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Modelling of Waterproofing Properties of Water-based Polyurethane

Membrane on Portland Cement Concrete and Fly-ash-based Geopolymer

Concrete using Varying Thickness

Elline Joy U. Fernando1, Cristal Haze A. Victoria1, Melizza Dane T. Viñas1

1
School of Civil, Environmental, and Geological Engineering,
Mapua University, Muralla St.,Intramuros, Manila, 1002 Philippines

*Corresponding author E-mail:

Abstract

Exposure to high temperature rise and water seepage influence the behavior of concrete
roof slabs. In this study, a water-based polyurethane membrane is selected to be applied
on Ordinary Portland Cement Concrete and Geopolymer Concrete to assess its
effectiveness. Seventy-two concrete samples were tested for Saltwater Absorption and
Surface Temperature Reading. The relationship among the thickness of the slab,
number of coatings applied, temperature change, water absorption, and hours of
immersion were analyzed. Results show that the greater thickness of concrete exhibits
lower heat transmission from the exposed face to the covered face. However, as the
number of coatings increase, the tendency of heat reflection also increases dramatically
but the concrete manifests a decrease in heat transmission. With regards to saltwater
absorption, thickness and number of coating varies inversely with its percentage of
absorption. The results show that the most effective and optimum thickness and number
of coatings that they have obtained, is to use 130 mm thickness and 2 coatings of
waterproofing for the OPC and to use 130 mm thickness and 4 coatings of
waterproofing for the GPC. Thus, if the thickness is subjected to change due to the
design constraints of the thickness of the slab, the number of coatings shall be
determined using the said mathematical models.
Keywords: waterproofing, polyurethane membrane, Portland cement, geopolymer
1. Introduction points. Otherwise, water ponding on
Concrete is known to be flat roof would occur which will cause
evidently prone to tension failures, thermal differences to the wet and dry
cracks and voids. Corrosion of steel side of the slab. It is also important to
reinforcement happens when water choose the suitable waterproofing
seep through the concrete with high membrane in accordance to the
permeability. While concrete is one of environment, area of the roof slab, cost
most durable manmade materials, it and other parameters.
becomes permeable after it hardens. Without waterproofing that
Chloride attack is one way that could keeps the moisture out, the concrete
possibly cause damage to it. This will be prone to expansion leading to
happens when a poor quality concrete the cracking of concrete, the formation
had contact with such substance that of rust from the water reacting with
allows its passage, which leads to the impurities or reinforcing metals in the
breakdown of the protection of the concrete, aggregate expansion, and
steel reinforcement bars that bacterial corrosion. Waterproofing of
accelerates the corrosion of the steel concrete ensures that almost all
and eventually causes concrete failure. moisture is kept out of the material. It
Porosity is often mistaken to provides a great deal of benefit to
permeability. The former is the concrete such as added strength,
measure of voids in concrete while the reduced maintenance costs and keep
latter is the rate of flow of a fluid in the concrete water-tight since they are
these pores. exposed to the weather.
On the other hand, concrete is a However, polyurethane
composite material that has thermal compounds have attracted scientific
properties. Its behavior is influenced interests due to its extraordinary
by several factors and one of it is the features. It has been widely used as a
rate of temperature rise. When exposed coating to protect the concrete from its
to high temperatures, deterioration corrosive environment. UV-curable
happens in its compressive strength, coating’s one auspicious area is the
tensile strength, modulus of elasticity, water-based polyurethane membrane
bond with reinforcements, etc. that constitutes safety to the
Concrete undergoes changes in its environment [1]. Thus, this membrane
chemical composition, physical particularly concerns its thermal
structure and water content reflection as well as the water
demonstrated by cracks and explosive penetration capabilities in concrete.
spalling due to the buildup of steam
pressure. It indicates that high 2. Methodology
temperature has a negative effect on This study is focused in
the workability of concrete. assessing the effectiveness of a water-
As a result, waterproofing is based polyurethane membrane on
utilized in order to keep a concrete roof Ordinary Portland Cement Concrete
water-tight. Proper design of the roof and Fly-ash-based Geopolymer
slab must be considered to effectively Concrete with each material varying
utilize the full effects of the waterproof from thickness and the number of
coatings. It must have flow paths that coatings applied. The researchers will
directs water to suitable discharge
conduct two laboratory tests which are used to compute for the concrete mix
Saltwater Penetration Test and Surface ratio. Table 1 shows the details of the
Temperature Reading Test. The mix.
Saltwater Penetration Test shall be
conducted in accordance to ASTM
D6489-99 and the Surface Heat Test
shall be in accordance to ASTM E
1862 – 14.
The conduction of tests of this Table 1. Mix Details per 1m3
study consists of seventy-two concrete
specimens. Ordinary Portland cement The concrete mixing is divided
and Geopolymer concrete are used as into parts due to time and space
the two classification of samples. Each constraints. A slump of 15cm, 13cm
concrete specimen varies from number and 15cm are obtained for each batch,
of coatings applied and thickness. respectively. After the specimens are
Thirty-six ordinary concrete samples removed from the formworks, the
