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EQUIPMENT DESIGN
APPLICATION
1. In a shell-and-tube heat exchanger with the shell-side having an entering pressure of 588 psig,
calculate the design pressure of the shell-side.
A. 613 psig B. 563 psig C. 646.8 psig D. 529.2 E. None
psig of
the
abov
e
Solution:
In calculating the design pressure, the maximum allowable pressure is calculated by the addition of 25
psig or 10% safety factor (depending which is higher). Since 10% is higher than 25 psig, the addition of
10% safety factor was used.
10
𝑀𝐴𝑊𝑃 = 588 + (588 𝑥 ) = 646.8
100
2. What schedule number can be used for ordinary steel pipe having an allowable stress of
10,000 psi for use at working pressure of 350 psig?
A. 80 B. 120 C. 40 D. 160 E. None
of the
above
𝑃
𝑆𝑐ℎ. 𝑁𝑜. = 1000 ( )
𝑆
10, 000 𝑝𝑠𝑖
𝑆𝑐ℎ. 𝑁𝑜. = 1000 ( )
350 𝑝𝑠𝑖𝑔
𝑆𝑐ℎ. 𝑁𝑜. = 35 ≈ 40 (𝑛𝑒𝑎𝑟𝑒𝑠𝑡)
3. It is required to design a cylindrical shell having 32 inch radius. The internal pressure inside is
663 psi and the material unit stress is 17,000 and it is fully radiographed. Determine the
required thickness of the shell.
A. 1.40 inch B. 1.37 inch C. 1.35 inch D. 1.30 inch E. None
of
these
Given:
𝑃 = 700 𝑝𝑠𝑖
𝑅 = 32 𝑖𝑛𝑐ℎ
𝑆 = 17000 𝑝𝑠𝑖
𝐸 = 1 (𝑓𝑢𝑙𝑙𝑦 𝑟𝑎𝑑𝑖𝑜𝑔𝑟𝑎𝑝ℎ𝑒𝑑)
𝑃𝑅
𝑡=
𝑆𝐸 − 0.6𝑃
A. B. C. D. E. None of
29, 883.50724 𝑚3 298, 83.50724 𝑐𝑚3 29, 883.50724 𝑐𝑚3 30, 793.50724 𝑐𝑚3 these
Solution:
42
𝐷 = 42 𝑐𝑚 , 𝑅= = 21 , ℎ = 14 𝑐𝑚
2
Compute for Af
𝑅−ℎ
𝐴𝑓 = 𝑅 2 ∗ cos−1 ( ) − (𝑅 − ℎ) (√2 ∗ 𝑅 ∗ ℎ − ℎ2 )
𝑅
21𝑐𝑚 − 14𝑐𝑚
𝐴𝑓 = 21𝑐𝑚2 ∗ cos −1 ( ) − (21𝑐𝑚 − 14𝑐𝑚) (√2 ∗ 21𝑐𝑚 ∗ 14𝑐𝑚 − 14𝑐𝑚2 )
21𝑐𝑚
𝐴𝑓 = 404.2601739 𝑐𝑚2
Ellipsoidal Head (Volume)
ℎ
𝑉𝑓 = 𝐴𝑓 ∗ 𝐿 + 𝜋 ∗ 𝑎 ∗ ℎ2 (1 − )
3𝑅
14 𝑐𝑚
𝑉𝑓 = 404.2601739 𝑐𝑚2 ∗ 62 𝑐𝑚 + 𝜋 ∗ 16.5 𝑐𝑚 ∗ 14 𝑐𝑚2 (1 − )
3 ∗ 21 𝑐𝑚
𝑉𝑓 = 32 ,966.2835 𝑐𝑚3
Guppy Head (Volume)
2 ∗ 𝑎 ∗ 𝑅2 ℎ 2∗𝑎
𝑉𝑓 = 𝐴𝑓 ∗ 𝐿 + cos−1 (1 − ) + (√2 ∗ 𝑅 ∗ ℎ − ℎ2 ) (ℎ + 𝑅)
3 𝑅 9∗𝑅
2 ∗ 16.5 𝑐𝑚 ∗ 21 𝑐𝑚2 14 𝑐𝑚
𝑉𝑓 = 404.2601739 𝑐𝑚2 ∗ 62 𝑐𝑚 + cos−1 (1 − )
3 21 𝑐𝑚
2 ∗ 16.5 𝑐𝑚
+ (√2 ∗ 21 𝑐𝑚 ∗ 14 𝑐𝑚 − 14 𝑐𝑚2 ) (14 𝑐𝑚 + 21 𝑐𝑚)
9 ∗ 21 𝑐𝑚
𝑉𝑓 = 26 800.73097 𝑐𝑚3
Volume
32, 966.2835 𝑐𝑚3 + 26,800.73097 𝑐𝑚3
𝑉= = 29, 883.50724 𝑐𝑚3
2
5. What is the volume of a half-filled horizontal tank with flat heads with diameter D and length
L?
𝜋 𝜋 𝜋 𝜋
A. 4 𝐷 2 𝐿 B. 6 𝐷 2 𝐿 C. 8 𝐷 2 𝐿 D. 2 𝐷 2 𝐿 E. None of these
Solution:
𝑉 =𝐵×ℎ
𝜋 𝐿
𝑉 = 𝐷2 ×
4 2
References:
1. In an underdamped second order system, the values of the time constant and damping ratio
were pre-determined. With the value of 0.5 and 0.4 respectively, calculate the period of
oscillation of the system.
A. 2.90 B. 1.45 C. 1.71 D. 3.43 E. of
these
Solution:
2𝜋𝜏 2𝜋(0.5)
𝑇= = = 3.43
√1 − 𝜁 2 √1 − (0.4)2
2. A step input of magnitude 4 is applied to a system having a transfer function of
𝑌(𝑠) 10
= 2
𝑋(𝑠) 𝑠 + 1.6𝑠 + 4
Solution:
𝑌(𝑆) 10 1⁄ 4
= 2 ∗ 4 𝑋(𝑠) =
𝑋(𝑆) 𝑠 + 16𝑠 + 4 1⁄ 𝑠
4
𝑌(𝑆) 2.5
= 2
𝑋(𝑆) 0.25𝑠 + 0.4𝑠 + 1
4 2.5
𝑌(𝑠) = ∗ 𝜏 2 = 0.25 𝜏 = 0.5 2𝜉𝜏 = 0.4 𝜉 = 0.4
𝑠 0.25𝑠 2 + 0.4𝑠 + 1
−𝜋 ∗ 𝜏
% 𝑂𝑆 = exp ( ) ∗ 100
√1 − 𝜉 2
−𝜋 ∗ 0.5
% 𝑂𝑆 = exp ( ) ∗ 100 = 25.38 %
√1 − 0.42
2 𝑠−2
𝐹(𝑠) = 3 2 2
+
(𝑠 − 2) + 2 (𝑠 − 2)2 + 22
𝑠+4
𝐹(𝑠) =
(𝑠 − 2)2 + 22
𝒔+𝟒
𝑭(𝒔) = 𝟐
𝒔 − 𝟒𝒔 + 𝟏𝟑
5. Approximate the transfer function shown below with a second-order-plus-delay model using
Skogestad’s Half-Rule.
1−𝑠
𝐺(𝑠) =
(2𝑠 + 1)2 (8𝑠 + 1)(10𝑠 + 1)
Solution:
1−𝑠
(10𝑠 + 1)(8𝑠 + 1)(2𝑠 + 1)(2𝑠 + 1)
1−𝑠
2
(10𝑠 + 1)(8𝑠 + 1) (2 𝑠 + 1) (2𝑠 + 1)
𝑒 −𝑠 𝑒 −𝑠 𝑒 −2𝑠
(10𝑠 + 1)((8 + 1)𝑠 + 1)
𝑒 −4𝑠
𝐺(𝑠) =
(10𝑠 + 1)(9𝑠 + 1)
References:
STEP RESPONSE OF AN UNDERDAMPED SECOND ORDER SYSTEM by Engr. Basil James Santos
(lecture)
Process Control
A. 𝑒 −4𝑡 sin √5𝑡 − B. 𝑒 −4𝑡 cos √5𝑡 − C. 𝑒 −4𝑡 cos √5𝑡 − D. 𝑒 −4𝑡 sin √5𝑡 − E. None of
4 4 4 4 the
𝑒 −4𝑡 cos √5𝑡 𝑒 −4𝑡 sin √5𝑡 𝑒 −4𝑡 sin √5𝑡 𝑒 −4𝑡 cos √5𝑡
√5𝑡 √5𝑡 √5𝑡 √5𝑡 Choices
Solution:
𝑠
𝐹(𝑠) =
𝑠2
+ 8𝑠 + 21
𝑠+4−4
𝐹(𝑠) =
(𝑠 + 4)2 + 5
𝑠+4 4
𝐹(𝑠) = −
(𝑠 + 4) + 5 (𝑠 + 4)2 + 5
2
𝟒 −𝟒𝒕
𝑓(𝑡) = 𝒆−𝟒𝒕 𝐜𝐨𝐬 √𝟓𝒕 − 𝒆 𝐬𝐢𝐧 √𝟓𝒕
√𝟓
2. Water enters a 1000 L mixed tank heater at a flow rate of 220 L/min. The outlet temperature of the tank
is 80⁰C. Determine the response of the outlet temperature of a mixed-tank heater to a step change in
the inlet temperature from 65 to 73⁰C.
A. 80 + 8(1 − B. 80 + 8(1 − C. 80 + 9(1 − D. 85 + 8(1 − E. None of the
−𝑡/4.545 −𝑡/4.45 −𝑡/4.545 −𝑡/4.545
𝑒 ) 𝑒 ) 𝑒 ) 𝑒 ) choices
Solution:
1000 𝐿
𝜏= = 4.545 𝑚𝑖𝑛
220 𝐿/𝑚𝑖𝑛
𝑇′(𝑠) 1
=
𝑇𝑖 ′(𝑠) 4.545𝑠 + 1
8 1
𝑇 ′ (𝑠) = ( )
𝑠 4.545𝑠 + 1
𝑌(𝑠) 10
3. A step change with a magnitude of 4 is introduced in a transfer system of = . Determine
𝑋(𝑠) 𝑠2 +1.6𝑠+4
the % Overshoot
A. 24.5% B. 25.4% C. 34.5% D. 35.4% E. None of the
choices
Solution:
𝑌(𝑠) 10
=
𝑋(𝑠) 𝑠2 + 1.6𝑠 + 4
𝑌(𝑠) 2.5
=
𝑋(𝑠) 0.25𝑠2 + 0.4𝑠 + 1
𝜏2 = 0.25
2𝜖𝜏 = 0.4
𝜖 = 0.4
−𝜋 × 0.4
%𝑂𝑣𝑒𝑟𝑠ℎ𝑜𝑜𝑡 = (exp { )) × 100 = 𝟐𝟓. 𝟒%
√0.84
4. The characteristics of a controlled system is as shown below. Determine the range of Kc in which the
system will be stable.
𝑠 2 + 𝑠 + 2.5
1 + 𝐾𝑐 ∗ =6
𝑠(4𝑠 2 + 4𝑠 + 1)
4𝑠 3 + 4𝑠 2 + 𝑠 + 𝐾𝑐 2 + 𝐾𝐶 + 2.5𝐾𝑐 = 0
4𝑠 2 + (4 + 𝐾𝑐)𝑠 2 + (1 + 𝐾𝑐)𝑠 + 2.5𝐾𝑐 = 0
1 4 1+Kc
2 4+Kc 2.5Kc
3 1+Kc-10Kc/(4+Kc)
4 2.5Kc
10𝐾𝑐
1 + 𝐾𝑐 − >0
4 + 𝐾𝑐
4 + 5𝐾𝑐 + 𝐾𝑐 2 − 10𝐾𝑐 > 0
𝐾𝑐 2 − 5𝐾𝑐 + 4 > 0
𝑲𝒄 > 𝟏
5. Given a thermometer that has a time constant of 1 min is initially at 50°C. It is immersed in a bath
maintained at 100⁰C at t = 0. Determine the temperature reading in Celsius at 1.2 min.
6. A thermometer is placed in a water bath that is initially at steady state at a temperature of 27°C and was
maintained at a temperature of 85°C. Its time constant is 0.38 min. How long will it take for the
thermometer to reach a 72°C reading?
A. 0.58628 min B. 0.58286 min C. 0.56828 min D. 0.56882 min E. None of the
Choices
Solution:
X(t) = 0, t<0
58, t>0
58
𝑋(𝑠) = 𝑠
58 1
𝑌(𝑠) = ( )
𝑠 0.38𝑠+1
− 𝑡⁄
𝑌(𝑡) = 58 (1 − 𝑒 0.38 ) @ y = 72°C ; t = 0.5683 min
Equipment Design
1. A horizontal cylinder tank with hemispherical heads is design to a liquid. The dimension of the tank is
0.76 m for the height of the fluid. What is the volume occupied by the liquid if the tank is to be filled
half full and its L/D ratio is 3?
