23

CHEMISTRY
TEST-II
PART-I
SECTION–I
Single Correct Choice Type

1. (D) With one equivalent of AlBr3 only Cl binds to AlBr3, Since methoxy
substituted ring is more activated, so acylation takes place there to give
MeO
. But with three equivalent of AlBr3, chlorine as well
MeO O
(b)
as both oxygens of methoxy groups reacts with AlBr3 and deactivating the methoxy
substituted ring so acylation takes place in the other ring to give
MeO

MeO .
O
(a)

2. (B)

3. (B) The concentration term is in the denominator

E cell = E 0cell −
0.0591 [
Zn 2+ ]
2
log
[
Cu 2+ ]
4. (B)

5. (B)
O– O–
CH3 H H CH3
6. (A) Severe van der Waal’s repulsion
H CH3 H CH3
Br Br
2R, 3S 2R, 3R

SECTION–II
Integer Type
CH3
Base – – H3 C O–
7. CH3–C–CH3 –H base
CH3–C–CH2 , HO + C=O C
base H3 C OH
O O CH3
acid acid

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+ + + +
:O: H–OH2 acid OH :O: H–OH2 OH
CH3–C–CH3 CH3–C–CH3 , Ph–C–Ph Ph–C–Ph
–H2O –H2O
base base
O O–
acid Ph–C–Ph Ph–C–Ph , CH3COOH + –OH CH3COO– + H2O
acid
–
OH base OH
+ +
:O: H–OH2 OH
base –
CH3–C–OH –H2O CH3–C–OH , CH3–CN CH2–CN
–H+
base acid

.. + +
CH3–C≡N + H–OH2 –H2O
CH3–C≡NH , NH3 + PhLi LiNH2 + PhH

+ .. +
H2O–H + NH3 H2O + NH4
..
H2O + RO– –
OH + ROH, H2 O
. . + H–Cl H3O+ + Cl–
+
O OH O O
.. –
S=O
.. H–HSO4 S + HSO4– , HO S=O HO–S–O–
O O O O O
Ans. 7

ν
8. ν = 7.312 × 1014 s −1 → ∴ ν= = 2437200 m −1
C
ν in cm −1 = 24372 cm −1
For Ist excited state ⇒ n = 2
1 1 
∴ 24372 = 109677  − 2 
4 n2 
⇒ n 2 = 6 i.e. 5 excited state
th

Ans. 5
9. ∆Tf = K f m ⇒ 0.93 = 1.86 × m
⇒ m = 0.5 molal
∆Tb = K b m ⇒ 0.26 = K b × 0.5
⇒ K b = 0.52 K kg mol–1
7.9 × 1000
Similarly 0.44 = 0.52 × [Molecular mass = 31 n]
31 n × 100
⇒ n=3

Ans. 3

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*
10. CH3–CH–CH=CH2 CH2–CH2–CH=CH2
Cl Cl
(2 products) (1 product)

CH3–CH=CH–CH2Cl (2 products)
CH3 CH2Cl CH3 H
C=C C=C
H H H CH2Cl
Ans. 5

1
11. H2 + O2 → H 2 O(l), ∆H = −285.85 kJ …(i)
2
→ CO 2 (g ), ∆H = –293.7 kJ
C + O2  …(ii)
Given, combustion of 1 g gives 17.49 kJ energy
∴ 162 n g will give 17.49 × 162 n kJ = 2833.38 n kJ
∴ (C 6 H10 O 5 ) n + 6nO 2 
→ 6nCO 2 + 5nH 2 O ; ∆H = −2833.38 kJ …(iii)
multiplying equation (ii) by 6n and equation (i) by 5n then adding
5n
5nH 2 + O 2 + 6nC + 6nO 2 
→ 5nH 2 O + 6nCO 2 …(iv)
2
∆H = −3191.45 kJ
equation (iv) – (iii)
5n
6nC + 5nH 2 + O2 
→(C 6 H10 O 5 ) n , ∆H = −358.07 n kJ
2
heat of formation = – 358.07 n kJ/mol
– 2148.42 kJ mol–1 = – 358.07 × n kJ mol–1
∴ n=6
Ans. 6

SECTION–III
Paragraph Type

12. (D)
13. (D)

