Chapter 6

THERMAL CONDUCTIVITY OF GAS -INORGANIC COMPOUNDS

Carl L. Yaws
Lamar University, Beaumont, Texas

Tabulation Results
The results are given in Table 6. For the tabulation, thermal conductivity of gas as a function of
temperature is given by the equation shown below:
kgas =A + B T + C T + D r'
2
(6)
where =
kgas thermal conductivity of gas, W/(m K)
A, B, C, and D =regression coefficients for chemical compound
T = temperature, K
The tabulation is arranged by alphabetical order (Ag, AI, Ar, , Zr ) to provide ease of use in
quickly locating the data by using the chemical formula. The compound name and CAS No (Chemical
Abstracts Registry Number) are next provided. Values for regression coefficients are given in the adjacent
columns. The temperature range for use is given in the next columns (TMIN and TMAX). The equation
should not be used for temperatures outside this range. The next column provides the code for the
tabulation. The last three columns provide values for thermal conductivity of gas at representative
temperatures. The tabulation is applicable to gas at low pressure.
In preparing the tabulation, a literature search was conducted to identify data source publications
(1-44). Both experimental values for the property under consideration and parameter values for
estimation of the property are included in the source publications. The publications were screened and
copies of appropriate data were made. These data were then keyed into the computer to provide a
database of values for compounds for which experimental data are available. The database also served
as a basis to check the accuracy of the estimation methods. Upon completion of data collection,
estimation of values for the remaining compounds was performed.
The compilations of Beaton and Hewitt (2); CRC (3-4); Daubert and Danner (5); and Yaws (26-
42) were used extensively for the tabulation. In the absence of experimental data, estimates were primarily
based on the on Stief and Thodos correlation and modified Eucken models (14). Experimental data and
estimates were then regressed to provide the same equation for all compounds.
Very limited experimental data are available for highly polar and high molecular weight compounds.
Also, very few experimental data are available at high temperatures above 600 K. Thus, the values for these
compounds and high temperatures should be considered rough approximations.
A comparison of calculated and data values is shown in Figure 6 for a representative compound.
The graph shows favorable agreement of equation and data.
Example
In an engineering analysis, thermal conductivity of gas is needed for oxygen (02) at 500 K.
Determine the thermal conductivity of gas for oxygen at this temperature.
Substitution of the coefficients from the tabulation and temperature into the above equation
yields:
2 3
kgas = 1.5475E-04 + 9.4153E-05*500 - 2.7529E-08*500 + 5.2069E-12*500
kgas =0.0410 W/(m K)
References
1. Assael, M. J., S. Mixafendi, and W. A. Wakeham, "The Viscosity and Thermal Conductivity of Normal Hydrogen
in the Limit Zero Density", J. Phys. Chem. Ref. Data, 15, 1315 (1986).
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(1994-2006).
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(1994).
5. Daubert, T. E. and R. P. Danner, DATA CaMpI! ATION OF PROPERTIES OF PURE COMPO! JNDS, Parts 1,

292
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Temperature and Pressure", J. Phys. Chem. Ref. Data, 12, 933 (1983).
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METAl S, Blackwell-Scientific Publications, London, England (1985).
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1997).
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McGraw-Hili, New York, NY (2000).
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McGraw-Hili, New York, NY (1987).
16. Reid, R. C. and T. K. Sherwood, THE PROPERTIES OF GASES ANO IIOIIIOS, 3rd ed., McGraw-Hili, New
York, NY (1977).
17. Sengers, J. V. and J. T. R. Watson, "Improved International Formulation for the Viscosity and Thermal
Conductivity of Water Substance", J. Phys. Chem. Ref. Data, 15,1291 (1986).
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MIXTURES, Chemistry Data Series, Volume X, Part 1, DECHEMA, FrankurtlMain, Germany (1988).
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20. Trengove, R. D. and W. A. Wakeham, "The Viscosity of Carbon Dioxide, Methane, and Sulfur Hexafluoride in
the Limit of Zero Density", J. Phys. Chem. Ref. Data, 16, 175 (1987).
21. Tsederberg, N. V., THERMAL CONPlJCTIVITY OF GASES ANO L1011l0S, MIT Press, Cambridge, MA (1965).
22. Vargaftik, N. B., TABI ES ON THE THERMOPHYSICAL PROPERTIES OF I 10lUOS ANO GASES, 2nd ed.,
English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983).
23. Vargaftik, N. B. and others, HANDBOOK OF THERMAL CONOUCTIVITY OF L10lUOS AND GASES,
Standards Press, Moscow, USSR (1978).
24. Vargaftik, N. B. and others, HANDBOOK OF THERMAL CONPlJCTIVITY OF L10lJlDS AND GASES, CRC
Press, Inc., Boca Raton, FL (1993).
25. Vescovic, V., et aI., "The Transport Properties of Carbon Dioxide", J. Phys. Chem. Ref. Data, 19, (1990).
26. Yaws, C. L. and Others, "Carbon Oxides (Carbon Monoxide and Dioxide) - Phy. and Thermo. Prop. (4)", Chem.
Eng., 81 (20),115 (Sept. 30,1974).
27. Yaws, C. L. and Others, "Ammonia and Hydrazine - Phy. and Thermo. Prop. (6)", Chem. Eng., 81 (25), 178
(Nov. 25,1974).
28. Yaws, C. L. and Others, "Major Diatomic Gases (Hydrogen, Nitrogen and Oxygen) - Phy. and Thermo. Prop.
(8)", Chem. Eng., B2 (2),99 (Jan. 20,1975).
29. Yaws, C. L. and Others, "N-Type Gas Phase Dopants - Physical and Thermodynamic Properties of Arsine,
Phosphine and Stibine", Solid State Technology, 11 (1),47 (1974).
30. Yaws, C. L. and Others, 'Oxides of Nitrogen (Nitrous Oxide, Nitric Oxide and Nitrogen Dioxide) - Phy. and
Thermo. Prop. (3)", Chem. Eng., 81 (17), 99 (August 19,1974).
31. Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silane", Solid State Techn., 21 (1), 43
(January, 1978).
32. Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrachloride", Solid State Techn.,
22 (No.2), 65 (February, 1979).
33. Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrafluoride", J.Ch.I.Ch.E., 12 (1),
33 (1981).
34. Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Trichlorosilane", J.Ch.I.Ch.E., .1.4, 205
(1983).
35. Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Dichlorosilane", Ind. Eng. Chem. Process
Des. Dev., 23,48 (1984).
36. Yaws, C. L. and Others, "P-Type Gas Phase Dopants (Diborane and Pentaborane): Physical and
Thermodynamic Properties", Solid State Technology,l1 (11), 31 (1974).
37. Yaws, C. L., PHYSICAl PROPERTIES, McGraw-Hili, New York, NY (1977).
38. Yaws, C. L., HANDBOOK OF THERMAL CONPlJCTIVITY, Vols. 1 and 4, Gulf Publishing Company, Houston,
TX (1995,1997).

293
39. Yaws, C. l., CHEMICAl PROPERTIES HANDBOOK, McGraw-Hili, New York, NY (1999).
h
40. Yaws, C. L., MATHESON GAS DATA BOOK, i ed., Matheson Tri-Gas (Parisppany, NJ), McGraw-Hili, New
York, NY (2001).
41. Yaws, C. l., YAWS HANDBOOK OF THERMODYNAMIC AND PHYSICAL PROpERTIES OF CHEMICAL
COMPOllNDS, electronicedition, www.knovel.com. knovel, Norwich,NY (2003-present).
42. Yaws, C. L., YAWS HANDBOOK OF PHYSICAl PROPERTIES FOR HYDROCARBONS AND
CHEMICAl S, Gulf PUblishingCompany, Houston, TX (2005).
43. Yaws, C. L., YAWS HANDBOOK OF THERMODYNAMIC PROPERTIES FOR HYDROCARBONS AND
CHEMICAl S, Gulf Publishing Company, Houston, TX (2006).
44. Younglove, B. A. and H. J. M. Hanley, "The Viscosity and Thermal ConductiVity Coefficients of Gaseous and
Liquid Argon", J. Phys. Chem. Ref. Data, 15, 1323 (1986).