A. 9 m3 B. 10.11 m3 C. 9.5 m3 D. 11.01 m3 E. None of the
Choices
Solution:
𝑉𝑇𝑜𝑡𝑎𝑙 = 𝑉𝐻𝑒𝑎𝑑𝑠 + 𝑉𝐶𝑦𝑙𝑖𝑛𝑑𝑒𝑟
𝜋 𝜋
𝑉𝑇𝑜𝑡𝑎𝑙 = 𝐷 2 (𝐿) + 2 [ 𝐻 2 (1.5𝐷 − 𝐻)]
4 3
𝐷 𝐿
𝑏𝑢𝑡 𝐻 = 𝑎𝑛𝑑 = 3
2 𝐷
𝑠𝑜 𝐻 = 0.76𝑚, 𝐷 = 1.52𝑚, 𝑎𝑛𝑑 𝐿 = 4.56𝑚
𝜋 𝜋
𝑉𝑇𝑜𝑡𝑎𝑙 = (1.52𝑚)2 (4.56𝑚) + 2 [ (0.76𝑚)2 (1.5(1.52𝑚) − 0.76𝑚)]
4 3
𝑉𝑇𝑜𝑡𝑎𝑙 = 𝟏𝟎. 𝟏𝟏𝒎𝟑
2. In a distillation column, for a distillate of 95% purity with a given withdrawal of 4 and α = 2.5. Estimate
the total number of trays.
A. 8 B. 7 C. 6 D. 9 E. None of the
Chioces
Solution:
3. Consider a shell and tube heat exchanger equipment with an entering pressure of steam of 588 psig and
an entering pressure of oil of 400 psig. What should be the design pressure of the shell-side?
A. 613 psig B. 646.8 psig C. 425 psig D. 440 psig E. None of the
choices
Solution:
References:
- LeBlanc, S. E., & Coughanowr, D. R. (2009). Process systems analysis and control. Boston:
McGraw-Hill.
- Seborg, D. E., Edgar, T. F., Mellichamp, D. A., & Doyle, F. J. (2017). Process dynamics and
control. Hoboken, NJ: Wiley.
- CPI PowerPoint Presentations
- Equipment Design PowerPoint Lectures by Prof. Evelyn Laurito, PhD.
- Shreve, R. N., & Brink, J. A. (1977). Chemical processes industries. New York: McGraw-Hill.
- Kirkpatrick, S., Shreve, N. (2011). The Chemical Process Industries (2nd ed., Vol. 2, 1-15).
- Coughanowr, D. (2016). Process Systems Analysis and Control (2nd ed., 125-126).
- Roberts, M. (2017). Principles of Equipment Design (3rd ed., 331-338).
CPI
1. Sulfuric acid solution is ordinarily sold according to their specific gravity, or their Baumé degree.
What is the specific gravity of Sulfuric acid with a Baumé of 15.
Solution:
2. What is the correct order for the paper and paperboard process
I. Recycling
II. Thickening
III. Deinking
IV. Bleaching
Reference: https://en.wikipedia.org/wiki/Baum%C3%A9_scale
PROCON
1. By using the S-shift Theorem, find the Laplace Transform of f(t) = 3t7e3t.
15120 15120 21 21 E. None of
A. (𝑠−3)7 B. (𝑠−3)8 C. (𝑠−3)7 D. (𝑠−3)8
these
Note:
f(t) F(s)
tn n!/sn+1
eat 1/(s-a)
3(7!) 15120
F(s)=(𝑠−3)8 = (𝑠−3)8
2. Derive an approximate first order plus time delay model using Skogestad’s half rule for the following
transfer function:
k(−0.2s + 1)
G(s) =
(6s + 1)(2s + 1)(s + 1)
k∙e−2.2s k∙e−3.2s k∙e−0.2s k∙e−3.2s E. None
A. G(s) = 7s+1
B. G(s) = 8s+1
C. G(s) = 9s+1
D. G(s) = 6s+1
of
these
Solution:
A. 11 B.10 C. 9 D. 12 E. None of
these
(Y(s))/(X(s))=(10/(s^2+1.6s+4))1/4
𝑌(𝑠) 2.5
=
𝑋(𝑠) 0.25𝑠 2 + 0.4𝑠 + 1
Ultimate Value = AKp=4(2.5)=10
6. A cylindrical tank has a diameter of 4 ft and an outflow with flow resistance of 0.2 min/ft2. It is initially
operating at steady-state with inlet flowrate of 25 ft3/min. At t=0, the inlet is closed. At what time will
the depth of water be reduced to 2 ft?
Solution:
𝜋
𝐴𝑟 = (4)2 = 4𝜋
4
25 𝑡 < 0
𝑞=
0 𝑡>0
0 𝑡<0
𝑄=
−25 𝑡 > 0
25
𝑄(𝑠) =
𝑠
𝐻(𝑠) 0.2
=
𝑄(𝑠) 4 𝜋𝑠 + 1
5
25 0.2
𝐻(𝑠) = − ( )
𝑠 4 𝜋𝑠 + 1
5
𝑡
−4
𝐻(𝑡) = −5 (1 − 𝑒 5𝜋 )
𝑡
−4
ℎ = 5 − 5 (1 − 𝑒 5𝜋 )
when h = 2
𝑡
−4
2 = 5 − 5 (1 − 𝑒 5𝜋 )
t = 2.30 min
1. Stagnation suction pressure is found to be 1 psig at a sea level installation. The liquid’s vapor
pressure is 9 psia. Calculate the Net Positive Suction Head (NPSH) for a liquid with a specific gravity of
0.91.
Solution:
NPSH = Ps – Pvap
2. What schedule number can be used for ordinary steel pipe having an allowable stress of 10000 psi
for use at a working pressure of 400 psig?
A. 20 B. 25 C. 40 D. 35 E. None of these
Solution:
𝑊𝑜𝑟𝑘𝑖𝑛𝑔 𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒
𝑆𝑐ℎ𝑒𝑑𝑢𝑙𝑒 𝑁𝑢𝑚𝑏𝑒𝑟 = 1000 𝑥
𝐴𝑙𝑙𝑜𝑤𝑎𝑏𝑙𝑒 𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒
400 𝑝𝑠𝑖
𝑆𝑐ℎ𝑒𝑑𝑢𝑙𝑒 𝑁𝑢𝑚𝑏𝑒𝑟 = 1000 𝑥 = 40
10000 𝑝𝑠𝑖
3. A water tank 10m in ∅ and 15m high is half-filled. Determine the minimum thickness of the tank
plating if the stress is limited to 60MPa?
Solution:
t=6.13125mm
4. A spherical pressure vessel has a 2ft inner radius and 5/16 inch wall thickness. If the working
tensile stress of the material is 8000psi determine the maximum allowable internal pressure.
Solution:
𝑖𝑛
𝑙𝑏 𝑃∗(2𝑓𝑡∗2∗12 )
𝑓𝑡
800 𝑖𝑛2 = 5 =208.34 psi
4∗( )
16
5. Calculate the design pressure when the maximum internal pressure of a cylindrical vessel is 14 bar
(abs).
𝑃𝑎𝑏𝑠 = 𝑃𝑔 + 𝑃𝑎𝑡𝑚
𝑃𝑔 = 𝑃𝑎𝑏𝑠 − 𝑃𝑎𝑡𝑚
1.01325
𝐷𝑒𝑠𝑖𝑔𝑛 𝑃 = (12.99 − 1.01325) + 25 ( ) = 13.7 𝑏𝑎𝑟 (𝑔𝑎𝑢𝑔𝑒) = 13.7 + 1.01325
14.7
= 14.72 𝑏𝑎𝑟 (𝑎𝑏𝑠)
6. Liquid Methanol is flowing on a SCH 40 pipe steel with NRE = 4623. Calculate for the friction factor
using Blasius Equation.
Solution:
𝑁𝑅𝐸 = 4623
0.079
𝑓= = 0.00958
46230.25
Reference: https://www.pumpsandsystems.com/topics/understanding-npsh-npsh-definitions
EQUIPMENT DESIGN
PROBLEM SOLVING
1. What is the Reynold’s Number of a 2” Sch 40 Steel pipe where the velocity in pipe is 6 m/s,
viscosity is 0.9cP, and density is 1000 kg/m3?
A. 346268.67 B. 342686.67 C. 348266.67 D. 346286.67 E. None of the
choices
Solution:
𝐷𝑖 𝑣𝜌
𝑁𝑅𝑒 =
𝜇
Di = 2.045 in. = 0.051943 m
v = 6 m/s
𝜇 = 0.9 cP = 0.0009 kg/m-s
𝜌 = 1000 kg/m3
𝑚 𝑘𝑔
0.051943 𝑚 (6 𝑠 ) (1000 3 )
𝑚
𝑁𝑅𝑒 =
𝑘𝑔
(0.0009 𝑚 − 𝑠)
NRe = 346286.666667
2. A double pipe heat exchanger has a 2in Sch40 steel pipe inside a 4-in Sch40 Steel pipe. The
operating pressure in the inner tubes is 40 psig and in the annulus it is 70 psig. What is the maximum
allowable pressure (MAWP)?
Solution:
4. Determine the thickness of a half-filled water tank with height of 15 m and a diameter of 10 m. The
working tensile stress of the material is 60 MPa.
𝑡 = 6. 13125 𝑚𝑚
5. Find the volume of fluid in horizontal cylindrical tanks of 46 cm in diameter with cylinder lengths of
62cm (no heads). The fluid depth of the tank is 15cm.
A. 20138.25 B. 20195.75 C 19825.25 D. 19348.25 E. None of the
Choices
Solution: Solution:
R= 23cm
H =15 cm
L = 62cm
𝑅−ℎ
𝐴 = 𝑅 2 cos ( 𝑅
)− (𝑅 − ℎ)√2𝑅ℎ − ℎ2
A = 324.8104cm2
Vf = AL
Vf = 20138.25
6. Based on the diagram given below, what is the shell-side design pressure?
A. 621.5 psig B. 590.5 psig C. 565 psig D. 565.5 psig E. None of the
Choices
Solution: Design Pressure based on Maximum Allowable Working Pressure
MAWP= Operating Pressure + (25 psig or 10% safety factor)
MAWP= 565+ (.10*565)
MAWP= 621.5 psig
References:
PROCESS CONTROL
2. A step change magnitude of 5 is introduced into a system with a 𝜏 = 0.5 , 𝜁 = 0.4 𝑎𝑛𝑑 𝐾𝑝 =
2.5. Determine the maximum value of Y(t).
Solution:
𝑌𝑚𝑎𝑥 = 𝐴𝐾𝑝(1 + 𝑂𝑆)
−𝜋𝜁 −𝜋(0.4)
𝑌𝑚𝑎𝑥 = 𝐴𝐾𝑝(1 + exp ( ) 𝑌𝑚𝑎𝑥 = (5)(2.5)(1 + exp ( )
√1−𝜁 2 √1−(0.4)2
𝑌𝑚𝑎𝑥 = 15.6725
3. Assume q1 is independent of h, derive the transfer function H(s)/ Q0(s) for the system.
1 1 1 1 E. None of the
F. 𝐴𝑟 𝑠
B. 𝐴𝑟 𝑠 + 1 C. 𝑠 + 1 D. 𝐴𝑟 ℎ + 1
choices
Solution:
5. 5. Find the Laplace transform of the function that satisfies the equation and the
conditions:
𝑑3 𝑠 𝑑2 𝑠 5𝑑𝑠 𝑑2 𝑥(0) 𝑑𝑥(0)
𝑑𝑡 3 + 𝑑𝑡 2 + 𝑑𝑡
+ 2𝑥 = 2 ; x(0) =
𝑑𝑡 2
+
𝑑𝑡
=0
A. 𝑋(𝑆) = B. 𝑋(𝑆) = C. 𝑋(𝑆) = D. 𝑋(𝑆) = E. None of the
2 2 2 2 Choices
(𝑆 3 ) 𝑆(𝑆 3 +5𝑆+2) 𝑆(𝑆 3 +𝑆 2 +5𝑆+2) (𝑆 3 +𝑆 2 +5𝑆+2)
3 2
𝑑 𝑠 𝑑 𝑠 5𝑑𝑠
Solution: 3+ 2 + 𝑑𝑡 + 2𝑥 = 2
𝑑𝑡 𝑑𝑡
2
S3x(S)-S2x(0)-Sx’(0)-x”(0) + S2x(S)-Sx’(0)-x”(0) + 5(Sx(S)-x(0))+ 2x(S) = 𝑆
2
S3x(S)+ S2x(S)+ 5Sx(S) +2x(S) = 𝑆
2
X(S)(S3+S2+5S+2) =
𝑆
2
𝑋(𝑆) =
𝑆(𝑆 3 +𝑆 2 +5𝑆+2)
6 . A step change of magnitude 5 is introduced into a system having a transfer function of:
𝑌(𝑠) 10
= 2
𝑋(𝑠) 𝑠 + 1.6𝑠 + 4
Determine the ultimate value of Y(t).
Solution: Since transfer function of the second order system can be expressed as:
𝑌(𝑠) 𝐾𝑝
= 2
𝑋(𝑠) 𝜏𝑠 + 2𝜁𝜏𝑠 + 1
Therefore,
1
𝑌(𝑠) 10
= 2 (4)
𝑋(𝑠) 𝑠 + 1.6𝑠 + 4 1
4
𝑌(𝑠) 2.5 5
= 2
, 𝑋(𝑠) =
𝑋(𝑠) 0.25 + 0.4𝑠 + 1 𝑠
Ultimate Value formula= 𝐴𝐾𝑝
CPI
1. 1800 kg of wet solids which contain 65% solids by weight are fed to tray dryer where it is dried
by hot air. The product attained is found to contain 2% moisture by weight. Calculate the
amount of water removed from wet solids.
A. 601.62 kg B. 602.61 kg C. 606.12 kg D. 612.06 kg E. None
of the
choices
Solution: Basis: 1800 kg of wet solids
Water
removed
Let x be the amount of product obtained, and y be the amount of water removed.