14. (B)

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For Question Nos. 15 to 17

(A) (B)
+
* Ag(NH3)2 *
HOCH2–CH2–CH–CH2–CHO HO–CH2–CH2–CH–CH2–COOH
CH3 CH3
H2CrO4
CrO3 in pyridine

(C) (D)
OHC–CH2–CH–CH2–CHO HOOC–CH2–CH–CH2COOH
CH3 CH3
Zn-Hg/HCl

CH3–CH2–CH–CH2–CH3
CH3
3 methylpentane

CH3 CH2 O
15. (B) C COOH dil
H O
OH H2SO4
CH2–CH2
cyclic ester
16. (A)
O
OCH3
CH2–C–H CH2––CH OCH3 OCH3
– CH3OH
CH3–CH OCH3 CH3–CH O– O O
–CH3O–
CH2–C–H CH2––C–H O– OH
O O

O O
CH2––C CH2––C
O–H ∆, P2O5
17. (C) CH3–CH CH3–CH O
– H2O
O–H
CH2––C CH2––C
O O

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SECTION –IV
Matrix Type

18. (A) – (s), (t) ; (B) – (p), (q), (r), (s) ; (C) – (p), (r), (s) ; (D) – (p)
(A) Nucleophilic substitution of C2H5OH by H2O
+
H–OH2 .. + +
C2H5O–CH=CH2 C2H5O–CH–CH3 C2H5O=CH–CH3
..
H2 O
H H
+
CH3–C–H C2H5O––C–CH3 C2H5O–C–CH3
O H :OH H–O–H
+
CH3 CH3 CH3 CH3
2+ +
Hg , H3O
(B) HO–C–C≡C–C–OH HO–C–CH=C––C–OH
CH3 CH3 CH3 OH CH3
enol
O
C CH3
CH2 C CH3 CH3
CH3 H3O+
CH3––C + :OH HO–C–CH2–C––C–OH
–H2O
CH3 SN1 CH3 O CH3
O

O
cyclic ketone

O
O O CH2
CH3–C–CH SNi
–
OH – CH2
(C) CH3–C–CH2CH2 CH2Cl CH3–C–CH––CH2
–Cl–
CH2
Cl
OH O
(D) Ph–C–CH3 Ph–C–CH3 + HBr

Br
19. (A) – (q), (r) ; (B) – (p), (q) ; (C) – (r), (t) ; (D) – (r), (s)

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PHYSICS
PART-II
SECTION–I
Single Correct Choice Type

MgL
20. iL2 B =
2
L
iL2 B + Mg = TL
2
MgL = TL
T = Mg
∴ (A)

1 2 1 v2 1
21. kA + 2m 0 = kA'2 (by energy and momentum considerations)
2 2 4 2
1
kA2 + mv02 = kA'2 ⇒ A'= 2 A
2
5π
A'= 2 A ⇒ φ =
4
x = A' sin (ω' t + φ)
k
ω' =
2m
 k π
x = − 2 A sin  t + 
 2m 4 
∴ (A)
22. As process is isochoric, let temperature at any instant of time t be T.
dQ KA · (2T0 − T ) 5 RdT
= =
dt d 2 dt
T t
dT 2 KA
⇒ ∫T 2T0 − T = ∫0 5 dR dt
0

2 KAt
−
⇒ T = T0 (2 − e 5 dR
).
∴ (A)
23. Increase in length of wire is = 2 a 2 + L2 − 2 L

Strain in wire =
(
2 a 2 + L2 − L )
2L
T/A
Y=
strain
T = YA(strain )

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Yπr
(a )
2
= 2
+ L2 − L
L
Yπr 2   a 2 1/ 2 
=  L 1 +  − L 
L   L2  
 
Yπr 
2
a 2

=  L + − L 
L  2L 
πYa 2 r 2
=
2L2
∴ (C)
24. By the principle of balanced Wheatstone bridge, the given circuit can be redrawn as
R R/2 R/4 to ∞