[ - - equation • data]
0.14 ,..---------,-------,---- T-----,------~l

0.12 +------+-----+------+--~--""7i__---_I

0.10 +-----

0.08 +------+- -------1I--~....'----~-+-------+---____j

0.06 +-----+-----..1---+-------1------+--------1

0.04 + - - - - . - - - - t - - - -1-------+-------1

0.02 +----tII.=---+--

0.00
o 500 1000 1500 2000 2500
Temperature, K

Figure 6 Thermal Conductivity of Gas for Oxygen

294
 Table 6 Thermal Conductivity of Gas - Inorganic Compounds

ka..=A+BT+cr+or (kg.. - W/(m K), T - K)

NO 10 FORMULA NAME CAS No A B C 0 TMIN TMAX code .....TMIN .....25C kp,.TMAX
1 80 A1B3HI2 aluminum borohydride 16962-07-5 -5.8628E-03 4.9500E-05 4.3454E-07 -6.8523E-l0 209 309 2 0.01716 0.02936 0.03066
2 82 A1Br3 aluminum bromide 7727-15-3 -8.1783E-G2 3.7168E-04 ·2.8287E-07 -1.9973E-ll 478 578 2 0.03366 -- 0.04138
3 86 A1C2H6CI aluminum, dimethyl chloride 1184·58·3 ·2.8578E-03 2.9499E-05 4.0947E·08 -1.3975E·ll 295 1000 2 0.00905 0.00921 0.05361
4 96 A1C6HI5 aluminum, triethyl 97-93-8 -2.8452E-G3 4.6162E-05 9.5447E-08 -1.6238E-ll 295 1000 2 0.01866 0.01897 0.12253
5 200 Ar argon 7440-37-1 -3.0142E-04 6.8128E-05 -3.1822E-08 6.854OE-12 90 2000 1,2 0.00558 0.01736 0.06350
6 203 AsBr3 arseniC (iii) bromide 7784-33-0 -1.5313E-02 1.0779E-04 -5. 1546E-08 -8.1638E-ll 304 404 2 0.01041 --- 0.01445
7 226 AsCI3 arsenic trichloride 7784-34'1 -1.6448E-02 1.3781E-04 -5.1791E·06 -1.5884E-l0 257 357 2 0.01286 0.01583 0.01893
8 230 AsF3 arsenic trifluoride 7784·35-2 -1.0810E-02 7.3272E-05 1.0328E-07 -2.6067E-l0 267 367 2 0.01117 0.01331 0.01712
9 231 AsF5 arsenic penta/luoride 7784-36-3 -1.2112E-02 1.3386E-04 2.3624E-07 -6.3360E-l0 193 293 2 0.01802 --- 0.03149
10 234 AsH3 arsine 7784-42-1 -2.9159E-03 5.1229E-G5 1.0056E-06 -7.3774E-12 21t 1000 2 0.00825 0.01306 0.05099
11 245 As203 arsenic trioxide 1327-53-3 -8.3793E-04 1.1692E-G5 -1.3119E-l0 -4.1049E-14 730 1000 2 0.00761 --- 0.01068
12 265 BBr3 boron tribromide 10294-33-4 -1.1429E·02 l.oo30E·04 3.2101E-08 -2.4727E-l 0 226 328 2 0.01019 0.01478 0.01620
13 361 BCI3 boron trichloride 10294-34-5 -4.1806E·03 6.7432E-05 ·7.0335E·06 6.5584E-ll 273 1000 2 0.01033 0.01141 0.058SO
14 363 BF3 boron trifluoride 7637-07·2 -3.8789E-04 6.0520E-05 6.7399E-09 -2.0024E-12 173 1000 1,2 0.01030 0.01820 0.06487
15 369 BH3CO borane carbonYl t3205-44-2 -6.3705E-03 1.8297E-04 -6.4655E-08 -2.0672E-l0 150 236 2 0.01692 --- 0.02851
16 372 BI3 boron trilodide 13517-10-7 -1.5319E-02 l.oo73E-04 -4.0351E-08 -6.0835E-ll 316 416 2 0.00994 --- 0.01379
17 390 B2C14 diborane, tetrachloro 13701-67-2 -1.3407E-02 1.3162E-04 3.7780E-07 -9.9605E·l0 181 281 2 0.01681 --- 0.03126
18 391 B2D6 diborane, deutero 20396-66-1 -2.8656E-02 7.6495E-04 -3.3334E-07 -2. 1439E-09 ISO 200 2 0.07135 --- 0.09385
19 392 B2F4 diborane, tetralluoro 13965-73-6 -1.8715E-02 1.0495E-04 5.6982E-07 ·1.1324E-09 217 317 2 0.02229 0.03699 0.03977
20 393 B2H5Br diborane hydrobromide --- -8.4518E·03 1.2741E-04 8.2961E-06 -3.6026E-l0 169 269 2 0.01370 --- 0.02481
21 394 B2H6 diborane 19287-45-7 -3.5568E-03 4.7778E-05 1.7087E-07 -5.5618E·ll 181 1000 2 0.01032 0.02440 0.15947
22 401 B3N3H6 borazine 6589-51-3 2.6731E-03 -1.7029E-04 1.7661E-06 ·2.3373E-09 216 316 2 0.02467 0.04695 0.05141
23 404 B4Hl0 tetraborane 18283-93-7 -1.1889E-02 2.5114E-04 2.7548E-08 -2.6869E-l0 152 252 2 0.02594 --- 0.04856
24 405 BSH9 pentaborane 19824-22-7 1.2789E-02 -2.8106E-04 1.9647E-06 -2.3276E-09 227 327 2 0.02289 0.04195 0.04947
25 406 B5Hll pentaborane 18433-84-8 -8.7515E-03
_.-
2. 1752E-04 3.4053E-08 -2.2927E-l0 ISO 2SO 2 0.02390 -- 0.04420
26 413 Bl0H14 decaborane 5.1661E-03 -4.3842E-04 2.4726E-06 -2.3520E-09 373 473 2 0.06348 --- 0.10201
27
28
579
626
B1F5
BrF3
bismuth pentafluoride
bromine trifluoride
7787-62-4 -4.2919E-02
7787-71-5 -1.2957E-02
1.5112E-04
8.5502E·05
1.4917E-07
2.8771E-08
-2.7497E-l0
-1.7231E-l0
453
282
553
382
2
2
0.03060
0.00957
--
0.01053
0.03977
0.01430
29
30
628
633
BrF5
Br2
bromine pentafluoride
bromine
7789-30-2 -2.8551E-03
7726-95-6 -4.1129E-05
3.5280E·05
1.3233E-05
4.1402E-G7
7.0867E-09
-1.0787E-09
-3.5344E-12
ISO
295
200
1500
2
1,2
0.00611
0.00439
--
0.00444
0.01213
0.02383
31 640 CBr20 carbonyl bromide 593-95-3 -1.3968E-03 5.8183E-05 ·2.7330E-06 -1.3962E-l0 ISO 200 2 0.00624 _.- 0.00803
32 641 CCI20 carbonyl chloride 75-44-5 -5.1302E-G3 6.7857E-05 2.1508E-07 -6.2409E-l0 ISO 245 2 0.00778 --- 0.01525
33 842 CF20 carbonyl fluoride 353-50-4 -6.8849E-G3 9.1946E-05 1.8754E-G7 -5.3799E-l0 159 259 2 0.01033 --- 0.02017
34 644 CH4N20 urea 57-13-6 -2.1856E-02 1.6059E-05 4.9122E-07 -5.4oo8E-l0 406 506 2 0.02947 .-- 0.04205
35 645 CH4N2S thiourea 62-56-6 -1.7559E-03 2.4153E-05 2.4794E-06 -3.9699E-12 536 1000 2 0.01770 _.- 0.04322
36
37
846
647
CNBr
CNCl
cyanogen bromide
cyanogen chloride
506-68-3 -2.3665E-02
506-77-4 -2.2865E-02
1.5063E·04
1.7038E-04
-7.7437E·08
-5.9426E-09
-9.0863E-ll
-2.6648E-l0
325
267
425
367
2
2
0.01400
0.01709
--
0.02034
0.01939
0.02567
38 848 CNF cyanogen fluoride 1495-SO·7 -1.1275E-02 1.1939E-04 6.3086E-06 -3.8551E-l0 191 291 2 0.01116 ._- 0.01932