Material balance for Solids:
Solids in wet solids = Solids in product
1800(0.65) = 0.98x
1170 = 0.98x
x = 1193.87755102 kg
Overall material balance:
F=x+y
1800 = 1193.87755102 + y
y = 606.12244898 kg
Therefore,
Amount of water removed = y = 606.12 kg
PROCESS CONTROL
1. Apply the second-order-plus-time-delay model using Skogestad’s half-rule to approximate the transfer
function of the given.
1−𝑠
𝐺(𝑠) =
(2𝑠 + 1)2 (8𝑠 + 1)(10𝑠 + 1)
𝑒 −4𝑠 𝑒 −9𝑠 𝑒 −4𝑠 𝑒 −6𝑠 e. None of the
a. (10𝑠+1)(9𝑠+1)
b. c. (𝑠+1)(9𝑠+1)
d.
(10𝑠+1)(4𝑠+1) (10𝑠+1)(9𝑠+1) choices
Solution:
1−𝑠
𝐺(𝑠) =
(10𝑠 + 1)(8𝑠 + 1)(2𝑠 + 1)(2𝑠 + 1)
2
(2𝑠) −𝑠
𝑒 −𝑠 𝑒 2
𝑒
=
2
(10𝑠 + 1)((8 + 2) 𝑠 + 1)
𝑒 −4𝑠
𝐺(𝑠) =
(10𝑠 + 1)(9𝑠 + 1)
3. Determine the unit-step response of a system that has a unit-impulse response of Y(t) = cos 2t.
a. y(t) = 0.5 sin 2t b. 0.5 cos 2t c. 0.25 sin 2t d. 0.25 cos 2t e. None of the choices
Solution:
𝑠
𝑌(𝑠) = = 𝐺(𝑠)
𝑠2 + 4
1 𝑠 1
𝑌(𝑠) = ∙ 2 = 2
𝑠 𝑠 +4 𝑠 +4
𝒚(𝒕) = 𝟎. 𝟓 𝐬𝐢𝐧 𝟐𝒕
4. A 200-L tank heater is being fed with water at 20 C at a flow rate of 25 L/min initially, the heater is switched
off. At t=0, the heater is then switched on, supplying heat at a constant rate. The temperature of the outlet at t=10
min measures 60 C. What would be the temperature of the outlet at t=30 min?
A. 40.74 C B. 74.74 C C. 76.06 D. 71.46 E 71.27
1 1 𝑉 200
𝐾𝑝 = = ;𝐴 = 𝑞;𝜏 = = =8
𝑝𝐹𝑐𝑝 104600 𝐹 25
𝑡 −𝑡
𝑞
𝑇(𝑠) = 𝐴𝐾𝑝 (1 − 𝑒 −𝜏 ) = (1 − 𝑒 8 )
104600
𝑞 −10
𝑇(𝑡) = 20 + 104600 (1 − 𝑒 8 )
𝑞 −10
60= 20 + 104600 (1 − 𝑒 8 )
𝑞 = 5864089.88 𝐿/𝑚𝑖𝑛
𝑞 −30
𝑇(𝑡) = 20 + 104600 (1 − 𝑒 8 )
𝑇(30) = 74.74
5. A cylindrical tank has a diameter of 6 ft and an outflow with flow resistance of 0.2 min/ft2. It is initially operating
at a steady state with an inlet flowrate of 25 ft 3/min. At t=0, the inlet is closed. At what time will the depth of
water be reduced to 1 ft?
A. 10.9 min B. 9.01 min C. 1.09 min D. 8.01 min E. None of the choices
Solution:
𝑞𝑠 = 25 ℎ𝑠 = 𝑞𝑠 𝑅 = 5 𝐾𝑝 = 𝑅 = 0.2 𝜏 = 𝐴𝑟𝑅 = 𝜋(32 )(0.2) = 1.8𝜋
𝐾𝑝 25 0.2
𝐻(𝑠) = 𝑄(𝑠) = −
𝜏𝑠 + 1 𝑠 1.8𝜋𝑠 + 1
If h = 1, t = 9.01 min
6. A thermometer with a time constant of 0.30 min is initially at equilibrium with water at 25 C. The water is then
heated such that the temperature of the water increases linearly until it reaches its boiling point after 6.0 min.
What is the temperature reading of the thermometer as soon as the water starts to boil?
A. 96,00 ° C B. 96.25 °C C. 100 °C D. 99.0 °C E. None of the choices
Solution:
12.5 1 1 𝜏 𝜏
𝑌(𝑠) = ( ) = 12.5( 2 + + )
𝑠 2 𝜏𝑠 + 1 𝑠 𝑠 1
𝑠+𝜏
𝜏
𝑌(𝑠) = 12.5( 𝑡 − 𝜏 + 𝜏𝑒 0.3 )
𝜏
𝑦(𝑡) − 25 = 12.5( 𝑡 − 𝜏 + 𝜏𝑒 0.3 )
If t = 6, t = 96.25 C
EQUIPMENT DESIGN
1. What is the design temperature and pressure of the given system below respectively?
2. Calculate the inner diameter of the pipe given that the outside diameter is 1.315 in. and the wall thickness is
0.133 in.
F. 1.049 in. G. 1.249 in. H. 1.581 in. I. 1.182 in. J. None of the choices
Solution:
Do = 1.315 in
∆x = 0.133 in
Di = Do – 2(∆x)
Di = 1.314 – 2(0.133)
Di = 1.049 in.
𝑃𝐷
𝑆=
4𝑡
𝑃(48 𝑖𝑛)
8000 𝑝𝑠𝑖 =
5
4(16 𝑖𝑛)
𝑷 = 𝟐𝟎𝟖. 𝟑𝟑 𝒑𝒔𝒊
4. What will be an optimum Schedule Number of a steel pipe having an allowable stress of 5000psi at a working
pressure of 200 psig
A. 40 B. 20 C. 4 D. 0.4 E. 0.2
𝑷
𝑺𝒄𝒉. 𝑵𝒖𝒎𝒃𝒆𝒓 = 𝟏𝟎𝟎𝟎 ∗
𝑺
𝟐𝟎𝟎
𝑺𝒄𝒉. 𝑵𝒐. = 𝟏𝟎𝟎𝟎 ∗ = 𝟒𝟎
𝟓𝟎𝟎𝟎
5. Find the volume of a fluid inside a process vessel of the shape shown above that if the liquid level is maintained
at 1/3 of the diameter of the cylinder. Assume one head to be ellipsoidal with a = ¼ of the major axis. The
conical head has a height of 1.25 times the cylinder diameter (D=1m, L=2m)
A. 0.625 B. 0.265 C. 0.562 D. 0.652 E. None of the
choices
Solution:
Cone
D=1 R = 0.5 L=2 h = 1/3 a = 1.25
|𝑅−ℎ| 1
𝑀= = 0.333 𝐾1 = 𝑎𝑐𝑜𝑠(𝑀) + 𝑀3 ∗ 𝑎𝑐𝑜𝑠ℎ ( ) − 2𝑀 √1 − 𝑀2 = 0.668.
|𝑅| 𝑀
𝑅−ℎ 2∗𝑎∗𝑅2
𝑉𝑓𝑐 = ((𝑅 2 ∗ 𝑎𝑐𝑜𝑠( ) − (𝑅 − ℎ) ∗ √2 ∗ 𝑅 ∗ ℎ − ℎ2 ) ∗ 𝐿 + ∗ 𝐾1) = 0.59745
𝑅 3
Ellipsoidal
𝑎 = 1/4
𝑅−ℎ ℎ
𝑉𝑓𝑒 = (𝑅 2 ∗ 𝑎𝑐𝑜𝑠( 𝑅
) − (𝑅 − ℎ) ∗ √2 ∗ 𝑅 ∗ ℎ − ℎ2 ) ∗ 𝐿 + 𝜋 ∗ 𝑎 ∗ ℎ2 ∗ (1 − 3∗𝑅
) = 0.52622
𝑉𝑓𝑐 + 𝑉𝑓𝑒
𝑉𝑓 = = 𝟎. 𝟓𝟔𝟐
2
6. A Dorr Thickener has a rake mechanism speed of 0.125 rpm, Torque of 69,154 Nm. Using an overall efficiency
of 0.5, calculate the power requirement of the thickener.
Power Requirement
2𝜋𝑁𝑇
𝑃=
60(𝐸)(1000)
2𝜋(0.125 𝑟𝑝𝑚)(69,154.265𝑁𝑚)
𝑃=
60(0.5)(1000)
𝑷 = 𝟏. 𝟖𝟏𝒌𝑾
Reference: Equipment Design report Dorr Thickener by Joshua A. Castillo under Dr. Pestano
CHEMICAL PROCESS INDUSTRIES
A. 15 B. 17 C. 20 D. 25 E. None of
these
4. In leather manufacturing, what process converts the protein of the raw hide or skin
into a stable material which will not putrefy and it is suitable for a wide variety of end
applications?
1. The range of value of K for a system with characteristic equation given by s4 + 6s3 +
11s2 + 6s + K = 0
A. 0<K<10 B. K<10 C.K>10 D. -10<K<0 E. None of
these
Solution:
1 11 𝐾
6 6
10 𝐾
60 − 6𝐾
10
𝐾
𝐾 < 10 , 𝐾 > 0
0 < 𝐾 < 10
2. A liquid level system is being operated at steady-state. The tank has a height of 5 ft
and a base area of 12 ft2. At t = 0, 30 ft3 of water was added to the system. Another 40
ft3 of water was added at 2 min. Determine the depth of the liquid right before 40 ft3 of
water was added.
5, 𝑡<0
𝑥={
1, 𝑡>0 𝑡
𝑌(𝑡) = −4 (1 − 𝑒 − ⁄5 )
0, 𝑡<0
𝑥={ 𝑡
−4, 𝑡>0 𝑦 = 5 − 4 (1 − 𝑒 − ⁄5 )
4
𝑋(𝑠) = − 𝑎𝑡 𝑦 = 2, 𝑡 = 3.68 𝑚𝑖𝑛
𝑠
4. Approximate the transfer function shown below with a second-order-plus-time-delay
model using Skogestad’s Half-Rule.
4 1 1−𝑠
𝑌(𝑠) = − ∙ 100𝐺(𝑠) =
𝑠 20 𝑠 + 1 (2𝑠 + 1)2 (8𝑠 + 1)(10𝑠 + 1)
A. B. C. D. E. None of
𝑒 −3𝑠 𝑒 −4𝑠 𝑒 −3𝑠 𝑒 −4𝑠 these
(10𝑠+1)(8𝑠+1) (10𝑠+1)(9𝑠+1) (9𝑠+1)(8𝑠+1) (11𝑠+1)(8𝑠+1)
1−𝑠
𝐺(𝑠) =
(2𝑠 + 1)2 (8𝑠 + 1)(10𝑠 + 1)
1−𝑠
𝐺(𝑠) =
(10𝑠 + 1)(8𝑠 + 1)(2𝑠 + 1)(2𝑠 + 1)
1−𝑠
𝐺(𝑠) =
2 2
(10𝑠 + 1) ((8 + )𝑠 + 1) ( 𝑠 + 1)
2 2
𝑒−4𝑠
𝐺(𝑠) =
(10𝑠 + 1)(9𝑠 + 1)
References:
[1] S. Olano Jr., V. Bungay, C. Centeno, L. Medina Jr., C. Salazar. Reviewer for
Chemical Engineering Licensure Examination (3rd Edition)
[2, 4, 5] Coughanowr, D. R. & LeBlanc S. E. Process Systems Analysis and Control,
3rd ed. New York, USA: McGraw Hill
[3] Process Control Lecture
EQUIPMENT DESIGN
1. Calculate the minimum wall thickness for a cylindrical vessel that is to carry a gas at a
pressure of 1400 psi. The diameter of the vessel is 2 ft, and the stress is limited to 12
ksi. All joints are to be butt-welded (E=0.90) and assume no corrosion is necessary
A. 1.66 in B. 0.14 in C. 0.30 in D. 3.57 in E. None of these
Solution: 𝑘𝑖𝑛𝑒𝑡𝑖𝑐𝑠 𝑜𝑓 𝐵𝑂𝐷
𝑃𝐷
𝑡= +𝐶
2𝑆𝐸 − 𝑃
12 𝑖𝑛
(1400 𝑝𝑠𝑖) (2𝑓𝑡 ( ))
𝑓𝑡
𝑡= +0
2(12000 𝑝𝑠𝑖)(0.9) − (1400 𝑝𝑠𝑖)
𝑡 = 1.66 𝑖𝑛
2. What schedule number can be used for ordinary steel pipe having allowable stress of
10,000 psi for use at a working pressure of 250 psig.
A. 32 B. 25 C. 35 D. 41 E. None of these
Solution:
𝑃 250 𝑝𝑠𝑖𝑔
𝑆𝑐ℎ𝑒𝑑𝑢𝑙𝑒 𝑁𝑢𝑚𝑏𝑒𝑟 = 1000 = 1000 = 25
𝑆 10,000 𝑝𝑠𝑖
3. Calculate the maximum allowable pressure of a shell and tube heat exchanger
operating at a pressure of 500 psig
A. 510 psig B. 525 psig C. 550 psig D. 575 psig E. None of these
Solution:
𝑀𝐴𝑊𝑃 = 𝑂𝑝𝑒𝑟𝑎𝑡𝑖𝑛𝑔 𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 + (25 psig or) 10% safety factor
A. 7.35 MPa B. 6.45 MPa C. 7.48 MPa D. 6.78 MPa E. None of these
𝐷𝑜 − 𝐷𝑖 15 − 10
𝑡= = = 0.5 𝑚
2 2
𝑃𝑟𝑖
𝑡= + 𝐶𝑐
2𝑆𝐸𝑗 − 0.2𝑃
𝑃(7)
0.5 = +0
2(75.85)(0.7) − 0.2𝑃
𝑃 = 7.478 = 7.48 𝑀𝑃𝑎
5. What is the maximum allowable pressure of a vessel working under absolute pressure
of 2500 kPa?