A B

R/2 R/4 R/8 to ∞

R1

A B

R2
 
 1 
R1 = R  = 2R
1− 1 
 
 2
 
R 1 
R2 =  =R
2 1− 1 
 
 2
2R × R 2R
∴ R AB = =
2R + R 3
∴ (D)
25. mv0 = 3mv ⇒ v = v0 / 3
2
v  1
velocity of block when θ = 60º is v' =  0  − 2 g × = 10 m/s
3 2
∴ ac = 100 ms –2

at = g sin 60 = 5 3 ms–2
∴ ratio at : ac = 3 : 20
∴ (C)

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SECTION–II
Integer Type
26. Since, electron is accelerated through a potential difference V, its initial velocity v 0 is given
1
by mv 02 = eV
2
2eV
or v0 = ..... (i)
m
v

θ
E
v0

l
Since, initial velocity is parallel to plates or normal to the direction of electric field,
component of velocity parallel to plates remains constant as v 0 .
l
Hence, time taken by the electron to cross electric field is t 0 =
v0
Now consider motion of electron, normal to plates.
eE eat
At some instant t, its acceleration = =
m m
Let velocity component normal to plates be v y
d e at
∴ vy =
dt m
vy e a t0
∴ ∫0 dv y = m ∫0 t dt
ea 2 al2
or vy = t0 = ..... (ii)
2m 4V
If θ is angular deviation of electron from its initial direction of motion,
then pitch of its helical path.
2πm
p= v cos (90 − θ)
eB
2πm 2πm
∴ p= v sin θ = vy
eB eB
πm a l 2
or p=
2e B V
p = 9 mm.
Ans.: 9

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27. When only switch 2 is closed
V1

J
A B

R R R
G

r V
3RV V
= 1 λL1 … (i) (λ - resistance per unit length)
r + 3 R λL
When all switches are closed
V1

A J1
B

R
G

r V
V R V
× = 1 λL2 … (ii)
+ r 3 λL
R
3
Dividing (i) and (ii)
3R + 9r = 3r + 9 R
r=R
∴ n =1
Ans.: 1
28. Drawing F.B.D of piston
P1 A + kx − P2 A = ma … (i)
a a
P1 , V1 , T 1 P2 , V2 , T 2

P1A P2A

m
kx

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l 
V1 = A − x 
 2 
 l 
V2 = A + x 
 2 
l
V0 = A
2
γ
Since process is adiabatic, P0V0γ = P1V1 = P2V2γ
γ γ
V   l 
⇒ P1 = P0  0  = P0  
 V1   l − 2x 
−γ
 2x 
P1 = P0 1 − 
 l 
 2 γx 
P1 = P0 1 +  (∵ x << l)
 l 
 2 γx 
Similarly P2 = P0 1 −  … (i)
 l 
(P1 − P2 )A + kx = ma
4 P0 γxA
+ kx = ma
l
ma 4 n
x= = =
4 P γA 4 P γA nP γA
k+ 0 k+ 0 k+ 0
l l l
∴ n=4
Ans.: 4
29. The given arrangement can be redrawn as

k l

l
k
m

Since rod is massless

k (lθ)l + (k (2lθ − x ))2l = 0

kl 2 θ + k 4l 2 θ − 2klx = 0

2kl
θ= x … (i)
5kl 2

For block

k (2lθ − x ) = ma
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 2klx 
k 2l 2
− x  = ma
 5 kl 

 4x 
k  − x  = ma
5 

k
a=− x
5m

5m
T = 2π
k

∴ n=5
Ans.: 5
vy Jy

30. vx θ
ω0 v0
Jx
v0 = Rω0
Since collision is elastic
v
e = 1 = x ⇒ v x = v0
v0
∴ J x = 2mv0
Also J y = µ ∫ Ndt = µJ x = mv y
Jy

Jx

µ × 2mv0
∴ vy = = 2µv0
m
Now for Rmax θ = 450
∴ vy = vx
1
⇒ µ=
2
∴ n=2
Ans.: 2

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SECTION−III
Paragraph Type
31. k 1 , k 2 and k 3 are closed
 12 × 6 
Time constant =  + 6  R × 2C = 20 RC
 12 + 6 
V
Initial current in R 2 =
30R
V
Final current in R 2 =
18R
t
V  V V  − 20 RC
Current in R2 at an instant t = + −  e
18 R  30 R 18 R 
−
t  t 
=
V
−
V
e 20RC =
V  5 − 2 e − 20 RC .
18R 45R 90R  
 
