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3.(D)
1.(6)
2.(4) The product of Diels-Alder reaction has four chiral carbon atoms.
40
3.(4) Ar is produced due to radioactive decay of 19 K .
40
19 K + -1e0
18 Ar 40 K - electron capture
40
Mol of Ar formed = mol of K decayed.
25 75 100
So, N0
40 40 40
25
Nt
40
N0
Nt
2n
t
n2
2 109
t 4 109 years
4.(5) Resistance of solution 2.5 103
1
Conductivity (G) cellconstant
Resis tan ce
1
3
1.25 5 104 1cm 1
2.5 10
1000
Equivalent conductance ( ) G
N
1000
5 104 5 1cm 2 eq 1
0.1
Monosubstituted benzene on electrophilic substitution yield three products, o, m and para substituted product.
2 K1 (2 K1 ) 2 8 K 2 mV 2
x2
2K 2
1/ 2 1/ 2
K 4 K12 8 K 2 mV 2 K
2 K 2 mV 2
x 1 1 x 1 1 1
K2
4 K14 4 K12 K2
K 2
1
3.(B) Q U W
P dV
C CV
n dT
R
C CV 1 V
V
4.(D) Imagine 3 loops.
B0
d 2T 6V
2
0 maxima at V
dV R 3
dT
3 V 2
, which is maximum when volume is minimum.
dV R
9.(B) As pressure in tube increases more air will be pushed in the bubble.
Hence radius increases.
4T
10.(B)
2R
R 2 mg ma
g
a
2
5t 10 dt dv
2 0
V= 10 m/sec n2
1 1
2.(1) KQ V
r R
KQ K 3Q KQ K 3Q
KV
r R R R
KQ KQ
V k 1
r R
3.(5)
T0 mg T0 2T
mg
T
2
2mg mg ma p T mg m 4 a
mg mg
ag P 4 mg
2 2
P mg 4mg
P 5 mg
P
5
mg
4.(2)
mg
T1 cos 37
4
3mg 3 mg
T1 sin 37 T
4 4
tan 37 3
tan 37 1
3 4
5.(4) Current through 10Ω is zero, by applying wheat stone network conditions.
6.(1) Pressure Amplitude, pmax 100 N / m 2
100
Bks0 s0
Bk
B
V B 0V 2
0
1 2 2 100 1
L3 l L 2m K m 1 s0 = m a=1
2 3 1 330 330 1089
2.(A) When a steady is reached, no current passes though the capacitor or the branch CE.
Considering the loop ABEFA,
5 I1 I 2 10 or I1 I 2 2 A
Considering the loop BCDEB :
4 I 2 12 10 2
I 2 0.5 A
So, I1 2 0.5 1.5 A
To find the charge on capacitor, we must known potential difference across the plates.
Consider the loop CEDC : 12 4 I 2 3 0 VC 8 0
Or VC 2V . So charge on capacitor Q CV 10C .
2 x 2 1 4 x4 1 4 x 2 4 x4 4 x 2 x 2 1 2 x 1
1.(A) 2
2
a 2x 1 a x x 0 4
a
2
2
2 2 2 2
a x x, x x 1 x x a 0 or x x 1 a 0
3
1 4a 0 and 1 4 4a 0 a
4
1 1 2
2.(A) Area of triangle OAB x OB AB x e x
2 2
2
Let f x xe x . We need to maximize f x
2 2 2
f x e x x 2 x e x e x 1 2 x 2
1
At x f x has local max.
2
1
As x f x 0 and f 0 0 At x , we have absolute maximum
2
1 1 1 1 1 1
e 1 2
2 2 2 8 e 8e
3.(B) Since AB is fixed and AC is perpendicular to BC. So, locus of C is a circle whose diameter is AB. So, family of
circles passing through AB is
x 2 y 2 6 x 8 y 21 x y 5 0 x 2 y 2 6 x 8 y 21 5 0
6 8
So, centre is ,
2 2
Since AB is diameter so centre must lie on AB
6 8
5 2 Locus is x 2 y 2 4 x 6 y 11 0 .