39 851 CN408 tetranltromethane 509-14·8 ·4.7784E-03 3.3223E-05 3.7381E·08 -2.2239E·ll 295 1000 2 0.00770 0.00786 0.04359
40 852 CO carbon monoxide 630-08-0 9.9186E-04 9.4020E·05 -4.0761E-08 1.3751E-ll 70 1500 1,2 0.00738 0.02576 0.09672
41 653 COS carbonyl sulfide 463-58-1 -3.2182E-03 5.6192E-05 6.6223E-09 -6.2634E-12 223 1000 2 0.00957 0.01396 0.05333
42 655 CO2 carbon dioxide 124'38-9 -6.0783E-03 7.5351E-05 9.4928E-09 -1.1275E-l1 195 1500 1,2 0.00867 0.01693 0.09025
43 656 CS2 carbon disulfide 75-15-0 -2.5681E-03 3.5506E-05 9.8144E-09 -5.3013E-12 273 1000 2 0.00776 0.00875 0.03745
44 661 C2N2 cyanogen 460-19·5 -2.5269E-02 1.9602E-04 6.5321E-08 -4.7630E-l 0 245 345 2 0.02092 0.02814 0.03298
45 863 C302 carbon suboxide 504-64-3 -1.0169E-02 1.2448E·04 2.5608E-07 -7.9173E-l0 162 262 2 0.01333 _.- 0.02577
46 891 CIF chlorine monofluoride 7790-89-8 -4.7144E-03 1.0459E-04 -1.2255E-07 ·1.oo56E-l0 ISO 218 2 0.00788 --- 0.01120
47 892 CIF03 perchloryl fluoride 7616-94-6 -5.1892E-03 5.9871E-05 1.2S07E-08 -8.7075E-12 150 1500 2 0.00404 0.01354 0.06337
48 893 CIF3 chlorine trifluoride 7790-91-2 -1.2945E-02 1.0635E-04 3.2745E-07 -6.0678E-l0 197 297 2 0.014SO --- 0.02632
49 894 ClF5 chlorine pentafluoride 13637-63-3 ·7.9164E-03 3.7111E-05 7.3467E-07 -1.4709E-09 170 270 2 0.01242 --- 0.02673
SO 896 CIN02 nitryl chloride 13444-90-1 -5.6848E-03 1.2043E-04 -4.7521E-08 -2.6344E-l0 ISO 228 2 0.01022 --- 0.01599
51 898 CI02 chlorine dioxide 10049-04-4 -1.1690E-02 1.1519E·04 -2.1418E-08 -2.0714E-l0 214 314 2 0.00992 0.01526 0.01594
52 899 Cl2 chlorine 7782·50-5 -4.6211E-03 5.2370E-05 -2.4171 E-08 5.8757E-12 200 1500 1,2 0.00493 0.00900 0.03938
53
54
900
903
CI20
Cl205S2
chlorine monoxide
pyrosulfurvt chloride
7791-21-1 -5.2636E-03
7791-27-7 -1.4568E-02
7.54SOE-05
1.6268E-04
6.0317E-08
1.9833E-G7
-3.3655E-l0
-6.1665E-l0
153 253
200 300
2
2
0.00646
0.02097
--
0.03522
0.01222
0.03543
55 905 Cl207 chlorine heptoxlde 10294-48-1 -9.7495E-03 1.3067E-04 1.0627E-07 -4.2777E-l0 182 282 2 0.01500 --- 0.02609
56 1002 CoNC304 coball nltrosyitricartJonyi 14096-82-3 -9.2492E-03 2.oo57E-05 6.2536E-07 -8.8888E-l0 262 362 2 0.02297 0.02876 0.03781
57 1099 Cr02Cl2 chromium oxychloride 14977-61-8 ·7.7457E-03 1.0738E·04 -3.6081E·09 -2.4801E-l0 177 277 2 0.00974 --- 0.01643
58 1124 Cs cesium 7440-48-2 2.8190E-02 -4.7985E-G5 3.6325E-08 -8.2500E-12 1000 1500 1,2 0.00828 --- 0.01010
59 1302 02 deuterium 7782-39-0 3.7319E-02 3.5503E-04 -1.0634E-G7 3.4037E-ll 233 1500 1,2 0.11474 0.13462 0.44547
60 1303 020 deuterium oxide 7789-20-0 -6.2280E·03 9.4286E-05 -6.9560E-06 1.0380E-l0 277 773 1,2 0.01675 0.01845 0.07298
61 1404 FH03S fluorosulfonlc acid 7789-21-1 -4.6813E-03 3.7828E-05 2.5884E-07 -5.3307E-l0 184 284 2 0.00773 _.- 0.01474
62 1406 FNO nitrosyl fluoride 7789·25-5 -2.4256E-02 1.8856E·04 -4.3003E-08 -5.0657E-l0 ISO 241 2 0.00134 --- 0.01154
63 1407 FN02 nitryl fluoride 10022-50-1 -3.3430E-03 7.8402E·05 1.4160E-07 -5.5267E·l0 ISO 207 2 0.00974 --- 0.01406
64 1408 FN03 fluorine nitrate 7789-26·6 -3.2051E-03 7.9434E-05 2.5775E-07 -8.3020E-l0 ISO 198 2 0.01171 --- 0.01620
65 1409 F2 fluorine 7782-41-4 -4.4107E-03 1.2636E-04 -7.9654E·06 3.0842E-l1 70 1500 1,2 0.00405 0.02700 0.11000
66 1412 F20 fluorine oxide 7783-41-7 -1.6197E-G3 1.2478E-04 -5.9593E-08 -5.0990E-l0 ISO 149 2 0.01404 ---_.- 0.01399
67 1413 F202 dlfluorine dioxide 7783-44-0 -5.2346E-03 8.4969E-05 2.5685E-07 -6.4196E-l0 ISO 219 2 0.01045 0.01686
66 1434 FeC505 Iron pentacarbonyl 13483-40-6 -4.5242E-02 3.0776E-04 3.5561E-07 -1.0601E-09 253 353 2 0.03826 0.05003 0.06110
69 1585 GaCI3 gallium trichloride 13450-90-3 ·1.4283E-03 2.0275E-05 2.3274E-09 -1.7806E-12 295 1000 2 0.00471 0.00478 0.01939
70 1639 GeBr4 germanium bromide 13450-92-5 -2.7927E-Q2 2.0559E-G4 -I. 7692E-07 ·5.6478E-ll 299 399 2 0.01624 -- 0.02236
71
72
1640
1660
GeCH6
GeCI3F
gennane, methyl
germane, trichlorofluoro
1449-65-6 -4.8701E-03
24422-20-6 -1.9979E-02
1.3524E-04
1.8755E-04
-9.0492E-06
3.6465E-08
-1.6001E-l0
-4.1871E-l0
ISO 215
223 323
2
2
0.01304
0.01906
--
0.02806
0.01864
0.03032
73 1661 GeCI4 Igermanium chloride 10038-98-9 -2.1912E-02 1.9667E-04 1.9546E-06 -4.4731E-l0 222 322 2 0.01777 0.02661 0.02848
74 1663 GeF2CI2 germane, dlchlorodlfluoro 24422-21-7 -1.9079E-Q2 1.7736E-04 1.0459E-07 -5.0105E-l0 221 321 2 0.01987 0.02982 0.03209
75 1664 GeF3C1 germane, chlorotrifluoro 14188-40-0 -1.4741E-Q2 1.4835E-04 1.4229E-07 -5.1879E-l0 207 307 2 0.01746 0.02839 0.02920
76 1665 GeF4 gennanium (iv) fluoride 7783-58-6 -2.6297E-02 1.8137E-04 2.0264E-07 ·6.0383E-l0 258 358 2 0.02364 0.02979 0.03691
77 1668 GeHCI3 germane, trichloro 1184-65-2 ·1.3192E-02 1.4587E-04 -1.8407E-08 -2.8311E-l0 202 302 2 0.01320 0.02116 0.02139
78 1669 GeH2Br2 germane, dlbromo 13769-38-3 -1.4585E·02 1.1792E-04 -1.4804E-08 -1.7104E-l0 258 358 2 0.01193 0.01472 0.01789
79 1670 GeH2CI2 gennane, dichloro 15230-48-5 -1.2149E-02 1.3125E-04 -1.8572E-08 -2.4349E-l0 205 305 2 0.01189 0.01888 0.01925
80 1671 GeH3Br 1germane, bromo 13589-43-2 -1.2318E-02 1.0789E-04 ·1.1856E-08 -1.6805E·l0 241 341 2 0.01065 0.01434 0.01644

