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Lead-Acid Batteries
Making battery
technology
easier to
understand
European Edition 3
Page 1
Exide Technical Guide to Lead-Acid Batteries
Contents
Rotterdam
Vejle Moscow
Manchester
3Bad Lauterberg 16 Pinsk
35
Exide serves the A new generation Stock management
European of batteries and maintenance
aftermarket Poznan
4 18 0 3 6 36
9 12
La Cartuja 6 22 38
zuqueca A look inside the box Considerations for CV The power of
applications Exide’s brands
ares
7 24 77 39
760
Carbon Boost Dual Battery System Exide – OE
batteries designed for Scania
8 26 42
Battery types and Exide Motorbike & Apps and mobile
their applications Sport Batteries product information
11 28 77 43
Lithium-ion vs Supply Batteries 760 New standards for
Lead-Acid for marine and leisure on-shelf and online
Dubai communication
12 31 44
Product life and Battery chargers for Exide Battery Range
performance workshops and
end-users
14 32 48
The road ahead A second century of Exide Transportation
48 V > 400 V > 500 V
innovation – driving a &
V 12 V 12 V
better future GNB Industrial Power
Page 2
Exide serves the European aftermarket
with strong regional battery brands and local representation
Oslo Helsinki
Mölnlycke
Vejle Moscow
Rotterdam
Manchester
Bad Lauterberg
Pinsk
Poznan
Azambuja La Cartuja
Castanheira Azuqueca
Manzanares
Page 3
Exide Technical Guide to Lead-Acid Batteries
The lead-acid battery has come a long way since that The cavernous space under the bonnet of a classic car
pivotal point in car manufacturing history, when the was soon filled with a vast array of new electrical and
alternator was introduced in the early 1960s. Previously, mechanical components. At the same time, the trend was
the number of electrical devices in a vehicle was limited towards sleeker, more compact body styling. Efforts
by the older DC generator, or dynamo as it was also towards better fuel economy also meant that every gram
known. of each component counted towards the car’s overall
running cost.
Although early alternators had a much lower capacity
than those fitted in today’s vehicles, it was enough to As a world-leading manufacturer, Exide has constantly
allow car manufacturers to introduce more electrical met the challenges to make batteries better, smaller and
devices to their vehicles. lighter. As a trusted partner, Exide works with major
carmakers to produce OE batteries that
fulfil the specification, deliver
reliable performance and
have excellent lifespan.
Page 4
How the battery works much harder than ever before
Basic electrical devices that Over 100 control units, including climate control, electric
included lighting, radio and windows/mirrors/seats, mobile communications, satellite
window wipers navigation, high-quality sound/vision entertainment, enhanced
safety features, automatic sensors, Start-Stop battery
management control...
Excellent Oxide
Page 5
Exide Technical Guide to Lead-Acid Batteries
Page 6
Each cell produces 2.16 volts, regardless of the
plate size and quality. Modern automotive batteries
consist of six cells connected in series to produce a
total of 12.84 volts (6V batteries still exist but only on
older vehicles).
77
6 x 2.16 volts = EA770 760
12.84 volts
www.exide.info/ea770
EX2FF317
Exide introduced its groundbreaking Carbon Boost technology, which enables batteries to
recharge up to 1.5 times faster. How does this work?
Page 7
Exide Technical Guide to Lead-Acid Batteries
Page 8
EFB (Enhanced GEL Batteries
Flooded Battery) Exide invented the
Batteries patented GEL battery
technology under the dryfit®
Developed by Exide in
trademark.* Instead of being
partnership with major
in liquid form, the electrolyte
European car manufacturers,
is thickened into a gel-like
the EFB battery combines
mass. The GEL battery is
3DX Grid plates with higher-
a highly robust energy-system with best-in-class deep
density active material and additives.
cycle properties, allowing unmatched safe depth of
The plate is contained in a polyethylene envelope and discharge to 90%.
combined with a polymat inlay, increasing cyclability.
Some manufacturers use the word ‘gel’ in the description
EFB is specifically designed for small to mid-sized
of their AGM products, but this partial use of the process
vehicles with Start-Stop, regenerative braking and other
does not come close to delivering the same performance
powerful fuel-saving features.
and benefits. Exide’s special patented design of pressure-
relief valves results in a fully sealed battery that can
be safely stored and used in almost any location or
environment, even transported by air. Crucially, GEL also
has the smallest volume and weight ratio for the amount
of Watt hours supplied.