2 2
4.(B)
x 1
Since lim x 2 1 = 0, so limit will exists only, when lim a sin | x 1 | b cos( x 1) 4 = 0
x1
b + 4 = 0 b = –4
Now applying L’Hospital rule, we get :
a cos x 1 b sin x 1
lim 2
x 1 2x
a
2 a 4
2
MULTIPLE CORRECT ANSWERS
x 1 x 1
x
x x 1
5.(BCD) f x lim 2
n x 2 n 1
0 x 1
x 1
1 3
f 1 f 1 0 1 1 f 1 f 1 f 1 0 1
2 2
f 1 f 1 1 0 1 f 1 f 1 0 0 0
x 2
7.(ABCD) f y f f x . Let x y 1 f 1 f 1 f 1 1 f 1 0
y
x 1
Differentiating w.r.t. x keeping y constant f y f f x . Let y x
y y
1 f x 3
f x f 1 f x log f x 3log x log k f x k x3
x f x x
f 1 1 f x x3
x x
x 2 2 sin 2 2 sin 2
(B) lim 2 lim 2 x2 0 (C) x3 x 3 solutions 1, 0, 1
x0 x3 x 0 x2
4x
4
3 3 3
(D) f f x f x3 x3
x9
f x x3 x 9 So x9 x9 0 has infinite solutions.
D z 21 4 z2 4m
z 21 2
4 z 2 16 20 i , are roots of t z 1 t z 2 m 0
a 1
A.T.Q: z 21 4 z2 4m 2 7 16 20 i 4m 2 7 4 5i m 7
4 5i m 7 m 4 5i 7
m 41 m 4 5 i m 41
1.(6) Let f x x 2 2 p 3 x 9 . Since the roots lie in 6 , 1 , so we should have the following conditions :
2
(i) D 0 4 p 3 36 0
p p 6 0 p 0 or p 6 . . . .(i)
27
(ii) f 6 0 p . . . .(ii)
4
(iii) f 1 0 p 2 . . . .(iii)
(iv) 6 1 2 p9 . . . .(iv)
2
27
From equations (i) – (iv), we get : 6 p
4
Therefore, integral value of ‘p’ is 6.
Since 2 , g1 , g 2 , g3 , . . ., g17 , g18 , g19 , g 20 , 6 are in G.P. Therefore, g 4 g17 2 6 12
2.(1) 3.(2)
4.(2) C1 : x 2 y 2 1 and C2 : x 2 y 2 3 x 2 2 y 2 0
A
Let the point of intersection be P(h, k)
AB is chord of contact w.r.t. P to circle C1
AB : hx ky 1 0 . . . .(i)
P(h, k)
AB is also common chord of C1 and C2
AB : 3 x 2 2 y 3 0 . . . .(ii) C1 B C2
(i) (ii)
3 2 2 3
Comparing coefficients of x, y constants, we get :
h k 1
(A) (B) (C)
3k 2
(A) = (C) 3h 3 ; (B) = (C)
2
3h 3 3k 2
6h 6 3k 2 6h 3k 8 0
1 2
Locus is 6 x 3 y 8 0 Slope = 2
5.(2) Case 1 : 3 digits are wrong. We select the 3 digits in 5C3 ways and de-arrange them in 2 ways.
Rest 2 are placed correctly in 1 way. So, by FPC number of ways = 5 C3 2 1 20
2 cos 1 cos 2 cos i sin 2 sin
2
2 cos
2
2 cos 2 cos i sin 2 cos 1
2 cos cos 2 cos 1 i sin 2 cos 1 2 cos 2 cos 1
2 2
Or f (z) = 2 cos 4 cos 2 3
2 2
Let cos x
2
Now f z 2 x 4 x 2 3 x 0 1
2 3
4 x 2 x 3 g x 0 x
2
f z
2 3
4 x 2 x 3 h x
x 1
2
1
g x 8x 2 0 x
4
3 1 1 13
g 0 3, g 3, g 3
2 4 4 4
3
h x 8 x 2 0 x 1
2
3
h 3 , h 1 3
2
13
Range of f z is 3
4
The integers are 2, 3 Number of integers = 2
(A)
A general point on the parabola y x 2 7 x 2 is x, x 2 7 x 2 .
3x x 7 x 2 3
2
Distance of this point from the line y 3x 3 is
10
x2 4 x 5 x2 4 x 5
P as x 2 4 x 5 0 x R .
10 10
dP 2x 4 dP
Differentiate w.r.t. x to get : 0 x 2
dx 10 dx
Also, x 2 is a point of local minima Required point is 2, 8
Sum of abscissa and ordinate = 2 8 10 .
(B) x ay 5 0 x 5 a y 0
So, the above line always passes through the point (5, 0) which is the focus of the parabola y 2 20 x .
4t 4 t 3 h tk 4 0 . . . . (1)
h k
t1 4 t1t2 0 t1t2t3 4
t1t2 t3t4 1
2 h2
Sum of slopes of normal = t12 t1 2 t1t2
16
1 1
Sum of ordinates of the feet of the normals 4
1 1
4
t1t2t3
4
k
t
1 t 2 t3 t 4 t t t t 4 1
1234
h2
According to question k h2 16k
16