295
 Table 6 Thermal Conductivity of Gas· Inorganic Compounds

k... =A+BT+cr+or (k..•• W/(m K), T • K)

NO 10 FORMULA NAME CAS No A B C 0 TMIN TMAX code ""OTMIN ",,025C ""'OTMAX
81 1672 GeH3Cf gennane, chloro 13637-65·5 -1.3369E-02 1.3009E-04 ·1.7108E-08 ·2.1896E·l0 221 321 2 0.01220 0.01809 0.01939
82 1675 GeH4 gennane 7782·65-2 ·1.2400E·02 9.1289E·05 ·1.5424E-08 O.OOOOE+OO 250 1000 2 0.00946 0.01345 0.06347
83 1686 Ge2H6 digennane 13818-89-8 -9.1592E-03 1.3684E-04 ·2.7316E-G8 -2.6514E-l0 164 264 2 0.01139 --0.02020
84 1687 Ge3H8 trigennane 14691-44-2 -8.1425E-03 1.2711E-04 -3.4770E·09 -2.6821E-l0 168 268 2 0.01180 ---
0.02048
85 1691 HBr hydrogen bromide 10035-10-6 -8.3366E-04 2.8693E-05 9.5348E·09 -3.9500E-12 223 1500 1,2 0.00600 0.00846 0.05033
86 1694 HCN hydrogen cyanide 74-90-8 -2.4455E-02 1.8827E-04 6.0312E-08 -3.8547E-l0 260 360 2 0.02178 0.02682 0.03314
87 1695 HCI hydrogen chloride 7647·01-0 ·2.7487E-03 6.1287E-05 -7.9739E-09 1.2821E-12 159 1500 1,2 0.00680 0.01485 0.07557
88 1696 HCI03S chlorosulfonic acid 7790-94-5 ·4.6741 E·03 5.7225E-05 1.2119E-07 -3.0550E-l0 193 293 2 0.00870 ._-
0.01482
89 1697 HCI04 perchloric acid 7601-90-3 ·9.4298E-G3 1.4377E-04 3.8598E-08 -3.6486E·l0 172 272 2 0.01458 ...
0.02518
90 1698 HF hydrogen fluoride 7664-39-3 ·1.7093E-03 6.3912E-05 2.8049E-08 ·1.2417E·ll 295 450 2 0.01927 0.01951 0.03160
91 1699 HI hydrogen Iodide 10034-85-2 -2.0000E-04 2.3010E-05 ·3.4897E-09 9.5771E·13 230 1500 1,2 0.00492 0.00638 0.02970
92 1702 HN03 nitric acid 7697·37-2 ·3.7606E-03 4.7737E·05 2.1888E-G8 ·9.9748E·12 295 1000 2 0.01197 0.01215 0.05569
93 1709 H2 hydrogen 1333-74.0 1.0979E-02 6.6411E-04 ·3.4378E-07 9.7283E-l1 14 1500 1,2 0.02021 0.18100 0.56195
94 1712 H2O water 7732-18-5 5.6199E-03 1.5699E-G5 1.0106E-07 -2.4282E-l1 150 1500 1,2 0.01017 0.01864 0.17461
95 1713 H202 hydrogen peroxide 7722-84-1 -6.1976E-03 7.5527E-05 9.7463E-G9 -6.9303E-12 295 1500 1,2 0.01675 0.01700 0.10563
95 1714 H2S hydrogen sulfide 7783-06-4 3.1184E·03 3.5162E·05 4.4168E-08 ·1.4768E-ll 213 1500 1,2 0.01246 0.01714 0.10540
97 1716 H2SO4 sulfuric acid 7664-93-9 ·3.5316E-03 3.0385E·05 9.0703E-09 -3.3673E-12 610 1000 2 0.01761 .-0.03256
98 1718 H2S2 hydrogen disulfida 13465-07-1 ·6.6190E·03 8.4463E·05 -6.1993E-G9 -1.7666E-l0 183 283 2 0.00758 ---
0.01280
99 1719 H2Se hydrogen selenide 7783-07-5 -1.3315E-03 4.2854E-05 5.1062E-09 -1.6227E-12 231 1000 2 0.00883 0.01186 0.04501
100 1721 H2Te hydrogen telluride 7783-09-7 -8.4098E-03 8.4825E-05 -5.6937E-08 -6.9966E-ll 298 324 2 0.00996 0.00997 0.01072
101 1722 H3NO hydroxylamine 7803-49-8 ·6.7108E-03 8.4479E-05 3.9258E·08 -1.7731E-ll 295 1000 2 0.02117 0.02150 0.09929
102 1723 H3P02 hypophosphorous acid 6303·21-5 -1.5224E-02 8.1OO4E·05 1.9082E-07 -3.5177E-l0 300 400 2 0,01672 .-0.02517
103 1724 H3P03 phosphorous acid 13598-36-2 -1.8835E-02 6.8964E-05 2.6232E-07 -3.8653E-l0 348 448 2 0.02059 ---
0.02992
104 1738 He helium-3 14762-55-1 1.313OE-02 7.3068E-04 ·6.3117E-07 2.7567E-l0 10 1000 1,2 0.02037 0.18218 0.38831
105 1739 He helium-4 7440-59-7 3.0000E-02 4.2897E-04 -1.2065E-G7 2.6846E-l1 100 2000 1,2 0.07172 0.14788 0.62010
106 1771 Hg mercury 7439-97-6 1.8250E·03 6.5254E-06 1.5652E·08 -6.7644E-12 295 1500 1,2 0.00494 0.00498 0.02400
107 1774 HgCH3CI methylmercury chloride 115-09-3 ·4.2819E-03 3.3691E·05 5.0288E-08 -1.2490E-l0 250 350 2 0.00533 0.00692 0.00832
108 1868 IF5 iodine pentafluoride 7783-66-6 ·2.1528E-G2 1.3274E·04 9.7639E·08 -3.4164E-l0 283 383 2 0.01607 0.01767 0.02442
109 1869 1F7 iodine heptafluoride 16921-98-3 -4.0046E-02 2.2149E-04 3.6975E·07 -8.6953E·l0 280 380 2 0.03179 0.03581 0.04976
110 1873 12 iodine 7553-56-2 -1.1796E·03 1.7719E-05 ·1.0367E·08 3.1131E-12 295 1500 1,2 0.00323 0.00326 0.01258
111 1960 K potassium 7440-09-7 1.4143E-Ol ·2.4121E-04 1.5250E-07 -2.9167E·l1 1100 1500 1,2 0.02180 .- 0.02430
112 2162 Kr krypton 7439-90-9 1.2610E-04 3.3619E-05 ·8.2505E·09 2.1564E-13 100 2000 1,2 0.00341 0.00942 0.03609
113 2203 U lithium 7439-93-2 1.5767E+OO ·1.4000E-03 3.3333E-07 1.3245E-23 1700 2000 1,2 0.16000 .-0.11000
114 2567 MoGI5 molybdenum (v) chloride 10241.05-1 ·9.0564E-02 4.0355E·04 ·2.9799E-07 -2.1741E·12 491 591 2 0.03550 .-0.04341
115 2572 MoF5 molybdenum (v) fluoride 13819-84-6 ·2.5178E-G2 1.3030E-04 7.1037E-08 ·2.4554E·l0 340 440 2 0.01770 - 0.02500
116 2573 MoF6 molybdenum fluoride 7783-77-9 -3.9354E-02 2.3809E-G4 1.7024E·07 -5.8493E-l0 291 391 2 0.02987 0.03126 0.04476
117 2582 MoOF4 molybdenum (vi) oxytetrafluoride 14459-59-7 -2.0543E-02 7.2517E·05 2.1394E-G7 ·3.2564E-l0 371 471 2 0.01919 .-.
0.02706
118 2607 NCIO nitrosyl chloride 2696-92-6 ·3.2585E-03 5.4642E-05 -2.6315E-09 ·1.8322E-12 268 1000 2 0.01115 0.01275 0.04692
119
120
2608
2610
NCI3
ND3
nitrogen trichloride
heavy ammonia _.
10025-85-1 -5.1900E-03
·2.5994E-02
4.8811E-05
2.8906E·04
-1.0609E-08
-1.2694E-07
O.OOOOE+OO
-4.5781E-l0
250 1000
197 297
2
2
0.00635
0.02255
_.
0.00842 0.03301
