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July 2014

Tempil- Basic Guide to Ferrous Metallurgy


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( TEMPILO
Basic: Guide to Ferrous Metallurgy
2900"F~--------------------------------------------.--,
0 TRANSFORMATION RANGE. In this range steels undergo internal atomic
changes which radically affect the properties of the material.
2800"
f) LOWER TRANSFORMATION TEMPERATURE (A,) . Termed Ac, on heating, Ar,
on cooling. Below Ac 1 structure ordinarily consists of FERRITE and
2700" PEARLITE (see below). On heating through Ac 1 these constituents begin
to dissolve in each other to form AUSTENITE (see below) which is non-
magnetic. This dissolving action continues on heating through the TRANS·
FORMATION RANGE until the solid solution is complete at the upper
transformation temperature .

• UPPER TRANSFORMATION TEMPERATURE (A,) . Termed Ac 3 on heating, Ar 8


on cooling. Above this temperature the structure consists wholly of
AUSTENITE which coarsens with. increasing time and temperature. Upper
transformation temperature is lowered as carbon increases to 0.85o/o
( eutectoid point) .

• FERRill is practically pure iron (in plain carbon steels) existing below
the lower transformation temperature. It is magnetic and has very slight
solid solubility for carbon .

• PEARLITE is. a mechanical mixture of FERRITE and CEMENTITE •

• CEMENTITE or IRON CARBIDE is a compound of iron and carbon, Fe8C.

• AUSTENITE is the non-magnetic form of iron and has the power to


dissolve carbon and alloying elements.

0 ANNEALING, fre9uently referred to as FULL ANNEALING, consists of


heating steels to slightly above Ac,, holding for AUSTENITE to form, then
slowly cooling in order to produce small grain size, softness, good ductil-
ity and other desirable properties. On cooling slowly the AUSTENITE
transforms to FERRITE and PEARLITE .

• NORMALIZING consists of heating steels to slightly above Ac 3 , holding


for AUSTENITE to form, then followed by cooling (in still air). On cool-
ing, AUSTENITE transforms giving somewhat higher strength and hard-
ness and slightly less ductility than in annealing.

G FORGING RANGE extends to several hundred degrees above the


TRANSFORMATION TEMPERATURE .
UPPER

• BURNING RANGE is above the FORGING RANGE. Burned steel is ruined


and cannot be cured except by remelting.

0 STRESS RELIEVING consists of heating to a point below the LOWER


TRANSFORMATION TEMPERATURE, A1, holding for a sufficiently long
period to relieve locked-up stresses, then slowly cooling. This process is
SOmetimes called PROCESS ANNEALING.

0or working of steels should


occurs approximately from 300' to700'F. Peening
BLUE BRITTLE RANGE
· not be done between these temperatures,
since they are more brittle in this range than above or below it.

Cll) PREHEATING FOR WILDING is carried out to prevent crack formation. See
TEMPIL o PREHEATING CHART for recommended temperature for various
steels and non-ferrous metals.

CD CARBURIZING consists of dissolving carbon into surface of steel by heat-


ing to above transformation range in presence of carburizing compounds.

fD NITRIDING consists of heating certain special steels to about lOOO ' F


for long periods in the presence of ammonia gas. Nitrogen is absorbed
into the surface to produce extremely hard "skins".

G) SPHEROIDIZING consists of heating to just below the lower transforma-


tion temperature, A,, for a sufficient length of time to put the CEMENTITE
constituent of PEARLITE into globular form. This produces softness and
in many cases good machinability .

• MARTENSITE is the hardest of the transformation prqducts of AUSTEN·


ITE and is formed only on cooling below a certain temperature known as
theM, temperature (about 400 ' to 600' F for carbon steels). Cooling to
this temperature must be sufficiently rapid to prevent AUSTENITE from
transforming to softer constituents at higher temperatures .

• EUTICTOID STill contains approximately 0.85% carbon .

• FLAKING occurs in many alloy steels and is a defect characterized by


localized micro-cracking and "flake-like" fracturing. It is usually attrib-
uted to hydrogen bursts. Cure ~onsists of cycle cooling to at least 600'F
before air-cooling .

• OPEN OR RIMMING STill has not been completely deoxidized and the
ingot solidifies with a sound surface ("rim") and a core portion contain-
ing blowholes which are welded in subs09uent hot rolling .

• KILLED STilL has been deoxidized at least sufficiently to solidify with-


out appreciable gas evolution .

• SEMI-KillED STill has been partially deoxidized to reduce solidificatipn


shrinkage in the ingot.

• A SIMPLE RULE: Brinell Hardness divided by two, times 1000, e9uals


approximate Tensile Strength in pounds per square inch. (200 Brinell
-+ 2 X 1000 = approx. 100,000 Tensile Strength, p.s.i.)

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9


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59 70

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