Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 28-12-18
Time: 09:00 AM to12:00 Noon CODE-C Max.Marks:360
KEY SHEET
PHYSICS
1 1 2 2 3 2 4 1 5 1

6 4 7 4 8 2 9 4 10 2

11 2 12 4 13 4 14 2 15 3
16 3 17 1 18 2 19 1 20 2

21 2 22 4 23 1 24 1 25 2

26 4 27 1 28 1 29 2 30 2

MATHS
31 2 32 3 33 4 34 1 35 3

36 1 37 2 38 4 39 1 40 2

41 3 42 1 43 2 44 3 45 4
46 2 47 3 48 2 49 1 50 4

51 1 52 2 53 3 54 4 55 4

56 2 57 1 58 3 59 2 60 4

CHEMISTRY
61 2 62 4 63 2 64 3 65 4

66 2 67 1 68 3 69 1 70 2

71 2 72 1 73 3 74 3 75 2
76 2 77 1 78 1 79 1 80 2

81 2 82 3 83 4 84 4 85 4

86 3 87 3 88 4 89 3 90 1
Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
SOLUTIONS
PHYSICS
1
1. For AG, h  gt12
2
2h
t12 
g

For AB,
h 1 2
 gt2
n 2
2h
t22 
ng
1/ 2 1/2
 2h   2h 
 t1  t2      
 g   ng 
1/ 2
 2h 
  n
1/2
 1  t2  n1/2  1
 g 

If t2  t AB ,  t1  t2   tBG  t AB  n1/2  1
t AB 1 1
or  1/2 
t BG  n  1  7 1 
So n=7
h h
So, AB  
g 7

1
2. W  k f  k f  m  v 2f  vi2 
2
2 2
1  1  1  
 m  a2 t2    a1t1  
2  2  2  

1  t4   t2 
 m  2 a12  a12t12   Since, a2  a1 
8  t1 2   t1 

ma12 4 4

8t12
 t2  t1 
F   mg  kx0

1 2
3. Kx  mg  R  R cos 450 
2

 1 
 mgR 1  
 2

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
R R R
But x   
2 4 4

So, K 
16 2mg 1  2  
2
 R

4. As shown in figure p2 should be mV 2 in opposite direction to PR for conservation of
linear momentum
So,  2m V '  mV 2
V
V '
2
1 1
Total energy released  2 mV 2   2m V '2
2 2
3
 mV 2
2
1 1 2 12
5. Mg  Iw    Ma 2 2
2 2 23
1/2 1/2
3g   3g 
Which gives      
 2a  a 2 
GM e m
6. Kinetic energy required to escape 
R
GM e m
Energy provided to the particle 
2R
So, kinetic energy at the surface of the earth
GM e m GM e m  GM e m 
 
2R  R  h   R 
A
2
7. t  a
g
 H1  H 2 
A 2 m0  1
 1  2 
a g A

A 2mo

2a  Ag

ma   av 2

a
a0  2g
A

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
2ga
dv  dt
A

2 ga 2 ga A 2M 0
v t 
A A 2a  Ag

2m0
=g
 Ag

2m0 g

A

8. For I mode
L 1

6 4
31
L
2
For II mode
L 3
 2
6 4
9
L  2
2
v  f11  f 2 2

f11 9
Or f 2   f  3f
2 3

n1v 3V
f1  
2L 2L
n2 v 9V
f2  
2 L 2L
f2
 3. f 2  300 Hz
f1

9. Radius of cylinder =R and outer radius of shell =nR

1 1

R1 R2 K1 R K 2  n  1  R 2
2 2

Req  
R1  R2 1 1

K 2  n  1  R 2
2 2
K1 R

 K1  K 2  n 2  1 
On solving k   2

n

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
4 K1  5K2
 (given)
9
k1  5k2 / 4

9/4
n=3/2
2
10. R  Cv
3
We know, C p  Cv  R
R
or   1 
Cv

or R  Cv    1

Comparing   5 / 3
y
P1 T  constant=K

Or P  T  / 1
Given   5 / 3
   1  5 / 2

So, p T 5/2
11. Molar heat capacity
dQ
C  3R( given)
ndT
 3 
 2C0  As Cv  R 
 2 

dQ 2nCvT 2dU
C  
ndT ndT ndT
So, dQ  2dU
12. If nth minima of 400 nm is coinciding with mth minima of 560nm then
560 400
 2m  1   2n  1
2 2
 2n  1  7  14  21 
 2m  1 5 10 15
4th minima of 400 nm will coincide with 3rd minima of 560 nm. Its location is given by
 2  4  11000   400 106 

2  0.4

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
=14mm
Similarly,11th minima of 400 nm will coincide with 8th minima of 560nm.Its location
 2 11  11000   400 106 
is given by   42mm
2  0.1
Minima distance between two successive region of complete darkness=42-14=28m
3
13. The total length of concave lens= f
2
If focal length of concave lens is f
1 1 2 1
Now   
30 f f 3 f

Or f  10cm
Focal length of concave lens=10 cm and that of concave lens=15cm
14. Ep  0

or q1  q2  q  q
q1   q2

q1 2q1
V 
C 2C
q1   q1  q1  q2
 
2C 2C
15. Q  Q'

2CV   KC  2C V '

 3 
V ' V
 K 2
16. 13.6eV energy needed to liberate the electron form hydrogen atom.So electron will
liberate with kinetic energy=15-13.6=1.4eV
H AB RAB
17. 
H BC RBC
 as H  I 2 Rt 
2


1/ 2r  1 1 1
  as R  2 
2
1/ r  4 4 r 

H BC  4 H AB

18. Magnetic field in region be upwards as points in this region are to right of the wires
and in such condition, If current flows out of page, magnetic field will be upwards.