*GEL was originally patented by Sonnenschein, which is now part of the Exide group
Page 9
EXIDE BATTERY COMPONENTS & ASSEMBLY
Note that other battery maufacturers may use slightly different materials and configurations
Features Grid Type 3DX Grid Framed Flat Cast Orbital 3DX Grid Cast Flat
3DX Grid 3DX Grid Cast Orbital 3DX Grid Cast Flat
Separator Microporous Absorbent Absorbent Polyethylene Polyethylene
Method Envelope Glass Mat Glass Mat Envelope/Mat Envelope
Electrolyte Liquid Absorbed Absorbed Liquid GEL
APPLICATIONS
LIGHT VEHICLE
Car Start-Stop
Start-Stop Start-Stop
Starting + Regenerative braking
+ Regenerative braking + Regenerative braking
+ Coasting mode
Van
Exceptional Exceptional
Specialist Starting
endurance endurance
COMMERCIAL VEHICLE
Delivery Truck
Long-Haul Truck
Agriculture
Specialist
BIKE
Motorbike
Moped
High Power Starting
Quad/Utility High Power Starting
+ Side Mounting
Starting + Side Mounting
Garden
+ Deep discharge
Jet Ski
Snowmobile
LEISURE
Separate supply
Motorhomes Starting & Supply Starting & Supply Starting & Supply
battery use
Caravan/Cabin Supply battery use Supply battery use Supply battery use
MARINE
Motor Boat
Separate supply
Starting & Supply Starting & Supply Starting & Supply
battery use
Sail Boat
Page 10
An introduction to
Lithium-ion vs. Lead-Acid batteries
What is Lithium? and parallel fashion to attain the required voltage. To
better understand this arrangement let us consider two
Lithium is a chemical element with the symbol Li and
extreme ends of the spectrum. Exide’s Motorbike & Sport
atomic number 3. It is a soft, silver-white metal and under
Li-ion battery contains four cells of 3.2V each, connected
standard conditions, it is the lightest metal and the least
in serial to produce a total nominal voltage of 12.8V. At the
dense solid element. Because of its high reactivity, lithium
other end of the scale Tesla’s Model S electric car uses an
never occurs freely in nature, and instead, appears only
85 kWh battery pack containing 7,104 Lithium-ion battery
in compounds. Traces of Lithium can be found in water,
cells. It is worth mentioning cost at this point. The Li-ion
plant-life, food and even the human body. Commercial
Motorbike & Sport battery costs around 3-4 times more
extraction comes from specific rocks and granite with the
than a lead-acid equivalent. The list price of the Tesla
greatest abundance of lithium-containing minerals.
battery pack in 2015 was US$44,000.
What is a Lithium-ion battery?
These strong plus points come at a significantly higher Nobody can predict at this stage if, how, and when
cost. This is due to more expensive raw materials, complex Lithium-ion will enter mainstream use in the automotive
assembly of components and high precision required in sector. Lead-acid battery technology has come a long
the manufacturing process. Lithium-ion batteries pose way over recent years. It still offers the only economically
some unique safety hazards. A small fault or damage can viable solution to engine starting and the vast majority of
create an internal short-circuit and a subsequent build- supply battery requirements. Continuous development is
up of heat. In extreme cases an overheated battery can pushing lead-acid technology beyond its previous limits
possibly burst into flame. This situation is rare and is of performance and has even demonstrated success
protected against with a battery management system in new, full electric modes of Personal Rapid Transit
to prevent operation outside each cell’s safe operating [refer to page 33]. Of course, future developments in
range i.e. min-max charge, safe temperature etc. Lithium-ion will be focused on reducing battery costs,
further improving safety and addressing the question of
How do Lithium-ion batteries scale up and challenge recycling the end of life product. Within a decade we are
applications traditionally performed by Lead-Acid? likely to see crossover between lead-acid and Lithium-
Li-Ion batteries are made up from multiple cells ion in a number of applications, but no great change of
(typically 3.2V or 3.7V) that can be connected in serial dominance of one technology over the other.
Page 11
Exide Technical Guide to Lead-Acid Batteries
Engine Management
13% (Injection, Ignition, Sensors)
8% Engine
50% of breakdowns
are caused by the 6% Tyres
vehicle’s general
electrical system 5% Fuel System
At 50%, electrical problems are the single biggest cause of environment can all have a negative effect on the battery.
breakdowns, according to the latest figures from Europe’s Occasionally a faulty alternator can take its toll on the
largest roadside breakdown service. In Germany alone, battery. Regular testing of both battery and starter/
over 640,000 call-outs per year are due to a defective alternator avoids most unexpected car breakdowns.
or discharged battery. If the driver is away from home
or desperate to get started, it results in a costly battery
replacement on the spot.
Page 12
Main reasons for Battery self-discharge
reduced battery life All lead-acid batteries suffer from self-discharge. The pace of this self-
discharge depends on the storage conditions and the technology.
Generally, the cooler the storage conditions, the slower the self-discharge.
Calcium-Calcium batteries such as conventional flooded (maintenance-
free) car and truck batteries have a lower self-discharge than Calcium-
Antimony conventional batteries (Hybrid) like Marine Dual, Marine
Equipment and some truck batteries with filling plugs for water top-up.
Short distance trips with
maximum loads This is important for both distributors and battery users. Distributors have
to make sure that the FIFO (first-in, first-out) rule is applied for stock
management. At the same time, the voltage of the batteries should be
regularly controlled: when the voltage drops to 12.4V, the battery needs to
be recharged to avoid shortening the battery’s lifespan and introducing
performance problems.
