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B. G. Jeyaprakash
Assistant Professor
School of Electrical & Electronics Engineering
SASTRA University
Joint Initiative of IITs and IISc – Funded by MHRD Page 1 of 18
NPTEL – Electrical & Electronics Engineering – Semiconductor Nanodevices
Table of Content
1. INTRODUCTION TO MATERIALS................................................................3
3.1 SOLUTIONS............................................................................................................................17
4. REFERENCES..................................................................................................18
1 Introduction to Materials
This lecture provides you about the fundamentals of solid materials, its
classification and general properties
Metals Polymer
• Ferrous metals and alloys (irons, • Thermoplastics
carbon steels, alloys steels, stainless • Thermoset plastics
steels) • Elastomers
• Atomic structure, which includes features that cannot be seen, such as the types
of bonding between the atoms, and the way the atoms are arranged.
• Microstructure, which includes features that can be seen using a microscope, but
seldom with the naked eye.
• Macrostructure, which includes features that can be seen with the naked eye)
The atomic structure primarily affects the chemical, physical, thermal, electrical,
magnetic, and optical properties. The microstructure and macrostructure can also affect
these properties but they generally have a larger effect on mechanical properties and on
the rate of chemical reaction. The properties of a material offer clues as to the structure of
the material. The strength of metals suggests that these atoms are held together by strong
bonds. In solids, the way the atoms or molecules arrange themselves contributes to the
appearance and the properties of the materials.
1.6 Solidification
The crystallization of a large amount of material from a single point of nucleation
results in a single crystal. The moment a crystal begins to grow is known as nucleation
and the point where it occurs is the nucleation point. At the solidification temperature,
atoms of a liquid, such as melted metal, begin to bond together at the nucleation points
and start to form crystals. The final sizes of the individual crystals depend on the number
of nucleation points.
Fig. 1. a) Nucleation of crystals, b) crystal growth, c) irregular grains form as crystals grow together, d) grain boundaries
as seen in a microscope
In engineering materials, a crystal is usually referred to as a grain. A grain is
merely a crystal without smooth faces because its growth was impeded by contact with
another grain or a boundary surface. The interface formed between grains is called a
grain boundary. The atoms between the grains (at the grain boundaries) have no
crystalline structure and are said to be disordered and are shown in Fig. 1.
Grains are sometimes large enough to be visible under an ordinary light
microscope or even to the unaided eye. The spangles that are seen on newly galvanized
metals are grains. Rapid cooling generally results in more nucleation points and smaller
grains (a fine grain structure). Slow cooling generally results in larger grains which will
have lower strength, hardness and ductility.
• Solids can hold their own shape unless something happens to them.
• Liquid flow and take the shape of their container.
• Gases are usually invisible and spread out to fill up spaces.
• Plasma are invisible and spread out to fill up space
Materials can be classified according to their state, size, shape, texture, colours,
flexibility, strength, hardness, malleable and whether they are a good conductor or bad
conductor of heat/electricity.
Solid state materials with reduced dimension in one or two or three directions are
recognized as low dimensional materials. Based on reduced dimension, the low
dimensional materials are in generally classified as 2D, 1D and 0D, and are shown in Fig.
3. Bulk materials is called as 3D materials, Due to reduced dimension, electron motion in
the materials is restricted either in one or two or three directions.
The properties of any solids materials depend on the chemical composition, atomic
structure and the size of a solid in one, two or three dimensions. For example, Hardness
and optical reflection of carbon changes when it transform from diamond to graphite
(Fig. 4 (a&b)). Both are made up of carbon atoms, but the atom arrangements and bond
between them differs.
Also the change in microstructure (i.e. arrangement of atoms / molecules / ions) size
equivalent to a few inter-atomic spacing in one, two or three dimensions forming building
blocks of solid materials makes change in the properties. For example, colour changes of
gold at nanoscale. The materials synthesis with new properties by means of the controlled
microstructure size and shape on the atomic level has become important to achieve new
properties with enhanced device performance.
Nanomaterials have a relatively greater surface area when compared to the same
volume or mass of the same material in bulk form. For example, consider cube of 1m3
volume (Fig. 5), it has surface area of 6m2. If this cube of same volume is divided into
eight small cubes, then the total surface area increases to 12m2. Further dividing cube
leads to increase in surface area. This is illustrated in the following figure. Also if the
size of nanomaterials decreases, a greater proportion of atoms are found at the surface
compared to those inside. This makes materials more chemically reactive.
As seen in the previous topics, due to reduced physical size in one, two or three
dimension of a materials, leads to change in surface area and electron confinment, makes
the change in materials properties. The following section deals about different properties
of nanomaterials which differs from its bulk one.
Crystal structure of nanomaterials may or maynot same as its bulk one, but has
different lattice parameters. For example, gold and aluminium nanoparticles of size with
few nanometers are icosahedral rather than face-centered cubic in bulk (fig.6). Indium of
size less than 6.5nm is face-centered cubic rather than face-centered tetrahedral for size
greater than 6.5nm. Also, the inter atomic spacing in nanomaterials decreases than bulk
due to long range electrostatic forces and the short range core-core repulsion. For
example, decrease in aluminum separation to 2.81Å from 2.86Å and the binding energy
also decreases to 2.77eV from 3.39v.
Fig. 6. Crystal structure of (a) bulk (FCC) (b) nano (Icosahedral) Gold
media. Due to large proportion of surface atoms which have a different local environment
leads different magnetic coupling with neighbouring atoms and in turns differs in
magnetic properties than its bulk one. Ferromagnetic materials in bulk form has multiple
magnetic domains, whereas nanoparticle often has one domain as shown in Fig.8 and
exhibit superparamagnetism phenomena. Also Giant magnetoresistance (GMR shown in
Fig. 9) is a phenomenon observed in nanoscale multilayer consisting of a strong
ferromagnet(e.g, Fe , Co) and a weaker magnetic or non-magnetic buffer(e.g, Cr,Cu). It is
usually employed in data storage and sensing.
Fig. 9. GMR materials are made from alternating layers of magnetic and non- magnetic metals that are nanometers in
thickness.
modified non linear optical properties and enhanced gain for certain emission energy or
wavelength. Other properties which may affected by reduced dimensionality include
photocatalysis, photoconductivity, photoemission and electroluminescence.
The electonic properties changes occurs in the low dimensional material are related
to the wave like property of the electron and scaracity of the scattering centres. As the
size of the system becomes comparable with the de Broglie wavelength of the electrons,
the discrete nature of the energy states becomes occur as shown in Fig. 11. In certain
cases, conduction material become insulator below the critical length scale.
3.1 Solutions
1. Polymer
2. brittle
3. Scanning Tunneling
4. nucleation
5. smaller, larger
6. diamond
7. nano
8. thermodynamic
9. Quantum confinement effect
10. decreases
11. Thin films
12. decreases
13. higher
14. superparamagnetism
15. Ballastic
4 References
[1] William D. Callister, Jr. , Fundamentals of Materials Science and Engineering-An
Interactive e-text, John Wiley & Sons, Inc. , 2001.
[2] H. Hosono, Y. Mishima, H. Takezoe, K.J.D. Mackenzie, Nanomaterials from
Research to Applications, Elsevier Inc., 2006.
[3] Guozhong Cao, Nanostructures & Nanomaterials Synthesis, Properties &
Applications, Imperial College Press, 2004.