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Guwahati Refinery, one of the eight operating refineries owned by Indian Oil Corporation
Limited, is located among the picturesque surroundings near Brahmaputra river at
Guwahati city in the north east part of India. The refinery that process indigenously
available crude at Assam caters to the requirements of the petroleum products in the
region.
Inaugurated on 1st January 1962, Guwahati Refinery is the first public sector refinery in
India and was built using Rumanian technology available in the late 50s. The
original crude oil processing capacity of 0.75 MMTPA has been subsequently
increased to 1.0 MMTPA. The crude oil is supplied from Assam fields by M/s
OIL INDIA LIMITED through a cross-country pipeline.
Besides various processing units, Guwahati Refinery has a captive thermal power
station (TPS) inside the refinery which generates and supplies electric power and
process steam. TPS consists of two chains of DM plant, 2 boilers of 20 T/Hour, 1 boiler
of 40 T/Hour and 2 boilers of 50 T/Hour capacity as well as 2 STGs of 8 MW and one
STG of 12 MW capacity. Three new air compressors are also installed to supply
instrument & plant air and for Nitrogen production.
The other facilities consist of Crude oil, intermediate and product tanks, Hydrogen and
Nitrogen storage bullets, tank wagon loading /unloading gantry, tank truck loading/
unloading gantries, LPG storage and dispatch facilities. There is a well equipped
Laboratory and a modern effluent treatment plant besides fresh water supply from river
Brahmaputra to Refinery and other end users.
The main products currently manufactured in Guwahati Refinery are listed below:
i) Liquefied Petroleum Gas (LPG)
ii) Reformer Naphtha (RN)
iii) Motor Spirit (MS)
iv) Superior Kerosene Oil (SKO)
v) Aviation Turbine Fuel (ATF)
vi) High Speed Diesel (HSD)
vii) Light Diesel Oil (LDO)
viii) Internal Fuel Oil (IFO)
ix) Sulphur (S)
x) Raw Petroleum Coke (RPC)
2. Installed Capacity:
Year of
Name of the Units Installed Capacity Licensor
commissioning
The Crude Oil is pumped to unit by the unit feed pumps from the storage tanks at an
average temperature of 30C and passes through heat exchangers. In the heat
exchangers, the incoming feed exchanges heat with the hot stream products, thereby
attaining a temperature of 200 C before entering the pre-topping column CL-1. The feed
entering CL-1 is flashed and the overhead gases and light gasoline vapours from the top
of the column are condensed in the heat exchangers, overhead condensers and enter in
the reflux drum. Condensate from reflux drum goes to LPG stabilizer as feed for LPG
production.
The skimmed crude at 187 C comes out from the bottom of the column CL-1 and
pumped through heat exchangers where it is heated upto 263 C by exchanging heat
with RCO coming from CL-2 bottom and Gas oil circulating reflux. Then the skimmed
crude enters first in the convection zone and then the radiation zone of the vertical
balanced draft heater.
The heated skimmed crude at ~363 C is delivered through an overhead transfer line to
the main fractionator column CL-2. MP steam at 240 C is introduced at the bottom of
the column to strip off lighter fractions from reduced crude oil. The overhead vapour from
CL-2 is condensed and goes to the NSF Unit as feed along with stabilized gasoline
obtained from stabilizer bottom for Light Naphtha, Reformer Naphtha and Heavy
Naphtha production.
Two circulatory reflux of Kero-II & SRGO is withdrawn, cooled and returned to the
column for better control of vapour liquid traffic in the column. Three side streams viz.
SR Kero-I, II & SR Gas Oil are also drawn from CL-2 which enter the stripping column
CL-3, in the different sections. Steam is introduced in all the sections of the column CL-3
to strip off lighter components, which then go back to main fractionator column CL-2.
SR Kero-I after exchanging heat with NSF feed, gets cooled to 36 C and goes to the
rundown tank. Similarly SR Kero-II & SRGO are cooled in crude heat exchangers and
then in coolers and sent to respective rundown tanks. Reduced crude from the bottom of
CL-2 is pumped through crude oil heat exchangers. Reduced crude oil is then sent to
DCU as hot feed or to rundown tank via RCO cooler for storage.
