Solution 10.

1
(a) BUBL P
prepare a graph showing P vs x1 and P vs y1 for a temperature of 75oC
2945.47/
ln P1 sat /kPa = 14.2724 -
(𝑡+224.00)

2972.64/
ln P2 sat /kPa = 14.2043 -
(𝑡+209.00)

diketahui bahwa t=75 oC

Nilai t=75 disubstitusi ke persamaan Antoine sehingga didapat nilai:

ln P1 sat = 4.42132977
P1 sat = 83.2068575

ln P1 sat ln P2 sat P1 sat P2 sat x1 y1 P

4.42132977 3.73725775 83.2068575 41.9827049 0 0 41.9827049
4.42132977 3.73725775 83.2068575 41.9827049 0.1 0.1804721 46.1051202
4.42132977 3.73725775 83.2068575 41.9827049 0.2 0.3313197 50.2275354
4.42132977 3.73725775 83.2068575 41.9827049 0.3 0.4592839 54.3499507
4.42132977 3.73725775 83.2068575 41.9827049 0.4 0.5692047 58.472366
4.42132977 3.73725775 83.2068575 41.9827049 0.5 0.6646469 62.5947812
4.42132977 3.73725775 83.2068575 41.9827049 0.6 0.7482945 66.7171965
4.42132977 3.73725775 83.2068575 41.9827049 0.7 0.8222067 70.8396117
4.42132977 3.73725775 83.2068575 41.9827049 0.8 0.8879894 74.962027
4.42132977 3.73725775 83.2068575 41.9827049 0.9 0.9469141 79.0844422
4.42132977 3.73725775 83.2068575 41.9827049 1 1 83.2068575

GRAFIK

P vs x
100
t=
P vs x1
90 P vs y1

80
Supercooled
70 Liquid
P /kPa

60

50

40
 70 Liquid

P /kPa
60

50

40

P2 sat30= 41.98
Superhea
Vapor
20
0 0.1 0.2 0.3 0.4 0.5 0

x1, y1
 MOCHAMMAD SAIFUDDIN ZUHRI
17031010106/Paralel C

DEW P
P1 sat P2 sat y2 x1 y1 P
83.20686 41.9827 1 0 0 41.9827049
83.20686 41.9827 0.9 0.05308592 0.1 44.1711271
83.20686 41.9827 0.8 0.11201059 0.2 46.6002467
83.20686 41.9827 0.7 0.17779334 0.3 49.3120849
83.20686 41.9827 0.6 0.25170545 0.4 52.3590488
83.20686 41.9827 0.5 0.33535308 0.5 55.8073513
83.20686 41.9827 0.4 0.43079534 0.6 59.7418779
83.20686 41.9827 0.3 0.5407161 0.7 64.273268
83.20686 41.9827 0.2 0.66868031 0.8 69.548484
83.20686 41.9827 0.1 0.81952795 0.9 75.76705
83.20686 41.9827 0 1 1 83.2068575

P vs x1,y1
t = 75 oC P1 sat = 83.21
P vs x1
P vs y1
46.10512
40
Supercooled
Liquid 35
30
25
20
 Liquid

Superheated
Vapor
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1, y1
(b) prepare a graph showing P vs x1 and P vs y1 for a temperature of 75oC
2945.47/
ln P1 sat /kPa = 14.2724 - (𝑡+224.00)

2972.64/
ln P2 sat /kPa = 14.2043 - (𝑡+209.00)

P A1 B1 C1 t1 sat A2 B2
70 14.2724 2945.47 224 69.8445717 14.2023 2972.64

P t /oC ln P1 sat ln P2 sat P1 sat P2 sat x1

70 89.6435913 4.88126279 4.25049524 131.796991 70.1401401 0.00
70 87 4.80143537 4.1615973 121.684955 64.1739456 0.1013
70 85 4.74013463 4.09327959 114.449609 59.9361358 0.1846
70 83 4.67803518 4.02402603 107.558532 55.925812 0.2726
70 81 4.61512131 3.95381724 101.00008 52.1339955 0.3656
70 79 4.5513769 3.88263333 94.7627972 48.5519002 0.4641
70 77 4.48678538 3.81045385 88.8354145 45.1709349 0.5686
70 75 4.42132977 3.73725775 83.2068575 41.9827049 0.6796
70 73 4.35499259 3.6630234 77.8662485 38.9790142 0.7977
70 71 4.28775593 3.58772857 72.8029104 36.1518662 0.9235
70 69.8445717 4.24849524 3.54373744 70 34.5959784 1.0000

