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IIT2019, (Two Year CRP(17-19)-RIT-II-CPM -1

FIITJEE INTERNAL TEST


RANK IMPROVEMENT TEST – II
Batches: All 719
IIT- JEE 2019
QP CODE:
Time: 3 hours Maximum Marks: 186
 Please read the instructions carefully. You are allotted 5 minutes specially for this purpose.
 You are not allowed to leave the examination hall before end of the test.
 Use Blue/Black Ball Point Pen only for writing particulars on Side–1 and Side–2 of the
Answer Sheet. Use to Pencil is strictly prohibited.

Instructions
Note:
1. The question paper contains 3 sections (Sec-1, Chemistry, Sec-II, Physics & Sec-III, Mathematics.)
2. Each section is divided into one part, Part-A.
3. Part – A contains 18 questions which are further divided as follows:

i) PART – A (01 – 06) contains 6 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
ii) PART – A (07 – 14) contains 8 Multiple Choice Questions which have One or More Correct answer.
For each question in the group Q. 7 – 14 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in 2
marks, as a wrong option is also darkened.
iii) PART – A (15 – 18) contains 2 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions. Each
question has four choices (A), (B), (C) and (D), out of which only one is correct. Each question carries +3
marks for correct answer. There is no negative marking.

Name of the Candidate :

Enrolment Number :

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IIT2019, (Two Year CRP(17-19)-RIT-II-CPM -2

Section – I (Chemistry)
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
only ONE option is be correct.

1. Iron(II) polysulphide FeS3 is subjected to roasting to give ferric oxide and SO 2. The equivalent mass of
FeS3 is
[M stands for molecular mass of FeS3]
M M M
(A) M (B) (C) (D)
15 19 14

COOH
. H 2O
2. X gm of COONa reacts completely with 1 L of 0.1 N NaOH solution. What volume of 0.1 N
COOH
. H 2O
KMnO4 be needed in acidic medium to react completely with X gm of same COONa ?
(A) 1 L (B) 2 L (C) 0.5 L (D) 1.5 L

3. Pure Na2C2O4 and KHC2O4.H2C2O4 are mixed in such a proportion that each gm. of mixture will react
with equal volume of 0.10 M KMnO4 in acidic medium and 0.10 M NaOH separately, what is the
proportion in terms of weight ratio?
(A) 1 : 1 (B) 3.38 : 1 (C) 1 : 3.38 (D) 1 :4

4. Which of the following gas laws concept was used during making of first atom bomb?
(A) Boyle’s law (B) Charle’s law (C) Avagadro’s law (D) Graham’ law of effusion

5. 1 mole of Mohr’s salt is treated with 1 M KMnO4 solution in acidic, neutral and strongly alkaline
medium separately to reach at equivalence point require V 1 mL, V2 mL and V3 mL of oxidant
respectively. Which of the relationship is correct?
(A) V1 = V2 = V3 (B) V1 < V2 < V3 (C) V3 < V2 < V1 (D) V2 < V1 < V3

6. For one mole of a van der Waals gas when b = 0 and T = 300 K, the PV vs 1/V plot is shown below.
The value of the van der Waals constant a (atm.litre2mol–2) is

24.6
6
23.1
PV(litre atm)

21.6
20.1

0 1.0 2.0 3.0


–1
1/V(Litre )
(A) 1.0 (B) 4.5 (C) 1.5 (D) 3.0
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(Multiple Correct Choice Type)


This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

7. The van der Waal constants for gases A, B and C are follows
Gas a/dm6 kPa mol–2 b/dm3 mol–1
A 405.3 0.027
B 1215.9 0.030
C 607.95 0.032
The correct statement(s) is/are
(A) Gas B have highest critical temperature
(B) Gas C have largest molecular volume
(C) Gas A shows most ideal behaviour at STP
(D) All the three gases have identical Boyle temperature

8. Which of the following statement(s) is/are correct?


(A) If a gas has very large molar volume, then value of compressibility factor Z is equal to one.
(B) At the Boyle temperature, the gas obeys ideal gas behaviour over the wide range of pressure.
(C) At the Boyle temperature, the net attractive force among molecules is just counter balanced by net
repulsive forces among gaseous molecules.
(D) If a gas expands above inversion temperature, heating will be observed.