A. 363 psig B. 373 psig C.383 psig D. 393 psig E. None of these
Solution:
14.7 𝑝𝑠𝑖
𝑂𝑝𝑒𝑟𝑎𝑡𝑖𝑛𝑔 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = (2500 𝑘𝑃𝑎 × ) − 14.7 = 347.99 ≈ 348 𝑝𝑠𝑖𝑔
101.325 𝑘𝑃𝑎
References:
[1] Engineering Mathematics. https://www.mathalino.com/reviewer/mechanics-and-
strength-of-materials/solution-to-problem-133-pressure-vessel
[2, 3, 4] Sinnott, R. K. (2005). Chemical Engineering Design, 4th ed. Oxford:
Butterworth-Heinemann
[5] Walas, S. M. (1990). Chemical process equipment: Selection and design. Boston:
Butterworth-Heinemann.
2. Calculate the fluid volume, 𝑉𝑓 in 𝑚3 of a horizontal process vessel with an ellipsoidal head and a
1 1
cross-sectional area, 𝐴𝑓 = 0.2292 𝑚2; diameter, radius 𝐷 = 1𝑚, 𝑅 = 2 𝑚 ; height fluid, ℎ = 3 𝑚;
1
length, 𝐿 = 2𝑚; and distance a head extends, 𝑎 = 𝑚.
4
A. 0.5229 B. 0.5262 C. 0.5392 D. 0.5263 E. None of
the
choices
Solution:
ℎ
𝑉𝑓 = 𝐴𝑓 𝐿 + 𝜋𝑎ℎ2 (1 − )
3𝑅
1
1 1 2 (3)
𝑉𝑓 = 0.2292(2) + 𝜋 ( ) ( ) (1 − ) = 𝟎. 𝟓𝟐𝟔𝟑 𝒎𝟑
4 3 1
3 (2)
3. A cylindrical tank has a diameter of 6ft and an outflow with a flow resistance of 0.2min/ft2. It is
initially operating at steady-state with an inlet flowrate of 25 ft3/min. At t=0, the inlet is closed. At
what time will the depth of water be reduced to 1 ft?
A. 9.1 secs B. 10.2 secs C. 9.1 min D. 10.2 min E. None of the
choices
Solution: −25 𝐾𝑝
𝑄(𝑠) = 𝐻(𝑠) = 𝑄(𝑠) ∙ 𝜏𝑠+1
q= 25 t>0 𝑠 −25 0.2
0 t<0 = ∙
𝐻(𝑠) 𝐾𝑝 𝑠 1.8𝜋𝑠 + 1
−𝑡
= 𝐻(𝑡) = (−25)(0.2)(1 − 𝑒 1.8𝜋 )
Q= 0 t>0 𝑄(𝑠) 𝜏𝑠 + 1 −𝑡
-25 t<0 ℎ(𝑡) = 5 − 5(1 − 𝑒 1.8𝜋 )
∗ 𝜏 = 𝐴𝑟 ∙ 𝑅
= (𝜋⁄4)(6)2 (0.2) = 1.8𝜋 when h=1, t=9.1min
4. Compute for the outside diameter for a shell and tube given a design pressure of 370900 Pa, an
inside diameter of 0.67m and a maximum allowable stress of 16.076 ksi. Assume a fully-
radiographed butt joint and a corrosion coefficient of 3mm.
A. 0.678 m B. 0.702 mm C. 0.735 m D. 0.728 m E. None of the
choices
Solution:
5. Ethanolamine enters the shell side of a STHE at 424 and 232.22°C leaves at 390 psig at 194.44°C.
Cooling water enters the shell side at 422 psig and 120°F. What is the design pressure and
temperature of the equipment?
A. 466.4psig and B. 449psig and C. 466.4psig and D. 466.4psig and E. None of the
475°C 257.22°F 257.22°C 246.11°C choices
Solution:
Highest temperature 232.22°C
Highest pressure: 424 psig
(232.22 ∙ 1.8) + 32 = 450°F
424(1.1) = 466.4 psig 450°F + 25°F = 475°F
424+25 = 449 psig Design Temperature = 475°F or 246.11°C
Design pressure = 466.4 psig
6. Which of the following polymers represents the formula shown below in which n can be a very
large number?
Solution:
7. What are the raw materials for ‘Solvay Process’?
Solution:
ℎ𝑠 = 8.5 𝑐𝑚
𝑌(𝑡)𝑚𝑎𝑥 = 16 𝑐𝑚
𝐴𝐾𝑝 = 13 𝑐𝑚
𝐴 + 𝐴𝐾𝑝 = 1𝑠𝑡 𝑝𝑒𝑎𝑘
𝐶 + 𝐴𝐾𝑝 = 2𝑛𝑑 𝑝𝑒𝑎𝑘
𝐴 16 − 13
𝑂𝑆 = =
𝐵 13 − 8.5
𝐶
= 𝑂𝑆 2
𝐴
16 − 13 2
𝐶=( ) ( 16 − 13) = 1.333 𝑐𝑚
13 − 8.5
2𝑛𝑑 𝑝𝑒𝑎𝑘 = 14.333 𝑐𝑚
9. A flathead cylindrical storage tank is used at working pressure of 50 psig and 80°F. Its diameter is 30
ft and all joints are butt welded with backing strip. Estimate the necessary wall thickness assuming
there is no corrosion, efficiency is 80%, and allowable tensile strength is 13700 psi.
A. 1.237 in B. 0.738 in C. 0.823 in D. 1.480 in E. None of the
choices
Solution:
𝑃𝑟𝑖
𝑡= + 𝐶𝑐
𝑆𝐸 − 0.6𝑃
𝑃 = 50 𝑝𝑠𝑖𝑔 + 25 𝑝𝑠𝑖𝑔 + 14.7 𝑝𝑠𝑖𝑔 = 89.7 𝑝𝑠𝑖𝑎
(89.7 𝑝𝑠𝑖𝑎)(15 𝑥 12 𝑖𝑛𝑐ℎ𝑒𝑠)
𝑡=
(13700 𝑝𝑠𝑖𝑎)(0.8) − 0.6(89.7 𝑝𝑠𝑖𝑎)
𝑡 = 1.480 𝑖𝑛𝑐ℎ𝑒𝑠
10. What does FIFA mean?
A. First Inn First B. First Inn First C. First In First D. First Inside E. None of the
Out Outside Out First Outside choices
11. Steam and oil enters the shell and tube heat exchanger. Steam enters at 588 psig and 482 oF while
the oil enters at 400 psig and 120oF and leaves the exchanger at 390 psig and 450oF. What is the
design temperature of the exchanger?
A. 500oC B. 532 oF C. 532 oC D. 170 oF E. None of the
choices
Solution:
MAWT = 482oF + 50 oF = 532 oF
12. An open loop second – order syste is critically damped. What is/are its pole/s? Expresss in terms of
Ƭ.
1 B. 2Ƭ 1 D. Ƭ E. None of the
A. 𝜏
C. − 𝜏
choices
Solution:
𝜏 2 𝑠 2 + 2𝜏𝑠 + 1 = 0
s = - 1/Ƭ
13. Name this reaction:
2−𝑠
𝐺(𝑠) =
(𝑠 + 2)(8𝑠 + 1)2 (12𝑠 + 1)
A. B. C. D. E. None of the
choices
𝐺(𝑠) 𝐺(𝑠) 𝐺(𝑠) 𝐺(𝑠)
𝑒 −5𝑠 𝑒 −5𝑠 𝑒 −6𝑠 𝑒 −5𝑠
= = = =
(12𝑠 + 1)(12𝑠 + 1) (12𝑠 + 1)(10𝑠 + 1) (12𝑠 + 1)(10𝑠 + 1) (12𝑠 + 1)(8𝑠 + 1)
Solution:
2−𝑠
𝐺(𝑠) =
(𝑠 + 2)(8𝑠 + 1)2 (12𝑠 + 1)
2(1 − 0.5𝑠)
𝐺(𝑠) =
2(1 + 0.5𝑠)(8𝑠 + 1)(8𝑠 + 1)(12𝑠 + 1)
8
𝑒 −0.5𝑠 𝑒 −0.5𝑠 𝑒 −2𝑠
𝐺(𝑠) =
8
(12𝑠 + 1)((8 + 4) 𝑠 + 1)
𝑒 −5𝑠
𝐺(𝑠) =
(12𝑠 + 1)(12𝑠 + 1)
15. A double pipe heat exchanger vessel has a 2in Sch 40 steel pipe inside a 4-in Sch 40 steel pipe. The
operating pressure in the inner tubes is 40 psig and the annulus is 60 psig. What is the maximum
allowable working pressure?
A. 44 psig B. 60 psig C. 85 psig D. 65 psig E. None of the
choices
Solution:
16. Oil is entering the tube side of the heat exchanger at 400 psig and 120 F leaving at 390 psig at 450 F.
Steam enters the shell side at 588 psig and 482 F. What is the design pressure of the equipment?
𝑌(𝑠) 13.12
= 2
𝑋(𝑠) 𝑠 + 1.83𝑠 + 2
𝑌(𝑠) 6.56
= 2
𝑋(𝑠) 0.5𝑠 + 0.915𝑠 + 1
Kp =6.56
𝜏 2 = 0.5
√2
𝜏=
2
2𝜗𝜏 = 1.83
𝜗 = 0.77
AKp = 8 x 6.56 = 52.48
References:
[1] Coughanowr, D.R., (2009) Process Systems Analysis and Control. 3rd Edition
[2] University of Santo Tomas, Department of Chemical Engineering, Prof. Evelyn Laurito Notes in CHE
511, 2nd Term A.Y. 2018-2017
PROCESS CONTROL
1. A thermometer with a time constant of 0.40 min is initially at steady state at 25 ºC. The
thermometer is then placed in an ice bath maintained at 4 ºC at t=0. Determine the time
needed in seconds for the thermometer to read 5 ºC.
4. The unit step response of a system is given by 𝑌(𝑡) = 1 − 𝑐𝑜𝑠2𝑡. Determine the transfer
function of the system.
2 4 6
A. 2/s B. 𝑠 ⁄𝑠 + 2 C. 𝑠2 +4 D. 𝑠2 +7 E. None of the
choices
Solution
𝑌(𝑠)
= 𝐺𝑐(𝑆)
𝑋(𝑠)
1 𝑠
𝑌(𝑠) = − 2
𝑠 𝑠 +4
1
𝑋(𝑠) =
𝑠
1 𝑠
𝑌(𝑠) 𝑠 − 𝑠 2 + 4
=
𝑋(𝑠) 1
𝑠
4
𝐺𝑐(𝑠) = 2
𝑠 +4
5. The response of a First Order Plus Time Delay system to a step input of 3 has an ultimate
value of 6. What is its proportionality constant?
A. 4 B. 3 C. 8 D. 2 E. None of the
above
Solution:
A=3
AKp=6
Kp=6/3=2
6. An open loop second order system is critically damped. What is/are its poles? Express answer
interms of t.
A. 𝑆 = 𝜏 B. 𝑆 = 𝜏 −𝑒 C. . 𝑆 = 1𝜏 D. 𝑆 =
1 E. None of the
𝜏
Choices
Solution:
𝜏 𝑠 𝑠 2 + 2𝜏𝑠 + 1 = 0
1
𝑆=
𝜏
Reference:
[1] Coughanowr, D. and LeBlanc, Steven (2009). Process systems analysis and control. McGraw-Hill
Education
EQUIPMENT DESIGN
1. What would be the thickness of a spherical vessel whose inside diameter is 8 m and the
material of construction isStainlessSteelGrade304at100℉ (maximum allowable stress is 20
ksig) withnormaloperatingpressureof400kPa(gage).Typeofjointis doublebutt-weld and it is
fully radiographed (𝐸𝑗 = 1). Assume a corrosion allowance of 3 mm.
