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Review of
Semiconductor Barrier Potential PN Junction
material Intrinsic, Doping Piecewise linear model
Intrinsic, Doping
PN Junction Junction
Biasing Capacitance
Forward & Reverse Bias Structure
The behavior of solid state devices
Depends on
atomic theory,
quantum mechanics, and
electron models.
Plum pudding model
‘+’vely charged
"pudding”
Rutherford model
E4 hv = E4-E1
E3
E2
E1
E!
Number of shells = 4
Valence electrons = 1
IONS
IONS are atoms or groups of atoms with a positive or negative
charge.
Taking away an electron from an atom gives a CATION with a
positive charge
Adding an electron to an atom gives an ANION with a
negative charge.
Examples: Na+ Ca+2 I- O-2 (IONS)
Na Ca I O (atoms)
TECHNICAL TALK - PN JUNCTION
Energy Bands
Conduction band
Empty band
Electron energy
Bandgap forbidden gap
Outermost band
containing elelectrons Valence band
Partially full
Bandgap
Full
Bandgap
Full
nucleus
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TECHNICAL TALK - PN JUNCTION
Elements
18
Bonding Forces Between Atoms
• Nature of the material is a conductor, semiconductor
or insulator depends largely upon what happens to the
outer-shell electrons when the atoms bond themselves
together to form a solid.
• The three types of bonds are
– Metallic bonding (minor Bonding)
– Covalent bonding
– Ionic bonding
Chemical Bonds
• Chemically combining of two or more atoms
– Covalent Bonds
– Ionic Bonds
Covalent Bonds
• Metallic bonding
– Occurs between like atoms of a metal in the free state
– Valence e- are mobile (move freely among all metal atoms)
– Positive ions in a sea of electrons
• Metallic characteristics
– High mp temps, ductile, malleable, shiny
– Hard substances
– Good conductors of heat and electricity as (s) and (l)
TECHNICAL TALK - PN JUNCTION
Insulators
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Conductors
29
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Semiconductors
Semiconductors have a resistivity/resistance between that of conductors and
insulators
Their electrons are not free to move but a little energy will free them for
conduction
30
TECHNICAL TALK - PN JUNCTION
Semiconductor
31
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Conduction electrons and Holes
Energy
Free electron
Conduction band
Holes
32
TECHNICAL TALK - PN JUNCTION
The Silicon, Si, Atom
Silicon has a valency of 4 i.e. 4 This picture shows the
electrons in its outer shell shared electrons
Each silicon atom shares its 4
outer electrons with 4
neighbouring atoms
These shared electrons –
bonds – are shown as
horizontal and vertical lines
between the atoms
33
TECHNICAL TALK - PN JUNCTION
Silicon – the crystal lattice
If we extend this
arrangement throughout a
piece of silicon…
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TECHNICAL TALK - PN JUNCTION
Hole Movement in Silicon
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TECHNICAL TALK - PN JUNCTION
Hole Movement in Silicon
This hole can also move…
An electron – in a nearby
bond – may jump into this
hole…
Effectively causing the hole
to move…
Like this…
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TECHNICAL TALK - PN JUNCTION
Heating Silicon
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Intrinsic Conduction
40
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Intrinsic Conduction
41
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Intrinsic Conduction
If more heat is applies the
process continues…
More heat…
More current…
Less resistance…
The silicon is acting as a
thermistor
Its resistance decreases with
temperature
https://www.vascak.cz/data/android/physicsatschool/templateimg.php?s=pol_pohyb_der&l=
42
en
TECHNICAL TALK - PN JUNCTION
Intrinsic Material
No impurity
No charge carrier At 0ºk.
43
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Intrinsic Material
e-
Si
h+ Si
Si Si
Si
44
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Extrinsic Material
45
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The Phosphorus Atom
Phosphorus is number 15
in the periodic table
46
TECHNICAL TALK - PN JUNCTION
Doping – Making n-type Silicon
Relying on heat or light for
conduction does not make
for reliable electronics
We now have an electron that is not bonded – it is thus free for conduction
47
TECHNICAL TALK - PN JUNCTION
Doping – Making n-type Silicon
Let’s remove another silicon
atom…
and replace it with a
phosphorus atom
As more electrons are
available for conduction we
have increased the
conductivity of the material
49
TECHNICAL TALK - PN JUNCTION
N-type Silicon From now on
n-type will be
shown like this.
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The Boron Atom
Boron is number 5 in the
periodic table
52
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Doping – Making p-type Silicon
Let’s remove another silicon
atom…
and replace it with another
boron atom
As more holes are available for
conduction we have increased
the conductivity of the material
Boron is the dopant in this If we now apply a potential difference across the
case silicon…
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TECHNICAL TALK - PN JUNCTION
Extrinsic Conduction – p-type silicon
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P-type Silicon From now on
p-type will be
shown like this.