9. According to kinetic theory of gases


(A) collisions are always elastic
(B) heavier molecules transfer more momentum to the wall of container
(C) only a small number of molecules have very high velocity
(D) between collisions, the molecules move in a straight lines with constant velocities

10. Which of the following statement(s) is/are correct for mean free path().
(A) It is the average distance traveled by molecule between two successive intermolecular collisions.
(B) As P increase,  decreases
(C) As P increase,  also increases
(D)  also depends on molecular diameter

11. Which of the following ions are responsible for hardness in water?
(A) Mg2+ (B) Ca2+ (C) SO4  (D) HCO3

12. How many of these gases are absorbed in KOH solution?


(A) N2O (B) NO (C) N2O3 (D) N2O4

13. Which of the following reaction(s) is/are example of disproportionation?


(A) 2H2O2   2H2O  O2 (B) Cl2  OH   Cl  ClO3
1
(C) 2C2H5 
 H2C  CH2  C2H6 (D) HgO 
 Hg  O2
Radical 2
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14. The Maxwell distribution curve is shown for three different gases A, B and C at same temperature.

Which of the following statement is correct?


(A) MA = MB = MC (B) MA < MB < MC (C) MC < MB < MA (D) MB < MA < MC

Comprehension Type
Paragraph for question nos. 15 – 16

1.16 g of CH3(CH2)nCOOH was burnt in excess air and the resultant gases (CO 2 and H2O) were passed
through excess NaOH solution. The resulting solution is divided into two equal parts. One part required 50 mL
of 1 N HCl for neutralization using phenolphthalein as indicator. Another part required 80 mL of 1 N HCl for
neutralization using methyl orange as indicator.

15. What is the value of n?


(A) 1 (B) 2 (C) 3 (D) 4

16. What amount of excess NaOH was taken initially?


(A) 1.6 g (B) 33.2 g (C) 6.4 g (D) 8 g

Paragraph for question nos. 17 – 18

Two flasks A and B have equal volumes. A is maintained at 300 K and B at 600 K. The flask A contains H2
gas, B has an equal mass of CH4 gas. Assuming ideal behaviour for both gases.

17. Which of the following statement is NOT correct for these gases?
(A) PH2 : PCH4  4 :1 (B) Cav H  : Cav CH   2 : 1
2 4

KE / mol of H2  Total KE H
(C)  1: 2 (D) 2
 8 :1
KE / mol of CH4  Total KE CH 4

18. If the collision diameter of CH4 may be assumed to be twice as that of H2, then the which of the
following relationship is correct?
 Stands for mean free path
 Stands for viscosity of gas
H2 1 H2 2 H2 1 H2 2
(A)  (B)  (C)  (D) 
CH4 2 CH4 1 CH4 2 CH4 1
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Section – II (Physics)
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
only ONE option is be correct.

1. In adjacent figure, a boy, on a horizontal platform A, kept on a


smooth horizontal surface, holds a rope attached to a box B. Boy
pulls the rope with a constant force of 50 N. The co-efficient of B
friction between boy and platform is 0.5. (Mass of boy = 80 kg, A
mass of platform 120kg, mass of box = 100 kg)
(A) velocity of platform relative to box after 4 s is 3 m/s.
(B) velocity of boy relative to platform after 4 s is 2 m/s.
(C) friction force between boy and platform is 40 N.
(D) friction force between boy and platform is 50 N.

2. A ring of mass 200 gram is attached to one end of a light spring Y


of force constant 100 N/m and natural length 10 cm. The ring is
constrained to move on a rough wire in the shape of quarter
ellipse of major axis 24 cm and minor axis 16 cm with its centre A m v
at origin. The plane of ellipse is vertical and wire is fixed at points rough wire
A and B as shown in figure. Initially ring is at A with other end of 8cm
spring fixed at origin. If normal reaction of wire on ring at A is
zero and ring is given a horizontal velocity of 10 m/s towards right
O X
so that it just reaches point B, then select the correct alternative 12cm
B
(s) (g = 10 m/s2)

(A) Work done by friction is –10 Joule.