The feed is RCO and it is directly taken from CDU RCO R/D at 100 Deg C or from tanks
at about 90 C. Clarified Oil (CLO) ex INDMAX is routed to DCU feed with online
blending with RCO. Feed pump P1 takes suction and discharge passes through feed
preheat exchangers, where it gets heated from about 254 C. This heated feed then
goes into main distillation column partly in vapour zone above flash zone and partly in
liquid zone below flash zone.
The fractionator column bottom material (secondary feed) is pumped to heater by a
multistage pump P2/2A.The flow to heater is divided equally into 4 passes at heater
inlet. Fractionators bottom is heater upto 501 deg C in the balanced draft heater furnace
equipped with an Air pre-heater. At the furnace outlet BFW injected in all four passes to
avoid coking in transfer line from heater to coke chamber. Process fluid ex heater goes
to coke drums through the 4-way valve.
In coke chamber cracking and polymerization reactions take place from which Gas,
LPG, CGO, CG, CFO& RFO generated along with RPC. Gases containing all products
are routed to main fractionator flash zone through quench column where CGO reflux is
used to quench the vapours to avoid further polymerization.
The vapours from the quench column 03-CL-1 at about 425 C enters in the flash zone
(34 trays) of main fractionating column (03-Cl-02. A temp. gradient is maintained in
distillation column with top reflux. Top temp. is maintained at about 90 C and bottom at
about 365 C.
The products CK-I, CGO & CFO are steam stripped in stripper column (03-Cl-03A/B/C)
having 4 trays each. The vapours from strippers are returned to the main column (2 trays
above draw off) and the liquids are pumped under level control and sent to run down
tanks after exchanging heat and cooling in run down coolers with circulating water.
The overhead vapours from main fractionators are cooled in condensers S-2A to E to
40 C and taken to reflux vessel 03-V-1. The incondensable gases under pressure
control goes to fuel gas system/ LPG recovery section. The condensed liquid is partly
refluxed back to control column to temp at 40 C and excess liquid under level control
goes to CL-20. A new charge heater was commissioned in 2000 replacing the old heater
and capacity increased to 0.44 MMTPA. Vapour Blowdown Recovery Unit (VBDRU) was
commissioned in 2005 to recover uncondensed hydrocarbons, which were lost to
atmosphere from blowdown stack, to reduce atmospheric pollution and eliminate safety
hazard because of hydrocarbon venting to atmosphere and to make the unit more
efficient by installing the new blowdown scrubber and separator to recover the
hydrocarbon and oil by scrubbing with gas oil. During Sept’12, the main fractionator
column CL-2 was replaced with a new column as a part of reliability improvement. Coke
drum System Package (CDSP) was commissioned in Sep’12. The CDSP project
involved installation of new coke chambers (2 Nos.) with allied modernised facilities like
modern coke cutting system, automated heading/unheading device for top and bottom
cover, coke drum structure, New bridge crane, new coke pit, maze and coke cutting
water recovery system, new lift/elevator.
In LPG Recovery Unit Coker off gases are compressed followed by absorption of C-3/ C-
4 components with Naphtha and separation of C-3/C-4 from rich Naphtha in stabilizer.
3nos. of reciprocating compressors have been provided with a capacity of 2750 kg/hr
each for compressing the cooker off gases up to 15 kg/cmg. Normally two
compressors are in operation and one is standby. The compressed gas after being
cooling to 40 C is routed to absorber with 44 nos. of valves trays. Stabilized gasoline
enters 44th tray and unsterilized gasoline enters 40th tray for absorption of C-3/C-4
components. Condensate generated at inter stage / after stage cooler of compressor is
also transferred to absorber. MP steam heated reboiler is provided at the bottom to strip-
off C-1/C-2 components. The rich solvent from bottom of the absorber is feed to
stabilizer column (04-Cl-04) where gasoline is stabilized by removing LPG. From
stabilizer top LPG sent to bullets after caustic wash and gasoline from bottom sent to
tanks for storage.