are casted, twenty-four of which are specimens are submerged under water
coated with liquid applied for 20-day curing process.
waterproofing while twelve of them Aside from the Ordinary
are control specimens. Similarly, Portland Cement Concrete,
twenty-four Geopolymer concrete are Geopolymer is another kind of
coated while twelve of these thirty-six concrete specimen tested. It is
samples are control. Tests are carried currently being studied that sets forth
out using blocks of 200mm x 200mm to the future of cement alternative. Its
in which the thickness varies. An sample size will be the same as that of
interval of 30mm per thickness is used ordinary concrete with various
to gather a more distinctive result. thickness and coat. The making of the
Since roof slabs do not Geopolymer concrete blocks was made
experience very high water head simultaneously with the ordinary
throughout its lifespan, the test for the concrete. The mix details of
absorption of saltwater to the concrete Geopolymer concrete are shown in
does not require a pressurized test. Table 2.
Coatings vary from zero to four to
further assess its importance and Material Ratio
effectivity. Three concrete samples are Fly-ash 1.2 kg
casted per coat and thickness to collect Gravel 3 kg
accurate results by getting their means. Sand 2 kg
Ordinary Portland cement is a NaOH
usual material in the building 3.2 L
Activator
construction as one of the concrete mix Table 2. Geopolymer Concrete Mix
composition. The type of Portland Details
cement that is used in this study is in Maxelastic Pur HW
conformance to ASTM Type 1. In Thermocoat is a water-based
making the thirty-six ordinary concrete polyurethane membrane which is
blocks, the total volume of the mix is formulated to provide low thermal
initially computed. ACI Method is conductivity that is suitable for all
kinds of flat roofs especially concrete Due to time, space and equipment
roof slabs. Initially, all concrete constraints, the testing of the
samples except the control specimens specimens are tested with five
are coated with a primer prior to the specimens per batch. The Halogen
application of the waterproofing Spot Lamp is then turned on for 1 hour
compound. All coated specimens were to let the heat penetrate the concrete.
applied using a brush. Careful After an hour passed, the halogen spot
application and consistency of the lamps are turned off and the specimens
coatings are maintained and with the are removed from the stand to ensure
guidance of the experts in application. that the heat reading will purely come
In the conduction of absorption from the surface and not from the heat
test, the saltwater is replaced by a residue from the halogen spot lamp.
substitute water mixed with salt. In The temperature reading is recorded
reference to several studies and salinity using a device called Infrared
data of the Philippine ocean, a Radiometer Camera that takes a
percentage of salt on water was picture of the specimen that also shows
decided. According to Philippine the surface temperature of the surface.
Statistics Authority, marine water and The temperature of the top and bottom
body of ocean in the Philippines has a surface are recorded immediately after
salinity that ranges from 30,000 to removing it from the stand to ensure
40,000 ppm (part per million). These accurate data.
include the seawater environment, bay, The specimens are oven dried
gulf and channels. To elaborate and air dried after curing and are
further, the mean seawater salinity in placed faced down on the container.
Samar, Philippines is 32,130 ppm in The face of the concrete is the side
reference to a study conducted by E.H. wherein there is a waterproofing
Cebu and R. L. Orale. In this study, coating. To ensure that no water will
32,000 ppm of salinity is used. For penetrate on exposed sides of concrete,
every cubic meter of water used, there the researchers have also applied
will be 3.2% of that volume of water coating onto the 4 sides of each
already converted in kilograms. This is samples. Saltwater is free to circulate
to mimic the mixture and around the specimens since PVC pipes
concentration of salt in the marine were placed at the bottom. OPC and
environment. GPC are soaked for 24 hours and their
As a preparation for the surface weights are measured thereafter. The
temperature test, the researchers set up specimens are returned to the container
a stand for the artificial heat source and and weighed after 48 hours. Figure 1
the specimen in such a way that the shows the setup of the saltwater
surface of the specimen will have absorption test.
constant height from the heat source.
The researchers used Halogen Flood
Lamp of 500 watts as a heat source. As
for the setup of the test, the height of
the halogen spot lamp to the surface of
the blocks is maintained at 17 cm for Figure 1. Set-Up for the Salt-Water
more accurate results. Absorption Test
3. Results and Discussions Data obtained from the
3.1 Surface Temperature Test temperature reading of ordinary
Surface Temperature Test is concrete is given in Table 3. The table
the first test prior to conducting shows the average temperature
saltwater absorption test. All obtained from the top and bottom
specimens are subjected to around surfaces of the specimens including
100°C, measuring the temperature on their changes in temperature. Based
the exposed side and the covered side. from the results, it can be seen that
The exposed side of the concrete is the control specimens have higher
face of the specimen with temperature readings compared to
waterproofing. In the case of control specimens with waterproofing. To
specimens, the smoother face is treated further compare the results of the
as the exposed side. The measurement temperature between the top and
of the temperature is done using an bottom of each specimen, Figures 2, 3,
infrared radiometer camera, which also 4, 5. are given below.
takes photos of the subject with the
temperature reading.

