BTS-I(R)&M(S)-05.16-0770 [8 | B.Tech. Degree II Semester Regular and I Semester Supplementary Examination May 2016 IT/CS/EC/CE/EE/MEISE 1102 B / 1202 A ENGINEERING CHEMISTRY (2015 Scheme) Time : 3 Hours Maximum Marks : 60 PART A (Answer ALL questions) (10 x 2 = 20) 1 (@)_ Explain Beer-Lamberts law. (>) _ Differentiate Schottky and Frenkel defect. (©) What are the special features of fuel cell? (@)__ Explain pseudo order reaction with example. (© Derive the Nernst equation for electrode potential. (6) What is Eutectic system? Explain (g) Give the method of preparation and important properties of polystyrene. (h) What is refractories? Give the different types of refractories. (i) Write any four differences between thermoplastics and thermosets. What is chemical potential? Explain its importance in thermodynamic study of system. PART B (4x10 = 40) HL. @) Explain: 0) (i) Spin-Spin coupling in NMR spectroscopy. (ii) Positive and negative shielding in NMR spectroscopy. (b) Explain different postulates in free-electron theory. 4 OR TI. (a) Explain Born-Haber cycle taking Nacl as an example. ©) (b) Explain the principle and importance of ESCA in chemical analysis, 6) IV. (a) Whatare the important factors controlling corrosion? © (>) Derive the integral rate law equation for first order reaction. (4) oR 7.0)VL. vil. VI. Ix, @) ) @) ) (a) (b) @ (b) (a) ) © Derive the Integral Rate Law equation for first order reaction, What is the difference between primary and secondary cell? Explain the working of lead-acid storage cell, Derive the Kirchhof’s equation, What is eutectic system? Explain the phase diagram of Zn-Mg system. OR Explain phase rule taking two component pb-Ag system as example. Explain the following: (i) Trautons rule. (ii) Nernst heat theorem, Explain the importance of vulcanisation of rubber. Differentiate Injection molding and Extrusion molding. OR Explain the Ziegler-Natta coordination polymerization technique. What are the chemical reactions involved in cement hardening? Explain the importance of viscosity index in lubricants. oe ©) (4) @) @) ©). (4) 6) 6) (4) (4) Q)