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
For the same logic, magnetic field in region AX will be downwards. In region AC,
points are closer to A than B and they are to the right of A(and to the left of
B),magnetic field will be upwards. For the same logic, magnetic field in region BC
will be downwards, Hence, option (b) is correct.
hc
19. E1 

1240
 eV  2.25eV
550
1240
E2  eV  2.8eV
450
1240
and E  eV  3.5eV
3
250

For metal, r , 3 is able to generate photoelectron

For metal q, 2 , 2 are able to generate electrtons.
For metal p, all wavelength are able to generate electrons
Hence photoelectric current will be maximum for P and minimum for r.
V
20. iL 
R
1  et /1 
V t / 2
iC  e
R
iL  iC at t  CR ln  2 

1  e t /1  et / 2
At t  CR ln  2    ln  2  for CR  
t
So that  ln  2 

1
e  t / 
2
2e t /  1
From eq(1), et /  et /  1 1 2

From eq(2) 2et /  1

On camparing 1   2
L
or  CR
R

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
R  L/C

21.
P1
P2


m1=216 m2=4
M=220

K1  K 2  5.5MeV ……(i)

and P1  P2  2  216 K1  2  4K 2 …….ii)

on solving equation(i)and (ii),we get

K 2  5.4 MeV

22.
R L

100V

In dc circuit, resistance offered by inductor is zero in steady state

V 100
i 1  R  100
R R
R L

100V,50Hz

1
i'  A
2
V 1 100
i'  
R X2 2
L
2 R 2  X L2
2 2 2
R 2  X L2   200   X L2   200   100 

X L2  300  100
2
 2 fL   300 100

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
2 2
4 2   50    L   300  100

L2  0.3  L  0.3 H

1 1 1
23.  
50   25  f

1 1 100 100
  p   2D
f 50 f  cm  50

1 1 1
 
50  f
100 2
f '  150cm  p   D
150 3
24. A capacitor of 2 F is changed as shown in the diagram. When the switch S is turned
to position 2, the percentage of its stored energy dissipated is:
1 2

V 8 F
2 F

V V V 8 F
2 F
2 F

1 2 8 2
. V  0 
loss of energy 2  2  8 
  0.8 i.e 80%
stored energy 1 2
.2.V
2
25. The given electrical network is equivalent to:
A
B y

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
A  B  A B  A  B
26. If 1 and  2 be the apparent angles of dip observed in two vertical planes at right
angles to each other, then the true angle of dip  is given by:
tan  tan  tan 
tan 1  , tan  2  
cos  cos  90    sin 

cos2   sin 2   1
cot 2 1  cot 2  2  cot 2 

27. Conceptual
28. Conceptual
29. A  band c; B  b and c
C  b and a, D  a and d

   NBA 
30. Q  
R R
N 0 nA  i1  i2 

R
2
100  4 10 7  2 104    0.05    4  0 

10 2

 32 106 C  32  C
MATHS
31. Drawn both graph, two solutions is  2 ,  
32. Multiplying both, get answer x  y    2
33. tan 1  tan  6    2  6, cot 1  cot 4   4  

34. Cosine rule ,k=4

h
35. AC  , BC  3h
3
D h
B

C A
BC 2  AC 2  AB 2
36.   0  b 2  2  a  2  b  a 2  4a  4  0, b  R Again   0  a  1

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
2
1 1  1 1 
37. 1 2  2
 1   
n  n  1  n n  1 

p 3
38.  x the n 
v 2
39. The number of natural numbers is 4373.
40. If is ‘0’ in 74
3 1 1 1
41.   
4 3 3 12
100
42. k=
17
1 1
43. Solving, the common points are   sin 2 ,  sin 2  ,for both e= 1  tan 2 
 2 2 

44. Arg=  z  z  0  I is true z lies on z   5  i  = 5 => II is false
2
5 1
45. The circle is x 2  y 2  5 x  y   0
2 2
46. Take
P Q
T F

and from the table.

