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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING
1.1 Product information
Commercial Product Name
FennoSpec 1200

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture
Additive in paper industry., Professional use
Recommended restrictions on use

1.3 Details of the supplier of the safety data sheet


PT. Kemira Chemicals Indonesia
Jl. Rembang Industri III/32 Pier RT.RW.
67152 Rembang - Pasuruan INDONESIA
Telephone+6262343740127, Telefax. +6262343740128
ProductSafety.CN.Shanghai@kemira.com

HEAD OFFICE
Kemira Oyj
P.O. Box 330
00101 HELSINKI
FINLAND
Telephone +358108611 Telefax +358108621124

1.4 Emergency telephone number

Carechem 24 International: +86 512 8090 3042

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to the following national implementation of the Globally Harmonized
System (GHS):
Acute toxicity
; Category 4; Harmful if swallowed.

Serious eye damage


; Category 1; Causes serious eye damage.

Long-term (chronic) aquatic hazard


; Category 2; Toxic to aquatic life with long lasting effects.

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

2.2 Label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.


H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements
Prevention: P273 Avoid release to the environment.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.

Response: P301 + P312 IF SWALLOWED: Call a POISON


CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P391 Collect spillage.

Disposal: P501 Dispose of contents/container as special


waste in compliance with local and national
regulations.

Hazardous components which must be listed on the label:


 7733-02-0 zinc sulphate

2.3 Other hazards


Remarks; No data available

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
CAS-No. Chemical name of the substance Concentration

7733-02-0 zinc sulphate 28 - 30 %

4. FIRST AID MEASURES


4.1 Description of first aid measures
Inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
Skin contact
Wash off immediately with plenty of water removing all contaminated clothes and shoes.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 30 minutes. Remove contact
lenses. Get medical attention immediately. Continue to rinse during transport.
Ingestion
Rinse nose, throat and mouth with water. Do NOT induce vomiting. Get medical attention if any discomfort
continues.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Serious eye damage, Ingestion: Harmful if swallowed.

4.3 Protection for rescuers and special advice to doctors


Treatment : No information available.

5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Extinguishing media : No special requirements.

5.3 Special protective actions for fire-fighters


Wear self-contained breathing apparatus and protective suit.

5.4 Specific methods


Prevent fire extinguishing water from contaminating surface water or the ground water system.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.
6.2 Environmental precautions

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

Should not be released into the soil, surface water or ground water system.
6.3 Methods and materials for containment and cleaning up
Prevent from spreading into the environment. Must be disposed of in accordance with local and national
regulations.

7. HANDLING AND STORAGE


7.1 Precautions for safe handling

Handle with care. Avoid contact with eyes.


Advice on protection against fire and explosion:
None known.
7.2 Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a cool, well-ventilated place.
Materials to avoid:
No information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Exposure Limit Values


Contains no substances with occupational exposure limit values.

8.2 Exposure controls

8.2.1 Appropriate engineering controls


Handle in accordance with good industrial hygiene and safety practice.
Eye wash bottle or emergency eye-wash fountain must be found in the work place. Ensure adequate
ventilation.
General industrial hygiene practice.
8.2.2 Individual protection measures, such as personal protective equipment
Hand protection
Glove material: Nitrile rubber, Break through time: > 480 min, Please observe the instructions regarding
permeability and breakthrough time which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the product is used, such as the danger of cuts,
abrasion, and the contact time.
Eye protection
Tightly fitting safety goggles (EN 166)
Skin and body protection
Wear protective clothing.
Respiratory protection

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

not required under normal use


8.2.3 Environmental exposure controls
No data available

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties


General Information (appearance, odour)
Physical state liquid, Aqueous solution

Colour clear, colourless

Odour none

Important health safety and environmental information


pH 5
Freezing point : -11 °C
Flash point
No data available
Evaporation rate
No data available

Explosive properties:
Lower explosion limit
No data available
Upper explosion limit
No data available
Vapour pressure 5
Density 1.41 g/cm³

Solubility(ies):
Water solubility
completely soluble
Partition coefficient: n-octanol/water
No data available
Thermal decomposition
No data available

Viscosity:
Viscosity, dynamic
No data available
Viscosity, kinematic
No data available

Oxidizing
Not oxidizing

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

10. STABILITY AND REACTIVITY

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid


Conditions to avoid : No data available

10.5 Incompatible materials


Materials to avoid : No information available.