A. 20.50 mm B. 19.65 mm C. 18.75 mm D.8.6 mm E. None of the
choices
Solution:
14.7 𝑝𝑠𝑖
𝑃𝑔𝑎𝑔𝑒 = 400 𝑘𝑃𝑎𝑃 𝐷𝑒𝑠𝑖𝑔𝑛𝑔𝑎𝑔𝑒 = 400 𝑘𝑃𝑎 × + 25 𝑝𝑠𝑖𝑔 = 83.03 𝑝𝑠𝑖𝑔
101.325 𝑘𝑃𝑎
𝐷𝑖 = 8 𝑚𝑅𝑖 = 4 𝑚 = 4000 𝑚𝑚
𝐸𝑗 = 1𝑆 = 20 𝑘𝑠𝑖𝑔 = 20000 𝑝𝑠𝑖𝑔𝑐𝑐 = 3 𝑚𝑚
𝑃 𝐷𝑒𝑠𝑖𝑔𝑛𝑔𝑎𝑔𝑒 × 𝑅𝑖
𝑡= + 𝑐𝑐
𝑆 × 𝐸𝑗 − 0.6𝑃 𝐷𝑒𝑠𝑖𝑔𝑛𝑔𝑎𝑔𝑒
83.03 × 4000
𝑡= +3
20000 × 1 − 0.6 × 83.03
𝑡 = 19.65 𝑚𝑚
2. What is the design pressure of a vessel if its maximum operating pressure is 760 mmHg?
A. 1.7 atm B. 2.7 atm C. 3.7 atm D. 4.7 atm E. None of the
choices
Solution:
𝑃 = 760 𝑚𝑚𝐻𝑔 = 14.7 𝑝𝑠𝑖 = 1 𝑎𝑡𝑚
14.7(0.1) = 1.47 𝑝𝑠𝑖 < 25 𝑝𝑠𝑖
𝐷𝑒𝑠𝑖𝑔𝑛 𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 14.7 + 25 = 39.7 𝑝𝑠𝑖 = 2.7 𝑎𝑡𝑚
3. Determine the optimum pipe diameter for 55 gpm water at 35 °C.
A. 2.5933 in B. 2.7690 in C. 3.396 in D. 3.748 in E. None of the
choices
Solution:
𝑙𝑏
𝜌 = 62.3 3; 𝜇 = 0.74 𝑐𝑃 from PHB
𝑓𝑡
Assume 𝑁𝑅𝑒 > 2100
𝐷 𝑣𝜌
𝐷𝑖 = 3.9𝑞𝑓0.45 𝜌0.13 ; 𝑁𝑅𝑒 = 𝑖
𝜇
55 𝑔𝑎𝑙 3.785 𝐿 𝑚3 3.283 𝑓𝑡 3 1 𝑚𝑖𝑛 𝑓𝑡 3
𝑞𝑓 = × × × × = 0.1224
𝑚𝑖𝑛 1 𝑔𝑎𝑙 1000 𝐿 1 𝑚3 60 𝑠 𝑠
0.45 0.13
𝐷𝑖 = 3.9(0.1224) (62.3) = 2.5933 𝑖𝑛
Check 𝑁𝑅𝑒
1 𝑓𝑡 0.1224 𝑓𝑡 3 1 3600 𝑠 𝑙𝑏
(2.5933𝑖𝑛 × 12 𝑖𝑛) × ( 𝑠 × 2 × ) × 62.3 3
𝜋 2.5933 1 ℎ𝑟 𝑓𝑡
( ) 𝑓𝑡 2
𝑁𝑅𝑒 = 4 12 = 90345.61
𝑙𝑏
2.4192
𝑓𝑡 ℎ𝑟
0.74𝑐𝑃 × 1 𝑐𝑃
> 2100
4. What is the maximum design temperature of a heat exchanger if the maximum operating
temperature of the said vessel is 400°C.
A. 428°C B. 802°C C. 428°F D. 248°C E. None of the
choices
Solution:
9
400𝑥 + 32 = 752°𝐹
5
𝑀𝑎𝑥. 𝐷𝑒𝑠𝑖𝑔𝑛 𝑇𝑒𝑚𝑝 = 752 + 50 = 802°𝐹
5
(802 − 32)𝑥 = 428°𝐶
9
5. It is desired to design a horizontal cylinder with a hemispherical head to handle a liquid with
volume of 10 m3. Find its dimensions if it will be half full and L/D=3.
A. D= 2.0m B. D= 2.2m C. D= 2.5m D. D= 2.5m E. None of the
H=0.5m H=1.1m H=0.5m H=0.5m Choices
L=6.7m L=6.7m L=6.7m L=6.0m
Solution:
𝑉𝑇𝑜𝑡𝑎𝑙 = 𝑉𝑆𝑝ℎ𝑒𝑟𝑒 + 𝑉𝐶𝑦𝑙𝑖𝑛𝑑𝑒𝑟
𝜋 𝜋
10 = 𝐷 2 𝐻 + 2 ( 𝐻 2 (1.5𝐷 − 𝐻))
4 3
𝐷
𝐻=
2
𝜋 2𝐷 𝜋 𝐷 2 𝐷
10 = 𝐷 + 2 ( ( ) (1.5𝐷 − ))
4 2 3 2 2
𝐷 = 2.2
𝐻 = 1.1
𝐿 = 6.7
Reference:
[1] Towler, G. P. (2013). Chemical engineering design: Principles, practice and economics of plant and
process design, (2ndEdition). Kidlington, Oxford, U.K. ; Waltham, Mass.: Butterworth-Heinemann.
1.What is the maximum allowable working temperature of a countercurrent double pipe heat
exchanger with an inlet and outlet temperatures of 350F and 200F respectively for the inner tube, and
543F and 320F respectively for the outer tube.
Solution: You will base your solution on the highest temperature employed by the equipment.
The safety margin for maximum temperature is 50 F based on the rule of thumb.
MAWT = 543F + 50F
MAWT = 593F
2. Identify the value of the unit step response of a system that has a unit-impulse response of y(t) =
cos2t if t =10.
1 𝑠 1
Y(s) = 𝑠 𝑥 𝑠2 +4=𝑠2 +4
1
y(t) =2sin2t
1
y(10) =2sin2(10)=0.4565
3. They are added in the glass formulation in order to lower the melting point temperature of the glass.
Solution: N/A
4. Calculate the design pressure and temperature of a cylindrical vessel made with carbon steel with
flat heads given the following conditions:
Diameter: 450 mm Operating Temperature: 500°C
Length: 750 mm
Operating Pressure: 25 atm (abs)
The vessel has a corrosion allowance of 2 mm and is double-butt-weld, spot radiographed.
A.388.08 psig, B. 883.08 psig, C. 264 atm, D. 300 atm, E. None of the
982°F 289°F 142.79°C 256.7°C choices
𝟏𝟒. 𝟕 𝒑𝒔𝒊
𝑷𝑶𝒑𝒆𝒓𝒂𝒕𝒊𝒏𝒈 = [𝟐𝟓 𝒂𝒕𝒎 (𝒂𝒃𝒔)𝒙 ] − 𝟏𝟒. 𝟕 = 𝟑𝟓𝟐. 𝟖 𝒑𝒔𝒊𝒈
𝟏 𝒂𝒕𝒎
𝑷𝒅𝒆𝒔𝒊𝒈𝒏 = 𝟑𝟓𝟐. 𝟖 𝒑𝒔𝒊𝒈 (𝟎. 𝟏𝟎) = 𝟑𝟓. 𝟐𝟖 > 𝟐𝟓∴ 𝒂𝒅𝒅 𝟑𝟓. 𝟐𝟖 𝒑𝒔𝒊𝒈
𝑷𝒅𝒆𝒔𝒊𝒈𝒏 = 𝟑𝟓𝟐. 𝟖 𝒑𝒔𝒊𝒈 + 𝟑𝟓. 𝟐𝟖 𝒑𝒔𝒊𝒈 = 𝟑𝟖𝟖. 𝟎𝟖 𝒑𝒔𝒊𝒈
𝑻𝒐𝒑𝒆𝒓𝒂𝒕𝒊𝒏𝒈 = 𝟓𝟎𝟎°𝐶(𝟏. 𝟖) + 32 = 932°𝐹
𝑻𝒐𝒅𝒆𝒔𝒊𝒈𝒏 = 𝟗𝟑𝟐°𝐹 + 50°𝐹 = 982 °𝐹
5. A mixing tank operating at steady-state has brine flowing with an inlet flow rate of 45 L/min. The
brine has an inlet concentration of 1 g/L and at t=0, the brine feed concentration was suddenly
increased to 5.0 g/L. Calculate the volume of the tank if it takes 6 mins to further increase the outlet
concentration to 3.0 g/L.
4
𝑋(𝑠) =
𝑠
4 1
𝑌(𝑠) = ⋅
𝑠 𝑉 𝑠+1
45
𝑦(𝑡) = 3.0 𝑔/𝐿 𝑡 = 6 𝑚𝑖𝑛𝑠. 𝑉 =?
6
−
𝑦(𝑡) = 1 + 4(1 − 𝑒 𝑉/45 )
𝑉 = 389.527661 𝐿 ≈ 390 𝐿
6. It is a process in the production of vegetable oil wherein separation of higher melting parts like
waxes and triglycerides occurs that requires slow cooking to form crystals.
Solution: N/A
7. It is a type of chemical that is sometimes referred to as “fine chemicals”. These are typically high-
value-added products with many differentiations. The major products of this segment include paints
and coatings, adhesive sealants, catalysts, dyes and pigments, industrial gases, resins and plastic
additives.
Solution: N/A
8. A spherical pressure vessel has an internal diameter of 9 m and an outside diameter of 9.8 m.
Calculate the stress acting normal on the tank if it operates at 1.2 MPa internal pressure.
A. 6.75 MPa B. 7.35 MPa C. 1.35 MPa D. 1.47 MPa E. None of the
choices
Solution:
𝐷𝑜 = 𝐷𝑖 + 2𝑡 9.8 = 9 + 2𝑡 ; t = 0.4 m
𝜎𝐿 = 𝑃𝑑/4𝑡 = (1.2 𝑀𝑃𝑎)(9 𝑚) / 4(0.4 𝑚) = 6.75 𝑀𝑃𝑎
Solution:
10. The allowable working pressure has a safety factor of either 10% or +25psig of the operating
pressure in which the higher MAWP is chosen.
Solution:
The allowable working pressure has a safety factor of either 10% or +25psig of the operating pressure
in which the higher MAWP is chosen.
Solution
𝑌(𝑠) 1
𝑠𝑌(𝑠) − 𝑦(0) = − 2
𝑠 𝑠
Isolating 𝑌(𝑠)
3𝑠 2 − 1
𝑌(𝑠) =
𝑠(𝑠 2 − 1)
By Partial fraction
1 1 1
𝑌(𝑠) = + +
𝑠 𝑠+1 𝑠−1
𝑦(𝑡) = 1 + 𝑒 𝑡 +𝑒 −𝑡
12. In a water treatment plant, the lime soda process is used to remove water hardness. According to
the analysis of the waste water, it contained 90mg/L of 𝐶𝑎+2 and 40 mg/L of 𝑀𝑔+2 . Determine the
hardness of the wastewater.
3𝑠+2
13. Solve for the inverse laplace of the equation: 𝑠2 −25
13 17 13 17 13 17 13 17 E. None of the
A. 10 𝑒 5𝑡 + 10 𝑒 −5𝑡 B. 10 𝑒 −5𝑡 + 10 𝑒 5𝑡 C. 10 𝑒 5𝑡 − 10 𝑒 −5𝑡 D. 10 𝑒 −5𝑡 − 10 𝑒 5𝑡
choices
3𝑠 + 2 3𝑠 + 2 𝐴 𝐵
2
= = +
𝑠 − 25 (𝑠 + 5)(𝑠 − 5) 𝑠 + 5 𝑠 − 5
3𝑠 + 2 = 𝐴(𝑠 − 5) + 𝐵(𝑠 + 5)
𝑤ℎ𝑒𝑛 𝑠 = 5, 𝐵 = 17/10
14. The purpose of this primary component for fertilizers is to enhance root growth and flowering.
References:
[1] Coughanowr, Donald. Process Systems Analysis and Control, 3rd ed. 2009
[2] Seborg, Dale, Process Dynamics and Control, 3rd ed. 2011
[3] Walas, S. M. (1988). Chemical process equipment: Selection and design. Boston: Butterworths.
𝑠1 = −2.7983
𝑠2 = −0.10184 + 1.1917𝑖
𝑠3 = −0.10184 − 1.1917𝑖
3. Water at 35oC (density = 62.3 lb/ft3 and viscosity = 0.8 cP) is to be used in a
utility plant, what is the optimum pipe diameter to be utilized for 100 gpm of
water?
A. 1 ½ in B. 3 1/3 in Sch 40 C. 2 ½ in D. 3 in Sch 40 E. None of
Sch 40 Sch 40 the
choices
Solution:
𝐷𝑖 = 3.9𝑞𝑓0.45 𝜌0.13 (for turbulent and liquids with low viscosity only (< 20 cP); use
English units)
0.45
100 𝑔𝑎𝑙 1 𝑓𝑡 3 1 𝑚𝑖𝑛 𝑙𝑏 0.13
𝐷𝑖 = 3.9 ( × × ) (62.3 3 ) = 3.3957 𝑖𝑛𝑐ℎ𝑒𝑠
𝑚𝑖𝑛 7.47 𝑔𝑎𝑙 60 𝑠 𝑓𝑡
1 K+2
3 4
3(𝐾 + 2) − 1(4) 0
3
4 ---
3(𝐾 + 2) − 1(4)
>0
3
3𝐾 + 2 > 0
−𝟐
𝑲>
𝟑
5. Determine the schedule number of a pipe having a 480 ksig internal working
pressure with 12000 psi allowable working stress.
A. Sch 38 B. Sch 40 C. Sch 42 D. Sch 36 E. None of
the
choices
Solution:
𝑃
𝑆𝑐ℎ # = 1000 ( )
𝑆
480000
𝑆𝑐ℎ # = 1000 ( )
12000
𝑺𝒄𝒉 # = 𝟒𝟎
A. √5 B. 5 C. √21 D. 4 E. None of
the
choices
Solution:
𝑠
𝐹(𝑠) =
𝑠 2 + 8𝑠 + 21
𝑠+4−4 𝑠+4 4
𝐹(𝑠) = = −
(𝑠 + 4) + 5 (𝑠 + 4) + 5 (𝑠 + 4)2 + 5
2 2
𝟒 −𝟒𝒕
𝒇(𝒕) = 𝒆−𝟒𝒕 𝒄𝒐𝒔√𝟓𝒕 − 𝒆 𝒔𝒊𝒏√𝟓𝒕
√𝟓
7. Find the damping ratio of a system If the decay ratio of the known system is
equal to 85
A. -0.5773 B. 0.-7553 C. -0.3557 D. -0.3357 E. None of
the
choices
Solution:
2𝜋𝜁
−
√1−𝜁2
Decay ratio = 𝑒
2𝜋𝜁
−
√1−𝜁2
85 = 𝑒
ζ = -0.5773
9. If the operating pressure of a certain vessel is 2600 psi, what should the design
pressure for the said tank be?
