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OVERVIEW
• DESALTING THEORY
• DESALTER DESIGN
• DESALTER OPERATION
DESALTING GLOSSARY
API Gravity
A numeric measure of the specific gravity of a crude
oil. API gravity is defined as (141.5/sp.gr. – 131.5).
Brine Recycle
Desalter effluent water used as a portion of the
desalter wash water.
Capacitance
The ratio of the charge of electricity imparted to a
conductor to the resulting potential, expressed in farads.
DESALTING GLOSSARY
Carryover
Amount of water in the desalted crude measured
as percentage (%)
Crude Oil Rate (Charge Rate)
Bbls/day (@ 42 gal/bbl)
Cubic meters/hr (bbls/6.3)
Tonnes/day (bbls X 350 x sp. gr./2205)
DESALTING GLOSSARY
Cuff, Rag or Interface
The most concentrated water in oil emulsion just
above the water level.
Electrical Transactor
A transformer, and current limiting reactor in the
same enclosure.
Emulsion
A mixture of one immiscible liquid in another.
Emulsion normally refers to water mixed into an oil
continuous phase.
DESALTING GLOSSARY
Filterable Solids
Particles usually in the range of 4 to 20 microns,
which are insoluble in toluene. Determined by
filtration of a sample.
Impedance
An apparent resistance in an alternating current
circuit, made up of two components reactance and
true resistance.
KVA (Kilo Volt Amperes)
Power expressed in 1000 volt amperes
DESALTING GLOSSARY
Mixing
Methods for contacting crude oil with water
i.e.: pumps, heat exchangers, valves or static mixers.
PED
Portable electric desalter used as a laboratory to study
emulsion resolution, and emulsion stability.
ppm
Parts per million, either by weight (lbs/million lbs)
or by volume. To convert ptb in water to weight
ppm divide ptb by 0.35
ie. 35 ptb = 100 wppm (lbs/million lbs).
DESALTING GLOSSARY
ptb
Pounds per thousand barrels
Salt
Chloride content typically expressed as Sodium
Chloride (NaCl)
Undercarry
Oil in the effluent brine measured as volume percent
(%) or in ppm.
CRUDE OIL DESALTING
Desalter design and operation is impacted by:
a. Crude Oil Character
b. Crude Oil Quality
c. Crude Blends
d. Heavy Crudes
e. Reprocessed (slop) oils
CRUDE OIL DESALTING
CRUDE OIL CHARACTER CRUDE OIL QUALITY
1. API gravity 1. Water
2. Viscosity 2. Salt
3. Asphaltenes 3. Solids (oil and water
insoluble)
4. Waxes
4. Emulsion Stabilizers
5. Organic Acids
6. Conductivity
CRUDE OIL COMPONENTS
TYPICAL PARAFFINS
METHANE (CH4) BUTANE (C4H10) ISOBUTANE (C4H10)
TYPICAL AROMATICS.
NAPTHALENE (C10H8)
BENZENE (C6H6)
CRUDE OIL COMPONENTS
• NON HYDROCARBONS COMPONENTS
– SULFUR
• H2S
• Mercaptan, sulfides, disulfides, thiophenes, etc
• Elemental Sulfur
– OXYGEN
• Phenols, ketones, carboxylic acids, naphthenic acids
– NITROGEN
• Basic and non-basic compounds
CRUDE OIL COMPONENTS
O
C84H98N2S2O3 N C O
H NOTE: The structure
shown is hypothetical
S
N
Mol. Wt. 1247.9 O
S 80.85% C
7.92% H
2.24% N
H/C = 1.18 (w/w), 5.14% S
.