Overcharging with
risk of drying out
Extreme
temperature
Page 13
Exide Technical Guide to Lead-Acid Batteries
12 V 12 V 12 V
Fuel/Power Input
Fossil* Fossil* Fossil* Electric Electric
Vehicle Propulsion
Full Engine Engine supported by Engine or Full Electric
electric motor electric motor
...especially coasting, ...subject to available
braking & stopping battery energy
Battery Technology
12 V AGM or EFB 48 V Lithium-ion > 300 V Lithium-ion > 300 V
Lithium-ion
12 V AGM or Li-Ion Auxiliary 12 V AGM or Li-Ion Auxiliary 12 V AGM or Li-Ion Auxiliary
Energy Efficiency
Start-Stop + Start-Stop + Start-Stop + Start-Stop +
Regenerative braking Regenerative braking Regenerative braking, Regenerative braking,
& coasting (optional) & coasting coasting & kinetic coasting & kinetic
Reduction in CO2
≤ 100%
2-10% 12-20% 15-30%
Subject to level of
renewable energy
49% 1% 4% 2%
44% 44% 44% 44%
Standard Standard Standard Standard
Cars Cars Cars Cars
* Fossil fuels include: petrol, diesel and CNG Source for Market Projection: Eurobat 2014
Page 14
CO2
L
EU Regulations for the
160g
reduction of CO2 130g
During a global push to reduce CO2 emissions through 80g Car manufacturers’ compliance
various forms of carbon tax, some regions, as net to 95g target: 95% by 2020
importers of oil, have much more to gain by conserving 40g 100% by 2021
energy. This explains why automotive development in
greener cars has been most vigorously pursued in Europe 0g
and Japan, where end-users in these markets are more 2000 2005 2010 2015 2020
attracted by the offer of better fuel economy.
Lead-Acid
Start-Stop 17.0 21% 35.0 40% 44.0 48.5% 155M 124M 109M 98M 76M
Accessible
technology
for the IAM
Fastest
growth:
AGM & EFB Source: Eurostat figures for 2014
Conventional 63.0 78.5% 50.0 58% 43.0 47% Start-Stop
Batteries
Total Lead-Acid 80.0 99.5% 85.0 98% 87.0 95.5%
Page 15
Exide Technical Guide to Lead-Acid Batteries
Other EFB
120% 110%
Standard Standard
conventional conventional
battery battery
Power Cycle Charge Power Cycle Charge
Life Acceptance Life Acceptance
ABSORBENT REGENERATIVE SUPERIOR INTENSIVE 4 x STANDARD 3DX GRID REGENERATIVE SUPERIOR INTENSIVE 3 x STANDARD
GLASS MAT BRAKING POWER USE CYCLABILITY TECHNOLOGY BRAKING POWER USE CYCLABILITY
Today’s conventional car battery has come a long way, Today Exide is a well-respected and leading supplier of
but the tasks of starting the engine and supplying stored Start-Stop batteries to eleven of the main European car
energy for lighting, driving and comfort controls have manufacturer groups (see page 17).
remained largely unchanged. However, the new
On the outside, Start-Stop batteries appear very similar to
generation of Start-Stop cars puts far greater demand on
conventional car batteries, but the technology inside the
the battery to work harder and requires many more
box is vastly different. Even entry-level Start-Stop
thousands of starts during the battery’s lifetime.
vehicles demand twice the endurance of the very best
The global shift led by European car manufacturers premium battery. Larger cars with Start-Stop and those
towards Start-Stop cars required a totally new kind of featuring Regenerative Braking require up to 15% extra
battery. Exide’s expertise and vast experience in stored power and three times the endurance level.
energy for automotive and industrial applications put the
It is extremely important to respect the car
company in prime position to develop Start-Stop batteries
manufacturers’ specification. Always use an Original
designed to cut fuel consumption and reduce CO2
Spare Part AGM to replace AGM, and EFB to replace EFB.
emissions.
Incorrect fitment will reduce battery life and the
In 2004 Exide launched the first European AGM effectiveness of the Start-Stop system.
(Absorbent Glass Mat) Start-Stop battery, followed by
the first EFB (Enhanced Flooded Battery) battery in 2008.
Page 16
EXIDE START-STOP OFFER
Exide Car Brands Exide Exide’s IAM offer
Manufacturer OE
Start-Stop Group offer AGM AUX EFB
Auxiliary BMW
BMW
Battery
Mini
Mercedes-Benz
Daimler
Smart
Alfa Romeo
Designed by Exide to Chrysler
meet the latest Fiat Chrysler Ferrari
technical demands Fiat
Lancia
from car manufacturers, the new Auxiliary battery
provides voltage stabilisation during re-start operations. Ford Ford
Suzuki* Suzuki
Toyota* Toyota
Audi
Bentley
Porsche
VW Group
Seat
Skoda
VW
Volvo* Volvo
* Special recognition of Exide supplier quality and awards for our factories
Exide is one of the largest OE manufacturers of The chart shown here gives a simple overview of Exide
Start-Stop batteries, and its AGM and EFB ranges are Start-Stop battery types, covering a wide spectrum from
readily available as high-quality replacement parts for all popular entry-level cars to high-end luxury models.
European Start-Stop cars.