A. 2660 psi B. 2860 psi C. 2360 psi D. 2330 psi E. None of
the
choices
Solution:
Design pressure = 2600 psi + 0.10(2600) psi = 2860 psi
𝑌(𝑠) 1 65 1 1
= 𝜏𝑠+1 𝑌(𝑠) = 𝑠(𝜏𝑠+1) 𝑌(𝑠) = 65(𝑠 − 1 )
𝑋(𝑠) 𝑠+
𝜏
𝑡
𝑌(𝑡) = 65(1 − 𝑒 −𝑡/𝜏 ) 𝑦(𝑡) = 25 + 65(1 − 𝑒 −0.25 )
t= 0.6412 mins
11. Determine the design pressure of a cylindrical vessel with diameter of 1.5 m
that operates at a maximum internal pressure of 15 bar (abs).
A. 240.8 B. 230.8 psia C. 230.8 D. 2.38 atm E. None of
psig psig the
choices
Solution:
14.7 𝑝𝑠𝑖
𝑃𝑜𝑝𝑒𝑟𝑎𝑡𝑖𝑛𝑔 = 15𝑏𝑎𝑟 𝑥 = 220.5 𝑝𝑠𝑖
1𝑏𝑎𝑟 = 1𝑎𝑡𝑚
𝑃𝑔𝑎𝑢𝑔𝑒 = 220.5 − 14.7 = 205.8(0.1) 𝑝𝑠𝑖𝑔 < 25 𝑝𝑠𝑖𝑔
𝑃𝑑𝑒𝑠𝑖𝑔𝑛 = 205.8 𝑝𝑠𝑖𝑔 + 25 = 230.8 𝑝𝑠𝑖𝑔
Solution:
𝑑 𝑠
𝐿{𝑡𝑐𝑜𝑠(𝑡)} = − ( 2 )
𝑑𝑠 𝑠 + 1
(𝑠 2 + 1) ∙ 1 − 𝑠 ∙ 2𝑠
𝐿{𝑡𝑐𝑜𝑠(𝑡)} = −
(𝑠 2 + 1)2
−𝑠 2 + 1
𝐿{𝑡𝑐𝑜𝑠(𝑡)} = − 2
(𝑠 + 1)2
𝒔𝟐 − 𝟏
𝐿{𝑡𝑐𝑜𝑠(𝑡)} = 𝟐
(𝒔 + 𝟏)𝟐
14. Calculate the percentage of the volume of liquid with the total volume of the
process vessel horizontal cylindrical vessel of diameter 2 feet and length 6
feet, if the liquid level inside is maintained at height 0.2 meters.
A. 27.6 % B. 28.5 % C. 30.2 % D. 32.8 % E. None of
the choices
𝑅−ℎ
Solution: 𝐴𝑙𝑖𝑞𝑢𝑖𝑑 = 𝑅 2 𝑐𝑜𝑠 −1 ( ) − (𝑅 − ℎ)√2𝑅ℎ − ℎ2
𝑅
1 𝑓𝑡
2 2 −1
1−(0.2 𝑚× ) 0.2 0.2 0.2 2
𝐴𝑙𝑖𝑞𝑢𝑖𝑑 = (2) 𝑐𝑜𝑠 ( 0.3048 𝑚
) − (1 − 0.3048) √2(1) 0.3048 − 0.3048 = 0.9 𝑓𝑡 2
1
Solution:
𝑌(𝑠) 0.5 6
= 𝑋 (𝑠) =
𝑋(𝑠) 0.125𝑠 2 + 0.4𝑠 + 1 𝑠
6 0.5
𝑌(𝑠) = 2
𝑠 0.125𝑠 + 0.4𝑠 + 1
2
𝜏 = 0.125, 2𝜁𝜏 = 0.4
𝜏 = 0.3536, 𝜁 = 0.5657
−𝜋𝜁
𝑂𝑆% = exp ( ) = 0.1159
√1 − 𝜁 2
16. A fluid enters a 1-2 multi-pass shell and tube heat exchanger at 200 degC and
is cooled to 100 degC. Cooling water with a flowrate of 475 kg/hr enters the
exchanger at 27 degC and heated to 92 degC. The overall heat transfer
coefficient Ui is 1000 W/m2-k. Calculate the heat transfer rate.
A. 35.88 kW B. 55.21 kW C. 59.62 kW D. 95.51 kW E. None of the
choices
Solution:
𝑞 = 𝑚𝑐𝑝Δ𝑇
475 𝑘𝑔 𝑘𝐽
𝑞=( ) (4.184 ) (92 − 27)℃ = 35.88 𝑘𝑊
3600 𝑠 𝑘𝑔 ∙ ℃
17. Assuming counter-current flow, what is the log mean temperature difference in
the heat exchanger in deg C?
A. 53.68 B. 81.25 C. 59.63 D. 89.36 E. None of the
choices
Solution:
Δ𝑇1 = 100 ℃, Δ𝑇2 = 65 ℃
Δ𝑇1 − Δ𝑇2
Δ𝑇 = = 89.36
Δ𝑇
ln (Δ𝑇1 )
2
18. Which of the following is the raw material for Ostwald process
A. Nitrogen B. Hydrogen C. Sulfur D. Ammonia E. None of the
choices
References:
[1,16,17] S. Olano Jr., V. Bungay, C. Centeno, L. Medina Jr., C. Salazar.
Reviewer for Chemical Engineering Licensure Examination 3 rd Edition
[2,4,6,7,13,15] Santos, B.J., Process Control Lecture
[3,5,8,9,14] Laurito, E., Lecture Notes for Equipment Design. Piping Systems
[12,18] Gupta, O. (2016). Objective Type Questions & Answers in Chemical
Engineering. New Delhi: Khanna Book Publishing (P).
PROCESS CONTROL
1. A 300 L mixing tank is initially operating at steady-state with an inlet flow rate of 50 L/min,
and an inlet concentration of 5 g/L. At time zero, the feed was changed to another feed that
has a concentration of 1.5 g/L. Calculate the time it will take to increase again the
concentration in the system to 2 g/L.
A. 12.58 mins B. 11.67 mins C. 11.00 mins D. 12.00 mins F. None of
E. the Above
Solution:
xs=ys= 5
Kp=1
Tau (T) = 300/50 = 6 min
X(s) = -3.5/s
𝑌(𝑠) 𝐾𝑝
=
𝑋(𝑠) 𝑇𝑠 + 1
−3.5 𝐾𝑝
𝑌(𝑠) =
𝑠 6𝑠 + 1
Y(t) = -3.5(1-e^(-t/6))
y(t) = 5 -3.5(1-e^(-t/6))
y(2) = 5 -3.5(1-e^(-t/6))
t = 11.67 mins
(2) 6 k
(3) 3 − 2𝑘
3
(4) k
6 − 2𝑘 3 − 2𝑘
(3) = =
6 2
3 − 2𝑘
(𝑘) − 6(0)
(4) = 3 =𝑘
3 − 2𝑘
3
3 − 2𝑘 3
(3): > 0; > 𝑘
3 2
(4): 𝑘 > 0
𝟑
𝟎<𝒌<
𝟐
References
EQUIPMENT DESIGN
1. Calculate the thickness of the cylindrical vessel with 1.5 meter diameter to operate at
maximum internal pressure of 14 bar absolute and temperature of 400 deg C. Material is
made out of plain carbon steel, where its vessel is double butt-welded and fully radiographed.
The vessel will have 1 hemi-elliposoidal head (major axis is 2 times the minor axis) and one
flat head.
A. 0.013 m B. 0.011 m C. 0.012 m D. 0.010 m E. None of the
Above
Solution:
2. Find the fluid volume of a horizontal tank with ellipsoidal head if the radius (R) of the
horizontal tank is 3m, the height (h) of fluid is 1.7m, the length (L) of the cylindrical section is
6.3m and the distance of the head from the cylindrical section (a) is 0.7m.
A. 37.56m^3 B. 47.56m^3 C. 57.56m^3 D. 67.56m^3 E. None of the
Above
Solution:
ℎ 𝑅−ℎ
𝑉 = 𝐴𝑓 𝐿 + 𝜋𝑎ℎ2 (1 − ) ; 𝐴𝑓 = 𝑅 2 cos −1 ( ) − (𝑅 − ℎ)√2𝑅ℎ − ℎ2
3𝑅 𝑅
3 − 1.7
𝐴𝑓 = (3)2 cos−1 ( ) − (3 − 1.7)√2(3)(1.7) − (1.7)2 = 6.5886622
3
1.7
𝑉 = (6.5886622)(6.3) + 𝜋(0.7)(32 ) (1 − ) = 𝟓𝟕. 𝟓𝟔𝒎𝟑
3(3)
3. Given a spherical vessel with an internal and outer diameter of 10m and 14m, respectively. A
maximum allowable strength is given as 85MPa and a single butt weld joint, fully
radiographed is used. Assume no corrosion. Determine the design pressure of spherical vessel
in MPa.
A. 60.15MPa B. 70.00MPa C. 62.96MPa D. 50.55MPa E. None of the
Above
Solution:
Pri
t= +C
2SE-0.2P C
14-10
t= =2m
2
S=85MPa
E=1
CC =0
10
ri = =5m
2
P(5m)
2m=
(2)(85MPa)(1)-0.2P
P=62.96MPa
References
Solution:
5(𝑠+1) 22
F(s) = (𝑠+1)2 +22 + (𝑠+1)2 +22
5𝑠+9
F(s) =
𝑠2 +2𝑠+5
2. What would be the Maximum Allowable Working Pressure (MAWP) for a vessel having a pressure
of 590 psig?
A. 649 psig B. 627 psig C. 675 psig D. 603 psig E. None of the
Choices
Solution:
MAWP = Operating Pressure + (25psig or 10% safety factor)
MAWP = 590 + (0.10*590) = 649 psig
Solution:
20 𝑡 < 0 1
x(t) = { } Y(s) = X(s) * ( ) Y(t) = 68 (1 – 𝑒 −t/𝜏 ) = y(t) – Y(s)
88 𝑡 > 0 𝜏𝑠 + 1
0 𝑡<0 68 1
X(t) = { } Y(s) = * (𝜏𝑠 + 1) Y(t) = 68 (1 – 𝑒 −30/𝜏) = 63 – 20
68 𝑡 > 0 𝑠
𝝉 = 29.98 s
68
X(s) = 𝑠
4. In the refining process of petroleum, thermal alkylation is an essential step. Here, when ethylene
reacts with added isobutane, the product is _________.
Solution:
+
Note: The alkyl group will transfer to the other molecule producing neohexene or 2,2-dimethylbutane.
Solution:
6. In pipes, what is the equivalent Fanning friction factor of 378 Darcy friction factor?
A. 1512 B. 94.5 C. 374 D. 382 E. None of the
Choices
Solution:
7. A cylindrical tank has a diameter of 8 ft and an outflow with flow resistance of 0.2 min/ft2. It is
initially operating at steady-state with an inlet flowrate of 30 ft3/min. At t=0, the inlet is closed. At
what time will the depth of water be reduced to 2 ft?
A. 11.0445 B. 10. 0547 C. 11.0542 D. 10.0982 E. None of the
Choices
Solution:
16
qs = 30 R = Kp = 0.2 𝜏 = 𝐴𝑟𝑅 = 𝜋(42 )(0.2) = 5
𝜋ℎ𝑠 = 𝑞𝑠 𝑅 = (30)(0.2) = 6
30, 𝑡 < 0,
𝑞={
0, 𝑡 > 0
0, 𝑡 < 0,
𝑄(𝑡) = {
−30, 𝑡 > 0
30
𝑄(𝑠) = −
𝑠
𝐾𝑝 30 0.2
𝐻(𝑠) = 𝑄(𝑠) = (− )
𝜏𝑠 + 1 16
𝑠 ( 𝜋)𝑠 + 1
5
𝑡
−16
𝐻(𝑡) = ℎ(𝑡) − 6 = −30(0.2)(1 − 𝑒 5 𝜋)
If h =2, t = 11.04445534 mins
8. A 100-L mixing tank is initially operating at steady-state with an inlet flowrate of 20 L/min, and an
inlet concentration of 7 g/L. At t = 0, the feed was changed to another feed that has a concentration
of 1 g/L. Calculate the time it will take to reduce the concentration in the system to 3 g/L.
A. 6.3958 B. 5.4931 C. 7.8641 D. 4.6849 E. None of the
Choices
Solution:
𝑉 100
xs = 7 ys = 7𝜏 = = = 5𝐾𝑝 = 1
𝐹 20
7, 𝑡 < 0,
𝑥(𝑡) = {
1, 𝑡 > 0
0, 𝑡 < 0,
𝑋(𝑡) = {
−6, 𝑡 > 0
6
𝑋(𝑠) = −
𝑠
1 6 1
𝑌(𝑠) = 𝑋(𝑠) = (− )
𝜏𝑠 + 1 𝑠 5𝑠 + 1
𝑡
𝑌(𝑡) = 𝑦(𝑡) − 7 = −6(1 − 𝑒 −5 )
If y = 3, t = 5.4931 mins
9. A distillation column has a temperature of 200°F in the condenser and a 400°F in the reboiler.
What is its Maximum Allowable Working Temperature?