GRAFIK

t vs x1,y1
95
t2 sat = 89.58 P = 70 kPa
90 Superheated
Vapor

85

80
t /oC

75 Subcooled
Liquid
70
t vs x1
t vs y1
83 75 71 t1 sat = 69.84
65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1, y1
 Liquid
70
t vs x1
t vs y1
83 75 71 t1 sat = 69.84
65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1, y1
 TRIAL AND ERROR
Diketahui:
x1 = 0.6
C2 t2 sat x2 = 0.4
209 89.64359 t asumsi = 100
P= 70
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)
y1
0.00 A1 = 14.2724 A2 = 14.2043
0.1761 B1 = 2945.47 B2 = 2972.64
0.3018 C1 = 224 C2 = 209
0.4188
0.5275 x1 x2 T ln P1 sat ln P2 sat P1 sat P2 sat
0.6283 0.6 0.4 100 5.181443 4.584106 177.9394 97.91559
0.7216 0.6 0.4 95 5.038952 4.425879 154.3082 83.58624
0.8079 0.6 0.4 90 4.891922 4.26236 133.2094 70.97731
0.8874 0.6 0.4 85 4.740135 4.09328 114.4496 59.93614
0.9605 0.6 0.4 80 4.583354 3.918348 97.842 50.31727
1.0000 0.6 0.4 76.42224 4.467966 3.789414 87.17921 44.23048

> Dengan perhitungan goal seek didapat nilai

T = 76.42224

> menghitung nilai y1

�1=(𝑥1⁡ 〖
〖�_1 〗 ^𝑠𝑎𝑡)/�

y1 = 0.74725
ted

9.84
9.84
P
145.9299
126.0194
108.3166
92.64422
78.83211
69.99972
71
65
10.1 (a) (b) Diketahui:
Diketahui: y1 = 0.33
x1 = 0.33 y2 = 0.67
T= 100 T= 100
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶) 〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

Perhitungan: Perhitungan:
〖 ln⁡�1 〗 ^𝑠𝑎𝑡=13.7819−2726.81/(𝑡+217.572) 〖 ln⁡�1 〗 ^𝑠𝑎𝑡=13.7819−2726.81/(𝑡+217.5

〖 ln⁡�⁡2 〗 ^𝑠𝑎𝑡=13.9320−3056.96/(𝑡+217.625) 〖 ln⁡�⁡2 〗 ^𝑠𝑎𝑡=13.9320−3056.96/(𝑡+217.6

> untuk T=100, maka > untuk T=100, maka

ln P1 sat = 5.195469 ln P2 sat = 4.307569 ln P1 sat = 5.195469
P1 sat = 180.4528 P2 sat = 74.25972 P1 sat = 180.4528

> mencari nilai P > mencari nilai P

P = P2 sat + (P1 sat - P2 sat)x1 �=1/(�1/ 〖
〖�1 〗 ^𝑠𝑎𝑡⁡+�2/ 〖
〖�2 〗 ^𝑠𝑎𝑡⁡)
P = 109.3034

> mencari nilai y1 P = 92.15638

�1=(𝑥1⁡ 〖
〖�_1 〗 ^𝑠𝑎𝑡)/�
> mencari nilai y1
y1 = 0.544808 �1=(�1⁡�)/ 〖
〖�_1 〗 ^𝑠𝑎𝑡⁡

y1 = 0.168529
𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

=13.7819−2726.81/(𝑡+217.572)

=13.9320−3056.96/(𝑡+217.625)

=100, maka
ln P2 sat = 4.307569
P2 sat = 74.25972

^𝑠𝑎𝑡⁡+�2/ 〖
〖�2 〗 ^𝑠𝑎𝑡⁡)

�_1 〗 ^𝑠𝑎𝑡⁡
10.1 (c)
Diketahui:
x1 = 0.33
x2 = 0.67
t asumsi = 100
P= 120
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