Image: Creative Commons by Jaguar MENA
Page 17
Exide Technical Guide to Lead-Acid Batteries
Synergy is our programme to simplify battery replace- It is time for all workshop operators to review their
ment in the latest cars. Micro-Hybrids are the fastest capability in replacing Start-Stop batteries. With Exide’s
growing segment of the car parc, with the batteries support, it is very easy to adapt quickly to this new battery
tied more closely to the electrical management system technology and expand your current business.
and the ECU. Some diagnostic equipment was not yet
Trust Exide to provide the independent aftermarket with
capable of addressing this use case, so Exide has been
high-quality Start-Stop battery products, expert advice
pushing for this to change.
and straightforward installation solutions.
We met with the diagnostic equipment providers
to explain the problems our customers have
been facing. Many of the providers have since
announced software updates to introduce
battery replacement capabilities, which is
great news for our customers.
Page 18
Test, charge or replace new Start-Stop batteries
with Exide’s workshop tools
> Is your workshop ready? Check your existing devices now for compatibility with Start-Stop cars.
> If you use diagnostic equipment, ensure your software is up to date and able to complete the job.
> Exide supports workshops with individual ‘task-specific’ tools available at a reasonable price.
OK
Start-Stop
Test Charge
Battery
Replace
Exide EBT-165P with Exide 12/7
Battery Tester Battery Charger
A modern tester with test report
printouts that works for all batteries,
Exide AGM or EFB A charger with unique built-in safety
features, suitable for standard, Start-
including those found in the latest Start-
Stop generation.
Aftermarket battery Stop AGM/EFB and GEL batteries.
Ah
Find Install
Page 19
Exide Technical Guide to Lead-Acid Batteries
Page 20
European emission standards PM (g/kWh) Particulate Matter
CV
for trucks and buses Euro 1
1993 0.30
This table summarises the
emission standards and their Euro 4 Euro 5 Euro 6
2006 2009 2013 0.20
implementation dates for new
type approvals. A different set
Euro 2
1996 0.10
of standards apply to passenger
Euro 3
cars and light commercial 2001
vehicles. 0.01
7 6 5 4 3 2 1 7
0.4
NOX (g/kWh) Nitrogen Oxides
The Cost of High Emissions for Fleet Operators European Low-Emission Zones (LEZ)
> Higher Fuel Costs Currently over 220 cities and towns in fourteen countries
across Europe operate or are preparing to introduce Low-
> Higher Road Taxes
Emission Zones (LEZ’s), to help meet EU health-based air
> Higher Toll & Parking Charges quality limit values.
> Higher charges to enter Low Emission Zones
Restrictions are applied mainly to older diesel-engine
These are the key economic factors driving operators to trucks and buses, although in some cases cars too. This
upgrade their fleets by purchasing new Euro5/6 vehicles, means that vehicles may be banned from a LEZ, or a
fitting new engines or approved filter systems. charge is made to enter the zone when emissions exceed
a set level.
*Approx. exchange rate at the time of writing. Source: Transport for London
Page 21
Exide Technical Guide to Lead-Acid Batteries
Logistics is more important than ever, with customers Three main factors when selecting the
expecting faster and more predictable deliveries. In this right battery:
competitive environment, fleet owners are focusing on
Vibration resistance: For trucks with rear-
total cost of ownership. After all, when a truck is off the
chassis battery installations (e.g. Euro 5/ Euro
road, it leads to customer dissatisfaction, unused labor
6 trucks), robust and high-vibration-resistant
and capital, and potential fines and penalties.
batteries are mandatory to avoid breakdowns.
Exide designed its battery range to reduce the risk Vibration resistance is also required for any
of breakdowns and gives customers a competitive vehicle operating on bad roads or rough
advantage. You get market-leading performance, lower terrain.
total cost of ownership and battery options for any use
case. Cycling endurance: High cycling endurance
is important in batteries for long-haul trucks
As a true expert in OE batteries, Exide helps you select with life on-board, commercial vehicles
the right battery. For fleet owners and installers alike, doing intensive urban deliveries, and any
it is vital to make the right choice for the conditions commercial vehicle with extensive energy
of use. Three important requirements. This maximizes battery lifespan
criteria to consider in battery and ensures a safe battery start.
performance are: vibration
resistance, cycling endurance Vibration Cranking power: High cranking power allows
and cranking power. Resistance for engine starts in cold climates and is
required for many power-intensive vehicles in
agriculture and construction.