A. 425°F B. 400°F C. 375° F D. 450° F E. None of the
Choices
Solution:
11. Deionized water flows through the inner tube of 20-mm diameter in a thin-walled tube heat
exchanger of 3.2-m length. Hot process fluid at 98oC flows in the annulus formed with the outer tube
of 64-mm diameter and exits at 76oC. The deionized water is the be heated from 40oC to 70oC at a
flowrate of 5kg/s. Determine the minimum logarithmic mean temperature difference for this process
in a co-current flow.
A. 29.22oC B. 22.92oC C. 31.83oC D. 38.31oC E. None of the
choices
Solution:
58 − 6
∆𝑇1 − ∆𝑇2 ∆𝑇𝑙𝑚 =
∆𝑇𝑙𝑚 = 58
∆𝑇 ln 6
ln ∆𝑇1
2 ∆𝑇𝑙𝑚 = 22.92078
∆𝑇1 = (98 − 40) = 58
∆𝑇2 = (76 − 70) = 6
12. The Haber Process combines nitrogen from the air with hydrogen derived mainly from natural gas
(methane) into ammonia. The reaction is reversible and the production of ammonia is exothermic.
Determine the ideal ratio of the mixture of nitrogen and hydrogen going into the reactor.
A. 1:5 B. 2:3 C. 1:3 D. 1:1 E. None of the
choices
Solution:
1𝑁2 1
Nitrogen = N2(g) 3𝐻
= 3 = 1: 3
2
Hydrogen = H2(g)
13.Calculate the thickness of a Cylindrical Stainless Steel Grade 304 Shell with a diameter of 2 m that
will operate at 272.8oF with an operating pressure of 43.06psi that is fully radiographed with a
corrosion resistance of 3 mm.
A. 6.11 mm B. 2.75 mm C. 4.45 mm D. 5.75 mm E. None of the
choices
Solution:
P = 43.06psi
ri = 2/2 = 1m
CC = 3mm
Ej = 1
S for stainless steel 304 at 272.8oF = 15.68ksi = 15 680 psi
0.385(15680psi)(1) > 43.06 therefore, the equation to be used is
𝑃ri
𝑡= + Cc
𝑆Ej − 0.6P
43.06𝑝𝑠𝑖(1000𝑚𝑚)
𝑡= + 3mm = 𝟓. 𝟕𝟓𝐦𝐦
15680𝑝𝑠𝑖(1) − 0.6(43.06psi)
𝑌(𝑠)
14. A step change of magnitude 3 is introduced into a system having a transfer function of 𝑋(𝑠) =
9
3𝑠2 +1.5𝑠+3
find the time constant and the damping ratio.
A. 1, 0.25 B. 1, 0.5 C. 0.5, 1 D.0.25, 1 E. None of the
choices
Solution:
𝑌(𝑠) 9 1/3 3 3
= = , 𝑋(𝑠) =
𝑋(𝑠) 3𝑠2 +1.5𝑠+3 1/3 𝑠2 +0.5𝑠+1 𝑠
3 3
𝑌(𝑠) = 2
𝑠 𝑠 + 0.5𝑠 + 1
𝜏2 = 1, 2𝜁𝜏 = 0.5
𝜏 = 1, 𝜁 = 0.25
References:
PROCESS CONTROL
1. Given the characteristic equation: s^3+3s^2+3s+1+K = 0. What is the range of K so
that the system is stable?
A. -1<K<8 B. -2.75<K<0.54 C. K>3 D. K>0.3 E. None of
the above
Solution:
𝑠 3 + 3𝑠 2 + 3𝑠 + 1 + 𝐾 = 0
1| 1 3
2| 3 1+𝐾
8−𝑘
3 |
3
4| 1+𝐾
8−𝐾
>0→𝐾<8
3
1 + 𝐾 > 0 → 𝐾 > −1
Solution:
3. When D1=D2=0, determine the transfer function Y/X for the system shown below. Let
a= R1R2R3R4R5
𝑎 𝑎 𝑎𝑇1 𝑎𝑇2
A. B. C. D. E. None
1+𝑎𝑇2 +𝑅2 𝑅3 𝑇1 1+𝑎𝑇1 +𝑅2 𝑅3 𝑇2 1+𝑇1 +𝑎𝑅2 𝑅3 𝑇2 1+𝑅1 𝑇1 +𝑅2 𝑅3 𝑇2
of the
choic
es
Solution:
7𝑠 + 1 7𝑠 1
𝐹(𝑠) = 2
= 2 + 2
𝑠 −1 𝑠 −1 𝑠 −1
6 6
L(3e−3t sinh 2t) = 2
= 2
(s + 3) − 4 s + 6s + 9 − 4
6
L(3e−3t sinh 2t) =
s2 + 6s + 5
References:
[1] Olano, S. S., Jr., Bungay, V. C., Centeno, C. R., & Salazar, C. M. (2015). Reviewer for
Chemical Engineering Licensure Examination (3rd ed., p.374). Manila: Manila Review Institute.
[3] Coughanowr, D., LeBlanc, S., (2008). Process Systems Analysis and Control (3rd ed., p.224).
New York: McGraw-Hill Book Company, Inc.
[4] LeBlanc, S. E., & Coughanowr, D. R. (2009). Process systems analysis and control. Boston:
McGraw-Hill Higher Education.
[5] Santos, B. S. (2018). Process Control Notes.
[6] Santos, B. S. (2018). Process Control Notes.
EQUIPMENT DESIGN
𝑃𝑟𝑖
𝑡= + 𝐶𝑐
2𝑆𝐸 − 0.2𝑃
30 𝑓𝑡 12 𝑖𝑛
(5200)( × ) 1
2 1 𝑓𝑡
𝑡= + = 40.8 𝑖𝑛
2(15000)(0.8) − 0.2(5200) 16
Note that: The formula must comply to a thickness <= 0.356ri and an internal pressure
<=0.685SE
2.
Solution:
3. Water and glycerin were fed into a STHE with 1” BWG 14 tubes. Determine its
overall coefficient if the value of ho and hi were 1077.71 W/mK and 2499.55
W/mK, respectively. Use 5000 W/mK for the fluids’ fouling factor.
A. 1200.2 B. 936.3 C. 745.9 D. 526.7 E. None of
W/mK W/mK W/mK W/mK the
choices
Solution:
O.D. = 0.0254
I.D. = 0.211836
𝐷
1 1 1 𝐷𝑡 × ln ( 𝑡 ) 𝐷 1 𝐷𝑡 1
𝑑𝑡 𝑡
= + + + + = 526.694
𝑈𝑜 ℎ𝑜 ℎ𝑜𝑑 2 × 45 𝑑𝑡 ℎ𝑖𝑑 𝑑𝑡 ℎ𝑖
4. A cylindrical shell is used to handle corrosive fluids (CC=9mm). it uses stainless steel
type 316 at 167degF (S=18.526ksi) and double-welded butt joints that are fully
radiographed. With an internal pressure of 39.7 psi, calculate the thickness of the
cylindrical shell. Tank diameter is 2.952901696 m
F. 0.01217 G. 0.01217 H. 0.0168 in I. 0.0168 J. None of
m dm dm the
above
Solution:
𝑃𝑟𝑖
𝑡𝑠 = + 𝐶𝑐
𝑆𝐸 − 0.6𝑃
2.952901696
39.7 ∙ 2
𝑡𝑠 = + 0.009 = 0.0121680104 𝑚
(18526) − (0.6)(39.7)
5. Estimate the safe working pressure for a 4 in, Schedule 40 pipe, carbon steel, butt
welded with working temperature of 100°C. The safe working stress for butt welded
steel pipe up to 120°C. is 5000lb/in2
A. 1379 B. 1500 C. 1300 D. 1450 E. None of
KPa KPa KPa KPa the
above
Solution:
𝑙𝑏
𝑃𝑆 = 200 = 1379 𝐾𝑃𝑎
𝑖𝑛2
[3] Sinnot, R.K., (2005). Chemical Engineering Design (4th ed., p.635). Oxford: Elsevier
Butterworth-Heinemann.
[4] [5] Laurito, E. R. (2018). Notes on pressure vessels.
[5] Laurito, E. R. (2018). Notes on pressure vessels.
[6] Laurito, E. R. (2018). Notes on stresses in pressure-loaded thin-walled vessels.
CPI
1. A thermometer (τ = 0.3 min) is at equilibrium with water at 25°C. The water is then
heated such that the temperature of the water increases linearly until it reaches its
boiling point after 6 min. What is the temperature reading of the thermometer as soon
as the water starts to boil?
𝑥𝑠 = 25 𝑦𝑠 = 25
100 − 25
𝜏 = 0.3 = 12.5
6
25 𝑡<0
𝑥(𝑡) = {
25 + 12.5𝑡 𝑡>0
0 𝑡<0
𝑋(𝑡) = {
12.5𝑡 𝑡>0
12.5
𝑋(𝑠) =
𝑠2
12.5 1
𝑌(𝑠) = 2
∙
𝑠 𝜏𝑠 + 1
1 𝜏 𝜏
𝑌(𝑠) = 12.5 ( + + )
𝑠 2 𝑠 𝑠+1
𝜏
−𝑡
𝑌(𝑡) = 12.5 (𝑡 − 𝜏 + 𝜏𝑒 𝜏 )
−𝑡
𝑌(𝑡) = 12.5 (𝑡 − 0.3 + 0.3𝑒 0.3 ) + 25
𝑡 = 6, 𝑦 = 96.25℃
3000
𝐴𝑚𝑜𝑢𝑛𝑡 𝑜𝑓 𝑔𝑦𝑝𝑠𝑢𝑚 𝑛𝑒𝑒𝑑𝑒𝑑 = = 60 𝑀𝑇
50
3. A 200-L mixing tank, initially operated at steady state with an inlet flow rate of 40L/min,
and an inlet concentration of 10g/L, was disturbed at t=0 when the feed was changed
to another concentration (5g/L). Calculate the time it will take to reduce the
concentration of the system to 7g/L.
A. 4.595 s B. 4.581 s C. 4.577 s D. 4.568 s E. None of
the
above
Solution
𝑥𝑠 = 10 𝑦𝑠 = 10
𝑉 200
𝜏= = =5
𝐹 40
10 𝑡<0
𝑥(𝑡) = {
5 𝑡>0
0 𝑡<0
𝑋(𝑡) = {
−5 𝑡>0
5
𝑋(𝑠) = −
𝑠
1 5 1
𝑌(𝑠) = 𝑋(𝑠) =−
𝜏𝑠 + 1 𝑠 5𝑠 + 1
𝑡
𝑌(𝑡) = 𝑦(𝑡) − 10 = −5(1 − 𝑒 − ⁄5 )
𝑖𝑓 𝑦 = 7, 𝑡 = 4.58145365937 𝑠
[1] Olano, S. S., Jr., Bungay, V. C., Centeno, C. R., & Salazar, C. M. (2015). Reviewer for
Chemical Engineering Licensure Examination (3rd ed., p.391). Manila: Manila Review Institute.
[2] Servillano, S.B. Olano Jr (2015). Reviewer for Chemical Engineering Licensure Examination,
3rd Edition (2015). p.367
[3] Roque, Joshua Emmanuel V. (2018). Multiple CSTR in Series for the Production of Ethyl
Acetate. UST Manila, Philippines
𝑠3 + 2𝑠2 + 3𝑠 + 4 + 𝑠𝑠 = 0
Solution:
s = -2.132493688
s = 0.06624684424 + 1.810567124i
s = 0.06624684424 - 1.810567124i
If there are no poles with positive real part, the system is stable
∴ Unstable
(Approximation only)
Solution:
1
Gc(s) = Kc (1+ )
𝑠𝑠 𝑠
1
Gc(s) = 1 (1+ )
2𝑠
2𝑠+1
Gc(s) =
2𝑠
3. A tall vertical column made from carbon steel 2 m in diameter and 40 m in height is to be installed
with flat heads. The available specifications are: Operating temperature and pressure - 284℉and 57 psi.
Corrosion
allowance = 1.5
mm
Permissible
material stress =
12900 psi
Solution:
0.3𝑠
𝑠 = 2𝑠𝑠 √ + 𝑠𝑠
𝑠
0.3(82 𝑠𝑠𝑠)
𝑠 = 2(1000 𝑠𝑠)√ + 1.5 𝑠𝑠
(12900 𝑠𝑠𝑠)
𝑠 =88.84 mm
4. A 2 m diameter cylindrical tank has an outflow with resistance of 0.05 𝑠𝑠𝑠/𝑠2 . Initially, water enters
the tank steadily at a flowrate of8 𝑠3 /𝑠𝑠𝑠. At t = 0, the inlet is closed. In how many seconds will the
depth of water be reduced to 0.25 m?
Solution:
𝑠𝑠 8 0.05
𝑠(𝑠) = 𝑠(𝑠)( )= − ( )
𝑠𝑠 + 1 𝑠 0.05𝑠 𝑠 + 1
𝑠(𝑠) = 𝑠(𝑠) − 0.4 = −8(0.05)(1 − 𝑠−𝑠/0.05𝑠 )
𝑠 = 0.0738 𝑠𝑠𝑠 = 4.43 𝑠
5. Find the thickness of a 0.2 m in diameter vessel with flat head, has allowable stress of 100 MPa, and
internal pressure of 300 kPa. Assume a corrosion allowance of 2 mm.
