SR N40+LT N40 (PROG-1) NEET GRAND TEST-1 Date: 20-04-2018

CHEMISTRY

46. Crystal field stabilisation energy for 2) No change takes place

4
high spin d octahedral complex is 3) increases by four times
1) -1.2  0 2) -0.6  0 4) decreases by two times
53. Solid soda lime combines with the
3) -0.8  0 4) -1.6 0  P
following at high temperatures
47. Which of the following does not 1) CaO 2) N2O
give chromyl chloride test 3) BaO 4) P4O10
1) CaCl2 2) NaCl 54. The ratio of r.m.s velocity of CH4 at
3) Hg2Cl2 4) MgCl2 270C to most probable velocity of
N0 SO2 at 3270C is
48. atoms of X  g  are converted into
2
1) 1 : 1 2) 1: 3
N
X g  by enthalpy change H1 . If 0 3) 3 :1 4) 2 :1
2
atoms of X  g  are converted into 55.

X g  by enthalpy change H 2 . The

value of ionisation enthalpy of X is
2  H 2  H 1  2 H 1
1) atom 1 2) atom 1
NO NO
N 2 NO This reaction is known as
3) O atom 1 4) atom 1 1) Tishchenko reaction
2 H 1 H1
2) Cannizzaro reaction
49. The formation of following species
3) Aldol condensation
involve 2s-2p mixing
4) Oppenauer oxidation
1) N2 2) O2
56. Which of the following acts as a
3) B2 4) both 1 and 3
powerful oxidising agent in the
50. Branched polymer(s) of glucose
aqueous solution
1) Glycogen 2) amylopectin
1) Al 3 2) Ga 3
3) Cellulose 4)both 1 and 2
0 0 3) Tl 3 4) In3
51. EMnO 2 / MnO  2.26V and EMnO 
/ MnO 2
 0.5V ;
4 2 4 4
57. Which of the following monomers
then which of the following are unsuitable for condensation
reaction is spontaneous. polymerisation
1) MnO42  MnO41 1) propanoic acid and ethanol
2) MnO41  MnO2  MnO42 2) butane – dioic acid and glycol
3) diamines and dicarboxylic acids
3) MnO2  MnO42
4) hydroxy acids
4) All reactions are spontaneous 58. Arrange the following in the
increasing order of their pH values.
52. .
In this reaction, the concentration
of KCN is increased by two folds i) ii)
then what will be it’s effect on rate
of formation of alkyl cyanide.
iii) iv)
1) increases by the two times
 SR N40+LT N40 (PROG-1) NEET GRAND TEST-1 Date: 20-04-2018
1) i < ii < iii < iv 2) i < iv < iii < ii character
3) i < iii < iv < ii 4) ii < iii < iv < i 3) NO  NO  increase in bond order
59. Which types of defect is produced 4) NH 3  NH 4 decrease in bond length
when NaCl crystal is doped with
65. Calcium phosphate is a sparingly
SrCl2
soluble salt. The solubility of it in
1) Cation vacancy defect
aqueous solution
2) Non-stoichiometric defect
1) increases at higher pH
3) impurity defect
2) increases with increase in pH
4) all
3) decreases at lower pH
60. 3.9 g of benzoic acid is dissolved in
4) increases at lower pH
49 g of benzene shows a depression
66. IUPAC name of K 2 Cr  CO  CN 5  is
in freezing point of 1.62k. if Kf for
benzene is 4.9 k kg mol-1 and molar 1) potassium penta cyanocarbonyl
mass of benzoic acid is 122 g mol-1 chromate (III)
then 2) di potassium carbonyl
1) benzoic acid dimerises by 98.6% in pentacynochromium (III)
the solution 3) potassium carbonyl pentacyane
2) benzoic acid dimerises by 50.7% in chromium complex
the solution 4) potassium carbonyl penta
3) benzoic acid is dissociated by cyanochromate (III)
98.6% in the solution 67. Which of the following is a
4) benzoic acid is dissociated by herbicide
50.7% in the solution 1) 2, 4-D 2) NaClO3
warm
61. C2 H 5 NH 2  CS 2  HgCl
 A  2
 B  HCl  HgS 3) Na3AsO3 4) all
1% NaCN  
. In the above sequence ‘B’ is 68. Ag2 S 
chloridised
roasting
 X  compound of silver   aq

1) C2H5-CNS 2) C2H5CN Y  complex  

Zn
 Z S  . Incorrect
3) C2H5SCN 4) C2H5NCS
statement regarding to the
62. Assuming that if ‘l’ value is equal to
sequence of the reactions is
‘n’ value then the number of
1) Formation of Y from X is known as
elements that can be placed in
leaching
second period are
2) Function of Zn is an oxidising agent
1) 8 2) 18
3) Formation of Z from Y is known as
3) 32 4) 10
hydrometallurgy
4) NaCN is complexing agent
63. 69. Among the following the surfactant
that will form miscelles in aqueous
solution at lowest molar
concentration at ambient
1) 2) conditions is
1) CH 3  CH 2 11 OSO3 Na
3) 4)
2) CH 3  CH 2 11 N  CH 3 3 Br
64. Which of the following is incorrect
against its property 3) CH 3  CH 2 15 N  CH 3 3 Br
1) XeO3  XeO4 increase in bond angle 4) CH 3  CH 2 6 COONa
2) ClF3  SO2  LiF increase in ionic
 SR N40+LT N40 (PROG-1) NEET GRAND TEST-1 Date: 20-04-2018
70. Which of the following does exhibit
tautomerism
(i) HNO2 (ii) CH 3  CO  CH 2  COOC2 H 5
2)