Cycling Cranking
Endurance Power
Page 22
Page 22
Reinforced container wall Labyrinth integrated into the lid with
with additional ribs* flame arrestor and central degassing
outlet for maximum safety
* Latest generation of Exide’s leading HVR® design, meeting V4 requirements (EN 50342-1:2015)
Page 23
Dual Battery System designed for Scania
The Dual Battery System was developed by Exide The benefits of the Dual Battery System are clear. The first
Technologies in association with its customer Scania, advantage is improved starting reliability, as the power in
for intensive truck use and as the ultimate solution for the Orbital AGM units is reserved solely for starting the
reliable starting. engine. This means reduced truck downtime, as these
batteries are always ready. The GEL batteries provide
In contrast to the classic layout – two standard flooded
a better power supply for devices such as the heater,
truck batteries providing energy for both engine start and
television, fridge, etc. – items which need to run during the
supply functions – the Dual Battery System includes two
night, when the vehicle is off the road. Another advantage
Orbital AGM batteries for cranking the engine at start-up,
is the weight saved in comparison with conventional
plus two GEL batteries for on-board power supply. This
batteries, leading to reduced fuel consumption. The
optimised technology matches the best battery type
dimensions of the Dual Battery System are the same as
with each specific function. The Orbital AGM batteries
the classic system, so there is no impact on housing them
supply full power to crank the engine and then restore a
in the vehicle.
full charge before switching off. When the engine is off,
power is provided exclusively by the GEL batteries, which The Dual Battery System has been successfully integrated
ensures the Orbital AGM batteries remain fully charged into the new Scania Streamliner truck range and will be
for the next engine start. extended to other truck manufacturers in the near future.
Page 24
Traditional Truck Battery Configuration New Dual Battery System
Conventional Flooded Start and Supply Orbital AGM Start GEL Supply
75% 90%
50%
In normal day-to-day situations, the traditional configuration of Exide’s Dual Battery System copes far better with any unscheduled
heavy-duty batteries providing both start and supply functions delay in transit. The GEL battery set offers deeper discharge to
continues to serve vehicle operators well. Experienced drivers are supply power when the engine is off, while the independent Orbital
aware of and respect the limits of on-board power. AGM set remains fresh and ready to provide reliable starting power.
*Calculations based on an average battery life of 300 cycles and depth of discharge at 20º C.
Beyond these recommended levels: Deeper discharge = shorter average life. Shallower discharge = longer average life.
GEL is the ideal choice of battery as a reliable secondary power supply for any
vehicle with essential on-board equipment
©Au Morandarte CC BY-SA 2.0
Emergency vehicles carrying Urban buses with extensive use of Mobile cranes, power lifts and all
pumps, winches and electrical Closed-Circuit Television security specialist task vehicles
rescue equipment and passenger information
systems
Page 25
Exide Technical Guide to Lead-Acid Batteries
Page 26
Exide Li-Ion
Exide is speeding up your passion. It has launched a
new lithium-ion Motorbike & Sport battery range for
those who demand the ultimate riding experience. The
battery’s ultra-lightweight design reduces the overall
weight of your bike, enabling faster acceleration and
better performance. It has very low self-discharge, ideal
for starting your engine after long periods off the road.
Exide Li-ion can be installed in multiple positions and
comes with first-class safety features.
Benefits
> Ultra-lightweight – up to 80% lighter than lead-acid
batteries
Page 27
Exide Technical Guide to Lead-Acid Batteries
Supply Batteries
for marine and leisure
Page 28
Supply battery options and energy-needs formula
Starter Supply (Deep Cycle)
Battery Batteries
Thinner plates allows Thicker plates improve the cyclability for deeper and longer
for more plates in the discharge.
battery. Better for
short bursts of high Available as Dual/Dual AGM or dedicated Equipment GEL
energy needed for for starting and supply needs for best depth of discharge
starting. and longest life.
Start Start
plus equipment load equipment load only
Average Life
Recommended safe levels of battery discharge*
300+ Standard Start Exide Dual Exide Dual AGM Exide Equipment Gel
cycles
25%
based on
recommended
25% 40%
Depth of 50%
75%
Discharge 75% 90%
(DoD)
100%
Beyond these recommended levels: Deeper discharge = shorter average life. Shallower discharge = longer average life. *Estimates based on depth of discharge at 20∘C
300 × 1=300
40 × 3=120
35 × 2= 70
80 × 6=480 450Wh/95Ah 900Wh/100Ah 1300Wh/120Ah
The rated energy in Wh is calculated based on the safe DoD indicated above: 100Ah in AGM is equal to 900Wh because of allowed DoD is 75% (otherwise 100Ah at 12V would be 1200Wh)
Page 29
Exide AGM or Premium
for high discharge of energy
to start engine
The illustration above of a typical motorhome shows the A similar concept applies to caravans without the need
electrical power needs of a typical leisure vehicle. The for a starter battery and alternator input. In the case of
starter battery provides a regulated supply of energy for marine applications, the starter and supply batteries
the vehicle’s standard electrical devices, but a separate follow the same general principle of the motorhome, but
supply battery is installed to deal with the additional there is an ever-increasing trend to prioritise navigation,
loads on the AC and DC circuits. winching and communication, etc., which can be
absolutely critical, especially with sea-going vessels.
The major benefit of a supply battery is the depth of
Larger boats have more on-board electric equipment
discharge between recharging. When the vehicle is in
and generally operate on longer trips between battery
motion, the battery is replenished by sharing energy
recharges. It is not uncommon on these vessels to find
generated by the alternator. When the engine is off,
a bank of supply batteries configured to provide ample
input energy from an on-site power supply or portable
stored energy for the longest voyages.
generator (supplemented by solar panels) can be used to
rest or recharge the supply battery.
