MATERIAL SAFETY DATA SHEET

Section 1 Chemical Product and Company Identification

MSDS name: 2-cyano- 4'-Bromomethyl biphenyl

Manufacturer: Yancheng Cty Donggang Pharmaceutical Development Co.,Ltd
Address: Binhai Coastal Chemical Industry Garden, Yancheng City, Jiangsu Province, China,
224555
TEL: 0086-515-84383198
FAX: 0086-515-84383197
http://www. dgpharm.com
E-mail: dgp@dgpharm.com

Section2 Composition, Information on Ingredients

Chemical name: 2-cyano- 4'-Bromomethyl biphenyl

Percent: 99.0%
Molecular formula: C14H10NBr
Melting point: 125-128°C
CAS No: 114772-54-2

Section3 Hazards Identification

Classification of the substance or mixture

Acute oral toxicity Category

Acute dermal toxicity Category
Acute Inhalation Toxicity - Dusts and Mists Category
Skin Corrosion / irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Specific target organ systemic toxicity (single exposure) Category 3

* Classification according to EU Directives 67/548/EEC or 1999/45/EC

For the full text of the R phrases mentioned in this Section, see Section 16

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 Symbol(s) Xn - Harmful
R -phrase(s) none
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
Risk Combination Phrases
R36/37/38 - Irritating to eyes, respiratory system and skin.

Signal Word Hazard Statements

Warning:
H302 - Harmful if swallowed
H332 - Harmful if inhaled
H315 - Causes skin irritation
H335 - May cause respiratory irritation
H319 - Causes serious eye irritation
Precautionary Statements - EU (§28, 1272/2008)
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Other Hazards:
No information available.

Section4 First Aid Measures

Description of first aid measures

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Obtain medical attention
Skin Contact Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes.
Ingestion Clean mouth with water Get medical attention.
Inhalation Remove from exposure, lie down Move to fresh air if breathing is difficult, give oxygen
If not breathing, give artificial respiration Obtain medical attention

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Notes to Physician Treat symptomatically

Section5 Fire Fighting Measures

Extinguishing media
Suitable Extinguishing Media
Water spray .Carbon dioxide (CO2) .Dry chemical foam.
Extinguishing media which must not be used for safety reasons.
No information available.
Special hazards arising from the substance or mixture
Thermal decomposition can lead to release of irritating gases and vapors
Advice for fire-fighters
As in any fire, wear self-contained breathing apparatus pressure demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.

Section 6 Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment .Ensure adequate ventilation.
Environmental precautions
Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an
airtight container, taking care not to disperse it Containment and cleaning ,adhered or collected
material should be promptly disposed of, in accordance with appropriate laws and regulations .

Section 7 Handling and Storage

Precautions for safe handling Technical measures:

Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent
dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or
aerosol will be generated. Avoid contact with skin, eyes and clothing. Advice on safe handling:
Conditions for safe storage, including any incompatibilities :
Keep container tightly closed. Protect from light and moisture .Store at ambient temperature.
Store away from incompatible materials such as oxidizing agents. Comply with laws.

Section 8 Exposure Controls, Personal Protection

Control parameters
Exposure limits This product, as supplied, does not contain any hazardous materials with
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occupational exposure limits established by the region specific regulatory bodies.
Derived No Effect Level (DNEL) No information available.
Exposure controls
Engineering Measures Ensure adequate ventilation, especially in confined areas Ensure that
eyewash stations and safety showers are close to the workstation location
Personal protective equipment
Eye Protection Goggles
Hand Protection Protective gloves
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin
exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls No information available.

Section 9 Physical and Chemical Properties

Synonyms: 2-Cyano-4'-bromomethyl biphenyl

2-(4-Bromomethylphenyl)benzonitrile
Molecular formula: C14H10BrN

Molecular weight : 272,14

Physical State: Powder, Solid
Appearance : Off-white

Melting point: 125-128°C

Odor: Odorless
PH : No information available
Boiling Point/Range: No information available
Flash Point: No information available

Section 10 Stability and Reactivity

Stability: Stable at normal temperature of storage, handling and use

Conditions to avoid: Flame, high temperature, incompatible materials /products.
(Incompatible materials: Strong oxidizing agents, Acid anhydrides, Acid
chlorides)
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Hazardous decomposition components:
Nitrogen oxides (NOx), Bromide ,Carbon monoxide (CO).
Carbon dioxid(CO2),Hydrogen cyanide (hydrocyanic acid)

Section 11 Toxicological Information

Acute toxicity: No information available

Irritancy: No information available
Chronic Toxicity No information available
Carcinogenicity : No information available
Biodegradation: No information available
Abiotic degradation: No information available

Section 12 Ecological Information

General information :Not available

Section 13 Disposal Considerations

Waste disposal procedure: Do not dispose in environment, dispose the product in accordance with
federal state and local laws.
Contaminated Packaging Empty containers should be taken to local recyclers for disposal.

Section 14 Transport Information

14.1 UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (4-Bromomethyl-2’-cyanobiphenyl)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (4-Bromomethyl-2’-cyanobiphenyl)
IATA: Environmentally hazardous substance, solid, n.o.s. (2-Cyano-4'-bromomethylbiphenyl)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
14.6 Special precautions for user
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 Transportation note: should check whether the packing is in good condition before sealing. It
is strictly prohibited to do mixed transportations with oxidant, food chemicals ect. Should be far
away from fire and heat source.

Section 15 Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixture
International Inventories
Component 2-Cyano-4'-Methylbiphenyl
EINECS —
ELINCS —
NLP —
TSCA —
DSL —
NDSL —
PICCS —
ENCS X
CHINA —
AICS —
KECL —
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
EINECS/ELINCS - European Inventory Lists
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances
ENCS - Japan Existing and New Chemical Substances
CHINA - China Inventory of Existing Chemical Substances
AICS - Inventory of Chemical Substances
KECL - Existing and Evaluated Chemical Substances

Section 16 Other Information

The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express or
implied, with respect to such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the information for their
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particular purposes. In no way shall the company be liable for any claims, losses, or damages of
any third party or for lost profits or any special, indirect, incidental consequential or exemplary
damages, howsoever arising, even if the company has been advised of the possibility of such
damages.

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