Hints & Solutions: Mno I MN I I Naso Naso Nai

HINTS & SOLUTIONS
SECTION - I (CHEMISTRY)
PART– A
1. D
Sol. n-factor for H3PO2 is 1
n-factor for H3PO3 is 2
n-factor for H3PO4 is 3
2. A
Sol. MnO2  I  
 Mn2  I 2
I 2  Na2 S2O3 
 Na2 S4O6  2 NaI
No. of meq of Na2S2O4 = No. of meq of I 2 = No. of meq of MnO2
WMnO2
 1000  1 0.075  30
87 / 2
% MnO2 = 75.3%
3. C
Sol. Concept based
4. C
Sol. Concept based
5. B
Sol.
O O
5
0 0 5
Na O S S S S
O Na O O
6. C
Sol. At low pressure b = 0
a
PV  RT  (slope = – a )
V
7. A
M
Sol. Maxwell distribution curve is same if ratios of two gases are same.
T
8. D
Sol. Lead due to inert pair effect shows +2 state.
9. D
Sol. ms (spin quantum number)
10. B
h
Sol. Orbital angular momentum = l  l  1
2
11. D
 a 
Sol.  p  2  Vm  b   RT
 Vm 
a
P  Vm  P  2  P
Vm
P Vm  b   RT
PVm  RT  Pb
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector -KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
2
Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |1
12. C
Sol. Van der Waal’s constant a  Intermolecular force of attraction.
So CO2 gas can be more easily liquefied.
13. B
2 3 4
Sol. FeC2 O4 
n 3
Fe3  C O2
 7 
Ba  MnO4  
H
 Mn2
 2 n 10
1
Number of meq. of FeC2O4 = Number of meq. of Ba(MnO4)2 = 20  10  20 meq
10
14. B
Sol. C2O42  MnO4  CO2
1
= 20  10 = 20 meq of CO2
10
22.4
1 eq. of CO2 = L = 11.2 L at STP
2
1000 meq of CO2 = 11200 mL at STP
11200
 20 meq of CO2 = ×20 = 224mL
1000
15. C
Sol. PV = nRT
100
2 V   0.082  300
40
100  0.082  300 246
V   30.75 litre
40  2 8
16. B
Sol. Volume of cylinder after dent = 27.7 litre
Now
PV = nRT
100  0.082  300
P
40  27.7
P  2.22 atm
PART– B
17. A–R; B–Q; C–P; D–S

z2 Z n2
Sol. En  Vn  rn 
n2 n Z
18. A  P, Q, R; B  R, S; C P, Q; D P,Q,R,T
Sol. (A) nCO2  1 i.e. 1 g molecule ; VCO2 , STP  22.4L

Total number of electrons in 1 molecule of CO2 = 22
Total number of electrons in 1 mole of CO2 = 22 NAV,
So, total number of electrons in 2.2 mole = 22 NAV
35.2
(B) nCH 4   2.2
16
VSTP  49.28L at STP
Total number of electrons in 1 mole CH4 = 10 NAV
So, total number of electrons in 2.2 mole CH4 = 22 NAV
(C) nO3  1, VSTP  22.4L
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
2
Total number of electrons in 1 mole = 24 NAV

(D) nN2O  1 , VSTP  22.4L
Total number of electrons in 1 mole = 22 NAV
19. A–Q; B–P,Q,R,S; C–P,Q,R; D–P,Q,R

20. A–Q; B–P; C–S; D–R
Section – II (MATHEMATICS)
PART– A
1. A
Sol. Angle bisectors are given by x=0
x 2   y  1 x  y  1
2
(0,3)

1   1 0 y=1
 x  y  1  0 (0,1) (2,1)
1
Area =  2 2  2 sq. unit
2
x + y =3
2. C
Sol.  2 7
B , 
 3 3 C
7x+2y =0
11x+7y -9=0
5 4
O(0,0) 4x+5y =0 A  , 
 3 3
3. C
y
Sol. y  mx  m 
x
d  m   3cm  3bm  a  0
3 2
 , ,
a b c
 
b c d
4. D
2sin  1  sin   cos   cos  cos 
Sol. x  1   1 x
1  sin    cos 
2 2
1  sin  1  sin 
5. C
Sol. 16  cos 2A  cos 3A  16  2cos2 A  1  4cos 3 A  3cos A   11
6. D
tan A tan B
Sol.   K K  0
3 5
2tan A 3 tan B
2sin A  3 sin B  
1  tan A
2
1  tan2 B
1
K
5
7. C
a 1
Sol. a 2  3a  0 and a 2   0   a  3.
2 2
8. A
3 5
Sol. tan       , tan      
4 12
tan       tan     
tan  2   tan          
1  tan      tan     
9. B
10. C
2
Sol. [09 -10] A (1,3)