40.4% Aromatic Carbon 3.85% O
RESIN MOLECULE
C64H86NSO2
O
OH
N
H
S
hydrophobic tail
(likes oil)
WATER IN OIL
“NORMAL” EMULSION
Continuous Oil
Phase finely divided solid
dispersed
water
phase
OIL IN WATER
“REVERSE” EMULSLION
Continuous Water finely divided solid
Phase
dispersed
oil
phase
WATER IN OIL EMULSION
oil FLOCCULATION oil
SEDIMENTATION
COALESCENCE
oil oil
oil
OIL IN WATER EMULSION
water
FLOCCULATION
CREAMING COALESCENCE
water
water
water
DEMULSIFICATION PROCESS
COLLISION
LIQUID
DRAINAGE
COALESCENCE
SOLIDS AS STABILIZERS
SOLID PARTICULATES
CHARACTERISICS
SURFACES PARTIALLY COATED WITH OIL
INSOLUBLE IN OIL/WATER
ACCUMULATE AT INTERFACE
EMULSION STABILIZERS
• ASPHALTENES
• SEDIMENTS e.g. SAND, SILT, DRILLING MUDS
• INORGANIC PARTICULATES
– FeS, Fe2O3, CaSO4, CaCO3
• COKE / CATALYST FINES
• NAPHTHENIC ACIDS
• WAXES (AT TEMPS < 80 oC)
• PRODUCTION CHEMICALS
• CAUSTIC
DEMULSIFIER MECHANISM
DRAINAGE
DEMULSIFIER REDUCES
LOCAL REGIONS OF HIGH
INTERFACIAL TENSION ()
WATER WATER
OIL
= ENERGY
AREA
-
Typical Emulsion Breaker Chemistry
-OH
OH
O ( )
H-C-H + (x+2) x
+ H2O
R-
formaldehyde alkyphenol alkyhphenol formaldehyde resin
OH
( )
x
+ y(x+2) O
ethylene or
[ ] x
alkyhphenol formaldehyde resin propylene
oxide polyoxyethylene alkylphenyl
ether
DESALTING THEORY
DESALTING THEORY
- Benefits
- Process
- Operational factors
- Stabilization/destabilization
BENEFITS OF DESALTING
• Reduce Corrosion
• Reduce Fouling
• Extend Run Length
• Maximize Throughput
• Stabilize Operation
• Eliminate Heating Costs
EFFECT OF SALTS
RESIDUAL SALTS
• Present in water droplets of crude oil
• Lead to formation of HCl if not removed
CS-285
THE DESALTING PROCESS
• Contacting Step
– Injection of “clean” water (wash water) to
• Dilute Salt Concentration
BPG-054
• Increase Coalescing Efficiency
• Typical Wash Water Range 4 - 10 %
– Formation of Emulsion
• Dehydration Step
– Breaking of Emulsion
– Removal of water (effluent brine)
SINGLE-STAGE DESALTER
Demulsifier Desalted
Cold pre-Heat Crude
Exchangers
Desalter
Feed Oil Mix Valve
Water
Effluent Water
BPG-048
..
MULTI-STAGE DESALTING
Desalted
SERIES: Maximize Desalting Efficiency Crude
10ppm 1ppm
1st salt out 2nd salt out
Stage Stage
Heat
100ppm Exchangers
salt in
Feed Oil Mix Valve
Mix Valve
Water
Effluent Water
Feed Oil
Water
Effluent Water
MAXIMIZE COALESCENCE
H2O Undermixing
Oil
H2O Overmixing
Oil
D S G 2-3 Th e o ry
CONTACTING DEVICES
Oil
P
Pressure Pressure
Upstream Downstream
2-3
DSG
DESALTER EFFICIENCY
Salt Content
100 Mostly Water
BS&W
80
% of
60 1.0
Original
0.8 % BS&W
Salt in Optimum
40 in
Desalted Mixing Pressure 0.6
Desalted
Crude 0.4
20 Crude
0.2
0 0
Mostly BS Increasing Mixing Pressure Drop
BPG-051
EFFECTS OF OVERMIXING
100 Salt Content
BS&W
80
Overmixing
% of Original Salt 60 1.0
in Desalted 0.8
40 % BS&W in
Crude 0.6
Desalted
0.4 Crude
20
0.2
0 0
Increasing Mixing Pressure Drop
• Current Increases
• Voltage Decreases
• Grid Shorts
STOKE’S LAW
KD w o
2
V
V = Settling Velocity
Rapid Separation?