Table 3. Temperature Reading Results of Portland Cement Concrete Specimens

Figure 2 Figure 3
Figure 4 Figure 5

Figures 2, 3, 4, and 5 shows the surface temperature, whereas the


results of OPC specimens in each number of coatings applied increases,
thickness. The graphs display identical the top surface temperature decreases.
representation that shows a decreasing However, the bottom surface shows a
temperature on the top surface as uniform temperature in each thickness
number of coatings applied increases shows that the number of coating does
due to the reflective capabilities of the not affect the bottom surface
waterproofing, in which causing the temperature.
heat be reflected, thus lowering the

Figure 6. Figure 7

Figure 8
Figures 6, 7, and 8 shows the in which shows that the thickness of
graphical representation of the OPC the specimen does not affect the top
specimens with various coatings surface temperature. Meanwhile, the
applied. As shown in the graph, the bottom surface temperature evidently
specimens with 0 coating has reached shows that the temperature decreases
a top surface temperature ranging from as the thickness of the slab increases
85 ℃ to 95 ℃ while specimens with 4 due to the properties of heat
coatings has a range temperature of conduction where heat transfer will
60 ℃ to 75 ℃. From the graph shown, occur slower to thicker slabs that
the top surface temperature is uniform, thinner slabs.
Figure 9. Graphical Representation of the Change in Temperature of Ordinary
Portland Concrete with respect to its Thickness.

Figure 9 shows the graphical mm specimen. The main reason for


representation of the change in this change in temperature is that the
temperature between the top surface temperature at the bottom surface is
and bottom surface of the specimens lesser in the 130 mm specimens
with different thickness. As seen from compared to the bottom surface
Figure 3 that there is an increase in the temperature of the 40 mm specimens.
change in temperature as the specimen Thus the bigger the thickness, the less
becomes thicker. It is shown in table 1 heat will penetrate at the bottom
that the highest obtained change in surface of the specimen.
temperature is 51. 45 ℃ from the 130

Figure 10. Graph of Linear Regression based on Temperature Difference and


Thickness of Portland Concrete

Figure 10 shows the graphical Table 4 shows the experimental


representation of the linear regression results of Geopolymer Concrete
of the temperature difference with Specimens obtained from the Surface
varying thickness for 0 coat, 2 coats Temperature Test. Top Surface and
and 4 coats of Portland Concrete. Bottom Surface Temperature of the
Where x is the thickness of the specimens were gathered to compare
Portland Concrete and y is the change the change in temperature in various
in temperature. The equation are as coating and different thickness of the
follows: slab. Graphical Representations are
0 Coat: 0.4151x + 0.1578 presented to thoroughly distinguish the
2 Coats: 0.2564x + 5.4189 relationship among the temperature,
4 Coats: 0.2108x + 4.2422 thickness of the specimen, and the
number of coatings applied.
Table 4. Temperature Reading Results of Geopolymer Concrete Specimens

Figure 11. Figure 12.