3)

(iii) H 2 SO3 (iv)

1) All 2) Both iii and iv
4)
75. Which of the following is not
3) Both ii and iv 4) i, iii and iv
reactive towards Cl2 at moderate
71. In haematite  Fe2O3  O 2 ions have
, temperatures
CCP arrangement while Fe 3 ions 1) NaH 2) CsH
occupying interstitial positions. If 3) KH 4) LiH
0 0
ionic radii of Fe 3 and O 2 are 76. ECd 2 /Cd  0.40V , EHg 2 SO4 /2 Hg
 0.62V . For
0.56 A0 and 1.4 A0 then in the crystal 0
the spontaneous cell reaction Ecell is
1) Fe 3 ions occupy 2/3 of tetrahedral 1) +0.71V 2) +1.02V
voids 3) +0.22V 4) -0.22V
2) Fe 3 ions occupy all the edge 77. Match the following
centres
3) Fe 3 ions occupy 2/3 of octahedral Column –I Column –II
voids A Equanil I Antibacterial
4) Fe 3 ions occupy all octahedral
B Prontosil II Tranquilizer
voids C Bromphen II Antidepressan
72. Which of the following has more iramine I t
number of hybrid orbitals around D Veronal I Antihistamine
the central atom V
1) XeO3 2) XeF2 The correct match is
3) XeF4 4) XeO4 1) A-III, B-I, C-II, D-IV
OH
73. The p of the solution in which 2) A-II, B-III, C-I, D-IV
0.1M NH4Cl and 0.1 M NH3 are 3) A-III, B-I, C-IV, D-II
present in one litre solution is (PKb 4) A-III, B-II, C-IV, D-I
of NH3 is 4.75) 78. Which of the following electrolytic
1) 4.75 2) 8.95 solution has more limiting molar
3) 9.25 4) 5.05 conductivity at 298K
MgBr 1) HCl aq  2) NaCl aq 
3) NaOH  aq  4) CH 3COONa aq 
(i)
N X.
79. The repeating structural unit
74. (ii) EtOH
present in condensation chain
Here ‘X’ is polymer of silicones is
1) 2)
1) 3) 4)
 SR N40+LT N40 (PROG-1) NEET GRAND TEST-1 Date: 20-04-2018
80. Which of the following results in a 3) No change in colour takes place
single ketone product following 4) solution becomes colourless
acid catalysed hydration in 85. In Castner –Kellner cell the
presence of Hg ions 2+ products formed at cathode and
1) 3- octyne 2) 2-octyne anode are respectively
3) 1-octyne 4) 4-octyne 1) NaOH,Cl2 2) Cl2,H2
81. Under standard conditions, the 3) Na-Hg,Cl2 4) Na, Cl2
heats of atomisation of 86. Ln2C3 (or) LnC liberate
N 2 g  H 2 g  and NH 3 g  are 945 KJ/mole, 1) H2 on reaction with dilute acid
436 Kj/mole and 1170 KJ/mole. If 2) CO on reaction with boiling water
the standard heat of formation of 3) CO2 on reaction with cold water
4) all
N 2 H 4 g  is +106KJ/mole, then the N-
87. Which of the following acts as a
N bond strength is bleaching agent
1) 151 KJ/mole 2) 302 KJ/mole 1) Javelle water 2) Moist Cl2
3) 75.5 KJ/mole 4) 226.5 KJ/mole 3) Dry O3 4) All
82. Statement –I: NH3 is a strong
reducing agent while BiH3 is a weak
reducing agent
Statement –II: NH3 gives deep blue
colour with cupric ion is aqueous
solution 88.
1) both statements-I and II are correct . The functional groups present in Y
2) statement –I is correct and are
statement –II is incorrect 1) –CHO, -COOH 2) –OH, -CHO
3) statement –I is incorrect and 3) –OH, -COOH 4) –CO- , -COOH
statement –II is correct
4) both statements –I and II are 89. In which of the following stronger
incorrect hydrogen bonds are present
83. The volume of O2 liberated at S.T.P 1) H2O 2) C2H5OH
when excess SO2(g) reacts with one 3) H2SO4 4) NH3
mole of O3 is 90. Excess of SO2 gas is passed through
1) zero 2) 22.4L aqueous solution of NaOH. The
3) 11.2L 4) 67.2L resultant solution contains the
2 following ions along with Na+ ions.
84. Fe3  SCN    Fe  SCN    aq  . For
1) SO32 ions only
this aqueous solution if FeCl3 s  is
2) HSO3 ions only
added then
3) both SO32 and HSO3 ions
1) intensity of deep red colour
increases 4) SO42 ions only
2) intensity of yellow colour increases