K = A Constant
• Large D
D = Diameter of Water Droplet
• Large (w - o)
w = Density of Water
• Small
o = Density of Oil
= Viscosity of Oil
DENSITY EFFECT
1.00
3% NaCl solution
13 API
0.95
16 API
0.922
22 API
0.90
Specific 0.897 30 API
Gravity 0.85
36 API
0.80
40(100) 90(200) 150(300)
Temperature / °C (°F)
VISCOSITY EFFECT
5000
2000 10 API
1000
13 API
500
200 16 API
140
100
22 API
Viscosity 30 API
59 60
(SUS)
45 36 API
35
-
KD 2 w o
V
“16 API” @ 140 °C (280 °F) “13 API” @ 140 °C (280 °F)
w = 0.950, o = 0.897, = 59 w = 0.950, o = 0.922, = 140
KD 2 KD 2
V16 0.950 0.897 V13 0.950 0.922
59 140
8.98 10 4 KD 2 2.00 10 4 KD 2
V16
100 460%
V13
TEMPERATURE / DENSITY EFFECT
1.00
3% NaCl solution
13 API
0.95
16 API
0.938
0.922 22 API
0.90
0.912
0.80
40(100) 90(200) 150(300)
Temperature / °C (°F)
EFFECT OF TEMPERATURE / VISCOSITY
5000
2000 10 API
1000
13 API
500
200 16 API
140
Viscosity 90 100
(SUS) 22 API
59 60 30 API
49
45 36 API
35
-
“13 API” @ 140 °C (280 °F) “13 API” @ 150 °C (300 °F)
w = 0.950, o = 0.922, = 140 w = 0.938, o = 0.912, = 90
KD 2 KD 2
V13,140C 0.950 0.922 V13,150C 0.938 0.912
140 90
2.00 10 4 KD 2 2.89 10 4 KD 2
V13,150C
100 145%
V13,140C
EFFECT OF TEMPERATURE (16 API)
“16 API” @ 140 °C (280 °F) “16 API” @ 150 °C (300 °F)
w = 0.950, o = 0.897, = 59 w = 0.938, o = 0.880, = 49
KD 2 KD 2
V16,140C 0.950 0.897 V16,150C 0.938 0.880
59 49
8.98 10 4 KD 2 11.84 10 4 KD 2
V16,150C
100 132%
V16,140C
WATER SOLUBILITY
0.8
0.6 Increasing
API
50
Volume 0.4
% Water
0.2 Increasing
10 Specific
0.0 Gravity
65(150) 120(250) 180(350) 230(450)
Temperature / °C(°F)
ELECTRICAL FIELD
-- +
-
-- --
++ ++
+
Electrostatic
Induced Charge Attraction
--
- - ---
++ ++
“DEEP” ELECTRICAL FIELD
= 98%
DESALTING EFFICIENCY CANNOT EXCEED
DEHYDRATION EFFICIENCY!