Solution:
Flat Head:
0.3𝑠
𝑠 = 2𝑠√ + 𝑠𝑠
𝑠
0.3(300 𝑠𝑠𝑠) 3
𝑠 = 2(0.1 𝑠)√ +
(100,000 𝑠𝑠𝑠) 1000
𝑠 = 0.009 𝑠
6. H2SO4 is produced in a plant using contact process. A large storage tank currently holds 150,000 kg
of 25% oleum. The total capacity of the tank is 160,000 kg. If water is added to the tank to fill the
capacity, determine the percentage of H2SO4 in the final mixture.
Solution:
Initially,
New mixture:
Solution:
𝜏= 5 ; A = 70
8. Determine the safe working pressure for a 5 in., sch. 80 pipe, carbon steel, butt-welded, working
temperature 100 degrees celsius with a maximum allowable pressure of 12000 lb/in^2
A.960 lb/in^2 B. 4398 𝑠𝑠/𝑠𝑠2 C. 3100 lb/in^2 D. 4400 lb/in^2 E. None of these
Solution:
Schedule no. = 80
Solution:
1
𝑠(𝑠) 12
= 2 ∙4
𝑠(𝑠) 𝑠 + 1.2𝑠 + 4 1
4
𝑠(𝑠) 3 5
= ∙
𝑠(𝑠) 0.25𝑠2 + 0.3𝑠 + 1 𝑠
𝜏 2 = 0.25
𝜏 = 0.5
2𝑠𝑠 = 0.3
𝜁=0.3
−𝑠(𝑠)
%𝑠𝑠 = 𝑠√1−𝑠2
−𝑠(0.3)
%𝑠𝑠 = 𝑠√1−0.32 × 100% = 37.23%
10. Determine the design pressure and temperature for the figure below
A.185psig, 450F B.176psig,210F C.99psig,440F D.160psig,400F E. None of these
(160)0.10 = 16psig<25psig
11. Given a spherical shell with a diameter of 6m, a maximum allowable stress of 200 MPa, internal
pressure of 200 KPa, a joint efficiency of 85%, and a corrosion allowance of 2mm, find the thickness of
the shell.
Solution:
𝑠𝑠
𝑠= + 𝑠𝑠
2𝑠𝑠 − 0.2𝑠
(200 𝑠𝑠𝑠)(3𝑠) 2
𝑠= +
2(200000𝑠𝑠𝑠)(0.85) − 0.2(200 𝑠𝑠𝑠) 1000
t=3.76 mm
2𝑠−5
12. Find the inverse Laplace transform of 𝑠(𝑠) = 𝑠2+4𝑠+8
A.2𝑠−2𝑠 𝑠𝑠𝑠(2𝑠) − B. 2𝑠−2𝑠 𝑠𝑠𝑠(2𝑠) + C. 2𝑠2𝑠 𝑠𝑠𝑠(−2𝑠) − D. 2𝑠2𝑠 𝑠𝑠𝑠(2𝑠) + E. None of these
9 −2𝑠 9 −2𝑠 9 2𝑠
𝑠 𝑠𝑠𝑠(2𝑠) 𝑠 𝑠𝑠𝑠(2𝑠) 𝑠 𝑠𝑠𝑠(−2𝑠) 𝑠2𝑠 𝑠𝑠𝑠(2𝑠)
2 2 2
Solution:
2𝑠 − 5
𝑠(𝑠) =
𝑠2 + 4𝑠 + 8
2(𝑠 + 2) 9 2
𝑠(𝑠) = 2 −
(𝑠 + 2)2 + 2 2 (𝑠 + 2)2 + 22
9
𝑠(𝑠) = 2𝑠−2𝑠 𝑠𝑠𝑠(2𝑠) − 𝑠−2𝑠 𝑠𝑠𝑠(2𝑠)
2
13. What is the Maximum Allowable Working Pressure of a tank operating at 200 psig?
A. 225 psig B. 220 psig C. 210 psig D. 200 psig E. None of these
Solution:
14. A process of unknown transfer function is subjected to a unit impulse input. The output of the
process is measured accurately and is found to be represented by the function Y(t) = t e-^-t. Determine
the unit step response in this process.
Solution:
Y(t) = te^-t
Y(s) = 1/(s+1)^2
𝑠 𝑠
𝑠(𝑠) = 1/(𝑠 + 1)2 = +
𝑠 + 1 (𝑠 + 1)2
Solving for B and C:
B=0C=1
1
𝑠(𝑠) =
(𝑠 + 1)2
𝑠(𝑠) = 𝑠𝑠−𝑠
15.It is the conversion of heavy products to lighter products which utilizes high temperature to make
low value residues into petroleum coke.
A.Coking/Thermal B.Hydrocracking C.Fluid catalytic D. Catalytic E. None of these
cracking cracking cracking
References:
Coughanowr, Donald. Process Systems Analysis and Control, 3rd ed. 2009
Towler, G. P. (2013). Chemical engineering design: Principles, practice and economics of plant and
process design, second edition (2nd ed.). Kidlington, Oxford, U.K. ; Waltham, Mass.: Butterworth-
Heinemann.
CHEMICAL PROCESSES INDUSTRIES, PROCESS CONTROL & DYNAMICS AND EQUIPMENT DESIGN
1. Process wastewater flows at 750 m3/hr into a holding pond with a volume of 7500 m3 and then flow
from the pond to a river. Initially, the pond is at steady state with a negligible concentration of
pollutants. Because of a malfunction in the wastewater treating process, the concentration of the
pollutants in the inlet stream suddenly increases to 800 ppm and stays constant at that value for 1 day.
After which the treatment process was corrected and the concentration of the pollutants at the inlet
stream drops to zero. Assuming a perfectly mixed pond, for how long is the outlet stream from the
pond to the river exceeding the regular maximum pollutant concentration of 450 ppm?
A. 20.53585 hrs B. 16.35774 hrs C. 21.97448 hrs D. 14.73521 hrs E. None of
these
Solution: 𝑉 = 7500 𝐹 = 750 𝑥𝑠 = 𝑦𝑠 = 0
0 𝑡<0 0 𝑡<0
800 800 −24𝑠
𝑥(𝑡) = { 800 0 < 𝑡 < 24 𝑋(𝑡) = { 800 0 < 𝑡 < 24 𝑋(𝑠) = − 𝑒
𝑠 𝑠
0 𝑡 > 24 0 𝑡 > 24
𝑌(𝑠) 1
Transfer function for a Mixing tank system: 𝑋(𝑠)
=𝑉
𝑠+1
𝐹
Deriving the response of the system , y(t):
800 800 −24𝑠 1
𝑌(𝑠) = [ − 𝑒 ][ ]
𝑠 𝑠 7500
𝑠+1
750
𝑌(𝑡) = 800(1 − 𝑒 −𝑡/10 ) − 800𝑢(𝑡 − 24)(1 − 𝑒 −(𝑡−24)/10 )
800(1 − 𝑒 −𝑡/10 ) 𝑡 < 24
𝑦(𝑡) = { 𝑡−24
800(1 − 𝑒 −𝑡/10 ) − 800 (1 − 𝑒 − 10 ) 𝑡 > 24
Assume t<24 y(t)=450 t= 8.266785732 hrs VALID!
Assume t<24 y(t)=450 t= 28.80264194 hrs VALID!
Δt= 28.80264194 -8.266785732= 20.53585621 hrs
2. The equation shown below is the characteristic equation of a closed-loop system. Determine the
range of KC in which the system is stable? The transportation lag can be approximated by 1st-order Pade.
𝑘𝑐 𝑒 −𝑠
1+ =0
(𝑠 + 2)2
A. −5 < 𝑘𝑐 < 7 B. −3 < 𝑘𝑐 < 4 C. −4 < 𝑘𝑐 < 8 D. 3 < 𝑘𝑐 < 8 E. None of
these
Solution:
5. Determine the unit-impulse response of a system that has a unit-step response of Y(t) = sinh 3t.
A. 3cosh 3t B. 3sin 3t C.3cos 3t D. 3sinh 3t E. None of
these
Solution:
3
𝑌(𝑠) 𝑠 2 − 9 3𝑠
𝐺(𝑠) = = = 2
𝑋(𝑠) 1 𝑠 −9
𝑠
3𝑠
𝑌(𝑠) = 𝑋(𝑠)𝐺(𝑠) = 1( 2 )
𝑠 −9
𝑌(𝑡) = 3 𝑐𝑜𝑠ℎ 3𝑡
6. The internal diameter of a spherical vessel is 14m and the outer diameter is 15m. It is made up of
Type 304 stainless steel with maximum temperature of 450oC. A single butt weld joint not
radiographed is used. Compute for the design pressure of the vessel in MPa. Assume no corrosion.
A.7.5189 MPa B. 7.0092 MPa C.6.9872 MPa D.6.5239 MPa E. None of
these
Given:
Spherical Vessel
Di= 14m
Do= 15m
Type 304 SS; at T=450oC=842oF (by interpolation from Table 13.2 (Sinnott and Towler, Chemical
Engineering Design)
S=11.061 ksi=11.061x1000 psi=76.2629MPa
𝐷 −𝐷 15−14
𝑡 = 𝑜2 𝑖 = 2 =0.5m
Single butt weld joint not radiographed: Ej=0.7
No corrosion: Cc=0
Solution:
Spherical Tank:
𝑃𝑟𝑖
𝑡= + 𝐶𝑐
2𝑆𝐸𝑗 − 2𝑃
𝑃(7𝑚)
0.5 = +0
2(76.2629𝑀𝑃𝑎)(0.7) − 0.2𝑃
𝑃 = 7.5189 𝑀𝑃𝑎
7. A double pipe heat exchanger has 2” Sch 40 steel pipe inside a 4” Sch 40 steel pipe. The operating
pressure in the inner tubes is 35 psig and in the annulus it is 70 psig. What shall be the maximum
allowable working pressure?
A. 90 psig B. 60 psig C. 95 psig D. 70 psig E. None of
these
Solution:
** Since the pressure in the annulus is higher, 70 psig will be set as the operating pressure.
1−𝑠
G(s) =
(2𝑠+1)2 (8𝑠+1) (10𝑠+1)
1−𝑠
G(s) =
(10𝑠+1) (8𝑠+1)(2𝑠+1)( 2𝑠+1)
1−𝑠
G(s) = 2
(10𝑠+1) (8𝑠+1)( 𝑠+1)( 2𝑠+1)
2
𝑒 −𝑠 ∙ 𝑒 −𝑠 ∙ 𝑒 −2𝑠
G(s) =
(10𝑠+1) ((8+1)𝑠+1)
𝑒 −4𝑠
G(s) =
(10𝑠+1) (9𝑠+1)
9. A mixed tank heater is being operated as shown below. Determine the response of the outlet
temperature to a step change in the inlet to 70℃.
60 𝑡<0
𝑇𝑜 = {
70 𝑡>0
0 𝑡<0
𝑇𝑜′ = {
10 𝑡>0
10
To’(s) = 𝑠
10 1
T’(s) = 𝑠
∗ 5𝑠+1
13. A Schedule 40 pipe has a diameter of 4 inches and a maximum allowable stress of 17, 142 lb/in2
for a butt-welded steel pipe. Calculate for the safe working pressure.
A. 688.85 lb/in2 B. 668.85 lb/in2 C. 658.68 lb/in2 D. 685.68 lb/in2 E. None of these
Solution:
𝑆𝑐ℎ𝑒𝑑𝑢𝑙𝑒 𝑛𝑜. × 𝜎𝑠 40 × 17142 𝑙𝑏
𝑃𝑠 = = = 685.68 2
1000 1000 𝑖𝑛
14. Find the cross-sectional area of the fluid in a partially filled horizontal cylinder if the diameter is 42
cm and if the liquid level is maintained at 14 cm.
A. 410.35 cm2 B. 404.26 cm2 C. 405.72 cm2 D. 408.15 cm2 E. None of these
Solution:
𝑅−ℎ
𝐴𝑓 = 𝑅2 𝑐𝑜𝑠 −1 ( ) − (𝑅 − ℎ)√2𝑅ℎ − ℎ2
𝑅
21 − 14
𝐴𝑓 = (21)2 𝑐𝑜𝑠 −1 ( ) − (21 − 14)√2(21)(14) − (14)2
21
𝐴𝑓 = 404.26 𝑐𝑚2
15. The unit impulse response of a system is given by Y(t)= t5. Determine the response of the system
to a step input.
1 1 1 6 1 E. None of these
A. 𝑡 6
24
B. 𝑡 6
6
C. 𝑡
120
D. 𝑡 6
36
Solution:
𝑌(𝑡) = 𝑡 5
5!
𝑌(𝑠) = 6
𝑠
5!
𝑠 6 120
𝐺(𝑠) = = 6
1 𝑠
1 120 120
𝑌(𝑠) = ( 6 ) = 7
𝑠 𝑠 𝑠
1 6
𝑌(𝑡) = 𝑡
6
References:
Seborg, D.E., Edgar, T.F. & Mellichamp, D.A. (2004). Process Dynamics and Control (2nd ed). John
Wiley & Sons: Hoboken, NJ.
Towler, G. & Sinnott, R. (2008). Chemical Engineering Design: Principles, Practice and Economics
of Plant and Process Design. Elsevier, Inc.: London, UK.