(B) At B energy stored in spring is more than energy stored at A.
(C) Work done by friction is –10.16 Joule.
(D) Work done by spring force is positive.

3. A plank is held at an angle  to the horizontal on two fixed supports A


and B. The plank can slide against the supports (without friction)
because of its weight ‘Mg’. Acceleration and direction in which a man of
mass ‘m’ should move so that the plank does not move
 m
(A)  1  g sin  down the incline.
 M 
 M
(B)  1   g sin  down the incline. 
 m
 m
(C)  1   g sin  up the incline.
 M
 M
(D)  1  g sin  up the incline.
 m 
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4. A chain of length ‘’ and mass ‘m’ lies on the surface of a smooth
P
sphere of radius R >  with one end held at the point P as shown in
figure. If the chain is released from this position, then the tangential
acceleration of the chain just after release 

Rg   
(A) 1  cos  R  
  
Rg    
(B) cos   R   cos  
   
Rg   
(C) cos   cos    R  
  
(D) none of these

m
5. A block of mass m lies on the top of fixed wedge as shown in
figure-1 and another identical block lies on top of identical wedge h
which is free to move on smooth horizontal surface as shown in travel
wedge 
figure-2. Both blocks are released from rest, i.e. vertical height h
above the respective horizontal surface on which the wedge is Horizontal surface
placed. Let T1 and T2 be the time taken by the block in figure-1
and in figure-2 respectively to just reach the horizontal surface,
then m
(A) T1 > T2
(B) T1 < T2 h
(C) T1 = T2
(D) None of these 

Smooth horizontal surface

6. A stationary body of mass m is slowly lowered on to massive platform (M > > m) moving at a speed
0. If  is the co-efficient of friction between the body and the platform, the distance traveled by the
body before it stops sliding, is
v 02 v 02 v0 v 02 g
(A) (B) (C) (D)
2g g g 
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IIT2019, (Two Year CRP(17-19)-RIT-II-CPM -7

(Multiple Correct Choice Type)


This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

7. In the given figure, a block A rests on a smooth triangular block B and


the block B is given an acceleration of a = 2 m/s2 along the plane
(A) normal force on block A due to block B is m(g – a)
(B) acceleration of block A relative to block B is a cos  A
(C) if friction is present between block A and B, the coefficient of friction
B
a
should be greater than cos , for no relative motion between A
g
and B a
(D) If friction is present between block A and B, the coefficient of friction

a cos 
should be greater than , for no relative motion between
g  a sin 
A and B

8. A block B of mass 0.6 kg slides down the smooth face PR of a


wedge A of mass 1.7 kg which can move freely on a smooth P
horizontal surface. The inclination of the face PR to the
horizontal is 45°. Then
(A) the acceleration of A is 3g/20 B
(B) the vertical component of the acceleration of B is 23g/40 A
(C) the horizontal component of the acceleration of B is 17 45°
Q R
g/40.
(D) None of these

9. Two blocks each of mass 1 kg are placed as shown. They


are connected by a string which passes over a smooth F
(massless) pulley. There is no friction between m 1 and the m2
ground and the coefficient of friction between m 1 and m2 is
0.2. A force F is applied to m 2. Which of the following m1
statements is/are correct.
(A) The system will be in equilibrium if F  4N .
(B) If F  4N the tension in the string will be 4N .
(C) If F  4N the frictional force between the block will be 2N .
(D) If F  6N the tension in the string will be 3N .
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10. A particle of mass m is given a velocity v0 on a rough horizontal surface. The coefficient of friction
between the particle and surface is . There is also a variable external force acts on the particle given
as | F | k | v | where k is a positive constant and v is instantaneous velocity. The directions of force at
any instant is perpendicular to velocity. The particle moves in an instantaneously circular path of
variable radius then
(A) the time taken by the particle to stop is v0/g.
(B) the time taken to reduce the angle between the acceleration and the velocity from 60° to 30° is
2m
.
3k
v 02
(C) the total distance covered by the particle is .
2 g
m gt 
 v0 
2 
(D) the radius of curvature of the path at any time t is .
k

11. A strip of wood of mass M and length is placed on a smooth horizontal surface. An insect of mass
m starts at one end of the strip and walks to the other end in time t, moving with a constant speed.