10.6 Hazardous decomposition products


Hazardous decomposition : No data available
products
Thermal decomposition : Note: No data available

11. TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects
Acute toxicityLD50 /Oral/Rat: 862 mg/kg

Harmful if swallowed.
LD50 /Oral/Rat: 4,429 mg/kg

Harmful if swallowed.

Based on available data, the classification criteria are not met.

LD50/Dermal/Rat: > 2,000 mg/kg


Based on studies on similar products, this material is not expected to be toxic.

Zinc sulphate, hexahydrate:


LD50/Oral/Rat: 623 mg/kg
LD50/Oral/Mouse: 337 mg/kg

Irritation and corrosion


Skin:

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

Based on available data, the classification criteria are not met.

Eyes:
Causes serious eye damage.

Sensitisation

Based on available data, the classification criteria are not met.

Long term toxicity

Carcinogenicity

Based on available data, the classification criteria are not met.

Reproductive toxicity

Based on available data, the classification criteria are not met.

12. ECOLOGICAL INFORMATION


12.1 Ecotoxicity effects
Aquatic toxicity

Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Zinc sulphate, hexahydrate:


LC50/96 h/Pimephales promelas (fathead minnow)/Short-term (acute) aquatic hazard: 0.33 mg/l
EC50/48 h/Daphnia magna (Water flea)/Short-term (acute) aquatic hazard: 0.131 mg/l
EC10/48 h/algae (Chlorella sp.)/Short-term (acute) aquatic hazard: 0.105 mg/l

Toxicity to other organisms

Remarks: No data available

12.2 Persistence and degradability


Biological degradability:

The methods for determining biodegradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

Does not significantly accumulate in organisms.


Partition coefficient: n-octanol/water: No data available
12.4.Mobility in soil
Mobility
Vapour pressure: 5
Water solubility: completely soluble

12.5 Other adverse effects


Do not let product enter drains.

13. DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods
Product Do not release the material to drain, water system or soil to
avoid contamination of the groundwater.
Dispose of as special waste in compliance with local and
national regulations.

14. TRANSPORT INFORMATION


UN number 3082

Land transport
ADR:
Description of the goods:
UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (zinc sulphate )
Class 9
Packaging group: III
Risk code 90
ADR/RID-Labels: 9
Environmentally Hazardous Environmentally Hazardous

Sea transport
IMDG:
Description of the goods:

UN proper shipping name UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,


N.O.S. (zinc sulphate )
Class: 9
Packaging group: III
IMDG-Labels: 9
Environmentally Hazardous: Marine pollutant

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

Air transport
ICAO/IATA:
Description of the goods
UN proper shipping name UN3082, Environmentally hazardous substance, liquid, n.o.s. (zinc
sulphate )
Class: 9
Packaging group: III
ICAO-Labels: 9
Environmentally Hazardous Environmentally Hazardous
Special precautions for user

None known.

15. REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

: Comply with the requirements of following regulations:

1. Law of Control Dangerous Chemicals, Decree no. 591


2. GB/T 16483 – 2008 Safety data sheet for chemical
products – content and order of sections
3. GB 13690 – 2009 General rule for classification and hazard
communication of chemicals
4. GB 30000.2 - 2013 to GB 30000.29 - 2013 Rules for
classification and labelling of chemicals

Methods of waste disposal shall comply with the national,


provincial and local regulations.

Notification status
IECSC : All components of this product are included on the Chinese
inventory or are not required to be listed on the Chinese
inventory.
:

16. OTHER INFORMATION


Recommended use
Additive in paper industry.

Responsible Department

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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SAFETY DATA SHEET

FennoSpec 1200
/CN/EN
Revision Date: 2019-04-24 Previous date: 2016-12-21 Print Date:2019-09-02

Training advice
Read the safety data sheet before using the product.
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as
a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text. Information taken from
reference works and the literature.
Additions, Deletions, Revisions
Relevant changes have been marked with vertical lines.

(c) Kemira OYJ. All rights reserved. Reproduction and distribution is not permitted, unless used for the sole purpose of sales,
marketing and use of Kemira products only.
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