0.03668
121 2613 NF3 nllrogen trifluoride 7783-54·2 -3.9082E-03 6.9781E-05 1.9067E-08 -2.1173E-ll 144 1000 2 0.00648 0.01803 0.06377
122 2616 NHF2 difluoramine 10405-27-3 -1.9770E-03 7.4322E-05 ·4.4646E-08 -1.4066E-l0 150 200 2 0.00769 .-.
0.00998
123 2619 NH3 ammonia 7664-41-7 9.1414E-03 ·7.2945E-06 2.1686E-07 -6.4465E-ll 240 1500 1,2 0.01895 0.02452 0.26811
124 2674 NO nitric oxide 10102-43-9 2.9995E·03 8.3047E-05 ·1.5184E-08 1.8810E-12 121 1500 1,2 0.01286 0.02646 0.09975
125 2675 NOF3 trifluoramine oxide 13847-65-9 -4.4000E-03 1.2573E-04 ·6.0614E-08 -2.1098E-l0 150 212 2 0.01238 ...
0.01753
126 2676 N02 nitrogen dioxide 10102-44-0 2.8701E-03 5.4591E·05 2.5961E-08 -1.4272E-ll 295 1500 1,2 0.02087 0.02108 0.09500
127 2678 N2 nitrogen 7727·37·9 -2.2678E-04 1.0275E-04 -6.0151E-08 2.2332E-ll 63 1500 1,2 0.00603 0.02565 0.09392
128 2682 N2F2 cis-difluorodlazine 13812-43-6 ·2.6579E-03 7.2079E-05 1.5630E-07 -5.5807E-l0 150 200 2 0.00979 ---
0.01355
129
130
2683
2684
N2F2
N2F4
trans·difluorodiazine
tetrafluorohydrazine
13776-62-0 ·4.6696E-03
10036-47-2 ·6.0721 E-03
1.0201E-04
6.4653E·05
2.2127E-07
2.3992E-08
-8.5063E·l0
-2.1983E·ll
150 201
199 1000
2
2
0.01274
0.00757
--
0.01475
0.01788
0.06059
131 2685 N2H4 hydrazine 302-01-2 -6.0522E-03 6.5546E-05 7.0138E-08 -2.5329E·ll 295 1000 2 0.01874 0.01905 0.10430
132 2686 N2H4C ammonium cyanide 12211-52-8 -1.0962E-02 1.9761E-05 4.4512E-07 -5.7975E·l0 309 409 2 0.02056 .-.0.03193
133 2701 N2H60 hydrazine hydrate 7803-57-8 -8.6618E-03 7.7357E-05 2.1711E-07 -4.3120E-l0 221 321 2 0.01443 0.02227 0.02432
134 2747 N20 nitrous oxide 10024·97·2 -8.3454E-03 9.3978E-05 -l.6490E-08 1.1756E-12 173 1500 1,2 0.00744 0.01824 0.09949
135 2748 N203 nitrogen trioxide 10544-73-7 ·8.6155E·03 9.6383E-05 1.9104E·07 -5.9027E·l0 170 270 2 0.01039 --0.01972
136 2749 N204 nitrogen tetraoxide 10544-72-6 -1.4792E-02 8.4210E-05 2.5931E-07 -4.9955E-l0 262 362 2 0.01607 0.02013 0.02597
137
138
2750
2781
N205
Na
nitrogen pentoxide
sodium
10102·03-1 -2.9117E-02
7440-23-5 1.5488E+OO
1.2458E-04
-3.2414E-03
4.1364E-07
2.323OE-06
-6.9338E-l0
-5.5333E-l0
314 414 2 0.02935
1200 1450 1,2 0.04810
_..-.
0.04417
0.04600
139 3034 NbCI5 niobium (v) chloride 10026-12-7 -8.6134E-02 3.9313E-04 -2.8730E-07 ·1.1714E-ll 477 577 2 0.03477 -_.
0.04281
140
141
3037
3091
NbF5
Ne
niobium (v) fluoride
neon
7783·68·8 -4.6136E-02
7440-01-9 7.8034E-03
1.5381E·04
1.4979E-04
1.6515E·07
-4.8802E-08
-2.9501E·l0
6.1061E-12
452 552 2 0.02990
30 2000 1,2 0.01225
--
0.04829
0.03948
0.16102
142 3105 NiC404 nickel carbonyl 13463-39-3 -5.9075E-02 4.4038E-04 5.7309E-08 ·8.6007E-l0 254 354 2 0.04234 0.05452 0.06582
143 3198 02 oxygen 7782-44·7 1.5475E-04 9.4153E-05 ·2.7529E-G8 5.2069E-12 80 2000 1,2 0.00751 0.02592 0.12000
144 3199 03 ozone 10028-15-6 -3.2358E-03 7.7033E-05 4.2930E-09 -8.1952E·12 162 1000 2 0.00931 0.01990 0.06990
145 3222 Os04 osmium tetroxide 20816-12-0 -1.5268E-02 8.7216E-G5 8.0122E·08 -2.1313E-l0 314 414 2 0.01343 .-.
0.01946
146 3234 P phosphorus (white) 7723·14-0 2.7678E·04 2.24745E-05 ·2.08266E-09 4.5303E-13 200 1600 1,2 0.00469 ...
0.03276
147 3235 P phosphorus (red) 7723·14.0 ·1.9797E·03 2.7751E-05 ·5.0454E·09 7.4069E·13 700 1000 1,2 0.01523 ...
0.02147
148 3238 PBra phosphorus tribromide 7789-60-8 ·1.2275E-G2 1.1330E·04 ·4.6206E·08 -1.5113E·l0 233 333 2 0.00971 0.01339 0.01475
149 3378 PCIF2 phosphorus (iii) chloride difluoride 14335-40-1 -1.4657E·02 1.5573E-04 1.2415E-07 ·5.2511E-l0 200 300 2 0.01725 0.02889 0.02906
150 3379 PCf2F phosphorus (iii) dichloride fluoride 15597-63-4 -1.3347E-G2 1.4411E-04 4.7249E-08 -3.8733E·l0 200 300 2 0.01427 0.02355 0.02368
151 3380 PCI2F3 phosphorus (v) dichloride trifluoride 13454-99-4 ·8.8704E·03 1.5801E-04 4.3426E-09 -3.8010E·l0 150 248 2 0.01365 ..-
0.02480
152 3381 PCf3 phosphorus (iii) chloride 7719-12-2 ·1.5364E-03 3.0981E-05 -1.1549E-09 -1.7142E-12 200 1000 1,2 0.00460 0.00755 0.02658
153 3382 PCI5 phosphorus pentachloride 10026-13-8 -7.6631E-02 3.7537E-G4 -2.5201E-07 -5.7355E-ll 433 533 2 0.03402 ...
0.04317
154 3384 PF3 phosphorus (iii) fluoride 7783-55-3 -6.2490E-03 9.8371E·05 3.8260E-07 -l.l109E-09 150 222 2 0.01337 .-0.02225
155 3387 PF5 phosphorus (v) fluoride 7647·19-0 ·1.0077E·02 5.6298E-05 8.9195E-07 -1.6812E-09 179 279 2 0.01901 ---
0.03861
156 3389 PH3 phosphine 7803·51·2 ·2. 1589E·04 5.6917E·05 5.9919E-08 -2.5569E-ll 185 1000 2 0.01223 0.02140 0.09105
157 3392 PH41 phosphonium iodide 12125-09-6 -1.3540E·02 8.5633E-05 7.4957E-08 -2.1299E-l0 292 392 2 0.01253 0.01301 0.01870
158 3395 POBr3 phosphorus (v) oxybromide 7789·59-5 -2.7804E-02 1.7503E-04 -9.4781 E-08 ·9.9260E·l1 329 429 2 0.01600 --0.02201
159 3396 POCl3 phosphorus oxychloride 10025-87-3 ·1.5210E-03 2.5134E-05 ·5.6564E-l0 ·1.2929E-12 295 1000 2 0.00581 0.00589 0.02175
160 3398 PSCI3 IDhosphorus thiochloride 3982-91-0 -1.9215E·02 1.5359E-04 8.0854E-08 -4.2245E-l0 237 337 2 0.01610 0.02257 0.02556