(A) The speed of the insect as seen from the ground is <
t
 m 
t  M  m 
(B) The speed of the strip as seen from the ground is

 M 
(C) The speed of the strip as seen from the ground is 
t  M  m 
2
1 Mm  
2 m  M  t 
(D) The total kinetic energy of the system is

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12. For the arrangement shown in figure the coefficient of


friction between two surfaces is 0.5. Which of the following F
1 kg
graphs shows correct variation of frictional force / between
the 2 kg block and floor with the applied force F. (Take
2 kg
leftward direction of F as positive)

(A) (B)

(C) (D)

A C
13. In the given figure, all surface are frictionless and m m
strings pulleys are massless, then
(A) acceleration of block B is g/2. m B
m
(B) acceleration of block B is zero. D
(C) acceleration of block wedge is zero.
(D) acceleration of block wedge is g/2. 2m Wedge

14. A block P of mass 4 kg is placed on horizontal rough


surface with coefficient of friction  = 0.6 and two blocks
R and Q of masses 2 kg and 4 kg connected with the
help of massless strings. A and B respectively passing
over frictionless pulleys as shown, then (g = 10 m/s2)
(A) acceleration of block P is zero
(B) tension is string A is 20 N
(C) tension is string B is 40 N
(D) contact force on block P is 20 5 N
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Comprehension Type
Paragraph for question nos. 15 – 16

Block A of mass m and block B of mass 2m are placed on a


fixed triangular wedge by means of a massless, inextensible
string and a frictionless pulley as shown in figure. The
wedge is inclined at 45° to the horizontal on both sides. The B
A
coefficient of friction between block A and the wedge is 2/3
and that between block and the wedge is 1/3. If the system m 2m
of A and B is released from rest, find 45° 45°

15. The acceleration of A


(A) 2 m/s2 (B) 3 m/s2 (C) 5 m/s2 (D) zero

16. Tension in the string


2 2 2
(A) mg (B) mg (C) 2 mg (D) mg / 2
3 3

Paragraph for question nos. 17 – 18

The coefficient of friction between 20 kg and ground, between 10 kg and 20 kg and between 30 kg
and 40 kg is 0.2. No friction is present between 40 kg block and ground. A constant force F has been
applied on 40 kg mass. The friction force between 10 kg and 20 kg is f R1 and friction force between 30
kg and 40 kg mass is fR2. It is given that 2fR1=fR2.

10kg
=0.2

20kg =0.2
30kg
=0.2 40kg F

17. Magnitude of force F


(A) 50 N (B) 60 N (C) 70 N (D) 70.5 N

18. Acceleration of 10kg block


(A) Zero (B) 0.25 m/s2 (C) 1.25 m/s2 (D) 0.50 m/s2
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Section – III (Mathematics)


PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
only ONE option is be correct.

 k2 k2 
1. If limcos ec 1    exists, then k belongs to the interval
x 1
 ln x x  1
(A)   2, 2 
  
(B) , 2    2, 
  
(C)  , 2 (D) none of these

 2x  1
2.  
The function f  x   x cos    (where [.] denotes the greatest integer function) is
 2 
discontinuous at
n
(A) all x (B) x  , n  Z  1
2
(C) x  N (D) x  Z   0 


3. If f  x   x tan  sin x  , g  x   x sin  tan x  and h  x    sin x  tan x  , x   0,  , then the
 2
greatest function is
(A) f(x) (B) g(x)
(C) h(x) (D) depends on x

 5 
If g  x  is a continuous and differentiable function such that 2x 2  3 dx  g  x  dx  0 ,
2
4. 0   2
2

 
 
then g x  0 , where x   0,2 , has (here [ . ] denotes the greatest integer function)
(A) exactly one real root (B) at least one real root
(C) no real root (D) nothing can be said about the roots

5. Let f(x) be a positive, continuous and differentiable function on the interval a, b such that  
1
lim f  x   1 and lim f  x   31/ 4 . Also, f '  x   f 3  x   . Then
x  a x b f x
 
(A) b  a  (B) b  a 
24 24

(C) b  a  (D) none of these
12
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2
6. If x1  tan1  x2  x3 ... are positive real numbers satisfying
3
1 2n
sin  xn 1  xn   3 2 sin xn sin xn 1  0 for n  1 , then lim xn equals
x 
 