A1 = 13.7819 A2 = 13.932
B1 = 2726.81 B2 = 3056.96
C1 = 217.572 C2 = 217.625

x1 x2 T ln P1 sat ln P2 sat P1 sat P2 sat

0.33 0.67 100 5.19546921 4.30756867 180.452793 74.2597197
0.33 0.67 101 5.22242208 4.33777481 185.382652 76.5370405
0.33 0.67 102 5.24920627 4.36779194 190.415071 78.8692915
0.33 0.67 103.306817 5.28395668 4.40673688 197.148387 82.001446
0.33 0.67 104 5.30227491 4.42726623 200.793077 83.7022807
0.33 0.67 105 5.32856245 4.45672685 206.141423 86.2048853

> Dengan perhitungan goal seek didapat nilai

T = 103.306817

> menghitung nilai y1

�1=(𝑥1⁡ 〖
〖�_1 〗 ^𝑠𝑎𝑡)/�

y1 = 0.54215806
 (d)
Diketahui:
y1 = 0.33
y2 = 0.67
t asumsi = 100
P= 120
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

A1 = 13.7819 A2 = 13.932
B1 = 2726.81 B2 = 3056.96
C1 = 217.572 C2 = 217.625

P y1 y2 T ln P1 sat ln P2 sat P1 sat P2 sat

109.303434 0.33 0.67 100 5.195469 4.307569 180.4528 74.25972
112.456092 0.33 0.67 105 5.328562 4.456727 206.1414 86.20489
115.679399 0.33 0.67 109.1309 5.435448 4.576515 229.3956 97.17512
119.999936 0.33 0.67 115 5.582743 4.74159 265.7997 114.6163
122.342243 0.33 0.67 120 5.704186 4.877694 300.1211 131.3275
125.783943 0.33 0.67 125 5.822084 5.009826 337.6751 149.8786

> Dengan perhitungan goal seek didapat nilai

T = 109.1309

> menghitung nilai x1

𝑥1=(�1⁡�1)/ 〖
〖�1 〗 ^𝑠𝑎𝑡⁡

x1 = 0.630838
 (e)
Diketahui :
P= 120
T= 105
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

A1 = 13.7819 A2 = 13.932
B1 = 2726.81 B2 = 3056.96
C1 = 217.572 C2 = 217.625

> Menghitung P1 sat

〖 ln⁡�1 〗 ^𝑠𝑎𝑡=13.7819−2726.81/(105+217.572)
P
92.15638 ln P1 sat = 5.328562
106.6892 P1 sat = 206.1414
120
141.1009 > Menghitung P2 sat
161.2564 〖 ln⁡�2 〗 ^𝑠𝑎𝑡=13.932−3056.96/(105+217.625)
183.5686
ln P2 sat = 4.456727
P2 sat = 86.20489

> Menghitung nilai x1

𝑥1=(�⁡−⁡ 〖
〖�2 〗 ^𝑠𝑎𝑡)/( 〖
〖�1 〗 ^𝑠𝑎𝑡⁡ 〖−� 2 〗 ^𝑠𝑎𝑡⁡)

𝑥1=(120⁡−86.205)/(206.14−86.205)

x1 = 0.281775

> Menghitung nilai y1

y1=(𝑥1⁡⁡ 〖
〖�1 〗 ^𝑠𝑎𝑡)/�

y1=((0.2818⁡)(206.14))/120

y1 = 0.484046
10.2 (a) Benzene(1)/ethylbenzene(2)
Diketahui:
T= 90
P= 90
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

A1 = 13.7819 A2 = 13.9726 P
B1 = 2726.81 B2 = 3259.93 90
C1 = 217.572 C2 = 212.3
ln P1 sat = 4.916301 ln P2 sat = 3.188842 P
P1 sat = 136.4968 P2 sat = 24.26032 90
ln P1 sat ln P2 sat P1 sat P2 sat x1 y1 P 90
4.916301 3.188842 136.4968 24.26032 0 0 24.26032 90
4.916301 3.188842 136.4968 24.26032 0.1 0.384672 35.48397 90
4.916301 3.188842 136.4968 24.26032 0.2 0.584473 46.70761 90
4.916301 3.188842 136.4968 24.26032 0.3 0.706856 57.93126 90
4.916301 3.188842 136.4968 24.26032 0.4 0.789513 69.15491 90
4.916301 3.188842 136.4968 24.26032 0.5 0.849087 80.37855 90
4.916301 3.188842 136.4968 24.26032 0.6 0.894062 91.6022 90
4.916301 3.188842 136.4968 24.26032 0.7 0.929219 102.8258 90
4.916301 3.188842 136.4968 24.26032 0.8 0.957457 114.0495 90
4.916301 3.188842 136.4968 24.26032 0.9 0.980634 125.2731 90
4.916301 3.188842 136.4968 24.26032 1 1 136.4968 90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90