Figure 13. Figure 14.

Figures 11, 12, 13, and 14 which causing the heat be reflected,
shows the results of GPC specimens in thus lowering the surface temperature.
each thickness. The graphs display However, the bottom surface shows a
identical representation that shows a uniform temperature in each thickness
decreasing temperature on the top which shows that the number of
surface as number of coatings applied coating does not affect the bottom
increases, due to the reflective surface temperature.
capabilities of the waterproofing, in
Figure 15 Figure 16

Figure 17.

Figures 15, 16, and 17 temperature ranging from 85 to 93, and


represents the graphical representation lastly the specimens with 4 coatings
of the different number of coatings of had a top surface temperature ranging
the GPC specimens with respect to the from 78℃ to 84℃. Which shows that
surface temperature versus its the different number of coatings had an
thickness. As shown on the graph, the effect to the top surface temperature,
top surface shows a uniform where the controlled specimens had a
temperature in each thickness, this higher temperature range, whilst the
shows that the varying number of specimens with 4 coatings had lower
coatings had an effect to the temperature range. As for the bottom
temperature, although the top surface surface temperature, the graphs display
temperature is uniform for the different identical representation that shows a
number of coatings, they have different decrease of temperature due to the
ranges of temperature. Whereas the increasing thickness of the specimen
controlled specimen had a top top due to the properties of heat
surface temperature ranging from 89 conduction where heat transfer will
℃ to 103 ℃, while for the specimens occur slower to thicker slabs that
with 2 coatings had a top surface thinner slabs.

Figure 18. Graph Representation of the Change of Temperature of Geopolymer


Concrete with respect to its Thickness
Results of the Geopolymer lower in the 40 mm thickness than that
Concrete are the same with the of the specimens with higher thickness.
Portland Concrete specimens that there The maximum change in temperature
is an increase in the change in achieved is 52.83 ℃ in the controlled
temperature as the specimen becomes specimens with 130 mm thickness.
thicker. The change in temperature This means that the bigger the
between the top surface and the bottom thickness, the less heat will penetrate at
surface of the specimen is significantly the bottom surface of the specimen.

Figure 19. Graph of Linear Regression based on Temperature Difference and


Thickness of Geopolymer Concrete

Figure 19 shows the graphical Since another non-destructive


representation of the linear regression test was conducted in this study, all
of the temperature difference with samples were reused in Water
varying thickness for 0 coat, 2 coats Absorption Test after carrying out
and 4 coats of Geopolymer Concrete. Surface Temperature Test. Each
Where x is the thickness of the distinct specimens had been tripled to
Geopolymer Concrete and y is the come up for more accurate results. All
change in temperature. The equation procedures were carried out following
are as follows: the standard of ASTM D1141-98.
0 Coat: 0.2642x + 20.524 Test results of Ordinary
2 Coats: 0.2934x + 11.616 Concrete and Geopolymer Concrete
4 Coats: 0.2979x + 5.2361 are given in Table 5 and 6. These tables
show the mean of the three proceeding
3.2 Saltwater Absorption Test weights and their mean percent of
Two types of concrete water absorbed. It can be distinguished
compositions were used to test the that all specimens with waterproofing
behavior and properties of one type of have performed better than the control
waterproofing. All ordinary concrete specimens. It can also be seen that all
samples were tested subsequent to samples that has 4 coatings had given
oven drying procedure while all the best results. However, Geopolymer
Geopolymer concrete samples were concrete, in comparison with the
subjected to air drying procedure. ordinary concrete, has exhibited more
absorbed water.
Table 5. Water Absorption Test Results for Ordinary Portland Cement Concrete

Table 6. Water Absorption Test Results for Geopolymer Concrete

Graphical representations to coatings, and hours of immersion to


distinguish the relationship among the saltwater are given in Figures 20 and
percentage of absorption, thickness of 21.
concrete, number of waterproofing

Figure 20. Graphical representation of average water absorption test results for
ordinary concrete in 24-hour immersion to saltwater

Figure 21. Graphical representation of average water absorption test results for
ordinary concrete in 48-hour immersion to saltwater
Figures 20 and 21 above show without coating signifies the
that as the thickness of concrete importance of waterproofing. To
becomes greater, its percentage of compare the test results with respect to
water absorption lessens. In a constant the relationship of the 24-hour and 48-
thickness of concrete, a greater number hour immersion with the percent
of waterproofing coating manifests a absorption in concrete of various coat
better performance in resisting water and constant thickness, Figure 22, 23,
absorption. A considerable difference 24, and 25 are given below.
in the absorption of concrete with and