∴ (D)

V
32. Potential difference across each capacitor at t = ∞ is .
3
2 2
1 V  CV
Energy stored = (C )   = .
2 3 18
∴ (B)
33. When k1, k3 opened, k4 closed R
CV 2
Heat = R CV 2
36 18
∴ (A)

34. 20 sin 60º = v sin30º

v = 20 3 m/s.
∴ (B)

1 1
35. WF = ∆K = m (v2 − u2) = × 10 × [(20 3 )2 – (20)2] = 5(1200 – 400) = 4000 J.
2 2
∴ (D)
WF 4000 2000
36. Pav = = = W.
t 2 × 20 × 3 3
2 × 10
∴ (C)

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SECTION − IV
Matrix Type

37. In figure (A)

1 1 
= (1.5 − 1) −
1 1
=+
fe  ∞ − 20  40
1 1
=
f m 10
1 1 1 1 3
= + + =
f ' 40 10 40 20
20
f '= cm (concave mirror)
3
Power = +15 D
Velocity of image = 2 cm/s
In figure (B)
Focal length of device = 4 cm and it is a concave mirror of power = +25 D
Velocity of image = 4 cm/s
In figure (C)
Focal length = 40 cm and it is a concave mirror of power = +2.5 D
Velocity of image = 0.5 cm/s
In figure (D)
Focal length = 2.5 cm (concave mirror)
Power = +40 D
Velocity of image = 4 cm/s
∴ (A) – (p), (r), (s), (t) ; (B) – (r), (s), (t) ; (C) – (p), (q), (t) ; (D) – (p), (r), (s), (t)
38. (A)
Process is isobaric
5 7
So CV = R, C P = R
2 2
7 5
∆Q = RT0 , ∆U = RT0
2 2
∆W = RT0
P
(B) = constant , isochoric process
T
3
C = CV = R
2

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3
∆Q = ∆U = RT0
2
∆W = 0
R
(C) CV = = 2R
1. 5 − 1
P
VT = constant; PV 2 = constant; = constant
ρ2
dV
V +T =0
dT
dV V
=−
dT T
P dV PV
=− = −R
n dT nT
C = CV − R = R

∆Q = RT0 , ∆U = 2 RT0 ; ∆W = − RT0

2 3
(D) γ = 1+ =
4 2
R
CV = = 2R
3
−1
2
P2
PT = constant; P 2V = constant; = constant
ρ
∆U = 2RT0

∆W = 2RT0

∆Q = 4RT0

∴ (A) – (p), (q), (r) ; (B) – (q), (s) ; (C) – (q), (r), (t) ; (D) – (p), (q), (r), (t)

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MATHEMATICS
PART-III
SECTION–I
Single Correct Choice Type
39. (C) Let 2010 be in kth row
⇒ kth term of series 1, 2, 4, 7, ….. ≤ 2010
and (k + 1)th term of series 1, 2, 4, 7, ….. > 2010
S n = 1 + 2 + 4 + 7 + ..... + Tn
Sn = 1 + 2 + 4 + ..... + Tn −1 + Tn
⇒ 0 = 1 + (1 + 2 + 3 + .....(n − 1) terms) − Tn
n2 − n + 2
⇒ Tn =
2
k −k +2
2
k2 + k + 2
⇒ ≤ 2010 and > 2010
2 2
⇒ k 2 − k − 4018 ≤ 0 and k 2 + k − 4018 > 0
2 2
 1 16073  1 16073
⇒ k −  ≤ and  k +  >
 2 4  2 4
1 1
⇒ k − ≤ 63.3 and k + > 63.3
2 2
⇒ k = 63
40. (C) k cos 2 x − k cos x + 1 ≥ 0 ∀ x ∈ ( −∞, ∞ )
(
⇒ k cos 2 x − cos x + 1 ≥ 0 ) ……..(i)
2
 1 1
But cos 2 x − cos x =  cos x −  −
 2 4
1
⇒ − ≤ cos 2 x − cos x ≤ 2
4
1
∴ from (i), we get 2 k + 1 ≥ 0 ⇒ k ≥ −
2
k
⇒ − + 1≥ 0 ⇒ k ≤ 4
4
1
⇒ − ≤k≤4
2
2 2
2  1
2  1
2  1