(A)  (B)
8 6
 
(C) (D)
10 12

(Multiple Correct Choice Type)


This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

7. If f  x   ax 3  bx 2  cx  1 has extrema at x  ,  such that   0 and f    f     0, then


the equation f  x   0 has
(A) three equal real roots (B) three distinct real roots
(C) one positive root if f     0 and f     0 (D) one negative root if f     0 and f     0

8.    
Let f be a differentiable function satisfying f x  y  f x  f y  xy x  y     for all x,y  R . If
f '  0   2, then
(A) f is a polynomial function
(B) f is an exponential function
(C) f is thrice differentiable
(D) f is a polynomial of degree 3 whose roots are 0, i 2

 2g  x  
9. Iff  x   sin 1  , then
 1   g  x  2 
 
(A) f  x  is decreasing if g  x  is increasing and g  x   1

   
(B) f x is increasing if g x is increasing and g  x   1

(C) f  x  is decreasing if g  x  is decreasing and g  x   1

(D) f  x  is increasing if g  x  is decreasing and g  x   1


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min  f  t   : 0  t  x , 0  x  6
10. Let f  x   x3  9x2  15x  6 and g  x    , then
 x  18 , x6
(A) g  x  is continuous  x  0,  
(B) g  x  is differentiable at x = 6
(C) g  x  is not differentiable at exactly two points in 0,  

9  21
(D) at x  , g  x  is continuous but not differentiable
2

11. Which of the following are correct?



(A) 3   (B) 101  202
3 202 101

 
1 cos 1 sin
 
9/ 4 4/3
4 9  3  3
(C)     (D)  1  sin    1  cos 
3 4  3  3

12. If f is an odd continuous function in  1, 1 and differentiable in (–1, 1), then which of the following
statements are correct?
(A) f '  a   f 1 for some a   1, 0 
(B) f ' b   f 1 for some b   0, 1

 
(C) n f    f '      f 1  for some    1, 0  and n  N
n 1 n

(D) n  f     f '      f 1  for some    0, 1 and n  N


n 1 n

 
 sin x  1, 0x
 2 x ,
 1  x  1 
Consider f  x    and g  x   
13.
2 , where [.]
 x  2  x, 1  x  3
  x   cos  x  2  ,   x  

 2
denotes the greatest integer function. Identify the correct statements.

(A) lim g f  x   1
x 1
 
(B) lim g f g  x 

  0
x
2

f g  x  1 g  f  x  1
(C) lim  (D) lim 
x 2 f x  2 2 x 0
 f  x   2
2
2

14. Let f be a biquadratic function of x given by f  x   Ax 4  Bx3  Cx2  Dx  E, where A, B, C, D,


1
 f  x   x 3
E  R and A  0 . If lim    e , then
x 0  2x 3 
 
(A) A  4B  0 (B) A  3B  0 (C) f 1  8 (D) f ' 1  30
space for rough work

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IIT2019, (Two Year CRP(17-19)-RIT-II-CPM -14

Comprehension Type
Paragraph for question nos. 15 – 16

Let f be a differentiable function satisfying the relation


  
f  x  y   f  x   f  y   2xy  e x  1 e y  1  x, y  R and f '  0   1.

f  2x   4x 2  2x
15. The value of lim is equal to
x 0 x2
(A) 2 (B) 4
(C) 8 (D) 16

16. Let g  x   f  x   x 2  2 . If the equation g x   k has four distinct solutions, then the set of values
of k is
(A) (0, 1) (B) (–2, 2)
(C) (0, 3) (D) (0, 2)

Paragraph for question nos. 17 – 18

The function f(x)  ax  bx  cx  d has its non-zero local minimum and local maximum values
3 2

at x  2 and x  2 respectively. Given ‘a’ is a root of the equation x 2 – x – 6 = 0.

17. The smallest integral value of a  b  c  d is equal to


(A) 59 (B) 33
(C) 57 (D) 58

18. The roots of the equation ax2 + bx + c = 0


(A) are opposite in sign (B) are imaginary
(C) are both positive (D) are both negative
space for rough work

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