296
 Table 6 Thermal Conductivity of Gas - Inorganic Compounds

~=A+BT+cr+Dr (~. W/(m K), T· K)

NO ID FORMULA NAME CAS No A B C D TMIN TMAX code .....TMlN .....25C ......TMAX
161 3399 PSClF2 phosphoNS (v) sulfide chloride difluoride 2524-02-9 -5.2472E-03 1.3782E-04 -3.5839E-08 -3.3429E-l0 150 218 2 0.01349 --- 0.01964
182 3400 PSF3 phOSphoNs (v) sulfide trifluoride 2404-52-6 -5.7155E-03 7.0529E-05 5.7tt8E-07 -1.4112E-09 150 224 2 0.01295 -- 0.02292
163 3443 P2C14 phosphorous chloride 13497-91-1 -1.9907E-02 1.6811E-04 8.6485E-08 -4.2364E-l0 245 345 2 0.02026 0.02667 0.03099
164
165
34« P2F4
3448 P203
phosphorous difluoride
phOSphONS trioxide
13824-74-3 -1.2274E-Q2
1314-24-5 -1.8788E-Q2
1.4438E-04
1.1083E-04
2.3725E-Q7
1.5094E-07
-6.7283E-l 0
-3.5540E-l0
187
297
287
397
2
2
0.01857
0.01813
--
0.01825
0.03276
0.02676
166 3451 P2S5 phOSphoNS (v) sulfide 1314-80-3 -5.1602E-03 5.8960E-05 1.5038E-Q9 -7.2873E-13 787 1000 2 0.04184 --- 0.05460
167 3461 P406 phosphorous (iii) oxide 12440-00-5 -2.4785E-02 7.5717E-05 6.0969E-Q7 -9.2716E-l0 297 397 2 0.02718 0.02741 0.04335
168 3504 PbC8H20 tetraethyl leed 78-00-2 -2.0265E-03 2.0229E-05 3.4781E-08 -1.1389E-l1 295 1000 2 0.00668 0.00679 0.04159
169 3781 Rb Nbldium 7440-17-7 3.4200E-02 -4.79OOE-05 3.05OOE-08 -5.0000E-12 1000 1500 1,2 0.01160 -- 0.01410
170 3940 Rn radon 10043-92-2 -4.6415E-03 5.5608E-05 -7.3986E-08 O.OOOOE+OO 202 302 2 0.00362 0.00542 0.00547
_..
171 3974 RuF5 Nthenlum (v) fluoride 1452t-I8-7 -3.0828E-Q2 1.0333E-04 1.1429E-07 -2.0244E-l0 450 550 2 0.02038 0.02690
172
173
3991
3994
S
SCl2
sulfur
sulfur dichloride
7704-34-9 1.8213E-03
10545-99-0 -2.0640E-03
1.7486E-05
3.6292E-05
-7.5756E-l0
-3.3047E-09
-4.6016E-13
-9.8212E-13
717
295
1000
1000
1,2
2
0.01380
0.00833
--
0.00844
0.01809
0.02994
174 3996 SCl20 thlonyl chloride 7719-09-7 -2.3325E-03 3.8066E-05 -1.6990E·09 ·8.1021E·13 295 1000 2 0.00873 0.00884 0.03322
175 3998 SF4 sulfur tetrafluoride 7783-60-0 -6.5497E-03 8.1934E-05 5.3888E-07 ·1.2346E·09 150 248 2 0.01070 .- 0.02314
176 3999 SF5Br sulfur bromide pentefluoride 15607-89-3 ·1.0435E·02 1.1418E·04 2.4704E-07 -6.0171E·l0 194 294 2 0.01664 --- 0.02921
177 4000 SF5CI sulfur chloride pentafluoride 13780-57-9 ·1.3289E-02 3.6381E·05 9.5864E-07 -1.6556E-09 209 309 2 0.02111 0.03890 0.04066
178 4001 SF6 sulfur hexafluoride 2551-62·4 ·1.2608E·02 1.0098E-Q4 -4.0571E-08 8.6317E·12 273 1500 1,2 0.01212 0.01412 0.07670
179
160
4002
4004
SF80
SOBr2
sulfur fluoride hypofluorite
thlonyl bromide
15179-32-5 ·1.2263E·02
507-16-4 -8.3251E-03
1.4448E-04
8.2023E·05
3.7161E·07
8.223OE·09
·8.3367E-l0
·1.7006E·l0
187
223
287
323
2
2
0.02233
0.00850
--
0.01235
0.04013
0.01330
181 4005 SOCl2 thlonyl chloride 7719-09-7 -7.2367E-03 1.0154E-04 -7.2721E-09 -2.3489E-l0 172 272 2 0.00883 .- 0.01512
182 4008 SOF2 thlonyl fluoride 7783-42-8 ·5.4377E·03 6.9419E-05 2.7794E·07 -7.4156E·l0 150 244 2 0.00873 --- 0.01725
183 4007 S02 sulfur dioxide 7446-09-5 8.5308E-04 8.8212E·06 8.3662E-08 -5.0333E·ll 250 900 1,2 0.00745 0.00953 0.03969
184 4008 S02CI2 sulfuryl chloride 7791-25-5 -2.5536E-03 3.75OOE·05 5.0173E-09 -3.9111E-12 295 1000 2 0.00885 0.00897 0.03605
185 4009 S02F2 sulfuryl fluoride 2699-79-8 -4.9145E-03 5.2211E-05 5.1745E·07 -1.1550E-09 150 237 2 0.01066 ..- 0.02118
186 4010 S03 sulfur trioxide 7446·11-9 -5.2423E-03 5.9854E-05 3.9263E-Q9 -9.2357E-12 295 1000 2 0.01252 0.01271 0.04930
187 4013 S2CI2 sulfur monochloride 10025-67-9 -9.6121E-Q3 1.0069E·04 5.6946E·08 -3.3939E·l0 196 296 2 0.00977 ---
...
0.01639
188 4014 S2F2 1,1 dlfluorodlsulfane 1019<17-3G-2 ·3.3686E·03 6.2802E-05 2.4057E-07 -7.5580E·l0 150 209 2 0.00891 0.01334
189 4015 S2F2 difluorodisulfane 13709-35-6 ·5. 1977E-03 7.2546E·05 2.153OE·07 -6.6454E-l0 150 240 2 0.00829 ._. 0.01544
190 4020 S3C12 trisulfur dichloride 31703-09-0 -2.0807E-02 1.8946E·04 7.7029E-08 -4.7046E-l0 227 327 2 0.02069 0.03008 0.03295
191 4042 SbCI3 antimony trichloride 10025-91-9 -4.0347E-Q4 1.4994E-05 -2.1919E-Q9 5.4166E-13 295 1000 2 0.00384 0.00389 0.01294
192 4044 SbCI5 antimony pentachloride 7647-18-9 -2.4650E-02 1.8227E-04 9.5944E-Q9 -2.9383E-l0 276 376 2 0.02020 0.02276 0.02962
193 4047 SbH3 stiblne 7803-52·3 ·6.671 OE-03 8.1264E·05 -3.8140E-08 -1.2410E-l0 185 285 2 0.00828 .- 0.01052
194 4089 sees selenosulflde, carbon 5951·19-9 -6.223OE-Q3 7.0892E-05 1.0837E-08 -1.7160E-l0 198 298 2 0.00690 .- 0.01130
195 4109 SeF4 selenium tetrafluoride 13485-86-2 -8.9981E-Q3 5.6693E-Q5 1.6313E·07 -3. 1883E-l0 263 363 2 0.01141 0.01396 0.01783
196 4110 SaF6 salenlum hexafluoride 7783-79-1 ·1.3689E-02 9.1688E-Q5 5.5568E-07 -9.7582E·l0 238 338 2 0.02654 0.03718 0.04316
197 4115 SaOCI2 selanlum oxychlorida 7791-23-3 ·1.5264E-Q2 1.1463E-04 ·3.0764E·08 ·1.3052E·l0 282 382 2 0.01166 0.01272 0.01675
198 4116 SeOF2 selenium oxylluoride 7783-43-9 -1.1141E-02 7.1241E-05 6.7116E-08 -1.9351E-l0 288 388 2 0.01033 0.01094 0.01531
199 4118 Se02F2 selenium dioxvdlfluoride 14984-81-7 -9.0274E-Q3 1.2017E·04 4.1866E-08 -3.3514E-l0 174 274 2 0.01135 .- 0.02013
200 4123 Se2C dlselanlde, carbon 506-80-9 ·7.7052E-03 7.4120E·05 -1.7532E-08 ·1.1667E-l0 229 329 2 0.00697 0.00974 0.01064