P-x-y
160

140
 P-x-y
160
P1 sat = 136.497
140
t = 90 oC
120
Subcooled
liquid
100
P /kPa

80
P, x
y
P,
60

40
Superheated
20
vapor
P2 sat = 24.26
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x, y
A1 B1 C1 t1 sat A2 B2 C2 t2 sat
13.7819 2726.81 217.572 76.19911 13.9726 3259.93 212.3 131.8362

t /oC ln P1 sat ln P2 sat P1 sat P2 sat x1 y1

131.8362 5.977819 4.49981 394.5787 90 0.00 0.00
130 5.93659 4.448995 378.6417 85.54093 0.0152 0.0640
128 5.891185 4.393023 361.834 80.88458 0.0324 0.1304
126 5.845252 4.33639 345.5896 76.43109 0.0504 0.1936
124 5.798781 4.279082 329.8971 72.17418 0.0692 0.2535
122 5.751762 4.221089 314.7448 68.10764 0.0888 0.3104
120 5.704186 4.162398 300.1211 64.22537 0.1093 0.3644
118 5.656043 4.102997 286.0147 60.52138 0.1307 0.4155
116 5.607323 4.042871 272.414 56.98973 0.1532 0.4638
114 5.558015 3.982009 259.3076 53.62463 0.1769 0.5095
112 5.508109 3.920395 246.6841 50.42037 0.2017 0.5528
110 5.457593 3.858017 234.5321 47.37134 0.2278 0.5935
108 5.406456 3.79486 222.8405 44.47203 0.2552 0.6320
106 5.354688 3.73091 211.5978 41.71704 0.2842 0.6682
104 5.302275 3.66615 200.7931 39.10109 0.3148 0.7023
102 5.249206 3.600567 190.4151 36.61899 0.3471 0.7343
100 5.195469 3.534143 180.4528 34.26565 0.3813 0.7644
98 5.141051 3.466864 170.8953 32.03611 0.4174 0.7926
96 5.085939 3.398711 161.7317 29.9255 0.4558 0.8190
94 5.030119 3.329668 152.9512 27.92907 0.4965 0.8437
92 4.973578 3.259718 144.5431 26.04219 0.5397 0.8668
90 4.916301 3.188842 136.4968 24.26032 0.5857 0.8883
88 4.858275 3.117022 128.8018 22.57904 0.6347 0.9084
86 4.799484 3.044239 121.4477 20.99405 0.6869 0.9270
84 4.739913 2.970474 114.4243 19.50116 0.7427 0.9442
82 4.679547 2.895706 107.7213 18.09627 0.8023 0.9602
80 4.61837 2.819914 101.3287 16.77541 0.8660 0.9750
78 4.556364 2.743079 95.23661 15.53474 0.9343 0.9887
76.19911 4.49981 2.672981 90 14.48308 1.0000 1.0000

t-x-y
160

150 Superheated
 t-x-y
160
P = 90 kPa
150 Superheated
t2 sat = 131.84
140
vapor

130

120 P, y
P /kPa

110

100

90
P, x
Subcooled
80
liquid

70 t1 sat = 76.199
60
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

x, y
10.2 (b) 1-Chlorobutane(1)/chlorobenzene(2)
Diketahui: P
T= 90 90
P= 90
〖 ln⁡� 〗 ^𝑠𝑎𝑡=𝐴−𝐵/(𝑡+𝐶)