Industry Norms
Dehydration performance is generally rated as follows:
1935
1800's
50,000,000 BC
HISTORY
TM
Bilectric
Petreco Cylectric
1980's Deep Field
Tri-Grid
Low Velocity
1960's
Multi Phase/
Spherical Multi Grid 1980's
1940's
2 Grid
1960's
1935 MARSCO
TM
Petreco ELECTRO DYNAMIC
Alliance
National Oilfield
Tank Electrical
Company Dehydration
Vessel Differentiation
- Size, Shape
- Electrical Configuration
- Emulsion Distribution
- Interface Control
- Brine Removal
- Mud Washing
RESIDENCE TIME
10'-14' Diameter
60+ ' Diameter 50+ ' Length
3 3
50,000 Ft Volume 5600 Ft Volume
API 40 35 30 25 20 15 12
KVA/FT2 .1 .2 .2 .3 .3 .5 .6
Source: HOWE BAKER ENGINEERS 1994
EMULSION DISTRIBUTION SYSTEMS
PETRECO NATCO
Metal Plate
Grids
- “Hat” Adjusts
Effluent Water
Emulsion In
Adjustment Wheel
Petreco Low Velocity
Doghouse
Emulsion In
Petreco Cylectric
- Turbulent Distribution
- Good Flexibility
Petreco Bilectric
• Larger Transformers
• Very efficient
Grid Configuration
• Dual Polarity ®
• TriGrid
• TriVolt / TriVoltMax
• Electro-Dynamic ®
2 6 Transformer
C x (Vo) x D
F= 4
d Secondary Voltage
(12-35 kV)
Where:
F = Attractive force
C = Dielectric constant of the fluid in the electric field
Vo= Voltage gradient (volts/inch or volts/cm of grid separation)
D = Droplet diameter
d = Distance between droplets
COALESCENCE
Initial Water/Water 0.0066 Seconds after Voltage 0.0133 Seconds after Voltage
Emulsion
0.055 Seconds after 0.081 Seconds after Voltage 0.083 Seconds after
Voltage Voltage Complete
Coalescence
ELECTRICAL SYSTEMS
DIELECTRIC CONSTANT AND CONDUCTIVITY
KVA = (V x A)/1000
Where:
Amps FLA
Full Load Amperage (100)
• Emulsion Conductivity
• Emulsion Distribution System
• Centerline Velocity
• Primary Power Supply
ELECTRICAL SYSTEMS
Transformer Secondary
Line Voltage KVA Voltage
Rating
12-36 K V
Taps
BPG-052
ELECTRICAL SYSTEMS
VOLTAGE EFFECT ON COALESCENCE
Water Out vs. Voltage Gradient
(Typical 30 oAPI Crude) Maximize Power /
.10
Lowest Tap Setting
.9
.8 - Cost?
.7
.6 - Necessity?
WATER OUT %
.5
.4 - Reversals?
.3
.2
.1
0
VO LTAG E G R ADIE NT
ELECTRICAL SYSTEMS
200
100
200 250 300
TEMP (F)
F O R D O U B L E VO LT E D H O WE B A K E R D E S IG N
ELECTRICAL SYSTEMS
C RU D E A C RU D E C 2
0 .5 3 0 .5
kv / cm 2 kv / cm
1
Electrode Area
1
0 0
kv / cm
1 .0 1 .0
3
C RUD E D
C RUD E B 3 2
0 .5 0 .5
2
kv / cm
1 1
0 0
Operating Temperature oC
CRUDE BLEND CONDUCTIVITY
6
5 MAYA
Rho (Ohm-cm x 10^8)
MEREY
4
BLEND
3
0
160 180 200 220 240 260 280 300
Temp (F)
ELECTRICAL SYSTEMS
2400
Primary Volts
Conductivity
Reversal
“Cushion”
0 Primary Amps
0 60 60
0
ELECTRICAL SYSTEMS
GRID DESIGNS
Consider: Grid location, size, spacing, number, phases, grounding, AC vs. DC, etc.
PETRECO NATCO
Maximize Maximize
WATER OIL
Quality Quality
LEVEL CONTROL
Pressure
Transducer
Pneumatic
Control
PP&
uI
P&
I
Controller Level
BPG-053
LEVEL CONTROL CAPACITANCE
Suppliers:
Robert Shaw
DrexelBrook
Advantages
- Good for many systems
- Inexpensive
Disadvantages
- Shorts out at High % H20
- Cannot measure oil in water
- Prone to dirt problems
- Cannot Penetrate Coatings
- Averages Emulsion Content
MICROWAVE ENERGY ABSORBANCE
OIL WATE R
Probe Calibration
Oil 4 mA
Water 20 m A
LEVEL CONTROL AGAR
P+I
LEVEL CONTROL AGAR
ADVANTAGES
• Maintains Level @ 70-90% Water
• Gives clean effluent water
• Gives early warning to rag growth
• No fouling/coating problems
• Minimizes upsets
MUD WASH SYSTEMS
TOP VIEW TOP VIEW
3'
BPG-050
MUD WASH SYSTEMS
FREQUENCY DURATION
Once / Shift Short Blast
IMPORTANCE
- Solids buildup causes vortexing
- Turnaround Runlength Shortened
SUMMARY