1 1
47. p1   4, 9  , p2 = harmonic conjugate p1 max area = AB  PP
1 2
2 2
48. L also lies in the plane 9x-2y-5z+4=0
1
49. V  abc   2
2 

a b r
50. Expanding   0
a p bq cr

3
51. Two linear functions intersect at  0, 
 2

1
52. lim 1  sin x f  sin x  
x  /2
2
x y x y
53. Comparing   a,   2
cos  sin  x1 y1

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
54. 3 2
p  x   x  6 x  9x  2

55. Since f '  1  0 ,by rolle’s theorem no such k exists

2
56. f  x    x  1  4 x 2

57. ln ydy

58. sec y  1  x  e x

59. 0 1  x   0  x  20

60. aRb  bRa fails

aRb, bRc  aRc fails
CHEMISTRY
61. (2) MnO4- + 5e– + 8H + → Mn2+ + 4H 2O
Following Nernst equation, find out Ered(final) – Ered(initial). Thus Ered decreases by 0.189
V. The tendency of the half cell to get reduced is its oxidising power. Hence, the
oxidising power decreases by 0.189 V.
62. (4) Since there are six atoms (A) in the corner of the unit cell, the contribution of
atoms in 1 unit cell is 6/8. Since 3 face-centered atoms (B) contribute to one unit cell,
the formula is A6/8B3 or A6B24 or AB4.
63. (2)
64. (3) follows SN1 with conc.HI & SN2 with anhyd.HI
65. (4) more basic Nitrogen
66. (2) When KI is added to AgI it would increase the concentration of I– which is the
negative part of the colloid and hence will give negatively charged colloidal particle.
67. (1) cyanohydrin formation follows nucleophilic addition mechanism
68. (3) NF3 and H3O+ have sp3 hybridisation; NO3– and BF3 have sp2 hybridisation.
69. (1)
 BaCl2 Carbon
KO 2  S   K 2SO 4   BaSO 4 
 BaS
(A) (C)
(B)
HCl

(D) H S
2

70. (2) Step II, being r.d.s. Rate of overall reaction = Rate of Step II = KII [O3][O]
substituting the value of [O] from the equilibrium of Step I, we get

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2
Rate = KIIKC[O3] / [O2]
71. (2)

72. (1) Energy released in conversion of 6 × 1023 atoms of Cl– ions = 6 × 1023 × electron
affinity
= 6 × 1023 × 3.61 = 2.166 × 1024 eV
Let x Cl atoms be converted to Cl+ ion.
Energy absorbed = x × ionization energy
 x × 17.422 = 2.166 × 1024
 x = 1.243 × 1023 atoms
73. (3) Meq. of H2SO4 + Meq. of SO 3 = Meq. of NaOH
 [(0.5-x)/ (98/2) x 1000] + [x/(80/2) x 1000] = 26.7 × 0.4
 x = 0.103
∴ % of SO3 = 0.103/ 0.5 x 100 = 20.6%
74. (3) Conceptual
75. Conceptual
76. (1) Polar medium sec. alkyl halide undergoes SN1 mechanism.
77. (1) Na+ ions are not reduced at cathode and SO42- ions are not oxidized at anode.
78. (1) (CH 3)4C has twelve equivalent 1°H. Hence, H forms only one product on
monobromination.
79. (1) lactone is formed
80. (2) A is Ipc2BH. C is a methyl ketone.
81. (2) CH3CH(CH3)CH 2CH3; it has four sets of equivalent hydrogens which result in the
formation of four different monochlorination product. When chlorination takes place
at first and third carbon, this results in the formation of a racemic mixture.
82. (3) Charge density = Charge / Volume

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Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s

More the number of bonds, greater the delocalization of negative charge, so

lesser charge density.
83. conceptual
84. conceptual
85. (4)
Mole fraction = 0.07
Kf = 1.86
Tf = Kf m
n solute
 0.07
n solute  n solvent
 n solvent  0.93
0.07 1000
Tf  1.86   7.78o
0.93  18

86. (3) Buffer capacity

= No of moles of acid added per litre of buffer/Change in pH .
= 0.006/ 0.03 = 0.2

87. (3)

Volume of 2 mol of .

88. conceptual
89. (3)
(1) The magnitude of splitting energy increases down the group. Thus
Pt2+ – 5d8, Pd2+ – 4d 8 and Ni2+ – 3d 8.
(2) NH 3 is a borderline ligand which forces pairing of electrons in Co3+, whereas H2O
is a weak-field ligand and it can not force the pairing in Ni2+.
Co3+ in [Co(NH3)6]3+ – 4s0, 3d6

Ni2+ in [Ni(H2O)6]2+ – 3d8, 4s0

Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-C(10th Jan)_Key & Sol’s
So, there is no unpaired electron in [Co(NH3)63+] whereas there are unpaired electron
in [Ni(H2O)6]2+. Thus [Co(NH3)6]3+ is colourless and [Ni(H2O)6]2+ is coloured due to
d–d transition.
(3) O
NH2
O C
CH2
M(n – 1) + CH2
CH2
NH2 NH2

As en is symmetrical ligand thus there is no geometrical isomerism.

(4) In K3[Fe(CN)6], the oxidation state of Fe is +3.
[Fe(CN)6]3– – 3d 5, 4s0.

Number of unpaired electron = 1

 = n(n  2) B.M. = 1(1  2) B.M. = 3 B.M.

Thus answer is (3).

90. (1) It occurs during roasting in reverbetory furnace at moderate temperature in
presence of air..

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