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Polythylene
A widely used plastic containing polymer chains of ethylene units in various chain lengths.
Example:
Polyisoprene
A monomer used for the production of synthetic rubber called polyisoprenes which are used
in a wide variety of rubber applications
Example: medical equipment, baby bottle nipples, toys, shoe soles, tires, elastic films
and threads golf balls or textiles
Pentene
Typically mixed with gasoline that has the usual gasoline smell which helps to give
gasoline its distinctive odor. Gasoline is really just a mixture of many hydrocarbons.
Example: gasoline
Ethylene
An important industrial organic chemical that is a natural plant hormone and is used in
agriculture to force the ripening of fruits.
Example: fruit ripening machine
Isobutylene C4H8
A used in organic synthesis and in the production of high octane aviation gasoline.
Example: chewing gum
Propylene
A fuel for cutting and welding, heat treatment, as power and energy for transportation and
combined oxygen for various industrial processes.
Propylene - fuel
Propylene Glycon - antifreeze, used in fire extinguisher
Example: butyl rubber (98% of the raw materials used), fire extinguisher
Property Physical
Melting Point higher molecular weight, higher melting point
Boiling Point higher molecular weight, higher boiling point
Flamability high
Polarity nonpolar
PHYSICAL STATE
These double bonded compounds are colorless and odorless in nature.
However, ethene is an exception because it is a colorless gas but has a faintly sweet
odor.
The first three members of the alkene group are gaseous in nature, next fourteen
members are liquids and the remaining alkenes are solids.
SOLUBILITY
The alkenes are insoluble in water due to their nonpolar characteristics.
But are completely soluble in nonpolar solvents such as benzene, ligroin, etc.
POLARITY
Alkenes are weakly polar just like alkanes but are slightly more reactive than alkanes
due to the presence of double bonds.
The π electrons which make up the double bonds can easily be removed or added as
they are weakly held. Hence, the dipole moments exhibited by alkenes are more than
alkanes.
The polarity depends upon the functional group attached to the compounds and the
chemical structures.
MELTING AND BOILING POINT
The melting points of these double-bonded compounds depend upon the positioning
of the molecules.
The melting point of alkenes is similar to that of alkanes. However, cis-isomer
molecules have a lower melting point than trans- isomers as the molecules are
packed in a U-bending shape.
CIS – on this side (polar)
TRANS – across (nonpolar)
The boiling points of the compounds increase as the number of carbon atoms in the
compound increases.
The boiling point of straight chain alkenes is more that branched chain alkenes just
as in alkanes.
The Vander Waal Forces is the attraction of intermolecular forces.
Two types of VDW forces; London dispersion forces and dipole-dipole forces
GENERAL PROPERTIES OF ALKYNES
First three : gases,
next eight : liquids
The rest : solids
USES OF ALKANES
Rubber
- butane for synthetic rubber
- derived from petrochemicals
Fuel
- methane for electricity generation
- produces less carbon dioxide
Pesticides
- pentane C5H12
- similar to butane and hexane
- volatile, colorless liquid with gasoline-like odor
Paint
- bestine as solvent; used as the coating
- heptane as the rubber cement; flammable liquid, highly volatile minor component of
gasoline
Plastic
- ethane that produces ethylene to manufacture plastics