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Extrinsic Material
Si Si Si Si
Si Si e-
h+
Si Si Si
Si Si Si
56
Carriers Concentrations
f(E)
1
T=0ºK
T1>T
2 >0ºK
1
1/2
E
Ef
1 1 1
f (E f ) ( E f E f )
1 e kT 11 2
The Fermi Level
E
f(Ec) f(Ec)
Ec
Ef
[1-f(Ec)]
Ev
≈
f(E) Intrinsic
p-type
n-type
1 1/2 0
Electron and Hole Concentrations at Equilibrium
E
Electrons
N(E)f(E)
EC
Ef
EV
N(E)[1-f(E)]
Holes
Intrinsic
p-type
n-type
Optical Absorption
Luminescence
Photoluminescence
Fluorescence: emission stops in about 10-8 s.
Ex : fluorescence lamp
Phosphorescence: If emission stops in about seconds or
even minutes.
Ex : phosphors
Electroluminescence
By using electrical energy generating photon emission.
Ex: LEDs.
Effects of Heat and Light
• In conductors currents flows due to free electrons in the
interatomic spaces.
• As the temperature increases the vibration in the lattice will
increase due to which collision of free electrons with atoms
increase.
• This will lead to reduction of magnitude of current.
• Conductors will have positive temperature coefficient
• https://www.vascak.cz/data/android/physicsatschool/templ
ateimg.php?s=mf_vnitrni_energie&l=en
Effects of Heat and Light
• In semiconductor as the temperature increases more
charge carriers are generated because of which current
will increase.
• So Semiconductors will have negative temperature
coefficient
• https://www.vascak.cz/data/android/physicsatschool/t
emplateimg.php?s=pol_generace&l=en
Carrier Charge Density
• Intrinsic Semiconductor: Pure semiconductor.
• Number of atoms per cubic centimeter is 5 *1022,
• Electron density ni=1.5*1010/cm3
• This means 1.5*1010 electrons have released one
electron and consequently 1.5*1010 holes have been
created.
• So the hole density is same as the electron density
(pi=ni)
Doped Semiconductor
• If an n-type material has a density of n free electrons
per cubic centimeter.
• By law of mass action n*p=ni2
• n=ND+p
• p=Np+n
• ND+p=Np+n
Semiconductor Conductivity
Charge Carrier Velocity
• Electrons have greater mobility than holes.
• The mobility constants determine the electrons and
hole velocities under the influence of an electric field.
• Electron velocity vn=-μnε
• Hole velocity vp=-μpε
Mobile Charge Carriers in Semiconductors
• Three primary types of carrier action occur inside a semiconductor:
– Recombination-generation (R-G)
Diffusion of carriers
Diffusion Process
Carriers in semiconductor diffuse in a carrier gradient by random thermal motion and scattering from the
lattice and impurities.
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TECHNICAL TALK - PN JUNCTION
Diffusion of carriers
Drift and diffusion
Minority current flow is primarily diffusion.
Majority .current flow is primarily drift.
The hole drift and diffusion current densities are in the same direction.
The electron drift and diffusion current densities are in the opposite direction
J ( x) J n ( x ) J p ( x )
72
Electrons as Moving Particles
In vacuum In semiconductor
a
q electrons
mn*
a *
q holes
mp
3 1 * 2
Average electron kinetic energy kT mn vth
2 2
2
3 1
4 electron
5
E
Electrons drift in the direction opposite to the E-field net current
Because of scattering, electrons in a semiconductor do not undergo constant acceleration.
However, they can be viewed as quasi-classical particles moving at a constant average drift
velocity vdn
Carrier Mobility, m
Solution:
a) vdp = mpE
qt m p m*p m p
b) mp *
t mp
m p q
Mobility Dependence on Temperature
1 1 1
m m phonon mim purity
Hole Drift Current Density, Jp,drift
1
• The resistivity of a semiconductor is
– Unit: ohm-cm
Resistivity Dependence on Doping
W
t
uniformly doped semiconductor
V L
Resistance R [Unit: ohms]
I Wt
where is the resistivity
Example: Resistance Calculation
What is the resistivity of a Si sample doped with 1016/cm3 Boron?
Answer:
1 1
qnm n qpm p qpm p
(1.6 10 19 16
)(10 )( 450 ) 1
1.4 cm
Example: Dopant Compensation
Consider the same Si sample doped with 1016/cm3 Boron, and additionally doped with
1017/cm3 Arsenic. What is its resistivity?
Answer:
1 1
qnm n qpm p qnm n
(1.6 10 19
)(9 10 )(600 )
16
1
0.12 cm
Summary
• Electrons and holes can be considered as quasi-classical particles with
effective mass m*
• In the presence of an electric field E, carriers move with average drift
velocity vd = mE , m is the carrier mobility
– Mobility decreases w/ increasing total concentration of ionized dopants
– Mobility is dependent on temperature
• decreases w/ increasing T if lattice scattering is dominant
• decreases w/ decreasing T if impurity scattering is dominant
qpm p qnmn 1
TECHNICAL TALK - PN JUNCTION
Semiconductor Diode
Pn-junction Diode
The term diode indicates two-electrode device.
The two sides of the junction are provided with connecting terminals.
A diode is a one-way device, offering a low resistance when forward biased and behaving almost as an
insulator when reverse biased.