 2π 
41. (B) We have OP =t +  a +  t −  b + 2  t 2 − 2  a b cos  
 t  t  t   3 
2 2
2  1  1  1   −1
OP = 9  t +  + 4  t −  + 2  t 2 − 2 3.2. 
 t  t  t   2 
 1   1   1
= 9t2 + 2 + 2 + 4t2 + 2 − 2 − 6t2 − 2 
 t   t   t 
19
= 7 t 2 + 2 + 10
t
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2 19
⇒ OP ≥ 2. 7t 2 . + 10 (∵ A.M . ≥ G.M . )
t2
∴ minimum value of OP = 10 + 2 133
42. (B) As A.M. of roots is equal to G.M of roots, so all roots are equal and equal to 1.
⇒ a 2 + a3 = n C 2 − n C3 < 0 ⇒ n C 2 < n C3 ⇒ n > 2 + 3
43. (D)
For n ≥ 1
(x k
− 1)
− n −1
pn ( x ) =
d
dx
([ −n
]
x k − 1) .p( n −1) ( x )

= (−n) ( x k − 1) − n −1 (k x k −1 ) p n −1 ( x) + ( x k − 1) − n p ' n −1 ( x)
Or p n ( x) = ( x k − 1) p ' n−1 ( x) − n( k x k −1 ) p n −1 ( x)
at x = 1
p n (1) = − n k p ( n −1) (1)
⇒ p n (1) = −nk [− (n − 1)kp n −2 (1)]
By doing so on we get
p n (1) = n !(−k ) n p 0 (1)
44. (B) Putting x = f (t ) ⇒ dx = f ' (t ) dt
2π
I = ∫ t. f ' (t )dt (∵ f (π) = π and f ( 2π) = 2π)
π
2π
2π
= t. f (t ) π − ∫ 1. f (t )dt
π
2π
t2
= 2πf (2π) − πf (π) − − cos t
2 π

3π 2
= 4π 2 − π 2 −
1
2
(4π 2 − π 2 ) + (cos 2π − cos π) =
2
+ 2.

SECTION–II
Integer Type
45. Let the three sides be a ≤ b ≤ c = 11
Then 6 ≤ b ≤ 11 and c − b < a ≤ b. As b decreased by 1 unit the range of a decrease by 2.
When b = 11, we have 1 ≤ a ≤ 11.
Hence the total number of triangles is 11 + 9 + 7 + 5 + 3 + 1 = 36
Ans. 6
46. n
C0 − nC1 + nC2 − nC3 + .... + (−1) r . n Cr
= n−1C0 − ( n−1 C0 + n−1C1 ) + ( n−1 C1 + n−1C2 ) − ( n−1 C2 + n−1C3 ) + ... + (−1) r .( n−1 Cr −1 + n−1Cr )
= (−1) r . n−1Cr
(−1) r . n−1Cr = 28 ⇒ r must be even
7×8 8
n −1
Cr = 28 ⇒ n−1 Cr = 7 × 4 = = C2 ⇒ n − 1 = 8 ⇒ n = 9
2
Ans. 9
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5 3
47. The corresponding normals are y = x ± . P

3
N Q C
5 3
Considering y = x +
(–√3, 0)
, corresponding tangent is
3
y = −x − 3
−4 1 
⇒ Point of contact is  , 
 3 3
4 1
⇒ Length of sub tangent = NQ = NC − QC = − 3= ⇒ k =3
3 3
Ans. 3

cos x cos 2 x
48. Let C = 1 + + + .....
3 32
sin x sin 2 x
and S = + + .....
3 32
e ix e 2ix
⇒ C + iS = 1 + + 2 + .....
3 3
1 3
⇒ C + iS = =
e ix
3 − cos x − i sin x
1−
3
Comparing real parts
3(3 − cos x )
C=
(3 − cos x )2 + sin 2 x
 1
⇒ C = 1. ∵ cos x = 
 3
Ans. 1
49. S1 : C1 (−5, 12)
S 2 : C 2 (5, 12)
r1 = 16, r2 = 4
CC 2 = r + 4 (Where C is the centre of circle touching C2 externally and C1 internally)
CC1 = 16 − r (Not r − 16, ∵ S 2 is contained by S1)
⇒ CC1 + CC 2 = 20
∴ Locus of C is the ellipse with foci at C1 and C2 and length of major axis = 20
∴ Locus of C is
x 2 ( y − 12 )
2
+ =1 ..……(i)
100 75
According to question y = ax is tangent to this ellipse from (0, 0)
Equation of tangent to (i) is
y − 12 = mx + 100m 2 + 75
But this is passing through (0, 0)