Figure 22 Figure 23

Figure 24 Figure 25

In Figure 22, the results show result. Figure 24 and 25 show an


an identical percent absorption for 24- evident result that the water has
hour and 48-hour immersion. penetrated the concrete between the
However, the trend of lesser water time intervals. It can also be
absorption to more coating is still distinguished that the penetration of
exhibited in the data. In Figure 23, it water onto the concrete with respect to
shows a notable difference in the time gives a significant difference in
absorption of water in the time interval only greater thicknesses. Graphical
for the control specimen. Yet, the representation of data for Geopolymer
absorption for the specimens with 2- concrete are given in Figures 26 and
coatings 4-coatings has given an 27.
unnoticeable and an almost similar
Figure 26. Graphical representation of average water absorption test results for
Geopolymer concrete in 24-hour immersion to saltwater

Figure 27. Graphical representation of average water absorption test results for
Geopolymer concrete in 48-hour immersion to saltwater

Figures 26 and 27 manifest However, it can be seen in Figure 26


similar result with that of ordinary that 4-coat concrete samples have a
concrete. However, in Figure 27, it can very distinct low water absorption in
be seen that the percent absorption every thicknesses than in the transition
between 0-coat of 70mm and 100mm of 0-coat to 2-coat. Figure 27 also has
has fluctuated. It changes the trend of the same trend of graph except that of
lesser absorption to greater thickness. the 2-coat concrete specimens in each
This result is due to a factor that the thicknesses, as seen in a red line graph.
researchers have rejected two of the Although having an unnoticeable
samples of 70mm and excluded them difference in the graph, they have still
in testing, leaving only one sample to shown a variation of result which are
get datum from. Geopolymer shares 4.99%, 4.91%, 4.88% and 4.74% for
the same trend of relationships of 40mm, 70mm, 100mm, and 130mm,
variables to ordinary concrete but the respectively.
latter has a more prominent results.

Figure 28 Figure 29
Figure 30 Figure 31

Figure 28 shows that there is a differences in water absorption for 4-


significant difference in the water coated concrete samples between the
absorption of 0-coat concrete samples time intervals. In the Figure 31, the
between 24-hour and 48-hour interval, water absorption is lesser for greater
but has an almost uniform result for 2- number of coatings, and the graph
coat and 4-coat. Figures 29 and 30 shows a significant result in each coats
shares a similar trend of graph as the between the 24-hour and 48-hour
others but there are no significant immersion.

Figure 32. Water Absorption vs thickness of Geopolymer and ordinary concrete in 24-
hour immersion

Figure 33. Water Absorption vs thickness of Geopolymer and ordinary concrete in 48-
hour immersion

The two figures above that GP concrete gives a higher percent


showsthe comparison between the data absorption that PC. This is because the
on GP and PC concretes. It is shown GP concrete mixing was done only
once, and the researchers have no experiments, and the components of
indicator for good concrete quality. GP concrete was unattainable and
The mixture for the activator was given costly. However, the trend of
by the sponsoring company. Also, this relationships of the two concrete was
study had just a limited time for similar.

Figure 34. Linear Regression of % Absorption vs thickness of ordinary concrete in 24


hours of immersion

Figure 34 shows the graphical immersion. Where x is the thickness of


representation of the linear regression the Portland Concrete and y is the
of the percent absorption with varying change in temperature. The equation
thickness for 0 coat, 2 coats and 4 coats are as follows:
of Portland Concrete for 24 hours of
0 Coat: -0.0217x + 3.4705

2 Coats: -0.0209x + 2.6628

4 Coats: -0.0169x + 1.9903

Figure 35. Linear Regression of % Absorption vs thickness of ordinary concrete in 48


hours of immersion

Figure 35 shows the graphical representation of the linear regression of the


percent absorption with varying thickness for 0 coat, 2 coats and 4 coats of Portland
Concrete for 48 hours of immersion. Where x is the thickness of the Portland Concrete
and y is the change in temperature. The equation are as follows:
0 Coat: 0.0122x + 3.1777