A1 = 13.7965 A2 = 13.8635
B1 = 2723.73 B2 = 3174.78
C1 = 218.265 C2 = 211.7 P
ln P1 sat = 4.960823 ln P2 sat = 3.34053 90
P1 sat = 142.7112 P2 sat = 28.23409 90
ln P1 sat ln P2 sat P1 sat P2 sat x1 y1 P 90
4.960823 3.34053 142.7112 28.23409 0 0 28.23409 90
4.960823 3.34053 142.7112 28.23409 0.1 0.359639 39.6818 90
4.960823 3.34053 142.7112 28.23409 0.2 0.558234 51.12951 90
4.960823 3.34053 142.7112 28.23409 0.3 0.684168 62.57722 90
4.960823 3.34053 142.7112 28.23409 0.4 0.771152 74.02493 90
4.960823 3.34053 142.7112 28.23409 0.5 0.834835 85.47264 90
4.960823 3.34053 142.7112 28.23409 0.6 0.883475 96.92035 90
4.960823 3.34053 142.7112 28.23409 0.7 0.921838 108.3681 90
4.960823 3.34053 142.7112 28.23409 0.8 0.952871 119.8158 90
4.960823 3.34053 142.7112 28.23409 0.9 0.978491 131.2635 90
4.960823 3.34053 142.7112 28.23409 1 1 142.7112 90
90
90
90
90
90
90
90
90
90
90
90
90
90

P-x-y
160 P1 sat = 142.711 160

140 150
t = 90 oC
140
120
130
100
120
a
 P-x-y
160 160

140 150
t = 90 oC
140
120 Subcooled
liquid 130
100
120
P /kPa

80

P /kPa
110
60 100

40 90

Superheated 80
20
vapor
P2 sat = 28.2341 70
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 60
0.0
x, y
A1 B1 C1 t1 sat A2 B2 C2 t2 sat
13.7965 2723.73 218.265 74.71346 13.8635 3174.78 211.7 127.3522

t /oC ln P1 sat ln P2 sat P1 sat P2 sat x1 y1

127.3522 5.915729 4.49981 370.8247 90.00 0.0000 0.0000
125 5.861727 4.434394 351.3302 84.30102 0.0213 0.0833
123 5.815224 4.37805 335.3667 79.68253 0.0404 0.1504
121 5.768174 4.321029 319.953 75.26606 0.0602 0.2141
119 5.720566 4.263319 305.0774 71.04536 0.0810 0.2745
117 5.672389 4.204906 290.7283 67.01427 0.1027 0.3319
115 5.623635 4.145777 276.8939 63.1667 0.1255 0.3863
113 5.574291 4.085921 263.5627 59.49669 0.1495 0.4377
111 5.524348 4.025322 250.7229 55.99834 0.1746 0.4864
109 5.473795 3.963968 238.3631 52.66588 0.2010 0.5325
107 5.42262 3.901843 226.4718 49.4936 0.2289 0.5759
105 5.370812 3.838934 215.0374 46.47591 0.2582 0.6169
103 5.318359 3.775225 204.0487 43.60734 0.2892 0.6556
101 5.265249 3.710702 193.4944 40.88249 0.3218 0.6919
99 5.211469 3.645347 183.3631 38.29608 0.3564 0.7261
97 5.157006 3.579146 173.6438 35.84293 0.3930 0.7583
95 5.101849 3.512082 164.3254 33.51797 0.4318 0.7884
93 5.045982 3.444137 155.3968 31.31624 0.4729 0.8166
91 4.989393 3.375294 146.8472 29.23287 0.5167 0.8430
89 4.932067 3.305535 138.6658 27.26313 0.5632 0.8677
87 4.87399 3.234842 130.8419 25.40237 0.6127 0.8907
85 4.815147 3.163197 123.365 23.64606 0.6654 0.9121
83 4.755523 3.090578 116.2244 21.98979 0.7217 0.9320
81 4.695102 3.016968 109.4099 20.42925 0.7819 0.9505
79 4.633867 2.942344 102.9113 18.96024 0.8462 0.9676
77 4.571804 2.866687 96.71839 17.57868 0.9151 0.9834
74.71346 4.49981 2.778895 90 16.10122 1.0000 1.0000

t-x-y
160
P = 90 kPa
150 Superheated
t2 sat = 127.352
140
vapor

130

120
 t-x-y
160

150 Superheated
t2 sat = 127.352
140
vapor

130

120
P, y
P /kPa

110

100

90
Subcooled P, x
80 liquid

70 t1 sat = 74.714
60
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x, y