5) HYDROTREATMENT FACILITIES
Hydrotreatment Facilities is installed at Guwahati Refinery for improving the stability and
Cetane No. of HSD meeting BS-II & BS-III specification, Smoke point of Kerosene
streams and for up gradation of feed kerosene streams to SKO and ATF. The treatment
facilities consist of the following units:
- Hydro treating Unit (Capacity : 600 TMTPA)
- Hydrogen Unit (Capacity : 10 TMTPA H2 production)
- Amine Treating Unit (Capacity : 5500 Kg/hr Acid gas flow from INDMAX,
HDT & DCU )
- Sulphur Recovery Unit (Capacity : 5 TPD ‘S’ production)
- Sour Water Stripping Unit (Capacity : 6 M3/Hr, augmented to 13 M3/hr in
2009)
The Hydro treating unit (HDT) operates in three blocked out modes of operation, viz.,
ATF mode consisting of SR Kero-I, Kerosene mode consisting of SR Kero-I and SR
Kero-II and HSD mode consisting of SR Kero-II. SR Gas Oil, Coker Kero-I, Coker Gas
Oil & TCO.
Hydro processing technology is a proven & widely used technology licensed by several
reputed licensors like UOP, IFP etc. Guwahati Refinery has opted for UOP’s ‘Distillate
Unionfining’ Technology for this unit.
For supplying Hydrogen gas to HDT unit, a Hydrogen unit is installed based on Steam
Reforming Technology of KTI using a mixture of light naphtha (SRN) and off gases ex
LPG Recovery Unit (LRU) as primary feed (not in use due to diene contents higher than
design). For providing flexibility in feed composition, a pre-reforming step applied
upstream of Reformer using steam reforming technology from M/s Technip, Italy. After
the shift conversion, Pressure Swing Adsorption (PSA) process of UOP applies to
produce high purity hydrogen product from raw hydrogen. For supplying hydrogen during
start-up of hydrogen generation unit two hydrogen bullets are installed in the refinery
with flexibility of unloading hydrogen from potable cylinders.
In order to remove H2S from gaseous feed of Hydrogen unit, the wet gas obtained from
Delayed Coker Unit (DCU) and HDT treated in Amine Treating Unit (ATU) which is
combination of AAU and ARU. Amine Absorbers Unit (AAU) generates rich amine. The
generated rich amine from (AAU) is sent to Amine Regeneration unit (ARU) where
Stripping of H2S is done and regenerated lean amine. The lean amine is reused in AAU
for treating wet gas obtained from DCU from 5500 kg/hr of DCU and 940 kg/hr of HDT
wet gases. The Process licensor of this unit is KTI, BV.
As a part of Hydrotreatment Facility, a Sour Water Stripper (SWS) is also installed to
strip of H2S from sour water coming from HDT unit and existing DCU based on UOP’S
technology. The Acid gas recovered from stripper is sent to Sulphur Recovery Unit.
Acid gases from ATU and SWS is fed to Sulphur Recovery Unit (SRU). In SRU, H2S
present in the feed gas gets converted to elemental Sulphur. SRU of Guwahati Refinery
is based on ‘3 Stage Modified Claus Process’ having a single chain of 5.0 TPD capacity.
AAU, ARU and SWS are a part of SRU and installed at one place is called Sulphur
Block.
6) INDMAX UNIT
INDMAX unit is installed to maximize LPG and light olefin production from heavy
petroleum fractions. INDMAX, Indane Maximization Process, developed by Indian Oil
Corporation Limited (IOCL) is similar to conventional FCC process. In INDMAX, Coker
Gasoline and heavy oils such as RCO, CFO are cracked to more valuable light and
middle distillates such as LPG, Gasoline and Diesel. The capacity of INDMAX unit is
100,000 TPA. INDMAX unit consists of the following sections:
- Feed Storage and Pumping Section
- Reaction and Regeneration Section
- Fractionation Section
- Gas Concentration Section
- LPG/ Gasoline Treatment Section
RCO and CFO will be preheated to 180-220 deg.C in heat exchanger with steam.