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 40

⇒ − 12 = 100m + 75 2

69
⇒ m2 =
100
⇒ p + q = 169
⇒ k = 2.
Ans. 2

SECTION–III
Paragraph Type

50. (D)
51. (A)
52. (D)
Sol. The equations of the bisectors are given by x − y = 0 and x–y = 0
x+ y+2=0 (1, 1)
N
These bisectors intersect at the point (−1,−1) (–1,–1)
P

Focus S, is the foot of ⊥ from P to MN

S
i.e. point of intersection of lines
MN (3 x − y − 2 = 0 ) and PS ( x + 3 y + 4 = 0 )
M
(0,–2)
 1 7 
∴ Focus is  , −  x+y+2 = 0
 5 5 
2 2
MS = , NS = 4
.
5 5
  2 2
 2  4


  5 5  
Length of latus rectum = 2 
 2 2 
+4
 5 5 
(∵ H.M. of segments of focal chord is semi latus-rectum)
2
16 ×
= 5 = 16 × 2 = 16 2
5
2 5 5 (5)3 / 2
5
Circle passing through PMN is (x − 0 ) ( x − 1) + ( y − 1) ( y + 2 ) = 0
x2 + y 2 − x + y − 2 = 0
∴ equation of tangent at (−1, − 1), which is also the equation of directrix is 3 x + y + 4 = 0.

53. (A)
54. (D)
55. (C)
Sol. f ( x ) = x 4 − 6 x3 + 26 x 2 − 46 x + 65 .

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Since complex roots occur in conjugate pairs.
a1 = a2 , a3 = a4 , b1 = −b2 & b3 = −b4
( )( )
Product = a12 + b12 a 32 + b32 = 65 and sum of roots = 2(a1 + a3 ) = 6 ⇒ a1 + a 3 = 3
Without loss of generality let a12 + b12 < a 32 + b32
Case I a12 + b12 = 1, a32 + b32 = 65
⇒ a1 = 0, b1 = 1
⇒ a3 = 3 (∵ a1 + a3 = 3)
Not possible ∵ b3 = 65 − 9 not an integer
Case II a12 + b12 = 5, a 32 + b32 = 13
Sub-case I a1 = 2, b1 = 1
⇒ a 3 = 1, not possible ∵ b3 = 12 not an integer
Sub-case II a1 = 1, b1 = 2
⇒ a 3 = 2, b3 = 3 integer (only possible solution)
⇒ roots of equation are 1 ± 2i, 2 ± 3 i .
⇒ µ = 1 + 1 + 2 + 2 = 6, λ = 2 + 2 + 3 + 3 = 10
and S = {1, 2, − 2, 3, − 3}
⇒ Number of functions from S to C are 85

SECTION–IV
Matrix Type

56. (A) – (p), (q) ; (B) – (p), (q), (s) ; (C) – (q), (s), (t); (D) – (p), (q), (s).
57. (A) – (p), (q), (r), (s), (t) ; (B) – (r) ; (C) – (q) ; (D) – (p), (q).
7!
(A) 7 P4 = = 840
3!
(B) The image of the point (2, − 3, 3) in the plane x − 2 y − z + 1 = 0 is (0, 1, 5) . Its distance
from z-axis is 1.
(C) Total no. of ways = 2 ( 8 c3 ) + 4 ( 7 c3 + 6 c3 + 5 c3 + 4 c3 + 3 c3 ) = 392 .
8!
(D) Total number of ways that can be formed = = 420
2! 2! 4!
5!
Let ABBC be a unit, then this unit and other ABBC can be arranged in ways = 60
2!
But this includes ABBC ABBC two times.
∴ Actual number = 59
∴ Required number = 420 − 59 = 361.

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