Exide Start AGM, Dual AGM and Equipment GEL DNV GL is an independent foundation
batteries are approved by DNV GL for safe and reliable established in 1864 with the purpose
use at sea. This is the highest possible endorsement of of safeguarding life, property and the
a marine market product. Very few lead-acid batteries environment.
have passed the vigorous independent tests required
to attain this certification. It is an achievement Exide Find out more: www.dnvgl.com
Technologies is extremely proud of.
Page 30
Exide Technical Guide to Lead-Acid Batteries
Charging Tips
> Batteries should be charged off-vehicle if the voltage
drops below 12.45 volts (or 6.2 volts for 6V batteries)
> Use the specially developed Exide charger for best
results
> Avoid fire or flare and ensure good ventilation during
and after charging
> Allow the battery to rest for at least 12 hours after
charging
Page 31
Exide Technical Guide to Lead-Acid Batteries
The Exide story started over 120 years ago, and the Exide is also taking part in research partnerships with car
company has been at the forefront of innovation manufacturers and scientific research consortiums. The
throughout its rich and fascinating history. As the key focus points revolve around electronics, new alloys
automotive industry evolved from novelty to main- and additives, improved separators, and cutting-edge
stream, it served drivers with easier, safer, bigger and production processes. These are all essential aspects in
faster vehicles. At every stage, greater demand was put on the company’s own testing and performance evaluations
the battery, and Exide responded with constant product of smarter battery management systems and advanced
improvements or by developing entirely new variants of battery technology.
lead-acid batteries.
Exide is developing the batteries that will power the
Today’s priorities are centred on higher levels of vehicle next generation of cars.
automation, connectivity and greater fuel efficiency.
Exide has been making significant investments in these
areas, with large R&D initiatives underway at its state-of-
the-art research centres in Europe and the USA.
Page 32
Innovation
in action
Image: CC by Moshrunners
M5BAT Project
For the unique hybrid
5MW battery storage
project Exide is
pioneering technology
to improve energy
storage from renewable
PRT (Personal Rapid Transit) sources such as wind,
Exide Technologies helped the world’s first Personal water, solar and geothermal power. Funded by the
Rapid Transit System become a reality. Heathrow Pods German Federal Ministry for Economic Affairs and
are fully automated electric vehicles that transport up to Energy, this crucial project is at the forefront of the global
four people with luggage between London Heathrow’s quest to successfully balance power generation with
Terminal 5, various car park stations and a major hotel. consumption. Exide’s battery knowledge and experience
Passengers use a touch screen panel to call for the vehicle makes a valuable contribution to a greener world.
that usually arrives within 15 seconds and select their
destination for a non-stop trip at a maximum speed of
40kpm.
GNB
Each Pod employs a 7kW Synchronous AC drive motor
Sonnenschein
powered by a pack of 4 Exide 45Ah AGM Orbital batteries. Lithium
This battery combination meets the need for a high
Exide’s GNB Industrial
power draw over short periods time, low maintenance
Power division is
for continuous operation and the highest level of
making a strong
safety. Partial recharging takes place at every stopping
business case for
event when passengers board and disembark, and only
lithium battery power in 24/7 material handing. Forklift
occasionally during vehicle downtime is a full recharge
trucks and pallet moving is a huge part of the motive
required.
power sector. GNB have installed hundreds of new
Successfully operating since 2011, the Heathrow Pod lithium based systems since 2013, which yield substantial
system has delivered impressive results in reliability, cost and timesaving benefits. Sonnenschein Lithium’s
running costs and environmental benefits. This proven very fast recharge eliminates the requirement to switch
concepts is now the model for developments of new and battery packs and the need to maintain ventilated
even larger systems in the UK and Asia. battery charging stations.
Page 33
Exide Technical Guide to Lead-Acid Batteries
There are many battery suppliers on the market, but only Exide supports you in all these fields.
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Training designed
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Exide Technical Guide to Lead-Acid Batteries
New cases New grids & Neutralise Tips to identify battery types
and lids lead oxide or re-used Read the label - Look out for the
manufactured from produced from the clear water and Pb symbol on lead batteries or the
recycled pellets recycled material new electrolyte Li symbol on lithium batteries. You may
also be able to identify them by their
manufacturer.
Page 36
Terminology guide
Absorbed glass mat (AGM) two dissimilar substances, a positive electrode; similarly, the negative plates
electrode and a negative electrode, form the negative electrode.
Type of lead-acid battery in which the
that conduct electricity, and a third
electrolyte is absorbed into a fibreglass In the process of charging, the cell
substance, an electrolyte, that acts
mat. The plates in an AGM Battery may is made to operate in reverse of its
chemically on the electrodes. The two
be flat or, more exceptionally, wound in a discharging operation; i.e., current is
electrodes are connected by an external
tight spiral. In cylindrical AGMs, the plates forced through the cell in the opposite
circuit. The electrolyte functions as an
are thin and wound, like most consumer direction, causing the reverse of the
ionic conductor for the transfer of the
disposable and rechargeable cells, chemical reaction that ordinarily takes
electrons between the electrodes.
into spirals so they are also sometimes place during discharge, so that electrical
referred to as spiral wound. Cycle energy is converted into stored chemical
energy.