Mirror image of A 1,3 will lie on line BC.
A'   1,1 x + y =2
2
 1
Equation of BC y  1  5  x  1  7x  3y  4  0 B  2 2
2 C   , 
 1 A’  5 5
5
Vertex B is the intersection point of line 7x  3y  4  0 and
xy 2
11. C
2 2
Sol.   A  ,   A,   A 
3 3
12. D
 2   2 
Sol. x  sin  A   , y  sin A, z  sin  A  
 3   3 
 2   2 
p  cos  A   , q  cos A, r  cos  A  
 3   3 
x yz  pqr  0
 x  y  z   x2  y 2  z 2 
2
yz  zx  xy 
2
13. A
Sol. xy  x  y
14. B
4
3
tan 3 3  4sin 2  x
Sol.  
tan  4 cos   3
2
4
3
y
15. B
3 D C
Sol. tan  
4
Area of parallelogram M
1 
8   AC  BD  sin   –
2
1 3
8   4  BD  A B
2 5
20
BD 
3
16. A
4 AM 2  BM 2  AB 2
Sol. cos        
5 2 AM  BM
2 58
AB 
3
PART – B
1. A S B P C Q D R
Sol. (A) ax   2a  2c  y  c  0
a  x  2 y   c 1  2 y   0
1 3 2
(B) 3 2 5  0
a b 3
a b 3  0
 1 1 
(C) 1  cos135,1  sin135 
 2 2 
2
1 3 3 1
  ,  or  , 
2 2 2 2
(D)  3x  y  7     x  5 y  7   0
 x, y  =  2,1
2. A P, Q BS CP DS
3
Sol. cos A  cos B  cos C 
2
A B C 1
sin sin sin 
2 2 2 8
3. AR B S CQ DP
 2  
Sol. B  , AC  , A , C 
3 3 6 2
4. AS B  P, Q C  P, Q, R DS
1 3 5
Sol. (A) 3 k 1  0
5 2 12
k 5
1 3 5
(B) mL1   , mL2  , mL3  
3 k 2
Section – III (PHYSICS)

PART– A
1. D
2. D
Sol. Polygon law of vector addition gives required results.
3. A
Sol. Area of a  t curve is equal to change in velocity.
4. D
Sol. E  h
5. A
Sol. For perpendicular vectors P  Q  0
For collinear vectors P  Q  0
6. B
d 2d

Sol. vavg  3 3
d 2d

3v1  v2  v3 
3 
 2 
7. B
Sol. x   2t  3
x  4t 2  12t  9
v  8t  12
a 8
8. A
Sol. Since a is constant and initial velocity is not collinear with a , its path will be parabola.
9. B
10. D
Sol. [9 - 10]
Consider motion w.r.t. wedge 10 3 m/s
2u sin    
T  2sec
g cos  60
0
0
30
u 2 sin 2     5
  3m A
2 g cos  2
2
11. B
12. C
Sol. [11 - 12] z
From figure
A  7iˆ  4ˆj  3kˆ
B  7iˆ  4ˆj A 3
x
O
4
7 B
y
13. B
14. A
Sol. [13 - 14]
Let vR  vx iˆ  v y ˆj x (horizontal)
vx
 tan 30o
vy
vRM   vx  0.5 iˆ  vy ˆj y (vertical)
vx  0.5
 tan 0o
vy
 vx  0.5 and vy  0.5 3
15. C
16. C
Sol. [15 - 16]
dx
 u0  x0  V0 t
dt
d2 y t3
 2t  uy  t 2
 y 
dt 2 3
PART – B
1. AS BQ CP DR
3
Sol. (A) by E  kT
2
v
(B) by F   A
x
(C) by E  hf
KA    t
(D) by Q 
l
2. A  P, Q B  R, S C  R, S D  R, S
Sol. GMe Ms   F  r 2 
 3RT 
 M    v 
2
 F2 
 2 2   u 
2
q B 
 GMe   E
 
 Re   m
3. AR BP C  P, Q, R, S DP
Sol. For perpendicular vectors
P Q  0
For collinear vectors
P  nQ or P  Q  0
2
4. A  Q, S BP CP D  Q, R
Sol. from graph (A)  v  kx where k is positive constant
dv
acceleration = v  kx  k  k 2 x
dx
 Acceleration is non-uniform and directly proportional to x.
  A  Q, S
From graph (B)  v  kx Differentiating both sides with respect to x.
2
dv dv k
2v  k or v 
dx dx 2
Hence, acceleration is uniform
  B  P
From graph (C)  v  kt
dv
Acceleration = k
dt
Hence, acceleration is uniform
 C   P
From graph (D)  v  kt
2
Acceleration is non-uniform and directly proportional to t.

  D   Q, R

Hints & Solutions: Mno I MN I I Naso Naso Nai

Încărcat de

Informații document

Descriere originală:

Titlu original

Drepturi de autor

Formate disponibile

Partajați acest document

Partajați sau inserați document

Opțiuni de partajare

Vi se pare util acest document?

Este necorespunzător acest conținut?

Drepturi de autor:

Formate disponibile

Hints & Solutions: Mno I MN I I Naso Naso Nai

Încărcat de

Drepturi de autor:

Formate disponibile

HINTS & SOLUTIONS

17. A–R; B–Q; C–P; D–S

Sol. (A) nCO2  1 i.e. 1 g molecule ; VCO2 , STP  22.4L

(C) nO3  1, VSTP  22.4L

Total number of electrons in 1 mole = 24 NAV

19. A–Q; B–P,Q,R,S; C–P,Q,R; D–P,Q,R

Sol. [09 -10] A (1,3)

Section – III (PHYSICS)

Acceleration is non-uniform and directly proportional to t.

S-ar putea să vă placă și