Preheated feed will contact catalyst at 700 deg.C in the riser. On contact with catalyst
feed will get cracked to lighter HC’s and the final temperature will be 585 deg.C. Cracked
vapors will be separated from catalyst in the riser and reactor cyclone. Vapors from riser
cyclone will go to main column via vapor line where separation of HC’s in the various
streams will take place.
Main column over heads are separated into Gas, LPG and Gasoline in the Gas
Concentration section consists of wet gas compressor four columns and set of
exchangers and vessels etc. LPG and Gasoline are caustic washed to remove H2S and
then water washed to remove entrained caustic. Diesel withdrawn from the column goes
to diesel pool as well as for flushing oil after stripping in stripping column.
Main part of the main column bottom is recycled to column as quench and wash. Rest of
the bottom materials is clarified in either slurry settler or slurry filter and sent to tanks as
clarified oil.
Catalyst from reactor stripper after stripping out entrained HC’s gets back into the
regenerator through spent catalyst standpipe. Spent catalyst is regenerated in the
regenerator by combustion of coke formed on the catalyst with air. Specially designed air
grid ensures uniform distribution of air in the regenerator. Air blower supplies air for coke
burning. Regenerated catalyst travels back to riser through regenerated catalyst
standpipe.
Combustion gases form the regenerator at temperature of 730 deg.C with catalyst enters
regenerator primary and secondary cyclone to knock down the catalyst. Hot flue gases
from regenerator passes through Double Disc Slide Valve to the Orifice Chamber where
the pressure of the gases is reduced from 2.5 kg/cm2 to 0.2 kg/cm2. Heat of hot flue is
removed in WHB by generating HP Steam.
Fresh and equilibrium catalyst are stored in two different hoppers with requisite loading
unloading provision. Apart from these two hoppers automatic catalyst loading system
has been installed from M/s Intercat for smooth catalyst handling and continuous
catalyst loading. The unit has a dedicated flushing oil system. Flushing oil is required
during the normal operations as well as during shutdown/ start up.
With the upcoming MS quality up gradation project, a 3-cut splitter facility is added in
INDMAX unit as Object-55. A combined feed stream of wild naphtha and INDMAX
(FCCU) Gasoline is routed to 3-cut splitter column located at eastern side of existing
INDMAX unit, wherein the feed stream split up into 3 fractions:
Top Cut ( Light Gasoline, TBP Boiling Range: C5-70 deg C) High Octane and Low
Aromatics stream. The same is directly routed to MS pool.
Middle Cut (Heart Cut, TBP Boiling Range: 70-90 deg C rich in Benzene, Sulphur,
Aromatics and Olefins-hence, cannot be directly absorbed in Euro-III Grade MS pool.
This stream is routed to 56 unit as feed for NHDT, followed by further treatment in ISOM
and DIH sections.
Bottom Cut (Heavy Gasoline, TBP Boiling Range: 90-200 deg C) is absorbed in BS-III
MS pool.
7) ISOM UNIT
Straight Run Light Naphtha Splitter Column, a Naphtha Hydrotreater (NHDT), an
Isomerisation Unit (ISOM) and De-Iso-Hexanizer (DIH) Column have been installed in
ISOM unit for production of Euro-III Grade MS in Guwahati Refinery. New Light Naphtha
Splitter, NHDT, ISOM and DIH forms part of the object-56 unit and the same is located
at the eastern side of existing ISOSIV unit.
A new light naphtha splitter column is for reduction of C7+ hydrocarbon compound
content to below 2%wt in light naphtha feed to NHDT unit for protection of NHDT
catalyst. Straight Run Light Naphtha from the top of the new light naphtha splitter along
with Heart Cut from 3-Cut Splitter (55 unit) is routed to NHDT for catalytic
hydrotreatment for removal of sulphur content. This is essential in view of stringent
sulphur specifications in post Euro-III Grade MS scenario (150 ppm, max).
