge
density. If they are now brought in contact,
(A) No charge will be exchanged between them
(B) Charge will flow from the larger to the smaller sphere
(C) Charge will flow from the smaller to the larger sphere
(D) No heat will be produced
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-20
6. A particle moving with kinetic energy 3J makes an elastic head-on collision with a stationary particle
which has twice its mass. During the impact,
(A) the minimum kinetic energy of the system is 1.5 J
(B) the maximum elastic potential energy of the system is 1.5 J
(C) momentum and total energy are not conserved at every instant
(D) the ratio of kinetic energy to potential energy of the system first decreases and then increases
7. A converging lens of focal length f is placed in front of a fixed object, at a distance f from it. The lens
is then moved away from the object with a constant velocity. The velocity of the image will
(A) be constant
(B) always be directed towards the object.
(C) pass through a maximum
(D) be zero when the distance of the lens from the object is 2f.
9. A vessel is half filled with a liquid of refractive index . The other half of the vessel is filled with an
immiscible liquid of refractive index 1.5. The apparent depth of the vessel is 50% of the actual depth.
Then is
(A) 1.4 (B) 1.5
(C) 1.8 (D) 1.67
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-21
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion) and
STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
11. Statement 1: For non-uniformly charged thin circular ring having net charge zero, the electric field
intensity at any point on axis is zero.
and
Statement 2: For non-uniformly charged thin circular ring having net charge zero, the electric
potential at any point on axis is zero.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement -1 is True, Statement-2 is False.
(D) Statement -1 is False, Statement-2 is True.
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-22
and
13. Statement 1: A ring and a disc of same mass and same radius begin to roll without slipping from
the top of an inclined surface at t=0. the ring reaches the bottom of incline at time t1 while the disc
reaches the bottom at time t2,then t1>t2.
and
Statement 2: Disc will roll down the plane with large acceleration because of its smaller moment of
inertia.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement -1 is True, Statement-2 is False.
(D) Statement -1 is False, Statement-2 is True.
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-23
Comprehension Type
This section contains 2 groups of questions. Each group has 3 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.
1m 4m
15. The instant at which maximum intensity occurs at P for first time
1 59 1 27
(A) sin1 (B) sin1
160 80
1 1 59 1 1 27
(C) sin (D) sin
80 160
16. The instant at which minimum intensity occurs at P for this first time
1 59 1 27
(A) sin1 (B) sin1
160 80
1 59 1 27
(C) sin1 (D) sin1
80 160
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-24
Two soap bubbles are stuck to each other. One of the gained shape has a radius of R = 6 cm and the other
half has a radius of r = 2 cm.
17. What is the sphere-radius of the spherical cap which separates the two parts?
(A) 3 cm (B) 6 cm
(C) 9 cm (D) 12 cm
18. What is the difference between the pressures in the two parts? The surface tension of the soap
solution is ( = 0.029 N/m).
(A) 2 Pa (B) 4 Pa
(C) 6 Pa (D) 8 Pa
19. By what factor is R greater than r in case of two other bubbles which stick together, if the sphere-
radius of the cap separating the two parts is R?
(A) r (B) 2r
(C) 3r (D) 4r
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-25
SECTION – B
Matrix – Match Type
1. Some relations and laws related to fluids are given in column – I, while the physical reasons behind
them are given in column – II.
Column – I Column - II
(A)
Stoke’s law (p) Surface potential energy
(B)
Equation of continuity (q) Force of viscosity
(C)
Bernoulli’s theorem (r) Conservation of mass
(D)
Velocity of efflux (s) Conservation of energy
Rough work
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Mock Test-2–Paper-2 (100387.1)-CMP-IITJEE-26
Column – I Column – II
(A) Charge on capacitor 1 (p) 20/3 unit
(B) Charge on capacitor 2 (q) 20 unit
(C) Charge on capacitor 3 (r) 30 unit
(D) Voltage drop across capacitor 3 (s) 10 unit
3. In Column I some physical quantities are given while in Column II some possible SI units are given.
Match the entries of Column I with the entries of Column II.
Column – I Column – II
(A) B 2 qv (p) Watt sec ond
, where B is magnetic field intensity, q is charge, v
metre3
is velocity and is magnetic flux.
(B) hgR, where h is Planck’s constant, g is acceleration due (q) Farad volt 2
to gravity, and R is Rydberg constant.
sec ond
(C) b 4 (r) Newton
,where is Stefan’s constant, b is Wein’s constant,
A metre2
and A is area
(D) (s) Newton metre
,where is coefficient of viscosity, R is resistance,
RC sec ond
and C is capacitance
Rough work
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