Symbols of PN Junction diode
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The p-n Junction
Suppose we join a piece of p-type silicon to a piece of n-type silicon
‘+’ ve Ion
Ec Ec
Ef
Ef
Ev Ev
p-type n-type
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The p-n Junction
When initially joined electrons
from the
n-type migrate into the p-type
– less electron density there
This leaves a region with no free charge carriers – the depletion layer – this layer acts as
an insulator
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The p-n Junction 0.6 V
Therefore there is a voltage across the junction – the junction voltage – for silicon this is
approximately 0.6 V
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pn junction diode
Ec
Ec
Ef Ef
Ev
p-type Ev
93
n-type
TECHNICAL TALK - PN JUNCTION
pn junction diode
qV0
Ec qV0
Ec
Efp Efn
Ev
p-type Ev
n-type 94
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The Forward Biased P-N Junction
Take a p-n junction
Apply a voltage across
it with the
p-type postitive
n-type negative
Close the switch
The voltage sets up an
electric field
throughout the The junction is said to be forward –
junction biased
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TECHNICAL TALK - PN JUNCTION
The Forward Biased P-N Junction
Negative electrons in the
n-type feel a repulsive
force which pushes them
into the depletion layer
Forward bias
+ + + + +
+ + + + +
+ + +
+ + + + + + +
+ + +
+ + + + + +
+ + + + +
++
+ + + + + +
99
PN Junction Forward Biased Characteristics
TECHNICAL TALK - PN JUNCTION
The Reverse Biased P-N Junction
Take a p-n junction
Apply a voltage across
it with the
p-type negative
n-type positive
Close the switch
The voltage sets up an
electric field
throughout the
junction The junction is said to be reverse – biased
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TECHNICAL TALK - PN JUNCTION
The Reverse Biased P-N Junction
Negative electrons in the
n-type feel an attractive
force which pulls them
away from the depletion
layer
+ + + + +
+ + + + +
+ + +
+ + + + + + +
+ + +
+ + + + + +
+ + + + +
++
+ + + + + +
103
Reverse Bias Current
Junction Temperature Effects
• When the temperature of the semiconductor material
is raised, increasing numbers of electrons break away
from their atoms.
• This will generate additional minority charge carriers
causing Io to increase as the junction temperature
rises.
• Io(T2)=Io(T1)(2T2-T1/10)
Reverse Bias Current variation with Temperature
TECHNICAL TALK - PN JUNCTION
The Semiconductor Diode
• The semiconductor diode is a p-n junction
• In reverse bias it does not conduct
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The Semiconductor Diode
• The silver line drawn on one side of the diode
represents the line in its symbol
• This side should be connected to the negative terminal
for the diode to be forward biased
• Diodes are used to change alternating current to direct
current
• Diodes are also used to prevent damage in a circuit by
connecting a battery or power supply the wrong way
around
108
Ideal Current-Voltage Relationship
VD = - VS
Reverse-bias
Forward-bias
EXAMPLE: Determine the diode voltage and current
in the circuit using ideal model for a silicon diode.
Also determine the power dissipated in the diode.
CIRCUIT REPRESENTATION OF DIODE – Piecewise
Linear Model
VD = - VS
Reverse-bias
VD = - VS
Reverse-bias
Question
Determine the diode voltage and current for
the circuit.
Consider IS = 10-13 A.
VPS = IDR + VD
ITERATION METHOD
5 = (2 x103) (10-3) [e ( VD / 0.026) – 1 ] + VD
VD = 0.619 V
And ID = 2.19 mA
IDEAL MODEL PIECEWISE PIECEWISE DIRECT
LINEAR MODEL 1 LINEAR MODEL 2 APPROACH
Use KVL: VD
2ID + VD – 5 = 0
ID = -VD + 5 = - VD + 2.5
2 2
EXAMPLE
A diode circuit and its load line are as shown in the figure below
Design the circuit when the diode is operating in forward bias condition.
Determine the diode current ID and diode forward resistance rf in the circuit using a
piecewise linear model. Consider the cut-in voltage of the diode, Vγ = 0.65V.
IDR + VD – 5 = 0 at VD = 0.7V
ID = -VD/R + 5/ R ID = (5 – 0.7) / 2 = 2.15 mA
5/ R = 2.5 mA
R = 2 kΩ Now, VD = Vγ + ID rf
0.7 = 0.65 + 2.15 rf
rf = 0.05 / 2.15 mA = 23. 3 Ω
Diode AC Models
• The depletion region of a pn-junction is a layer
depleted of charge carriers situated between to blocks
of low-resistance material.
• The depletion layer capacitance may be calculated
from the equation for a parallel plate capacitor if the
junction dimensions are known.
• Typically Cpn=4 pF
Diode AC Model
• In forward biased junction if the applied voltage is
suddenly reversed, forward current IF ceases
immediately, leaving some majority carriers in the
depletion region.
• These carriers have to go back out of the depletion
region. i.e when a forward biased junction is suddenly
reversed, there is a reverse current. This is similar to
capacitor discharge and is given as Cd=τIF/VF
AC Equivalent Circuits (Reverse Biased and Forward Biased)
Reverse Recovery Time