Ampere, or Amp A “cycle” is a somewhat arbitrary
term used to describe the process of Valve-regulated sealed battery
The unit of measurement of current
discharging a fully charged battery
flow. One volt placed across a one ohm Battery in which cells are closed but
down to a particular state of discharge.
resistance will cause a current of one Amp have an arrangement (valve) which
The term “deep cycle” refers to batteries
to flow. One amp for one hour is called an allows the escape of gas if the internal
in which the cycle is from full charge to
“amp-hour” or AH. pressure exceeds a predetermined value.
80% discharge. A cycle for an automotive
Ampere-hour or Ah battery is about 5%, and for telephone Vented cell
batteries is usually 10%.
The unit of electrical capacity - this tells Cell with a cover having an opening
you how much energy the battery will Electrolyte through which products of electrolysis
store. Current multiplied by time in hours and evaporation are allowed to escape
Conductive chemical (such as acid),
equals ampere-hours. A current of one freely from the cell, in order to avoid
usually liquid, solid or gel, in which the
amp for one hour would be one amp- excessive pressure inside the cell.
flow of electricity takes place within the
hour; a current of 3 amps for 5 hours
battery, and which supports the chemical Vent valve
would be 15 Ah.
reactions required.
Part of certain types of batteries which
Battery
Lead-acid battery permits the escape of gas in the case of
A battery is an electric device that excess internal pressure but which does
Lead-acid batteries are the most
converts chemical energy into electrical not allow the entry of air
commonly used rechargeable auto-
energy, consisting of a group of electric
motive batteries today. Their power-to- Volt (V)
cells that are connected to act as a source
weight ratio is often quite good. Also,
of direct current. Batteries are made of The unit of measurement of electrical
the energy-to-volume ratio is good
connected cells encased in a container potential or “pressure”. Most batteries
compared to other types of batteries.
and fitted with terminals to provide a come in 6, 12, & 24 volt. A single cell is 2
They are cheap and can supply high
source of direct electric current at a given volts.
surge currents needed to start engines.
voltage. A battery is characterised by its
Every car uses a lead-acid battery for this Watt (W)
chemical composition (combination of
purpose.
metal(s) and electrolyte used), voltage, A unit of power. 1W is 1 Joule per second
size, terminal arrangements, capacity Separator (J/s), or also 1 amp multiplied by 1 volts
and rate of capability or more cells. (AxV). 1 amp at 120 volts gives the same
Material with an ion permeable structure
result in watts as 10 amps at 12 volts.
Battery pack (bank) that provides electrical insulation
between plates of opposite polarity in Watt-hour (Wh)
Set of any number of (preferably) identical
a cell
batteries or individual battery cells. They Watt-hours measure amounts of energy
may be configured in a series, parallel or Storage battery for a specific period of time. For example
a mixture of both to deliver the desired if a 60 W light bulb is on for one hour,
A storage battery consists of several
voltage, capacity, or power density. then that light bulb will have used 60 Wh
cells connected to each other. Each
of energy. If left on for two hours, then
Cell cell contains a number of alternately
the 60 W light bulb will have used 120Wh
positive and negative plates, a separator
Basic functional unit providing a source of energy.
and electrolyte. The positive plates of the
of electrical energy by direct conversion
cell are connected to form the positive
of chemical energy. A cell consists of
Page 37
The power of
Exide’s Brands
Keeping the Exide Brand in front of millions of motorsport fans across Europe
Page 38
Exide Technical Guide to Lead-Acid Batteries
There has never been such a wide choice of the largest network of European sales offices,
parts available in the aftermarket. This creates with knowledgeable people providing local
challenges for workshops, which must take support. When you see Exide on the label, you
into account the best product for a particular can be confident that the battery was
model of car, as well as the individual manufactured to the highest
needs of each motorist. In the standards, on the same
battery market, Exide has production lines as the
managed to simplify this company’s OE batteries.
complexity, and present our
Exide is committed to helping
partners with clear quality
you succeed in the
ranges and meticulous
aftermarket. We provide
fitment guides.
quality training and excellent
All our products are technical support, helping
designed to the correct you to understand the
specification and offer unique function and
the performance expect- performance benefits of
ed by vehicle manufact- every kind of lead-acid
urers. We have some of battery. This lets you make
the most advanced more informed decisions
technology in the industry, a and offer better
reputation for offering professional recommend-
industry-leading products, and ations to your customers.