In next processing stage, Isomerisation of the hydro treated feed naphtha is carried out
in a series of two fixed bed reactors. Isomerisation is the conversion of hydrocarbons to
their isomers, which have the same molecular formula but a different arrangement of
molecules. The C5 /C6 Isomerisation Unit specifically converts the normal C5/C6
paraffins to their isomers, i.e. to a higher octane branched arrangement, over a
proprietary platinum catalyst in the presence of hydrogen. The conversion per pass of
the normal paraffins to their isomers is determined by the reaction equilibrium at the
reactor operating conditions. The low octane methyl-pentanes and the unconverted n-
hexane are recycled back to the isomerisation reactors to achieve the objective of a
RON clear 87.0 according to the guaranteed value.
A Deisohexanizer (DIH) column is used for recovering and recycling the low octane
methyl-pentanes and the unconverted n-hexane from the reactor effluent. The
Deisohexanizer distillate and bottoms streams are combined to produce the final
isomerate product. A stabilizer is used for removing light ends from the reactor effluent,
before sending it to the de-isohexanizer. The off gas from the unit contains hydrogen
and chloride, which is removed by neutralisation with caustic soda in a Caustic
Scrubber.
8) FLARE SYSTEM
Hydrocarbon flare lines from HDT, Hydrogen unit, INDMAX and ISOSIV (abandone) is
connected with the new flare header (36”). There is other header provided called 10”
sour flare header from SRU, ATU & SWS is connected to the existing flare at the tip.
Sour gas KODs is provided in the Sulphur block as well as near flare stack. The Sour
flare header laid on the support of existing flare header. The existing flare contains a
Knock out drum, a water seal drum and a flare stack. Two skid mounted Liquid ring
compressors, a cooler and a three phase separator from M/s Garo, Italy is being
installed at the flare site for recovery of HC under CDM project.
9) FLARE GAS RECOVERY SYSTEM
The flare gas recovery system installation in Guwahati Refinery was conceived as an
energy conservation project. The flare gas recovery system is comprised of two liquid
ring compressors, a three-phase separator, an exchanger and associated piping. The
flare gas skid mounted package was supplied by M/s Garo, Italy. The benefits achieved
by commissioning of the project are:
(a) Reduction in average flare loss,
(b) Reduction in average CO2 emission to atmosphere
Liquid ring compressors compress gas isothermally i,e; within 10 deg C of the
compressor seal liquid (DM water) temperature, making it less sensitive to molecular
weight variability. Compression of gas is carried out through formation of liquid ring inside
the casing of the compressor, which eliminates chance of equipment damage by virtue of
liquid carryover from gas, variation in molecular weight of gas, frictional damage through
mechanical rotating parts. Liquid seal is maintained by DM water. Compressed gas is
separated in three-phase separator after cooling the same in the exchanger.
Separated fuel gas is routed to refinery FG network, sour water is routed to OWS and
liquid hydrocarbon is routed to slop tank at OM&S.
Guwahati Refinery is having 75 storage tanks (54 old and 20 new tanks) for storage of
Crude Oil, intermediate products & finished product tanks. Their details are given in
Table 3.1.1.
The finished products are dispatched from the refinery to meet the region’s demand
through product pipe line, tank lorries & tank wagons. A tank lorry gantry is with 26
loading points & a tank wagon gantry with 59 loading points.
After meeting the local demand for petroleum products, the excess products are pumped
to Siliguri/ Betkuchi through the 426 km long Guwahati – Siliguri product pipeline. This
product pipeline is also India’s first public sector product pipeline.
This facility include one hydrogen bullet of 100 M3 capacity at a pressure of 50 kg/cm2,
one loading/ unloading hydrogen compressor and the facility for unloading H2 from
cylinders.
There are two LPG mounded bullet of 750 m3 capacity each , two LPG horton sphere of
400 m3 capacity each and two LPG bullet of 100 m3 capacity to store it. LPG is
dispatched through tank truck Lorries by weight bases.
TABLE NO – 3.1.1
GAS
SULPHUR
LPG
NAPHTHA LN
NSF
NSU
RN H2 ISOM
RN
HN
KERO-I HGU
HDTU MS
KERO-II
ATF MODE
SKO MODE ATF
SKO
CRUDE OIL SR GASOIL
HSD MODE
HSD
CDU
3
RCO C
INDMAX U
T
LRU
CG TCO
CK-I
DCU
CGO
RCO CLO LDO
CFO
RFO IFO
RPC