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Chapter 3
Steam point A mixture of liquid water and water vapour (with no air) in
equilibrium at 1 atm.
A Pure Substance A pure substance is identified as one that has a homogeneous
and invariable chemical composition. It may exist in more than
one phase but the chemical composition is the same in all
phases.
Saturation Temperature The temperature at which vaporization takes place at a given
pressure (called the saturation pressure).
Saturated Liquid A liquid about to vaporize.
Substance exist as liquid at the saturation temperature and
pressure.
Saturated Vapour A liquid that is just about to condense.
Substance exist as vapour at the saturation temperature.
Superheated Vapour Vapour that is not about to condense. Substance exists as a
vapour at a temperature higher than the saturated temp.
,
P < Psat @ T T > Tsat @ P
Sub cooled Liquid Temperature of the liquid is lower than the saturation
temperature for the existing pressure.
T < Tsat @ P
Compressed Liquid The pressure is greater than the saturation pressure for a given
temperature.
P > Psat @ T
Quality When a substance exists as part liquid and part vapour. It is
defined as the ratio of the mass of the vapour to the total
mass.
Allotropic A transition from one solid phase to another solid phase.
Transformation
Chapter 4
Chapter 5
First Law of It states that during any cycle a system (control mass)
Thermodynamics undergoes, the cyclic integral of the heat Is proportional to the
cyclic integral of the work.
∫ δQ = Ñ
Ñ ∫ δW
Sensible Energy The portion of the internal energy of a system associated with
the kinetic energies of the molecules.
Latent Energy The portion of internal energy associated with the phase of a
system.
Chemical Energy Internal energy associated with the atomic bonds in a
molecule.
Nuclear Energy Energy associated with the strong bonds within the nucleus of
the atom itself.
Chapter 6
Conservation of Energy The net change of the energy of the control mass is always
equal to the net transfer of energy across the boundary as heat
and work.
Specific Heat The energy required to raise the temperature of a unit mass of
a substance by one degree.
Steady State A steady-state has no storage effects, with all properties
constant with time, and constitutes the majority of all flow-type
devices.
Assumptions for a 1. The control volume does not move relative to the
Steady-State process coordinate frame.
2. The state of the mass at each point in the control
volume does not vary with time.
3. As for the mass that flows across the control surface, the
mass flux and the state of this mass at each discrete
area of flow on the control surface do not vary with time.
The rate at which heat and work cross the control
surface remain constant.
Examples of Steady-
State Processes
• Heat Exchanger It is a simple fluid flowing through a pipe or system of pipes,
where heat is transferred to or from the fluid.
• Nozzle A nozzle is a steady-stae device whose purpose is to create a
high-velocity fluid stream at the expense of the fluid’s
pressure.
• Diffuser It is a device constructed to decelerate a high-velocity fluid in a
manner that results in an increase in pressure of the fluid.
• Throttle It occurs when a fluid flowing in a line suddenly encounters a
restriction in the flow passage.
• Turbine It is a rotary steady-state machine whose purpose is to produce
shaft work (power, on a rate basis) at the expense of the
pressure of the working fluid.
• Compressor & The purpose of a steady-state compressor (gas) or pump
Pump (liquid) is the same: to increase the pressure of a fluid by
putting in shaft work.
Transient Process Change in mass (storage) such as filling or emptying of a
container.
Assumptions for a 1. The control volume remains constant relative to the
Transient Model coordinate frame.
2. The state of the mass within the control volume may
change with time, but at any instant of time the state is
uniform throughout the entire control volume (or over
several identifiable regions that make up the entire
control volume)
3. The state of the mass crossing each of the areas of flow
on the control surface is constant with time although the
mass flow rates may be time varying.
Chapter 7
Heat Engine Defined as a device that operates in a thermodynamic cycle
and does a certain amount of net positive work through the
transfer of heat from a high-temperature body to a low
temperature body.
The Second Law Of
Thermodynamics
• Kelvin-Planck It is impossible to construct a device that will operate in a cycle
(Heat Engine) and produce no effect other than the raising of a weight and
the exchange of heat with a single reservoir.
• Clausius It is impossible to construct a device that operates in a cycle
(Refrigerator/Hea and produces no effect other than the transfer of heat from a
t Pump) cooler body to a hotter body.
Reversible Process Defined as a process that once having taken place can be
reversed and in so doing leave no change in either system or
surroundings.
Irreversible Process The initial process because it could not be reversed without
leaving a change in the surroundings.
The Carnot Cycle If every process in the cycle is reversible, the cycle is also
reversible; and if the cycle is reversed, the heat engine
becomes a refrigerator. This is the most efficient cycle that can
operate between two constant-temperature reservoirs.
• 1-2 Isothermal Heat Addition in at
QH TH
Chapter 8
Isentropic Process Constant entropy process. Entropy remains constant in a
reversible adiabatic process.
Standard Entropy Integrate the results of the calculations of statistical
thermodynamics from reference temperature to any other
T0
temperature .
T
Chapter 9
Steady State Process No change with time of the entropy per mass unit at any point
within the control volume.
Fluid Incompressible v = constant