Page 39
Exide Technical Guide to Lead-Acid Batteries
4 United Kingdom 30,557 4 United Kingdom 4,179 4 France 3,015 4 Netherlands 547
TOTAL EU28 +
Iceland, Norway
& Switzerland
270m
TOTAL EU28 +
Iceland, Norway
& Switzerland
38m TOTAL EU28 +
Iceland, Norway
& Switzerland
34m TOTAL EU28 +
Iceland, Norway
& Switzerland
5.5m
Other significant markets Other significant markets Other significant markets
Peak sales period: Peak sales period: Peak sales period: Peak sales period:
September to February October to March January to June February to July
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Battery replacement cycle
Boat Parc LV & CV Battery Replacement Cycle LV Average Battery Life by Country
1 2 3 4 5 6 7 8 9 10 Years
Italy 4.5
100%
‚000 units 100% 100%
98% Poland 5.0
1 Sweden 781 91%
Turkey 6.0
2 Norway 758
78% Austria 6.3
3 Finland 710 75%
4 Italy 510 Belgium/Luxembourg 6.3
65%
5 United Kingdom 500
Cyprus 6.3
56%
6 France 485
50% Czech Republic 6.3
7 Netherlands 408
Source:
Heavy vehicles’ replacement cycle Sweden 6.3
International Boat Industry (IBI) 2015
Boat > 20% of batteries replaced within the first year European Average 6.5
Seasonal Battery Sales > 65% of batteries replaced within the second year
Greece 7.0
JAN
> 100% of batteries replaced within three years
FEB Portugal 7.0
MAR
APR
Heavy vehicle batteries (for vehicles of more than 3.5 Spain 7.3
MAY tonnes) have a shorter battery life-cycle due to their
JUN higher utilisation and annual average mileage and their Iceland 8.4
JUL
higher energy requirements caused by their greater
AUG United Kingdom & Ireland 9.0
SEP
weight and usage.
OCT
NOV Factors that influence battery replacement rate
DEC include vehicle parc age, on-board electrical
Source: equipment, climate conditions and service frequency.
Peak sales period: Eurobat Study This differs from country to country as shown in
February to July (The availability of automotive lead-based batteries for recycling in the EU) the list above based on Exide estimates.
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Apps and mobile product information
FREE download for iPhone & Android Available on any internet-connected device
Page 42
Exide Technical Guide to Lead-Acid Batteries
77
760
77
760
Page 43
Exide Technical Guide to Lead-Acid Batteries
Start-Stop Start-Stop
x4
Conventional
Performance Very high
Other AGM
Premium
The high-performance
battery with Carbon Boost
120%
Standard
conventional
battery
Power Cycle Charge
Life Acceptance
SUPER FAST
RECHARGE
Start-Stop EFB
Premium Carbon Boost has improved charge acceptance and
Enhanced Flooded Battery recharges up to 1.5 times faster than standard batteries.
Ideal for small to mid-sized While battery failure remains the number one cause of car
cars with Start-Stop breakdowns, fast recharging considerably reduces the risk of
and other fuel-saving breakdowns by helping the battery retain a healthy state of
charge for longer.
features
x3
Performance High
Other EFB
110%
Standard
Excell Classic
conventional
battery The reference battery The economy
Power Cycle Charge with a range covering solution for older cars
Life Acceptance 99% of the car parc with basic equipment
Page 44
Commercial Vehicles
StrongPRO PowerPRO
New-generation HVR® (high vibration resistance) Superior cranking power with more plates and active
design with Carbon BoostTM material to maximize grid surface
Conventional
Page 45
Exide Technical Guide to Lead-Acid Batteries
Exide Bike
Recommended
applications
Could require
Maintenance water refilling
MAINTENANCE FREE MAINTENANCE FREE MAINTENANCE FREE
Side mounting
Upright mounting only
approved HIGH INCLINATION HIGH INCLINATION MEDIUM INCLINATION
*
Hermetic seal
HERMETIC SEAL HERMETIC SEAL HERMETIC SEAL
Acid pack
No initial filling No initial filling
included ACID PACK INCLUDED ACID PACK INCLUDED
Technology Gel AGM charged AGM dry charged Flooded dry charged
Page 46
Marine & Leisure
Up to 90% recommended
depth of discharge
Smallest volume/weight
ratio for Wh supplied
DNV-GL is an independent
foundation established in
1864 with the purpose of
safeguarding life, property
and the environment
Page 47
Exide Technologies, with operations in more than 80 countries and more than 120 years of experience, is one of the world’s
largest producers and recyclers of lead-acid batteries. The company develops state-of-the-art energy storage solutions for the
automotive and industrial market. Leading car, truck and lift truck manufacturers trust in Exide Technologies as an original
equipment supplier. Exide also serves the aftermarket through a portfolio of successful and well-known brands.
Exide Transportation manufactures batteries for light and commercial vehicles, as well as agricultural and marine leisure
applications. Industrial markets – under the division GNB Industrial Power – include efficient energy storage solutions for
motive power applications such as lift trucks, cleaning machines and other commercial electrical vehicles, and network power
applications such as telecommunications systems, renewables, and uninterruptible power supply (UPS).
Exide’s engineers have always been at the forefront of bringing important innovations to the industry. Exide’s ISO/TS-certified
manufacturing facilities ensure that customers receive products that are produced with maximum efficiency and fulfil the
highest quality standards, while minimising impact on the environment.
Exide’s extensive sales and distribution network provides quality service and delivers on time to its customers. Its world-class
recycling facilities ensure that batteries will be reused, helping to make a positive contribution to the environment. Exide also
provides services, accessories and energy consulting to its clients.
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