2 Coats: 0.0153x + 2.3901

4 Coats: 0.0134x + 1.98472

Figure 36. Linear Regression of % Absorption vs thickness of Geopolymer concrete in


48 hours of immersion

Figure 36 shows the graphical can significantly reduce its heat


representation of the linear regression transmission and water absorption.
of the percent absorption with varying Based from the experimental
thickness for 0 coat, 2 coats and 4 coats results of Surface Temperature
of Geopolymer Concrete for 48 hours Reading, greater thickness of concrete
of immersion. Where x is the thickness exhibits lower heat transmission from
of the Geopolymer Concrete and y is the exposed face to the covered face.
the change in temperature. The However, as the number of coatings
equation are as follows: applied to concrete becomes higher,
0 Coat: 0.0356x + 9.8693 the tendency of heat reflection also
becomes higher but the concrete
2 Coats: 0.002x + 5.0432 manifests lower heat transmission.
Thermal reflection is the amount of
4 Coats: 0.0188x + 4.5631 heat from the source that the surface of
concrete rejects.
4. Conclusions From the gathered data from
Four different thicknesses of Saltwater Absorption Test, the results
slabs were applied with distinct reveal that all waterproofed samples
number of water-based polyurethane have performed better than those raw
waterproofing coatings and were tested samples. Also, thickness of the
for surface heating and water concrete and number of coating varies
absorptivity. It was found out that the inversely with its percentage of
use of right amount of coatings with absorption. It was also found out that
regards to the thickness of a roof slab the absorptivity of concrete takes
noticeable effect after 48 hours only
for 100mm and 130mm. In a large waterproofing for the OPC and to use
scale, coatings are significant in the 130 mm thickness and 4 coatings of
actual condition and are useful for the waterproofing for the GPC. However,
lifespan of the structure. if the thickness is subjected to change
The laboratory results of this due to the design constraints of the
study only shows that the application thickness of the slab, the number of
of waterproofing coating can coatings shall be determined using the
significantly reduce the heat said mathematical models.
transmitted inside a structure. Determining the relationship of
Furthermore, thickening the concrete the number of waterproofing coatings
of a slab will not be practical, since the and the thickness of the slab to the
application of waterproofing is more amount of energy that could be saved
effective. This is not only beneficial in can be important to determine the most
reducing thermal conduction and water economical method for the design and
absorptivity, but also in the application of waterproofing on the
environment. Selecting waterproofing roof slab. Therefore, the researchers
instead of adding thickness to the slab recommend to conduct a further study
is a more efficient choice and that will the relationships of the waterproofing
mean lesser Portland Cement will be coatings and the thickness of the slab
used, since the manufacturing of PC to the amount of energy saved.
involves extremely high temperatures
ranging from 1400 to 1500°C and it
involves extraction of raw materials
from natural resources and not only the
emission of carbon dioxide, but also
nitrogen dioxide in the atmosphere
prompt researchers to study new
alternatives.
Addressing the issues caused
by roof slab with no waterproofing is
really costly. Waterproofing prevents
these over and over maintenance
repairs, thus providing extra benefits.
However, these conclusions are based
on the water absorption test and
surface temperature test carried out on
waterproofed specimens. More
comprehensive tests should be done to
check the effectiveness of
waterproofing systems under different
exposure conditions.
Ultimately, the most effective
and optimum thickness and number of
coatings based from the mathematical
model that they have obtained, is to use
130 mm thickness and 2 coatings of
Acknowledgments Determining the Water Absorption
The researchers would like to express of Hardened Concrete Treated
their sincerest gratitude to Tertex With a Water Repellent Coating.
International, Inc. for their assistance [7] Baby, A., & Mathew, J. (2016).
and support in terms of materials and Studies on properties of concrete
finances all throughout the study. Also with various Waterproofing
compounds. Studies on properties
to Engr. John Paul D. Carreon, for
of concrete with various
providing guidance and advices Waterproofing compounds(IOSR
regarding this study. To our family and Journal of Mechanical and Civil
friends as well, we would like to thank Engineering (IOSR-JMCE) ).
them for being encouraging and [8] Broomfield, J. (2003). Corrosion
supportive. Most importantly, this of steel in concrete: understanding,
study will not be possible without the investigation and repair. CRC
wisdom and strength given by our Press.
faithful God. [9] Chong-qi, S., Song, L., & SHANG,
P. (2007). Review of Water Based
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