201 4143 SIBrCI2F silane, bromodichlorofluoro ._- ·8.9533E-03 1.3726E·04 5.5239E-Q9 -3.4533E-l0 161 261 2 0.01183 ._. 0.02110
202
203
4144
4145
SlBr2CIF
SiBr3C1
silane, dlbromochlorofluoro
silane, tribromochloro
-- -8.6911E-03
f3485-78-4 ·1.5729E-02
1.1971E-04
1.2738E·04
2.5346E-Q8
3.8396E-08
-3.2052E-l0
-2.7071E-l0
174
252
274
352
2
2
0.01120
0.01451
--
0.01849
0.01941
0.02208
204 4146 SIBr4 tetrebromosilane 7789-66-4 -2.3264E-02 1.7652E-Q4 -9.7420E·08 -1.4022E-l0 279 379 2 0.01532 0.01699 0.02199
205 4149 SlCH3C13 silane, methyltrichloro 75·79·6 ·2.6130E-03 3.4047E·05 1.2907E-08 ·6.2541E-12 295 1000 2 0.00839 0.00852 0.03809
206 4150 SiCH4CI2 silane, methytdichloro 75-54-7 ·3.2504E-03 4.0189E-05 1.9973E-Q8 ·8.7801E-12 295 1000 2 0.01012 0.01027 0.04813
207 4152 SlC2HSCl3 silane, ethyttrichloro 115-21-9 -9.3268E-Q4 2.3483E-05 4.0105E-08 -1.1584E-ll 295 573 1,2 0.00919 0.00933 0.02352
208 4153 SiC2H8CI2 silane, dlmelhyldlchloro 75·78-5 ·1.1159E·03 2.2935E·05 4.9929E-08 -1.3574E-ll 295 650 1,2 0.00965 0.00980 0.03116
209 4157 SIC3Hl0 silane, lrimethyl 933-07-7 ·8.3073E-04 2.3087E-Q5 1.1845E-07 -5.0834E-ll 280 1000 2 0.01379 0.01523 0.08986
210 4187 SlC7H8CI2 silane, methylphenyldlchloro 149-74-6 -1.5783E-03 3.0123E-05 3.8835E-08 -7.6638E-12 295 1000 2 0.01049 0.01065 0.05972
211 4198 SICSH20 silane, letraethyl 631·36-7 -3.oo71E·03 2.7227E·05 7.0645E-08 -2.1156E·ll 295 1000 2 0.01063 0.01083 0.07371
212 4238 SiCIC3H9 chlorotrimelhylsllane 75-77·4 6.7184E-03 -1.8875E-05 1.3801E-07 -4.2549E-ll 295 650 1,2 0.01207 0.01223 0.04108
213 4240 SlCIF3 silane, chlorotrifluoro 14049·38..fl -9.1906E-03 1.1123E-04 6.0698E-07 -1.5879E-09 150 235 2 0.01579 ... 0.02988
214 4241 SlCI2F2 silane, dlchlorodilluoro 18356-71-3 ·2.0493E-02 1.7538E-04 2.5669E-07 -7.0289E-l0 229 329 2 0.02482 0.03616 0.04019
215 4242 SlCl3Br silane, bromotrichloro 13485-74-2 -1.503OE-02 "54'5E-04 3.5746E-08 -3.6750E-l0 211 311 2 0.01565 0.02437 0.02532
218 4243 SiCI3F silane, lrichlorofluoro 14985-52-7 -1.0837E-02 1.2395E·04 4.1979E-07 ·1.2273E·09 152 252 2 0.01345 ._. 0.02745
217 4244 SiCl4 silicon tetrachloride 10028-04-7 ·7.3845E-04 5.2908E-05 -1.0829E-07 1.1995E-l0 295 650 1,2 0.00852 0.00859 0.02084
218 4245 SlF4 silicon tetrafluoride 7783-61-1 -1.9431E-03 5.9859E-05 -3.9229E-09 5.8693E-13 295 702 1,2 0.01539 0.01557 0.03837
219 4246 SiHBr3 silane, tribromo 7789-57-3 ·9.0268E-03 8.8529E·05 9.5805E-08 ·3.8205E-l0 200 300 2 0.00963 0.01629 0.01639
220 4247 SIHCl3 silane, trichloro fOO25-78-2 -7.7555E-04 2.4950E-05 2.1286E-08 -6.4615E-12 295 650 1,2 0.00827 0.00838 0.02286
221 4248 SiHF3 silane, lrifluoro f3485-71·9 ·7.2282E·03 8.8952E-05 5.2255E-07 -1.2327E-09 150 242 2 0.01371 ._. 0.02740
222 4250 SiH2Br2 silene, dibromo 13786-94-0 ·7.2109E-03 6.1426E·05 1.7387E-07 -4.1483E-l0 203 303 2 0.00896 0.01556 0.01583
223 4251 SlH2CI2 silane, dichloro 4109-96-0 -7.0566E-04 3.6337E-05 -1.4033E-08 4.2415E-l1 281 650 1,2 0.00938 0.01000 0.02863
224 4252 SIH2F2 silane, difluoro 13824-36-7 -6.23OOE-Q3 8.1823E-05 3.4994E-07 -7.9597E-l0 151 251 2 0.01135 ._. 0.02373
225 4253 SIH212 silane, dllodo 13760-02-6 ·1.oo72E-02 6.53OOE-Q5 7.2794E-08 -2.0282E-l0 272 372 2 0.00900 0.01049 0.01386
226 4257 SiH3Br silane, monobromo 13465-73-1 -5.2162E-03 5.1159E-05 2.2254E-07 -4.8226E-l0 179 279 2 0.00833 -.. 0.01592
227 4258 SlH3CI silane, monochloro 13485-78-6 -5.84ooE-03 7.6210E-05 2.7326E-07 -6.4752E-l0 155 255 2 0.01013 -.- 0.02063
228 4259 SIH3F silane, monofluoro 13537-33-2 -2.8028E-03 1.0292E-04 1.1638E-07 -4.8913E-l0 150 200 2 0.01360 --. 0.01852
229 4280 SIH31 sllane,lodo 13598-42-0 -5.5943E-03 4.0629E·05 1.6963E-07 -3.3847E-l0 216 316 2 0.00769 0.01263 0.01351
230 4261 SIH4 silane 7803-62-5 -1.6229E-03 6.2666E·05 7.1298E-08 ·2.2874E·ll 161 750 1,2 0.01022 0.02279 0.07583
231 4274 Sl2C6H180 disiloxane, hexamethyl 107-46-0 -3.8403E-03 3.9305E·05 5.5859E·08 -1.8925E-ll 295 1000 2 0.01213 0.01234 0.07240
232 4275 Si2C6H19N disilazane, hexamethyl 999-97-3 -2.5185E-Q3 1.4591E-05 1.0514E-07 -4.4672E·ll 295 1000 2 0.00979 0.00999 0.07254
233 4288 Si2CI6 disilane, hexachloro 13465-77-5 ·3.0809E-02 2.1121E-Q4 2.4689E-07 ·6.6413E·l0 272 372 2 0.03153 0.03651 0.04773
234 4288 Si2F6 disilane, hexafluoro ... ·1.5427E-02 5.0062E·05 9.6593E-Q7 -1.4320E-09 255 355 2 0.03629 0.04741 0.05992
235 4289 Si2H8 dlsilane 1590-87-0 -4.9313E-Q3 6.0165E-05 5.2746E·08 -2.0866E-ll 259 1000 2 0.01383 0.01714 0.08711
_..
236 4290 Si2H60 dlslloxane 13597-73-4 ·8.4608E-Q3 2.0444E·04 ·1.1254E-07 -2.1824E-l0 150 229 2 0.01894 0.02985
237 4291 Si20C13F3 disiloxane, trichlorotrifluoro --- -1.7899E-02 1.8849E·04 3.4963E·07 -8.9756E-l0 200 300 2 0.02680 0.04579 0.04608
238 4295 Si3CI8 octachlorolrisilane --. ·1.6907E-02 2.0531E·04 1.8864E-07 -7.0565E-l0 200 300 2 0.02606 0.04237
_..
0.04261
239 4298 Si3H8 lrisilane 7783-26-8 ·1.0736E-Q2 2.0004E-Q4 -6.8285E-09 -3.1162E-l0 156 256 2 0.01908 0.03478
240 4297 Sl3H9N trisilazane --- ·1.3050E-Q2 2.1250E-04 1.2267E·07 -5.2087E·l0 167 267 2 0.02353 -.- 0.04259

297
 Table 6 Thermal Conductivity of Gas -Inorganic Compounds

~=A+BT+cr+Dr (kgo•• W/(m K), T - K)

NO ID FORMULA NAME CAS No A B C D TMIN TMAX code "".TMlN "".25C .....rMAX
241 4300 Si4Hl0 tetrasHane 7783-29-1 -1.2588E-02 1.6692E-04 3.5453E-07 -7.7895E-l0 189 289 2 0.02633 --- 0.04643
242 4335 SnBr4 stannic bromide 7789-67-5 -2.7116E-02 2.0092E-04 ·1.8596E-07 -3.5048E-l1 302 402 2 0.01566 -.- 0.02134
243 4337 SnCH6 methylstannane 1631-78-3 -6.5765E-03 1.1794E-04 ·3.8142E-08 -1.6328E-l0 150 250 2 0.00971 --- 0.01797
244 4424 SnC/4 stannic chloride 7646-78-8 -2.4663E-02 2. 1538E·04 -8.2927E-08 -2.8480E·l0 239 339 2 0.01820 0.02463 0.02773
245 4431 SnH4 stannane 2406-52-2 -5.1206E-03 1.0069E-04 -5.7443E-08 -1.9607E·l0 150 227 2 0.00803 _.- 0.01249
246 4590 TeF6 tellurium hexafluoride 7783-80-4 -2.0636E-02 1.6986E-04 3.8787E-07 -8.7462E-l0 236 336 2 0.02946 0.04130 0.04699
247 4643 TIBr4 titanium (Iv) bromide 7789-68-6 -5.0966E-02 2.4850E-04 ·1.9722E·07 5.6464E-13 453 553 2 0.02120 ... 0.02624
248 4678 TICI4 titanium tetrachloride 7550-45-0 -2.3964E-02 1.9895E-04 -5.3692E-08 -2.7946E-l0 249 349 2 0.01794 0.02317 0.02705
249 4787 UF6 uranium fluoride 7783-81·5 -3.8916E-02 2.2005E·04 6.6806E-08 ·3.5284E-10 337 437 2 0.02935 --- 0.04057
250 4860 VCI4 vanadium tetrachloride 7632-51-1 -1.4338E-03 2.9516E-05 -3.8382E-Q9 5.5586E·13 295 1000 2 0.00695 0.00704 0.02480
251 4880 VOCl3 vanadium oxytrichloride 7727-18-6 -1.3541E-Q3 2.4639E-05 -2.7181E·Q9 1.3869E-13 295 1000 2 0.00568 0.00575 0.02071
252 4917 WF6 tungsten fluoride 7783-82-6 -3.1551E-02 1.9198E·04 2.2078E-07 -6.1827E-l0 275 375 2 0.02516 0.02893 0.03893
253 4926 WOCl4 tungsten (vi) oxytetrachloride 1352().78-o ·5.7826E-02 2.6353E-04 ·1.3838E-07 -7.1789E-ll 451 551 2 0.02626 .- 0.03334
254 4927 WOF4 tungsten (vi) oxytetrafluoride 1352().79-1 -2.6155E·02 1.2233E-04 3.4948E-08 -1.6713E-l0 379 479 2 0.01614 ... 0.02210
255 4945 Xe xenon 744()'63-3 1.4358E-04 1.8766E-05 ·1.9673E·Q9 ·5.5315E·13 100 1500 1,2 0.00200 0.00555 0.02200
256 4947 XeF2 xenon difluoride 13709-36-9 -2.1064E-02 1.0324E-04 -2.4536E-08 -7.2597E-ll 402 502 2 0.01176 ._- 0.01540
.-.
257 4949 XeF4
258 4950 XeF6
xenon tetrafluoride
xenon hexafluoride
13709-61-0 -2.4509E-02
13693-09-9 ·1.71 Q9E·02
9.4028E-05
5.1363E·05
1.5041E-07
4.2030E-07
-2.6408E-l0
-5.9504E-l0
390 490
323 423
2
2
0.01940
0.02323
_. 0.02662
0.03475
259 5021 Zn zinc 744()'66-6 1.4926E·03 2.6956E-05 -7.1293E-Q9 1.5839E·12 250 1500 2 0.00781 0.00894 0.03123
code: 1 - data, 2· estimate
k.., - thermal conductivity of gas, W/(m K)
A, B, C, and 0 - regression coellicients for chemical compound
T • temperature, K
TMIN • minimum temperature. K
TMAX - maximum temoerature. K

298